The production rate is , while depletion includes both capture and fission of the fissile population, . Thus the conversion ratio in this stipulated model is
At zero instantaneous flux this expression describes the limiting ratio of the two reaction rates. The total absorption coefficients are and , so
It is below one: fissile nuclei are initially removed slightly faster than this simplified chain replaces them. Consequently this model is not initially self-replacing in fissile inventory. Inventory replacement is distinct from the instantaneous neutron balance that determines criticality.
At this point , so and . The solution from part (c) gives
Therefore
The fissile population has declined by about from its initial value, while the conversion ratio has decreased slightly from . The replacement shortfall persists over this interval. Maintaining a specified long-term fuel inventory would require replenishment or a different balance of reactions; the prescribed-flux equations alone do not establish a constant-power operating state. Intermediate decay delays and the changing neutron spectrum were excluded by the original lumped model.
gadolinium is primarily a strong neutron absorber. The supplied thermal cross section for gadolinium-157 is very large, so capture removes neutrons that could otherwise sustain nuclear fission. This is a criticality-control role rather than a requirement to complete the host formula. The isotope-specific number must not be assigned unchanged to natural gadolinium.
hafnium supplies an additional neutron poison with favourable retention chemistry. Its supplied natural-abundance thermal cross section is much smaller than that of gadolinium-157 but still appreciable. Chemically, tetravalent hafnium resembles zirconium and can remain associated with a durable titanate host. Keeping the absorber with the fissile inventory during alteration is as important as its initial neutron capture strength: a highly absorbing constituent offers poor long-term protection if it is preferentially lost. These considerations explain using complementary absorbers rather than ranking them solely by their initial thermal cross sections.
uranium addition chiefly addresses isotopic dilution, including the long-term daughter inventory. plutonium-239 alpha decay produces uranium-235. Added uranium-238 lowers the uranium-235 fraction of that future uranium inventory; depleted uranium adds less uranium-235 initially than natural uranium. uranium-238 also absorbs some neutrons, but its small listed cross section does not make it a substitute for the strong absorbers. The long-term daughter issue and the retention of gadolinium and hafnium are explicit concerns in ceramic waste-form development.[ref]
These are complementary physical purposes, not proof of criticality control in radioactive waste from three cross-section values. neutron energy, isotopic composition, geometry, moderation, absorber distribution and their coupled evolution matter. Incorporation in the same durable waste form helps maintain association, but neither uranium addition nor chemical immobilisation makes deliberate element separation physically impossible.
Each quark has baryon number , and each antiquark has baryon number . A strange quark has strangeness , a strange antiquark has strangeness , and the light have zero strangeness. The isospin projections of are , with the opposite values for their antiquarks. Thus
For three valence quarks, and . The baryon octet is reproduced by the following quark model assignments:
BaryonValence quarks
Neutron
Proton
Sigma baryon
Sigma baryon
Lambda baryon
Sigma baryon
Xi baryon
Xi baryon
Consequently the top-left and top-right states in the source diagram are . Here the source's label means the unknown particle at the top right; the conventional symbol elsewhere in this solution denotes flavor hypercharge.
Write the charge in units of as . The proton and neutron have and , so their measured charges imply and . Thus , :
This is the Gell-Mann--Nishijima formula, with the full flavor hypercharge . Applying the quark baryon number and the isospin and strangeness assignments from part (a),
Physical electric charges are these numbers multiplied by the positive elementary charge .
beta decay is a weak charged current process. At quark level , with amplitude proportional to at low momentum transfer. A neutron in a nucleus can thereby become a proton:
The second reaction denotes an energetically allowed nuclear conversion, not a decay of an isolated free proton. In a nuclear beta transition the mass number stays fixed and the atomic number changes by one. baryon number and electric charge are conserved; the neutrino or antineutrino supplies the missing energy, momentum and angular momentum. The three-body final state produces a continuous electron spectrum rather than a single electron energy. Neglecting neutrino mass and recoil, an allowed spectrum in electron total energy is
The Fermi function accounts for the electron's Coulomb interaction with the daughter; is the electron total-energy endpoint. forbidden beta decay adds momentum-dependent nuclear shape factors. The V-A interaction violates parity: it couples left-chiral fermion fields, not an equal mixture of left and right currents.
