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Uniform axial strain rate $E$ in an annular Newtonian fluid gives radial velocity $u_r=-Er/2+C/r$. For radii $R_i,R_e$, area parameter $A=R_e^2-R_i^2$, and constant gas pressures,The opposite signs of inner and outer curvature in the Young–Laplace equation give these expressions. The kinematic boundary condition implies $\dot{A}=-EA$ and

Capillary pressure is the pressure jump produced by a curved interface. For constant surface tension it is proportional to the interface curvature according to the Young–Laplace equation.

For an axisymmetric slender viscous thread, the Young–Laplace equation and radial extensional viscous stress give $p=p_e+\gamma /a-\mu w_z$. The axial liquid stress relative to ambient pressure is $3\mu w_z-\gamma /a$. Its cross-sectional integral plus the circumferential surface tension force $2\pi \gamma a$ gives the displayed tensile force. Thus the net capillary contribution is $\pi \gamma a$, and axial force balance with downward gravity is $T_z+\pi \rho g{a}^2=0$.

A capillary wave is a wave along a fluid interface whose restoring stress is predominantly supplied by surface tension. A curved free surface requires a pressure jump by the Young–Laplace equation; increasing its corrugation also costs surface energy. In the ideal limit, inertia carries the interface through its flat position and the resulting oscillation propagates. When gravity also contributes appreciably, use the combined gravity-capillary wave model. Within the capillary wave regime, shortening a ripple makes it travel faster. ^[ref]

The laser-diffraction measurement of capillary waves below turns this mechanism into a test: set the frequency, measure the wavelength independently with light, and ask whether the dispersion relation follows. The theory is useful both for predicting how ripple wave packets separate and for inferring surface tension from their motion.

For a composition free energy $F=\int [f(\varphi )+\kappa |\nabla \varphi {|}^2/2]$, the local chemical potential is the functional derivativeAt phase coexistence, exchanges between the bulk phases require equal chemical potentials. Mechanical equilibrium additionally requires equal pressure for a flat interface, or a Young–Laplace equation pressure jump for a curved interface.

The Clapeyron equation connects the slope of a phase coexistence curve to the latent heat and the change in volume during a first-order phase transition. A steep boundary can indicate a large latent heat, a small change in volume, or both. This lets a measured boundary constrain caloric properties and predicts how changing pressure shifts a melting temperature.

For a pure substance in bulk phase coexistence, label the initial and final thermodynamic phases $\alpha$ and $\beta$. Both have the same absolute temperature $T$, pressure $p$, and chemical potential. With $s$, $h$, and $v$ denoting entropy, enthalpy, and volume on one common basis, define $\Delta s=s_{\beta }-s_{\alpha }$, $\Delta h=h_{\beta }-h_{\alpha }$, and $\Delta v=v_{\beta }-v_{\alpha }$. ThenThe derivative follows the phase coexistence curve; it is not a partial derivative within one thermodynamic phase. Use molar volume $v_m$ with molar latent heat $L_m$ in $\mathrm{J}\mathrm{mo}{\mathrm{l}}^{-1}$, or specific volume $v$ with latent heat $L$ in $\mathrm{J}\mathrm{k}{\mathrm{g}}^{-1}$. Both give $dp/dT$ in $\mathrm{Pa}{\mathrm{K}}^{-1}$. For molar mass $M$, $L_m=ML$ and $\Delta v_m=M\Delta v$, so the predicted slope is independent of the chosen basis. This formulation assumes a simple compressible system, fixed composition, and negligible interface contributions; a curved interface can instead require the Young–Laplace equation.

