For a stationary film of uniform thickness, thermal conduction gives , so . The cooling boundary condition determines :
Consequently the surface temperature is
This is the quasistatic temperature of a conductively cooled film, with a weak-cooling expansion when .
Let the thickness and longitudinal scales be , with . Incompressibility gives transverse speed of order , and film evolution has the kinematic time scale . For the temperature variation scale , longitudinal diffusion divided by transverse diffusion is . Each advective term, and the time derivative on that evolution scale, divided by transverse diffusion is
Thus and make the leading thermal profile locally linear and quasistatic. Retaining the weak-cooling condition gives the same surface-temperature approximation with the local . For any independently imposed faster time variation one would also require its thermal relaxation ratio to be small.
Define the positive surface-tension gradient coefficient
The weak-cooling approximation gives , so the Marangoni stress is . The Young–Laplace equation gives the leading liquid pressure , with constant ambient pressure. In lubrication theory, and . The no-slip boundary condition at the wall and the tangential surface condition give
Hence the volume flux is
Conservation of mass gives the thermocapillary thin-film equation
The replacement of surface tension by in the capillary term needs . For comparable capillary and thermocapillary fluxes,
so the fractional tension change is only . Both the tension correction to and the differentiated-tension contribution are then higher-order. Weak cooling alone would not justify that replacement if were allowed to grow without bound.
The capillary term smooths the film: a crest has negative curvature and higher liquid pressure, causing flow away from it. The thermal term has the opposite effect. A thicker region has a colder surface and therefore higher surface tension; Marangoni stress pulls surface fluid toward that region, reinforcing the thickness disturbance. These mechanisms give fourth-order damping and second-order growth respectively.
Use , , and . The two dimensionless flux-divergence coefficients are and . Setting both equal to one gives the balanced scales for a thermocapillary film:
These choices yield . The predicted must be small for the assumed long-wave approximation.
Linearize about using a normal mode of amplitude . The resulting equation is , so the dispersion relation is
Modes with grow, while modes decay. Differentiating gives the most unstable wavenumbers
The physical fastest wavenumber is .
Figure 1.
Thermocapillary film growth rate showing the unstable band and fastest-growing wavenumber
. Details.
For a positive steady film with zero volume flux, . Divide by and integrate once:
Choosing the thickness scale so that when sets . Multiply by and integrate to obtain the zero-flux thermocapillary film profiles relation
Thus the stated potential is and the integration constant is the corresponding first integral.
For an inviscid fluid of constant density, with irrotational velocity and conservative body-force potential , the Unsteady Bernoulli equation is
It holds throughout a connected irrotational fluid region, up to the time-dependent gauge of . Indeed the Euler equations and imply that the gradient of the left side is zero. In the bubble problem there is no body-force contribution compatible with the assumed spherical symmetry.
Spherical incompressibility gives . The moving interface imposes , so
This potential tends to zero at infinity, where the velocity tends to zero and . Differentiate at fixed spatial , not along the moving interface: . At , pressure continuity without surface tension gives . Bernoulli therefore yields , or the Rayleigh equation for an inviscid spherical bubble
Integrating the kinetic energy over the exterior fluid gives
Differentiate and use the radius equation:
With and , the pressure-work energy balance for a spherical bubble integrates to
or
The collapsing branch takes the negative square root for . The energy gain is exactly the pressure difference times the lost bubble volume, providing a check on the sign and numerical factor.
Let point from fluid to fluid , , , and . A clean material interface without phase change has continuous velocity, with normal interface speed . Its surface stress is . The surface divergence of that tensor is . Balancing forces on a small interfacial patch therefore gives the interfacial stress balance with variable surface tension
The normal condition is ; the tangential condition is . On a stationary sphere with outward normal these reduce to when viscous normal stresses vanish. This fixes the sign convention for the Marangoni stress rather than leaving the direction ambiguous.
For the bubble take negligible internal dynamic viscosity, no contaminants, and initially the standard effectively insulating gas-bubble approximation. With heat advection neglected, the exterior temperature satisfies Laplace's equation, approaches remotely, and has zero normal heat flux at . The temperature dipole around an insulating sphere gives
The zero-flux condition follows by differentiating the radial factor. Let . To first order in the weak gradient,
In the laboratory frame the force-free bubble can be described by the harmonic Papkovich–Neuber representation potentials
They give constant exterior pressure and the decaying source dipole field
At the surface , so the normal kinematic boundary condition holds for translation. In coordinates aligned with , and . Direct differentiation gives
Equivalently, the surface tangential traction is . The tangential stress condition therefore requires
For the usual negative , the bubble moves toward hotter liquid. The normal condition is consistent as well: its viscous dipole is , exactly the dipolar part of . The constant part fixes . There is no Stokeslet term, hence no net applied force or drag imbalance.