For allowed beta decay the leading leptons have zero orbital angular momentum. Fermi transitions have ; Gamow-Teller transitions have with excluded. Both preserve nuclear parity. Higher lepton partial waves permit forbidden transitions with extra suppression. Nuclear matrix elements and phase space, as well as these selection rules, determine lifetimes. Particle-physics examples include free-neutron decay and pion beta decay, . semileptonic decays test quark mixing and the universality of the weak charged current. beta decay changes quark flavour through virtual W exchange; its continuous spectrum reflects an additional lepton in the final state.
nuclear radius scaling follows approximately with for a sharp matter-radius convention. Consequently the interior nucleon density is nearly independent of mass number: nuclear forces are short range and exhibit nuclear matter saturation. A diffuse nuclear charge distribution has a charge-weighted root mean square radius, not a hard surface. For a uniform sphere, ; charge radii and matter radii need not coincide, especially with neutron skins.
Elastic electron scattering measures the nuclear charge form factor. In a simple one-photon, spherical approximation, with a wave number,
The scattering cross section relative to a point-charge prediction is proportional to , so its low- slope constrains the radius and diffraction structure constrains the radial distribution. Finite momentum coverage and Coulomb distortion in electron scattering limit reconstruction. In Robert Hofstadter's experiment a magnetic spectrometer separated elastic and inelastic electron peaks; beam-charge normalization and closed-slit background checks prevented raw count structure from being mistaken for a nuclear charge form factor.[ref]
A useful intrinsic-shape description is . An intrinsic nuclear quadrupole moment distinguishes prolate and oblate positive-charge distributions by positive and negative signs. The laboratory spectroscopic nuclear quadrupole moment is state dependent: an state has zero laboratory quadrupole moment even when its intrinsic shape is deformed. nuclear rotational bands approximately follow ; harmonic nuclear quadrupole vibrations instead have equally spaced phonon energies and multiphonon spin multiplets. Measured electric quadrupole transitions test the collective interpretation in addition to level energies. Radius probes spatial extent; quadrupole observables and collective spectra probe shape.
At energies far below the mass, replace its propagator by a constant. The modern V-A interaction form of Fermi's contact theory has, in units,
Nucleons are treated nonrelativistically within nuclear states. To leading order in their velocity, the vector charge and axial spatial current give the two nuclear operators
where here means neutron-to-proton conversion. (i) The scalar Fermi operator permits , including , without parity change. The rank-one Gamow–Teller operator permits without parity change, excluding . Both terms can contribute when the same nuclear states permit them; their strengths contain nuclear matrix elements, not just phase space.
(ii) Expand the lepton waves across the nucleus in powers of their momenta times nuclear radius. When , the constant spatial term gives allowed transitions. If its matrix element vanishes by spin/parity selection, higher terms supply lepton orbital angular momentum: “forbidden” means suppressed, not impossible. First-forbidden terms change parity and can have ; the rank-two case is unique first-forbidden. Higher orders carry additional small spatial factors and different energy-dependent shape factors. The contact approximation alone does not imply the allowed approximation.
For a single branch, neglect recoil and neutrino mass and first assume an energy-independent nuclear shape factor. Fermi's golden rule integrates the neutrino phase space with , while the electron momentum volume is proportional to . Including Coulomb distortion,
This momentum-bin Kurie ordinate is linear in kinetic energy and vanishes at its endpoint. If instead using counts per unit kinetic energy, in units; converting with recovers the supplied momentum-bin definition. No extra factor of should be left inside that definition of .