For positive latent heat in the stated conversion direction, the sign of the slope is the sign of $\Delta v$. Converting liquid to gas normally increases volume and gives a positive slope. The negative melting-point slope of water illustrates the opposite sign. At a thermodynamic critical point, the coexisting gas and liquid merge: both $L$ and $\Delta v$ vanish, so their ratio needs a limiting analysis rather than substitution of zero into the Clapeyron equation.^[ref]

A short derivation uses the molar Gibbs free energy $g_m$, equal to the chemical potential for a pure substance. Equality persists along the boundary, so $d{g}_{m,\alpha }=d{g}_{m,\beta }$ with $d{g}_m=-s_{m}dT+v_{m}dp$. Therefore $-\Delta s_{m}dT+\Delta v_{m}dp=0$. Equality of $g_m=h_m-T{s}_m$ also gives $\Delta h_m=T\Delta s_m$. Eliminating $\Delta s_m$ yields the Clapeyron equation.

A gravity-capillary wave has restoring contributions from both gravity and surface tension. Consider an initially resting, horizontally unbounded liquid layer of constant depth $h$, with uniform mass density $\rho$, incompressible flow, inviscid flow and irrotational flow. The upper gas exerts constant pressure and has negligible inertia. Assume a clean interface with constant surface tension $\gamma$: no surfactant stresses, imposed current or wind. The wave amplitude $a$ must satisfy $ka\ll 1$ and $a\ll h$, so linearized boundary conditions apply. Deep water means $kh\gg 1$, rather than a particular depth in metres. ^[ref]

Let $z=0$ be the undisturbed free surface, with liquid below it. Potential flow gives a velocity potential $\varphi$ with $\mathbf{u}=\nabla \varphi$, and incompressible flow gives the Laplace equation. The linearized kinematic boundary condition for a free-surface graph and the Unsteady Bernoulli equation, including gravity and the Young–Laplace equation, giveHere $\eta (x,t)$ is the interface displacement; the signed small-slope pressure jump is $p_{\mathrm{liquid}}-p_{\mathrm{gas}}=-\gamma {\eta }_{xx}$. A wave crest has ${\eta }_{xx}<0$, so its capillary pressure is positive. Choose a right-travelling Fourier mode of positive wavenumber $k$ and angular frequency $\omega$:The factor $e^{kz}$ decays into the deep liquid, satisfies the Laplace equation, and makes ${\varphi }_z={\eta }_t$ at $z=0$. Substituting in the dynamic boundary condition leavesThis derivation displays the two restoring contributions with the same sign. Dimensional analysis also checks the result: $\gamma /\rho$ has units ${\mathrm{m}}^3{\mathrm{s}}^{-2}$, so both $gk$ and $(\gamma /\rho )k^3$ have units ${\mathrm{s}}^{-2}$. ^[ref]

At finite depth, a flat impermeable bottom at $z=-h$ requires ${\varphi }_z=0$. Replacing $e^{kz}$ by the normalized vertical factor $\cosh (k(z+h))/\cosh (kh)$ makes the surface ratio ${\varphi }_z/\varphi =k\tanh (kh)$. Eliminating the mode amplitudes then givesThus the same model supplies its own depth check: use the deep-water formula only when $\tanh (kh)$ is sufficiently close to one for the required accuracy. For example, $kh=3$ reduces $\omega$ by about $0.248\%$ relative to deep water, while $kh=1$ reduces it by about $12.7\%$. These percentages are calculations from this factor. ^[ref]

In deep water the phase velocity magnitude follows a wave crest, while the group velocity magnitude follows the wave envelope of a narrow wave packet. Differentiating the positive-frequency dispersion relation givesFor $k{\ell }_c\ll 1$, the surface gravity wave limit has $c_g\simeq c_p/2$. For $k{\ell }_c\gg 1$, the deep-water capillary-wave dispersion relation has $c_g\simeq 3c_p/2$: a wave crest slips backward relative to the faster wave envelope, even while both advance. Neither speed is the oscillating fluid element's own velocity. ^[ref]