The thermal assumption matters. The problem gives the exterior thermal diffusivity but no gas thermal conductivity. For an inviscid bubble with conductivity ratio , temperature and normal heat-flux continuity instead give
so the same stress calculation gives
The insulating-bubble result uses . If instead an undisturbed surface temperature gradient is imposed, corresponding to , the coefficient is rather than . Exterior thermal diffusivity alone does not select between those thermal boundary conditions. This dependence is explicit rather than silently treating a missing gas property as a prescribed value.
The small parameters can now be stated precisely. With and , require
Small Reynolds number justifies Stokes flow; small Péclet number allows quasi-static heat conduction without advective distortion; small capillary number and fractional surface-tension variation support a nearly spherical interface and a weak perturbation of its base surface tension. These last two conditions are proportional for this velocity scale but describe different approximations. Linearizing also needs if its derivative varies appreciably. Negligible internal viscosity and the insulating specialization require the corresponding gas-to-liquid viscosity and conductivity ratios to be small. Gravity has been excluded; if restored, its buoyancy-induced migration must be small compared with , not merely small enough to avoid deformation.
Finally, surfactants change both the constitutive surface tension and the surface stress dynamics. The surface flow driven by the thermal Marangoni effect carries insoluble surfactant toward the high-tension side, lowering its tension and producing an opposing concentration-driven gradient. When surface diffusion or exchange is slow, this tends to immobilize the interface, suppressing the clean-bubble thermocapillary migration of an insulating bubble, sometimes nearly stopping it. If the surfactant stays uniformly equilibrated, it can instead change without a large opposing gradient. Its concentration, surface diffusivity and adsorption kinetics must be supplied to compute a replacement speed; no universal numerical reduction factor follows merely from its presence.
Let measure height above the substrate, and write . In the lubrication approximation, the horizontal scale is much larger than the typical height . Vertical momentum balance is hydrostatic to leading order, while the horizontal balance retains the dominant vertical shear:
The no-slip boundary condition gives ; negligible air viscosity and constant surface tension give . Integrating twice and then through the depth yields
The free-surface kinematic boundary condition and incompressibility imply . Therefore
The cross-sectional area is conserved when the endpoint volume flux vanishes.
The relevant small groups follow from the same balances. Put and . Small suppresses horizontal viscous derivatives and makes vertical viscous corrections to hydrostatic pressure smaller by . The ratio of horizontal inertia to vertical viscous stress is
Thus a small full-length Reynolds number is sufficient but not necessary: thin-layer geometry reduces the inertial ratio. The unsteady viscous ratio must likewise be small; on the spreading timescale it equals the displayed group. If surface tension is retained, its pressure-gradient correction relative to gravity is
The Bond number here uses the horizontal scale, because the capillary pressure is whereas the hydrostatic pressure is . We also neglect air shear and evaporation and assume a Newtonian fluid with constant kinematic viscosity.
To find the similarity solution, put . Conservation of gives , and balancing the time derivative against the nonlinear diffusion gives . A normalized ansatz is
Substitution gives . For the symmetric zero-flux profile, one integration gives , and on its positive support a second integration gives
Thus the solution is a compactly supported Barenblatt solution of the porous medium equation. Let denote its half-width. In dimensional variables,
Here the positive-part notation sets the height to zero outside . The area normalization fixes the coefficient, not merely the exponent. With ,
Writing the remaining integral as , the final widths are
The height falls like and the width grows like . The volume flux tends to zero at the front, even though the profile slope diverges; this gives a valid compactly supported weak solution of the reduced equation. The diverging edge slope means the lubrication approximation is not uniform at a microscopic contact line. Surface-tension or contact-line physics supplies an inner regularization without changing the gravity-dominated bulk similarity law in its validity regime. This is an exact source-type solution for ; an arbitrary finite initial drop approaches an appropriate late-time profile rather than being exactly represented by this singular initial profile.