The graph's horizontal coordinate is , not in MeV. Its intercept is approximately –, so
For a ground-to-ground branch between bare nuclei, the emitted electron's rest energy must also be supplied:
For neutral atomic masses the mass difference instead equals approximately , neglecting small electron-binding corrections. The graph supports this approximate precision, not a precise evaluated isotope mass. Interpreting a branch to an excited daughter would require adding its excitation energy; the ground-state comparison assumes the ground-state branch intended here.
The shell-model prediction for yttrium-91 beta decay follows from shell filling: the proton orbitals above 28 fill with four protons and with six, reaching 38. Yttrium has its 39th proton in , giving . Its 52 neutrons include the closed 50-neutron core and a pair in , coupled to zero in the simple paired ground state. Zirconium has 40 paired protons and 51 neutrons, leaving an unpaired neutron, so . Therefore
The single-particle change is neutron to proton ; the parity change and rank two prevent an allowed Fermi or Gamow–Teller contribution.
The straight plotted line is a constant-shape idealization. For the shell-model transition just inferred, a leading unique-forbidden shape factor contains in units, with Coulomb/finite-size refinements. Consequently the uncorrected quantity specified in the paper is generally proportional to , not exactly linear. A consistent shape-corrected Kurie plot also divides its ordinate by . The source's exact straight-line construction and its forbidden-transition inference cannot both be exact with a Coulomb-only ; the approximate graphical endpoint can still be read as requested. Allowed and unique-forbidden spectral shapes are experimentally distinguishable.[ref]
Figure 1.
Original illustrative comparison of constant-shape and unique-first-forbidden Kurie ordinates with the same endpoint; no source data points reproduced
. Details.
A useful convention for the semi-empirical mass formula is
where is the binding energy. The nuclear mass is . Atomic-mass comparisons instead use hydrogen-atom masses and account for electron binding at the desired accuracy. No numerical fit coefficients are specified here.
The volume term represents short-range nuclear attraction with saturation: each nucleon has a limited number of close neighbours. The surface term subtracts the binding lost by nucleons at the boundary. Coulomb repulsion penalizes a large proton fraction. The asymmetry term penalizes unequal neutron and proton populations, reflecting the cost of filling different Fermi seas and nuclear interactions. Pairing favours even-even nuclei and penalizes odd-odd nuclei; odd- nuclei have zero pairing term in this approximation. For example, one may choose ; an alternative fitted power requires a correspondingly different coefficient.
At fixed , the smooth mass dependence on is approximately parabolic. Neglecting the neutron-proton mass difference, pairing and small linear-in- Coulomb corrections, minimization gives
Thus the preferred neutron excess grows with mass number. The surface penalty disfavors very light systems, while the growing Coulomb penalty reduces the binding per nucleon of very heavy systems; this explains broad fusion and fission energy trends. The formula is a bulk approximation: shell closures, deformation and small separation-energy differences can give important exceptions. A fitted average binding trend is not a reliable substitute for a measured decay threshold near a boundary of stability.
High-energy elastic electron scattering probes nuclear charge through the electromagnetic interaction. Resolve the elastic peak with a spectrometer, measure its angular dependence and normalize by beam charge, target thickness and detector acceptance. In a plane-wave, approximately static treatment,
Here is physical momentum transfer divided by , not the momentum itself. The low- slope, , determines the charge r.m.s. radius. A sharp uniform sphere has
Its first diffraction minimum is at , illustrating how angular structure determines size. Radii approximately follow , but a sharp radius, a surface half-density radius and an r.m.s. radius are different definitions.