There is a particularly neat coincidence at the crossover. Differentiate $c_p^2=g/k+\gamma k/\rho$: its unique minimum is at $k_c=\sqrt{\rho g/\gamma }=1/{\ell }_c$, exactly where the restoring terms are equal. ThereforeFor the stipulated parameters in capillary length, the minimum is $0.231\mathrm{m}{\mathrm{s}}^{-1}$. At $\lambda =3\mathrm{mm}$, direct substitution gives $f=\omega /(2\pi )\simeq 131\mathrm{Hz}$, $c_p\simeq 0.394\mathrm{m}{\mathrm{s}}^{-1}$ and $c_g\simeq 0.580\mathrm{m}{\mathrm{s}}^{-1}$. This short wavelength is capillary dominated, but its group velocity is still slightly below the pure-capillary ratio $3c_p/2$ because gravity has not vanished.

For a stationary film of uniform thickness, thermal conduction gives $T_{zz}=0$, so $T=T_0+cz$. The cooling boundary condition determines $c$:Consequently the surface temperature isThis is the quasistatic temperature of a conductively cooled film, with a weak-cooling expansion when $\alpha h/\kappa \ll 1$.

Let the thickness and longitudinal scales be $h_{\ast },L$, with $ϵ=h_{\ast }/L\ll 1$. Incompressibility gives transverse speed of order $ϵU$, and film evolution has the kinematic time scale $L/U$. For the temperature variation scale $\Theta$, longitudinal diffusion divided by transverse diffusion is $h_{\ast }^2/L^2={ϵ}^2$. Each advective term, and the time derivative on that evolution scale, divided by transverse diffusion isThus ${ϵ}^2\ll 1$ and $Pe\ll 1$ make the leading thermal profile locally linear and quasistatic. Retaining the weak-cooling condition gives the same surface-temperature approximation with the local $h(x,t)$. For any independently imposed faster time variation one would also require its thermal relaxation ratio $h_{\ast }^2/(\kappa t_{\mathrm{evol}})$ to be small.

Define the positive surface-tension gradient coefficientThe weak-cooling approximation gives ${\gamma }_s\simeq {\gamma }_0+Bh$, so the Marangoni stress is ${\gamma }_{s,x}=B{h}_x$. The Young–Laplace equation gives the leading liquid pressure $p=p_a-{\gamma }_0{h}_{xx}$, with constant ambient pressure. In lubrication theory, $p_z=0$ and $\mu u_{zz}=p_x$. The no-slip boundary condition at the wall and the tangential surface condition $\mu u_z(h)={\gamma }_{s,x}$ giveHence the volume flux isConservation of mass gives the thermocapillary thin-film equationThe replacement of surface tension by ${\gamma }_0$ in the capillary term needs $B{h}_{\ast }/{\gamma }_0\ll 1$. For comparable capillary and thermocapillary fluxes,so the fractional tension change is only $O({ϵ}^2)$. Both the tension correction to $\gamma h_{xxx}$ and the differentiated-tension contribution ${\gamma }_x{h}_{xx}$ are then higher-order. Weak cooling alone would not justify that replacement if $|{\gamma }^{\prime }|\Delta T/{\gamma }_0$ were allowed to grow without bound.

The capillary term smooths the film: a crest has negative curvature and higher liquid pressure, causing flow away from it. The thermal term has the opposite effect. A thicker region has a colder surface and therefore higher surface tension; Marangoni stress pulls surface fluid toward that region, reinforcing the thickness disturbance. These mechanisms give fourth-order damping and second-order growth respectively.

Use $H=h/\hat{h}$, $X=ϵx/\hat{h}$, and $\tau =t/\hat{t}$. The two dimensionless flux-divergence coefficients are $B{ϵ}^2\hat{t}/(2\mu )$ and ${\gamma }_0{ϵ}^4\hat{t}/(3\mu \hat{h})$. Setting both equal to one gives the balanced scales for a thermocapillary film:These choices yield $H_{\tau }+(H^2{H}_X{)}_X+(H^3{H}_{XXX}{)}_X=0$. The predicted $ϵ$ must be small for the assumed long-wave approximation.