Take downslope and normal to the plane. To leading order in the lubrication approximation, Newtonian gravity gives the hydrostatic pressure . The downslope Stokes equation is therefore . Imposing the no-slip boundary condition at and the stress-free boundary condition at gives
Here is the kinematic viscosity; is the downslope velocity. Applying mass conservation to this lubrication gravity-current flux,
For typical thickness and length , the transverse velocity is by incompressibility. Both convective terms are then , while transverse viscous acceleration is . Thus the inertia criterion for an inclined viscous film is , in addition to . With evolution time the same condition controls unsteady inertia. If a faster time is independently imposed, also require . Estimating from the velocity profile gives the two requested limits:
At long times, and the ratio of hydrostatic-gradient forcing to downslope Newtonian gravity in the bulk is . Put ; the bulk conservation law is . The finite-volume gravity-driven thin-film current scales as , . More explicitly, writing , , gives
The constant of integration is zero for the zero-flux dry tail. Consequently
The reduced bulk solution is zero outside this interval. Its thin nose region is resolved below. Integrating to impose the conserved area,
The bulk front height is , with . Differentiation of the front law gives
Equivalently, this is the Rankine-Hugoniot condition for the bulk shock wave, whose speed is flux divided by height.
In moving coordinate , the full thin-film equation becomes . A nose thickness and slope give axial scale . Since , the explicit time derivative is smaller than translation by that ratio. The travelling front of a gravity-driven thin film is therefore quasisteady. Integrate once with dry-tip flux zero to obtain , or
With , separation of variables and the convention at give
The nose approaches exponentially far behind its tip, then falls to zero with a vertical tangent in this small-slope model. The requested sketch shows this monotone profile:
Figure 1.
Quasisteady gravity-current nose, with a dry tip and an asymptotically uniform upstream film
. Details.
Expanding the inverse hyperbolic tangent, , so . Its slope has magnitude near the tip. The small-slope breakdown at an inclined-current nose occurs at , which gives
Finally, surface tension produces a pressure-gradient scale , whereas downslope Newtonian gravity gives . Their ratio is . Thus surface tension changes the principal nose length when
This is a bulk-nose crossover; capillarity and contact-line physics can already affect a smaller region very close to the dry tip even when the bulk nose is Newtonian gravity dominated.
Use incompressibility, negligible viscosity and surface tension, and an initially irrotational flow. Take the undisturbed free surface at and bed at . The velocity potential satisfies Laplace equation and . For a Fourier mode, write
The linear kinematic boundary condition and linear Bernoulli equation at the free surface are and . Eliminating gives the surface gravity wave dispersion relation
The rightward phase velocity and group velocity are
The phase velocity transports a crest; the group velocity transports a narrow-band envelope and its leading-order energy. For , and : deep-water surface gravity waves are dispersive. For , and , the nondispersive shallow-water dispersion relation. The boundary velocity controls the excited amplitude; it does not change the linear dispersion relation.
For potential flow in an inviscid fluid of constant density under the conservative force per unit mass , the unsteady Bernoulli equation is
It follows by inserting the velocity potential into the Euler equations and integrating the resulting spatial gradient. A time-only change of the velocity potential changes without altering the velocity field.
For spherical motion in an unbounded liquid, incompressibility gives ; the kinematic condition gives . Choose , vanishing at infinity. To obtain the displayed bubble relation, take no spatial body-force contribution, neglect viscosity and surface tension, and equate the liquid-side interface pressure to . With the far-field pressure , Bernoulli equation evaluated at the surface uses the partial derivative at fixed :
Hence the Rayleigh equation for an inviscid spherical bubble is
The exterior kinetic energy is
Differentiating it and using gives the pressure-work energy balance for a spherical bubble:
This derivation also holds at a turning point , without dividing by .
For constant and the stated inverse-volume bubble pressure, integrate this exact time derivative:
The relation is valid on physically accessible portions of the motion, where the resulting kinetic energy is nonnegative. In particular makes the bracket nonpositive, as expected for the restoring pressure about .
For , follow the unstable root near the clean-film value . Write in . At first order in , , giving
This expansion is uniform near the maximizing wavenumber. Differentiation gives . Evaluating the growth there yields
The change in maximizing wavenumber only affects the maximum at second order. The first-order decrease therefore has exactly the requested coefficient, relative to the clean-film rate with its surface tension replaced by .