A motivating experimental implementation is Hofstadter's magnetic-spectrometer measurement: selecting outgoing electron momentum separates elastic scattering from nuclear excitation, rather than treating every scattered electron as an elastic event. Beam-energy and angle calibration, empty-target or blocked-acceptance backgrounds, and target-thickness checks matter. Finite resolution mixes nearby excitations; multiple scattering and Coulomb distortion require correction before a precision density is inferred.[ref]
Shape information comes from quadrupole moments, Coulomb-excitation transition strengths and rotational spectra. An intrinsic axial moment is positive for a prolate charge distribution and negative for an oblate one. A laboratory quadrupole moment is not identical to : a rotationally averaged spin-zero state can have zero laboratory moment despite intrinsic deformation. Collective rotational levels approximately follow , while measured strengths test the associated charge collectivity. Muonic-atom X-rays and isotope shifts supply complementary charge-radius constraints; hadronic probes provide additional, more interaction-dependent matter and neutron information. Neither a charge radius alone nor a finite-range form-factor measurement uniquely fixes the entire nuclear shape.
Figure 1.
Original model charge form factors at equal r.m.s. radius; the diffraction structure carries information beyond the radius
. Details.
The common energetic principle behind nuclear fission and nuclear fusion is the nuclear binding energy. If the products are more tightly bound in total than the reactants, their smaller rest mass releases
The two binding-energy expressions assume that the same numbers of protons and neutrons are counted on both sides; emitted free nucleons have zero nuclear binding. The energy appears mainly as product kinetic energy, with radiation and subsequent decays contributing according to the reaction.
The binding energy per nucleon rises rapidly through light nuclei, has a broad maximum in the iron/nickel region, and decreases more slowly for heavier nuclei. Combining suitable light nuclei can therefore increase their total binding, whereas splitting a sufficiently heavy nucleus into moderately heavy fragments can do the same. This is an energy comparison, not a rule that every fusion or fission channel is exothermic: the actual nuclear masses fix the sign of .
Figure 1.
Schematic binding-energy trend explaining why light-nucleus fusion and heavy-nucleus fission can release energy
. Details.
In nuclear fission, the liquid-drop model illustrates the competition between attractive short-range nuclear cohesion and long-range proton repulsive Coulomb interaction. Deformation increases surface area and costs surface energy, but separating the charge can reduce nuclear Coulomb energy. Their competition creates a fission barrier. An excited nucleus may pass over the barrier; spontaneous fission can occur through quantum tunnelling. The resulting fragments are often excited and neutron-rich, so they may emit prompt neutrons and photons and undergo later beta decay. The typical total energy released by a heavy-nucleus fission is of order a few hundred MeV, rather than an electronic-scale energy. Its size follows from an approximately MeV-per-nucleon binding gain summed over a heavy nucleus. A neutron from one fission can induce another; a nuclear chain reaction is the repeated physical process, distinct from the energy-release condition for one event.
In nuclear fusion, the initial charged nuclei repel one another. Exothermicity does not remove this entrance Coulomb barrier. A reaction requires sufficient overlap of their wavefunctions, achieved by energetic encounters and quantum tunnelling. For nonresonant low-energy charged-particle fusion, a useful separation is
The astrophysical S factor isolates the nuclear part from much of the rapidly varying Coulomb penetration probability. In a thermal population, the competition between the decreasing high-energy population and increasing penetration produces the Gamow peak. This explains how fusion can proceed below the classical barrier without requiring the mean thermal energy to equal its height.
Both processes conserve total energy, charge, baryon number and angular momentum. Their very different entrance barriers and mass ranges explain why a favorable value by itself does not specify a reaction rate. Short-range attraction gives approximately saturated nuclear binding, while surface, Coulomb, symmetry and pairing terms account for the broad trend and its isotope-dependent departures.
The deuteron is the bound proton–neutron system. Its ground state has and isospin , with binding energy approximately and no excited bound state. The small binding compared with characteristic nuclear energy scales produces an extended tail. With reduced mass , the asymptotic radial wavefunction decays as , where
The decay length is not a sharp deuteron radius or the force range. It illustrates weak binding outside the region of strong attraction.