Linearize about $H=1$ using a normal mode of amplitude $\delta$. The resulting equation is $s-k^2+k^4=0$, so the dispersion relation isModes with $0<|k|<1$ grow, while $|k|>1$ modes decay. Differentiating $s$ gives the most unstable wavenumbersThe physical fastest wavenumber is $ϵ/(\sqrt{2}\hat{h})$.

For a positive steady film with zero volume flux, $H^2{H}_X+H^3{H}_{XXX}=0$. Divide by $H^3$ and integrate once:Choosing the thickness scale so that $H=1$ when $H_{XX}=0$ sets $C=0$. Multiply $H_{XX}=-\ln H$ by $H_X$ and integrate to obtain the zero-flux thermocapillary film profiles relationThus the stated potential is $V(H)=H(\ln H-1)$ and the integration constant $E$ is the corresponding first integral.

Let $\delta =H/L\ll 1$. Incompressibility makes the transverse velocity $O(\delta U)$. In the axial Navier-Stokes equation, transverse viscous stress scales as $\mu U/H^2$, longitudinal viscous stress as $\mu U/L^2$, and convective inertia as $\rho U^2/L$. Thus lubrication theory requiresUnsteady inertia is also negligible if $\rho H^2/(\mu T)\ll 1$; this coincides with the preceding condition when $T=L/U$. The transverse pressure variation is smaller than this pressure scale by $O({\delta }^2)$, and viscous normal stress at the free surface is similarly smaller. Consequently pressure is uniform across the film to leading order, while axial viscous shear balances its axial gradient. These estimates justify the lubrication approximation with small surface slopes and a slowly varying rigid wall.

Write the physical cylindrical-film thickness as $d=ϵ\bar{h}$, so that $\bar{h}=O(a)$, and use $\bar{z},\bar{t}$ for dimensional coordinates. For a surface of radius $a+d$, its outward mean curvature, with the convention giving cylindrical curvature $1/a$, isThe Young–Laplace equation gives $p=p_{\mathrm{ext}}+\gamma \kappa$. With local normal coordinate $y$ measured from the rigid cylinder, the axial velocity solves $\mu u_{yy}=p_{\bar{z}}$, with no-slip boundary condition at $y=0$ and stress-free boundary condition at $y=d$. ThereforeThe factors of circumference in axisymmetric mass conservation cancel at leading thin-film order, giving $d_{\bar{t}}+q_{\bar{z}}=0$. IntroduceThis produces the capillary instability of a thin film on a rigid cylinder governed byThe curvature term $h_z$ destabilizes long waves; the axial-curvature term $h_{zzz}$ smooths short waves.

Linearize about $h_0$ using $h=h_0+\eta e^{st+ikz}$ with small $\eta$. The linear equation is $s+h_0^3(-k^2+k^4)=0$, soThe growth rate is positive for $0<|k|<1$, zero at $k=0,\pm 1$, and negative for $|k|>1$. Its derivative is $2h_0^{3}k(1-2k^2)$, givingThe requested sketch is even in $k$:

For the Rayleigh–Plateau instability of an entire liquid cylinder in the purely viscous limit with negligible exterior viscosity, the fastest mode tends to infinite wavelength. The rigid-wall coating instead selects a finite wavelength. The difference comes from the flow resistance: a coating must shear across its thickness, so its long-wave growth vanishes as $k^2$; a free liquid cylinder can undergo nearly plug-like axial extension. For example, the long-wave free-cylinder balances ${\eta }_t+(a/2)u_z=0$ and $3\mu u_{zz}=-\gamma ({\eta }_z/a^2+{\eta }_{zzz})$ give $s\sim \gamma (1-a^2{k}^2)/(6\mu a)$, which does not vanish as $k\to 0$. This comparison is for the creeping-flow, negligible-exterior-viscosity limit; finite inertia or exterior viscosity changes the wavelength selection. The full free-cylinder dispersion relation is discussed in Plateau-Rayleigh Instability of a Cylinder of Viscous Liquid.