Without surfactant, capillary pressure drives a surface flow towards a growing bulge. Advection compresses the insoluble surfactant in converging parts of that motion, increasing concentration and lowering surface tension. The resulting gradient supplies a tangential Marangoni stress that opposes the surface motion. This additional resistance slows capillary-driven redistribution of liquid even after the base-tension decrease has already been accounted for.
In the strong-elasticity limit, concentration gradients suppress tangential interface motion. The surface behaves as effectively immobile at leading order. Setting in the velocity formula gives , hence
one-quarter of the clean shear-free mobility . This mobility reduction explains the quarter-rate limit; it slows the unstable capillary mode without removing the long-wave unstable band.
Let the positive undisturbed surface tension be . An insoluble surfactant perturbation produces . The tangential Marangoni stress changes the surface condition to . Solving the lubrication theory momentum equation now gives
At leading order, conservation of insoluble surfactant on a moving interface reduces to . Corrections from the changing circumference are smaller by . Likewise the normal-pressure contribution gives a coupling smaller by than the retained tangential Marangoni stress, so it is omitted at the same order.
For thickness and concentration amplitudes proportional to , put and use . The two conservation equations become
Set , and . The uncoupled capillary growth and elastic relaxation rates are and . The off-diagonal product is , so the determinant is . Thus the surfactant stabilization of an annular liquid lining relation is
This proves the dispersion relation before its lettered deductions. The physical assumption is needed for the claimed capillary instability band.
Let point out of the drop, and use for the interior and for the exterior. The interfacial velocity is continuous. Define ; for a sphere of radius it is . With constant surface tension, the interfacial stress balance with variable surface tension reduces to
Use the exterior-viscosity kernels to define and . The interior viscosity is , so its velocity kernel is , while its stress kernel is unchanged. The interior boundary equation is
For the decaying exterior flow, the inner boundary's fluid-domain normal is , so
Add these equations and use the traction jump. The required capillary boundary integral equation for a viscous drop is
The formula uses the drop-outward normal consistently in both integrals. If , the double-layer term cancels. A spherical drop of constant curvature has zero velocity: a constant Laplace-pressure jump is balanced without motion. A prescribed ambient flow would add its known far-boundary contribution; none is present for the surface-tension-driven flow here.
For a material interface with no mass transfer, the normal fluid velocity on both sides equals the interface's normal velocity. For ordinary viscous fluids without interfacial slip, tangential velocities also agree. The stress tensors have continuous tangential traction when surface tension is uniform; their normal traction jump balances surface-tension curvature. Nonuniform surface tension instead supplies a tangential Marangoni stress. These conditions express conservation of mass, no slip between the contacting fluids and force balance at the interface. For a flat interface of constant tension the full traction is continuous.
Choose down the plane and perpendicular outward from it. A steady parallel solution has velocity and equations
For a uniform free layer, , , and . Integration gives
Its flux per unit cross-slope width is
For the two-layer falling film of equal-density viscous fluids let and . Equal density gives the same continuous hydrostatic pressure in both, . The wall condition is , the upper condition , and at we require , . Integrating the two momentum equations with these conditions gives
The shear stress transmitted to the lower layer is the upper layer's downslope weight per unit area, , obtained by integrating the upper momentum balance from its stress-free surface. It depends on thickness but not upper viscosity. Changing changes the upper shear rate needed to transmit that stress, while the lower profile depends on alone.
For a slender viscous bubble, approximate the interface normal by the radial direction and its curvature by . Axial curvature and axial derivatives of the leading external motion are smaller by the slenderness factors. The exterior leading Stokes flow is locally radial. Incompressibility gives , while the kinematic boundary condition gives to leading order, hence
The radial viscous Laplacian of this velocity vanishes, so exterior pressure is constant to leading order; set its reference value to zero. Its radial normal stress at the interface is . Inner viscous normal stress is smaller by the viscosity ratio , and the bubble's leading normal stress is . The interfacial stress balance with variable surface tension, here with constant , consequently gives
These are local leading-order relations: the outer axial flow and tangential traction enter at higher slenderness order. The sign also has a useful check: a uniform cylinder with no imposed excess pressure contracts, , under surface tension.
An insoluble surfactant is advected with the surface fluid and has no exchange with the bulk. With negligible surface diffusion, its amount on a material surface strip is conserved. Under the small-slope lubrication approximation, surface arclength equals projected horizontal length to leading order, giving
This is the leading planar form of conservation of insoluble surfactant on a moving interface.