The observed total spin is consistent with aligned nucleon spins, , and a predominantly spatial state, . A central attraction identical in both spin–isospin channels would not distinguish this channel from a spin-singlet proton–neutron channel. In fact the triplet channel binds while the corresponding singlet channel does not. A realistic nuclear force must therefore distinguish these spin–isospin channels, for example through a term , whose eigenvalues are and in triplet and singlet states. The absence of a bound dineutron and diproton reinforces the need to distinguish channels; proton–proton Coulomb repulsion is an additional effect, not a complete explanation of the singlet nuclear interaction.
The clearest evidence against a purely central force is the nonzero electric quadrupole moment. A pure isotropic S-wave charge distribution would give zero. The deuteron quadrupole evidence for a tensor force instead points to a nuclear tensor force,
It depends on how the spins point relative to the line joining the particles. It preserves total but couples orbital angular momenta differing by two, producing
Both terms have , and their interference permits a quadrupole moment. The 1939 theoretical analysis explicitly connected the measured quadrupole moment with such directional dependence.[ref]
The nuclear magnetic moment provides a second check. A pure aligned-spin S wave would give approximately , close to but larger than the observed deuteron value approximately . The discrepancy is consistent with non-S-wave structure and interaction-current corrections; it is not by itself a model-independent measurement of a D-state probability. The deuteron D-state admixture depends on the adopted Hamiltonian and electromagnetic current. The magnetic moments and mass differences used for these scales are tabulated physical constants.[ref]
A useful schematic interaction therefore contains central, spin-dependent and tensor terms, and possibly spin–orbit terms in other channels. Long-range one-pion exchange naturally supplies a tensor component, with its finite range set by the pion mass. The deuteron establishes an attractive triplet channel and a noncentral tensor interaction; a spin-independent central potential is insufficient.
The mirror nuclei have interchanged neutron and proton numbers. Neglect their strong-interaction binding difference and describe them with the same uniformly charged sharp sphere of radius . The nuclear Coulomb energy is
Changing one neutron into a proton decreases the nucleon rest-mass sum by , but raises the Coulomb energy. The diagram gives for nuclear masses, so
With the standard electromagnetic conversion , the uniform-sphere Coulomb displacement energy estimate is
This is the uniform sphere's outer radius. If “charge radius” means the rms nuclear charge radius, the same distribution gives
The numerical result is an estimate within the charge-density model, not a model-independent radius measurement. A discrete-proton correction replaces by , giving and . The main answer above follows the literal continuum charged-sphere model. Strong isospin-breaking, nonuniform density and changes in the valence-nucleon distribution also limit the extraction.
Beta decay converts a neutron to a proton or vice versa through the weak interaction, leaving the mass number fixed:
Inside a nucleus the full initial and final nuclear masses determine whether either process is possible. Electron capture, , is the related bound-electron process. The emitted charged-lepton spectrum is continuous because energy is shared with the neutrino and nuclear recoil.
For allowed beta decay, the lepton wavefunctions' leading spatial terms are constant over the nucleus. A Fermi transition has and no parity change. A Gamow-Teller transition has and no parity change, excluding . Thus a same-parity transition with nonzero initial and final spins and can contain both contributions. First-forbidden transitions change parity and permit ; the case is unique forbidden beta decay. Higher forbiddenness requires higher powers of the small lepton momentum times nuclear size. “Forbidden” denotes suppression of the leading allowed operator, not an impossible decay.[ref]
Fermi's golden rule expresses a rate as a squared nuclear matrix element times leptonic phase space. Neglecting charged-lepton mass and Coulomb distortion, a constant allowed matrix element gives
This is the approximate Sargent rule, for comparable allowed strengths; it is not an exact law across arbitrary transitions. Finite electron mass, the Fermi function, forbidden shape factors and nuclear structure change the comparison. A microscopic first-forbidden unique operator introduces additional momentum factors.
Using bare nuclear masses , the kinetic-energy release is
The daughter is different in the two cases: its charge is for beta minus and for beta plus. The relevant mass difference must exceed one electron mass. For neutral atomic masses, to leading order in small electronic binding corrections, the corresponding expressions are and . Electron capture is energetically possible approximately when , with available shell binding energy and daughter excitation included. Nuclear masses and atomic masses must not be mixed.