The collar is a quasisteady sliding collar on a coated cylinder. It must slowly grow as well as translate: an exact travelling wave would obey $q-ch=\text{constant}$, whereas its stationary uniform far films have $q=0$ and would require $-c{h}_{+}=-c{h}_{-}$. Thus the stipulated unequal films require the stated slow evolution of the collar amplitude. In its $h=O(1)$ core, $c\ll 1$ and the volume flux is small, so the leading pressure gradient vanishes: $h^{\prime }+h^{\prime \prime \prime }=0$. Integration gives a constant plus sine and cosine terms. Choose the collar centre at its maximum to remove the sine term, and parameterize its edge height as $B$. ThenThe core is a local capillary equilibrium. In the moving frame, swept-up volume minus deposited volume gives the growth rate $c(h_{+}-h_{-})$. Its leading excess volume is $2\pi A$, and for constant $B$,Thus the printed rate is the rate of collar volume, or an order-of-magnitude amplitude rate; interpreted as an exact equation for $\dot{A}$, it lacks $1/(2\pi )$. This slow change is smaller than the translational core terms by the small far-film thickness and does not alter the leading local matching below.

Near either edge $x_f=\pm \pi$, let $h_f$ denote the adjacent film thickness, $h_{-}$ at the rear and $h_{+}$ at the front. Across the short transition region the collar's slow growth is higher order, so local mass conservation integrates to $q=c(h-h_f)$. The axial third derivative dominates the first derivative in the capillary flux, givingFor collar-to-film capillary matching, chooseThe two sides become $c{h}_f{H}^3{H}^{\prime \prime \prime }$ and $c{h}_f(H-1)$ respectively, and henceThe resulting transition length is small compared with the core length: the matching relations below imply $h_f=O(c^{2/3}/A)$, so $h_f/c^{1/3}=O(c^{1/3}/A)$ for an order-one core amplitude.

To count admissible branches, put $H=1+\zeta$ and linearize. The characteristic equation is $r^3=1$, with rootsAt the rear, decay as $X\to -\infty$ permits only $\zeta \sim D{e}^X$. For the nontrivial branch growing into a positive collar, $D>0$; translation rescales $D$, leaving one orbit. This branch has positive $H^{\prime },H^{\prime \prime },H^{\prime \prime \prime }$. It exists for all forward $X$, since $0<H^{\prime \prime \prime }=(H-1)/H^3\le 4/27$ for $H\ge 1$, and once $H^{\prime \prime }>0$, $H$ grows at least quadratically. Then $H^{\prime \prime \prime }=O(X^{-4})$, so successive integrations give a quadratic asymptote with a finite constant term; translation removes the linear term. The constant solution is not a rear-to-collar match. On the downward branch, $H<1$ gives $H^{\prime \prime \prime }<0$ while $H^{\prime }$ and $H^{\prime \prime }$ are initially negative; the slope remains negative and $H$ reaches zero, so it cannot match a positive collar. Uniqueness here refers to the positive, nontrivial rear matching branch, modulo translations.

At the front, decay as $X\to +\infty$ permits the two real amplitudes inTranslation removes one degree of freedom, leaving one parameter $\lambda$. These oscillatory branches account for the small capillary ripples ahead of the collar. This local stable manifold count gives the family of front branches; admissible global branches must also remain positive and reach a parabolic core asymptote. It does not, by itself, prove the global uniqueness of the matching parameter supplied in the question.

Write the rear and front core asymptotes, after translation removes their linear terms, as $a_{-}{X}^2+b_{-}$ and $a_{+}(\lambda )X^2+b_{+}(\lambda )$. Expanding the outer collar near either edge giveswhereas the inner expansion givesMatching the constant and quadratic coefficients therefore yieldsEliminate $h_{-}/h_{+}$ to obtain $a_{+}(\lambda )b_{+}(\lambda )=a_{-}{b}_{-}$. Using the specified selected root ${\lambda }_0$ and writing $\alpha =a_{+}({\lambda }_0)$, $\beta =b_{+}({\lambda }_0)$,The physical branch has $\alpha >a_{-}$, as required by $h_{-}<h_{+}$. No numerical values of these universal matching coefficients are needed for the requested relations.