Let measure height above the substrate. The normal-stress and vertical momentum conditions give , so . Horizontal Stokes flow obeys , with no slip at and Marangoni stress . Thus
Use and to obtain the thin-film equations with insoluble surfactant:
The differing flux coefficients are essential: the surfactant travels at the surface velocity, not at the depth-averaged liquid velocity.
Neglect the two pressure-gradient terms for the spreading outer region. If its half-length is , fixed surfactant mass gives , . The surface velocity is then . Equating this to gives . For the precise finite-mass Marangoni spreading on a liquid film solution choose
with symmetry about zero and support on the positive half-line. The reduced differential equations are
Their boundary conditions are zero flux at the centre and zero concentration at the moving front. The two integral constraints express conserved surfactant mass and zero net change of liquid volume relative to the original uniform layer:
The second follows by integrating across the whole layer: the localized release adds surfactant but no liquid, and the flux vanishes at infinity. Outside the spreading region the leading depth remains .
Integrating the concentration equation from the centre gives . Where , this is . Substituting into the height equation gives
Therefore , and . With , the linear similarity profiles for surfactant spreading are . The liquid-volume constraint gives , while the surfactant constraint gives . Thus , and
In physical variables, the leading profiles on the whole line are
Outside this interval and . The formal outer solution reaches zero depth at the central point, and height immediately inside the front. It is not a microscopic description of the central dry region or of the front transition. As a conservation check, the front velocity equals both the incoming surface velocity and the liquid Rankine–Hugoniot speed .
The jump from to cannot persist as a smooth solution with both hydrostatic and capillary gradients absent. In an edge region of width , a depth change of order produces and . Keep the stipulated concentration-gradient scale . The three liquid-flux scales are
For , balancing and gives the capillary smoothing of a Marangoni front width
Gravity dominates capillarity when . In physical units the condition is : the printed omits density and is dimensionally incomplete unless surface tension has already been divided by density. Balancing the gravity flux with yields the gravity smoothing of a Marangoni front:
This layer grows faster than the spreading half-length. It reaches the whole pool when
Only scaling constants can be fixed by this balance, so an exact numerical coefficient in is not implied. The gravity-dominant assumption must hold at this crossover as well.
For , the sharp-front linear-depth outer profile is replaced by a gravity-levelled surfactant film: the height approaches , with a small depression under the surfactant and redistributed liquid outside. The rapid hydrostatic return flow almost cancels the net Marangoni liquid flux. Setting and gives and fractional depth variation . The surface still moves outward, with , so leveling the bulk liquid does not stop surfactant spreading.
Assume a steady, incompressible, inviscid flow with a nearly uniform velocity across each water section. The channel varies slowly enough for vertical accelerations to be negligible, pressure to be hydrostatic and the water surface to be nearly horizontal across the width. Atmospheric pressure is uniform; neglect surface tension, wall friction and energy losses. The hydraulic equations apply away from jumps and short nonhydrostatic regions.
The Euler equation for horizontal momentum, with hydrostatic pressure, gives
Integrating gives a constant Bernoulli equation head . Conservation of mass gives the constant volume discharge . Thus the shallow-water specific energy, measured above the local bed, is
Define the Froude number by for the positive flow direction. Then
At fixed discharge and width, energy tends to infinity at both zero and infinite depth. It has a unique minimum at
Indeed . Above the minimum there are two depth branches: the shallower one is supercritical flow and the deeper one is subcritical flow.
Figure 1.
Specific-energy minimum and the subcritical and supercritical depth branches
. Details.
The local long-wave propagation speeds from the shallow water equations are . In subcritical positive flow, one wave family travels upstream and one downstream. In supercritical flow both travel downstream. At critical flow the upstream-directed speed is zero, so the flow can provide hydraulic control separating upstream adjustment from downstream conditions. This statement concerns long waves in the slowly varying hydraulic approximation, rather than all short-wave disturbances.
Without surface tension, the exact dynamic boundary condition for an inviscid interface is equality of pressure, , at . The Unsteady Bernoulli equation in each irrotational fluid is
Choose the potential gauge so that , its unperturbed value. Expanding the kinetic term as and evaluating gravity at the displaced interface gives
to first order. Equality of these pressures gives