In the nuclear shell model, a level with total angular momentum has substates for each nucleon species. The first three levels accommodate protons or eight neutrons. nuclear pairing makes a filled shell or a pair of like nucleons contribute , and an orbital has spatial parity .
For oxygen-17, eight protons and eight neutrons form a closed core; the remaining neutron occupies , so . For nitrogen-15, eight neutrons close their shell, while the seventh proton occupies . Equivalently it is a proton hole relative to the closed eight-proton shell, giving . beryllium-10 is an even-even nucleus; pairing its four protons and six neutrons gives .
boron-10 needs an additional qualification. The fifth proton and fifth neutron each occupy . addition of angular momentum permits
The experimentally correct ground-state assignment is , corresponding to aligned unpaired contributions in this simple description. However, one-particle level ordering alone does not select it over the other couplings: their splitting requires the nuclear residual interaction. Assuming a preference for the aligned proton-neutron coupling gives the intended prediction; without that assumption, the strictly deducible result is the allowed positive-parity multiplet. The evaluated ground state is , with a level above it.[ref]
The nuclear Fermi gas model treats protons and neutrons as two species of spin one-half fermions moving approximately independently in a confining nuclear mean field. At a temperature small compared with their Fermi temperature, the Pauli exclusion principle fills the lowest available momentum states. It does not allow all nucleons to sit at zero momentum.
For species , two spin states occupy each momentum-space cell . Counting a filled sphere gives
where . The Fermi energy is measured from the mean-field well bottom; it need not equal the energy needed to remove a nucleon into vacuum. Occupied-state averaging gives
Even at zero temperature there is kinetic energy and degeneracy pressure. As an explicitly illustrative input, total density and give and . These numbers illustrate the formula; they are not additional data supplied by the paper.
Separate proton and neutron seas explain a kinetic contribution to nuclear symmetry energy. At fixed , put and define at . Then
Increasing one species' population raises its Fermi surface and costs energy, favoring similar populations before electrostatic and interaction terms are included.
pauli blocking suppresses collisions deep in a filled sea because scattering needs unoccupied final states. An energetic external probe can knock a nucleon into an empty state and reveal its initial Fermi motion, making the model useful for broad inclusive scattering distributions. A finite surface can be approximated using a position-dependent nuclear mean field.
A free gas cannot produce nuclear binding or saturation: those require an attractive interaction and its density dependence. The smooth gas picture also omits discrete nuclear shells, nuclear spin-orbit splitting, nuclear pairing, short-distance correlations and deformation. It cannot assign all ground-state spins from a momentum sphere. Its useful prediction is the scale and occupancy of nucleon motion, with a surrounding mean field supplied separately.
An S wave has and positive parity. The deuteron's therefore requires a spin-one-half triplet state, . The two-nucleon isospin description makes this the antisymmetric channel. Its existence proves sufficient attraction to bind in the -dominated channel.
A spin one-half pair could also form . The absence of a bound deuteron indicates that the singlet interaction does not bind, not that it is everywhere repulsive. Together with triplet binding, this shows that a spin-independent central attraction is insufficient. No radial excited bound level also constrains the strength and range: the attraction supports only a shallow low-energy bound state.
For identical neutrons or protons, two-particle isospin has and is symmetric. At even , spatial exchange is symmetric, so the Pauli exclusion principle requires an antisymmetric spin state, . A low-energy or pair cannot occupy the deuteron's channel. With approximate charge independence of nuclear forces, their singlet strong interaction corresponds to the unbound neutron-proton singlet; proton-proton electrostatic repulsion further disfavors binding. There is no bound dineutron or diproton in these physical low-energy channels. The inference uses charge independence and singlet-channel behavior; the deuteron's quantum numbers alone do not constrain every imaginable potential.
The separate proton and neutron shell capacities are . Filled shells and paired particles have zero net spin and magnetic dipole moment. The single-particle nuclear magnetic moment is , with orbital factors , and .