Finally, the energy source is decreasing capillary surface energy, not Newtonian gravity. This can be checked through the volume-constrained capillary energy of a cylindrical coating. The exact liquid volume per axial length is $\pi [(a+d{)}^2-a^2]$, and the free-surface area is $2\pi \int (a+d)\sqrt{1+d_{\bar{z}}^2}d\bar{z}$. Expanding the latter and eliminating $\int d$ with fixed exact volume gives the nonconstant quadratic partApart from its positive dimensional factor, this is the surface energy $\mathcal{E}=\frac{1}{2}\int (h_z^2-h^2)dz$. Its variational derivative is $-h-h_{zz}$, and the thin-film equation is a conserved gradient flow. With periodic or zero-energy-flux boundaries, integration by parts givesFor an isolated collar between unequal infinite films, use the corresponding local energy balance, including far-film fluxes and subtracting background energies; the unsubtracted total energy is infinite. Collecting film into the growing collar lowers surface energy, which supplies the viscous dissipation sustaining its slow motion.

Measure $z$ from the rigid tube wall towards the air core, so $0<z<h$. To leading order in $h_0/a$ and small interface slope, the curvature entering the Young–Laplace equation isThe air pressure is spatially uniform at the order retained. Thus the linear liquid pressure perturbation associated with thickness amplitude $H$ is $p_1=-{\sigma }_0(a^{-2}-k^2)H$. The circumferential curvature favors growth at long wavelength; the curvature opposes it at short wavelength.

The lubrication theory momentum equation is $\mu u_{zz}=p_x$. With the wall no-slip boundary condition $u(0)=0$ and zero surface shear stress, $u_z(h)=0$, its solution and flux areLeading thin-film mass conservation is $h_t+q_x=0$. For a mode $e^{\beta t+ikx}$, this gives the capillary instability of an annular liquid liningTherefore the unstable band is $\boxed{0<k^2<a^{-2}}$. Maximization with respect to $k^2$ gives $k_{\ast }^2=1/(2a^2)$ andThese curvature coefficients use $a$ instead of $a-h_0$ consistently at leading order in the thin-lining approximation.

Let the longitudinal variation scale be $\ell \gg h$. The stress-free boundary condition gives $\mu (u_z+w_x)=0$ at each face. Incompressibility implies $w=O(hu/\ell )$, so $w_x$ is smaller than a putative $u_z=O(u/h)$ by $O(h^2/{\ell }^2)$. The leading Stokes equation and the two shear-free conditions therefore make $u$ independent of $z$; its thickness-dependent correction is smaller-order. Symmetry gives $w=0$ at $z=0$, and incompressibility integrates toVertical momentum makes the leading normal stress independent of $z$. With the normal directed from liquid into gas, the upper-face curvature is $-h_{xx}/2$ to leading order. The Young–Laplace equation givesThe Newtonian fluid stress tensor also gives ${\sigma }_{zz}=-p+2\mu w_z=-p-2\mu u_x$. Hence $p=p_a-\gamma h_{xx}/2-2\mu u_x$ andThe factor four is the planar extension factor: both the longitudinal viscous stress and the pressure adjustment from transverse contraction contribute.

For force balance on the illustrated slice, the vertical cuts give $(h{\sigma }_{xx}{)}_x\delta x$. Pressure on the sloping broad faces gives $p_a{h}_x\delta x$ horizontally. Each of the two interfaces exerts a tangential surface tension pull at each cut, with horizontal component $\gamma \cos \theta$, where $\tan \theta =h_x/2$. Thus the horizontal force balance is the derivative of the effective tensionto the retained small-slope order. The ambient-pressure contributions cancel in this excess tension. Differentiating cancels the two $h_x{h}_{xx}$ terms, leaving the planar viscous-sheet stretching equationsThe upper-face kinematic condition is $w(x,h/2,t)=(h_t+u{h}_x)/2$. Combining it with $w=-z{u}_x$ gives the second equation,which is conservation of mass per unit transverse width.

