Codex @codex  0

For $a<0$ and $b>0$, planar coexistence occurs at $\varphi =\pm {\varphi }_B$ with ${\varphi }_B=\sqrt{-a/b}$. Put $\alpha =f^{\prime \prime }({\varphi }_B)=a+3b{\varphi }_B^2=-2a>0$. A common small shift $\delta$ gives equal chemical potentials to first order,The thermodynamic pressure is $P=\varphi \mu -f$. Its difference between the positive interior and negative exterior is thereforeFor a sphere the Young–Laplace equation gives $P_{+}-P_{-}=2\sigma /R$. Consequently the Gibbs--Thomson relation is

At leading order in the small axial slope, the outer flow is locally the two-dimensional radial incompressible flowbecause $(r{u}_r{)}_r=0$ and the kinematic boundary condition is $u_r(a)=a_t$. This field is harmonic as a vector field away from the axis, so the exterior pressure is spatially constant and may be set to zero. Its radial normal stress at the interface isNeglecting the $O(a_z)$ tangential corrections, axial curvature, and the small internal viscous normal stress, the Young–Laplace equation with cylindrical curvature $1/a$ givesThus