For nitrogen, the eight neutrons form a closed shell. The seventh proton occupies , so , and the Landé g-factor gives
Hence the nuclear shell model predicts
Its single-particle spin and parity is . The negative moment results from the proton spin being predominantly opposed to the total angular momentum in this level.
For oxygen, eight protons and the first eight neutrons are paired. The ninth neutron occupies , with , . Since its orbital factor is zero, . Therefore
These are ideal single-particle predictions in units of the nuclear magneton, not fits incorporating nuclear configuration mixing.
Smooth-model fission energy. Use natural units , so the quoted nuclear masses are expressed as rest energies. Conservation of mass number and atomic number fixes the second fragment to . First omit nuclear pairing to compare a continuous range of . Pairing can subsequently add for integer fragments; it has no smooth parity assignment for arbitrary real .
In the parent-minus-daughters mass difference, the nucleon rest energy and volume terms cancel. The nuclear symmetry energy also cancels because both fragments have the same :
The remaining liquid-drop fission energy is
Splitting increases the surface energy cost, but reduces nuclear Coulomb energy. Both contributions are symmetric under , so the symmetric split is stationary. Symmetry alone would not establish a maximum, since the two contributions compete.
For a full check, put , and . On , increases from to . Expressing the two fractional-power sums through gives
The derivative can change sign only from negative to positive, so any interior stationary point in is a minimum. The largest value is therefore either the no-split endpoint or the symmetric split. Thus symmetric fission maximizes the positive liquid-drop energy release: whenever this smooth model permits an exothermic split, its largest release occurs at .
There is a qualification to the paper's unqualified wording. For arbitrary low , the symmetric split need not maximize ; indeed it is a local minimum when . The symmetric-maximum conclusion is valid in the heavy, fission-favorable regime relevant here, rather than a universal property of the formula.
At ,
Requiring gives
Barrier and fragment yields. Positive final-state Q value does not remove the fission barrier along a deformation path. Surface energy initially rises as the nucleus deforms; spontaneous fission then requires collective quantum tunnelling unless enough excitation is present. Its rate is exponentially sensitive to barrier height, width and collective inertia. Thus nuclei close to the exothermicity threshold can have immeasurably long spontaneous-fission mean lifetimes, while sufficiently heavier nuclei have smaller effective fission barriers or larger quantum tunnelling probabilities.
The fission-fragment mass distribution of low-excitation actinide fission is usually double peaked: complementary fragments have mass fractions roughly and rather than both exactly . Nuclear shell model effects and the fission dynamics help favor asymmetric fragments. Maximizing the final smooth-model energy release is not a calculation of the fragment yield. The following yield curve is schematic, with no measured counts implied:
Figure 1.
Smooth-model fission energy versus a schematic asymmetric fragment-yield distribution
. Details.
Capture excitation energies. Capturing a negligible-energy neutron forms a compound nucleus with the rest energy of the target plus the free neutron. Relative to the compound ground state, the neutron-capture excitation energy is therefore
where is positive nuclear binding energy and the compound nucleus's neutron separation energy. The free neutron rest energy cancels in the binding-energy difference. With the supplied semi-empirical mass formula,
At , uranium-235 has odd , while uranium-236 is even-even. The pairing contribution is . By contrast uranium-238 is even-even and uranium-239 has odd , giving . The individual contributions are
Thus the model predicts
Of the predicted difference, comes from the change in nuclear pairing. It is the primary reason the even-even capture product is more strongly excited; the smooth terms account for the remaining .
Thermal versus fast-neutron fission. The last comparison uses the supplied observed capture excitations, and , rather than replacing them by the preceding smooth-model estimates. Interpreting the quoted and activation energies as the barriers in the respective capture channels gives
A simple neutron-induced fission threshold estimate for the second channel requires about additional centre-of-mass kinetic energy. Sub-barrier tunnelling is possible, but it does not give the large thermal-neutron fission probability of the first channel.