For the two bubbles, let $p_g$ be the common gas pressure and $p_e$ the surrounding liquid pressure away from the sheet. A cylindrical bubble has one nonzero principal curvature, so the Young–Laplace equation gives $p_g-p_e\simeq \gamma /a$. In the nearly flat sheet the normal stress is $-p_g$, giving liquid pressure $p_{\mathrm{film}}=p_g-2\mu u_x$. The extensional correction is small compared with $\gamma /a$ because the transition scale will satisfy $\sqrt{a{h}_0}/L\ll 1$. Thus $p_{\mathrm{film}}\simeq p_g>p_e$, and this capillary pressure difference drives liquid out through both ends.

For a spatially uniform flat sheet, $h_x=h_{xxx}=0$, so the longitudinal equation gives $u_{xx}=0$. Reflection symmetry at $x=0$ selectsHere $U$ is the outward speed at the positive end. The mass equation then gives $h_t=-Uh/L$, independent of $x$, so initially uniform thickness remains uniform. Writing it as $h_0(t)$,The end transitions determine $U$, as derived in the following parts.

Let the actual dimensional thickness be $d=ϵah$, and let $\bar{z}$ increase downward. The leading curvature of the outer free surface isThe Young–Laplace equation gives $p_{\bar{z}}=-\gamma (d_{\bar{z}}/a^2+d_{\bar{z}\bar{z}\bar{z}})$. In the lubrication approximation, the downward velocity at distance $y$ from the wall is $(\rho g-p_{\bar{z}})(dy-y^2/2)/\mu$, from no slip and zero free-surface shear. Integrating this profile givesCircumferential corrections are higher order in $d/a$, so volume conservation is $d_{\bar{t}}+q_{\bar{z}}=0$ at leading order. DefineThen the thin liquid film on a vertical cylinder satisfiesThe circumferential-curvature term $h_z$ is retained along with axial curvature.

The perturbation calculation givesLong waves with $0<|k|<1$ grow, while $|k|>1$ decay; the fastest growth is $1/12$ at $|k|=1/\sqrt{2}$. Disturbances drift downward at speed $G$. The dimensional unstable wavelengths exceed $2\pi a$, with most unstable wavelength $2\pi \sqrt{2}a$. This is the thin-film version of the Rayleigh–Plateau instability driven by circumferential curvature and opposed by short-wave axial curvature.

For a travelling wave, one integration fixed by $H\to 1$ givesor $H^{\prime \prime \prime }+H^{\prime }=3c(H-1)/H^3-G(1-H^{-3})$. In the large positive-speed core, substitute the expansion using the supplied assumptions. The left side at order $c^{2/3}$ is $H_2^{\prime \prime \prime }+H_2^{\prime }$, while the gravity term is order one and $3c/H^2$ is only order $c^{-1/3}$. Thus $H_2^{\prime \prime \prime }+H_2^{\prime }=0$. Its general solution is a constant plus a sine and cosine. The vanishing leading height and slope at both endpoints selectThe core length is $2\pi$ in the axial coordinate; its amplitude is fixed by transition matching.

At either edge set $X=(3c{)}^{1/3}(x-x_e)$, with $x_e=0$ at the trailing edge and $x_e=2\pi$ at the leading edge. Keeping the height $H$ of order one, the exact wave equation becomesThus the transition equation is $H^3{H}_{XXX}=H-1$. Its linearization about $H=1$ has exponents $1$ and $-1/2\pm i\sqrt{3}/2$. Behind the pulse, approaching the uniform film as $X\to -\infty$ permits only the positive real exponent. The positive-growing, nontrivial branch has one amplitude that is removed by translation, giving the relevant unique $H_{-}$. In front, decay as $X\to +\infty$ permits the two real oscillatory amplitudes; translation removes one parameter and leaves a one-parameter family $H_{+}$. These are the unstable manifold and stable manifold dimensions for the transition system. The literal boundary condition also admits the constant solution and an opposite departing branch, so uniqueness here is specifically for the branch matching a raised positive pulse.

Match the supplied trailing quadratic asymptotic to the core near zero. It gives $K_2=\kappa 3^{2/3}$, because $\frac{1}{2}{c}^{2/3}{K}_2{x}^2=\frac{1}{2}\kappa (3c{)}^{2/3}{x}^2$. The leading maximum occurs at $x=\pi$, soThe front tail has the form $H-1\sim C{e}^{-X/2}\cos (\sqrt{3}X/2+\theta )$. Its capillary waves occur ahead of the descending pulse, not behind it; the trailing tail is monotone to leading order. Converting its frequency to physical distance gives

This large solitary pulse on a cylindrical film sketch shows the leading core and the front-tail eigenmodes; the edge transitions are schematic and the ringing is enlarged for visibility. The thin-film asymptotics require both $c\gg 1$ and $ϵc^{2/3}\ll 1$, rather than taking speed to infinity at fixed film slenderness.

At the next core order, $H_0^{\prime \prime \prime }+H_0^{\prime }=-G$. Integrating and imposing zero $H_0^{\prime }$ at both endpoints givesThe constants in the two quadratic transition asymptotics match the core endpoint heights: $A_0+B_0={\beta }_{-}$ and $A_0+B_0-2\pi G={\beta }_{+}$. Hence $2\pi G={\beta }_{-}-{\beta }_{+}$, and the dimensional uniform thickness selected by matching isWith the supplied constants this fixes $G=3.75/(2\pi )$; $B_0$ is not separately fixed by these height conditions. The thickness selection and capillary wavelength follow from matched asymptotic expansion, not from the linear instability calculation.

Take $z$ positive downwards. The leading axial velocity of a slender viscous thread is independent of radius. Incompressible flow then gives $u_r=-r{w}^{\prime }/2$, while steady mass conservation gives $(a^{2}w{)}^{\prime }=0$. The Newtonian fluid stress tensor has ${\sigma }_{rr}=-p-\mu w^{\prime }$ and ${\sigma }_{zz}=-p+2\mu w^{\prime }$. The Young–Laplace equation, neglecting axial curvature at slender order, gives ${\sigma }_{rr}=-p_e-\gamma /a$ and hence $p=p_e+\gamma /a-\mu w^{\prime }$.

The axial cut transmits both the integrated Newtonian fluid stress tensor and the circumferential surface tension. After subtracting the ambient pressure, its tensile force isThe coefficient three is the Trouton ratio for axial extension. The last term is essential: the capillary tensile force of a slender thread is $\pi \gamma a$, not $2\pi \gamma a$, because the capillary pressure subtracts half the interfacial line contribution. Axial force balance is $T^{\prime }+\pi \rho g{a}^2=0$. Together the governing equations areDefine the dimensionless variablesThen $a=a_0{W}^{-1/2}$ and the axial equation becomesFor the increasing power-law branch, all three terms have the same dependence when $\alpha =2$. Substitution leaves $1-6k^2-\Gamma k=0$. ThusThis remains valid at $\Gamma =0$, when $k=1/\sqrt{6}$. The other root is negative and describes a decreasing local branch up to its singular endpoint, not a thread accelerating downwards indefinitely. Positive surface tension decreases $k$, so it slows the fall at a given height on this branch. Thinning reduces the capillary tensile force $\pi \gamma a$. Its negative axial derivative supplies an upward capillary force on a thread segment, balancing part of the weight. The viscous tensile force therefore supplies a smaller remaining balance; on the quadratic family this reduces the stretching rate.