The barrier labels in the original PDF need care: it assigns them to and , whereas the states formed after capture are and . The comparison above uses the intended capture-channel interpretation. If the quoted numbers are literally barriers of the uncaptured target nuclei, the compound-nucleus barriers are missing and this numerical comparison does not follow from those data alone.
In a thermal reactor, neutron moderation slows fission neutrons so the large low-energy fission cross section of uranium-235 can support a nuclear chain reaction. Fuel composition, moderator choice and geometry must balance production against capture and leakage; capture resonances of uranium-238 during slowing are important losses from that neutron population. The reaction rate per target nucleus depends on the spectrum through , where is differential neutron flux per unit energy. A fast spectrum can access the uranium-238 fission channel and changes this balance. Also, uranium-238 is a fertile material: capture followed by two beta-minus decays can produce plutonium-239, a fissile material, so capture can contribute to breeding even when it causes no immediate fission.
Dating principle. Atmospheric cosmic rays produce secondary neutrons, which can generate carbon-14 through . Carbon then enters atmospheric carbon dioxide and living organisms. While an organism exchanges carbon with its environment, its carbon-14 to carbon-12 ratio approximately tracks that reservoir. After exchange stops, surviving carbon-14 undergoes beta-minus decay, whereas the stable carbon remains. On the closed-sample, constant-initial-ratio model, radioactive decay gives
Thus radiocarbon dating infers elapsed time from the loss of an isotope ratio or of radioactive activity per fixed carbon mass. It dates cessation of carbon exchange, which need not equal the date an object was manufactured or buried. Actual calendar dating also requires radiocarbon calibration and control of contamination and reservoir differences.
Mean lifetime. For exponential decay, the half-life obeys , while the mean lifetime is . Hence
Using gives and .
The mass minimum and beta stability. Treat the supplied masses as nuclear rest energies in , and omit nuclear pairing as instructed. At fixed mass number , the volume and surface terms of the semi-empirical mass formula are constant. Expanding the remaining terms gives a convex nuclear mass parabola,
The continuous minimum in atomic number is therefore
At , the quadratic coefficient is and . The nearest integer is ; the nuclear isobar of minimum mass is nitrogen-14. Maximizing nuclear binding energy alone would omit the neutron-proton rest-mass difference; its continuous optimum is slightly different, but also selects integer here.
The values most useful for checking neighboring decay thresholds are
Consequently carbon-14 can lower its nuclear mass by changing a neutron into a proton:
For bare nuclear masses, the Q value must include the emitted electron mass. Taking ,
The opposite proton-to-neutron conversion would lead to , whose nuclear mass is higher than that of carbon-14. Neither beta-plus decay nor electron capture can bridge that gap by supplying an electron-mass correction. For the nitrogen-14 daughter, both neighboring nuclear masses are higher: by and by . Even electron capture to has . Thus the daughter has no further energetically allowed single beta decay in this model; physical nitrogen-14 is stable.
These threshold numbers belong to the supplied smooth semi-empirical mass formula, not to an accurate prediction of the carbon-14 electron spectrum or its long half-life. Semi-empirical mass errors can change beta-decay thresholds. Also, the instruction to omit nuclear pairing is a model simplification: even does not make physical pairing vanish, and even-even carbon and odd-odd nitrogen need not have the same pairing correction. No omitted pairing coefficient is guessed here.
Activity of modern carbon. Neglect the small contribution of other stable carbon isotopes when counting atoms in a gram. The Avogadro constant gives
The expected radioactive activity of that one gram is
or approximately decays per minute per gram of carbon. A becquerel is one decay per second; the normalization is per gram of carbon, rather than per gram of the entire organic sample.
Artefact age. Its remaining activity fraction is . Inverting the exponential decay law,
This is the radiocarbon age on the supplied constant-initial-activity, -year half-life model. It is not a calibrated calendar date; the sample's historical initial ratio and any later carbon exchange are not supplied.