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Expanding the cosine gives a wave equation $I{\varphi }_{tt}=J{\varphi }_{xx}$ and a gapless phase mode with physical frequency $\sqrt{J/I}|q|$. The exact harmonic lattice frequency is $2\sqrt{J/I}|\sin (q/2)|$. It resembles superfluid sound. In one dimension, Gaussian phase fluctuations and possible compact phase slips require care before inferring true long-range order from this branch.

The normal component of a superfluid describes the momentum and entropy carried by excitations rather than the phase-gradient condensate current. Its velocity need not equal the superfluid velocity. In phenomenological condensate equations, prescribing its motion supplies a reference flow for dissipation; a full two-component fluid theory would also evolve its momentum and energy.

For smooth phase differences, $-J\cos ({\varphi }_{n+1}-{\varphi }_n)=-J+J({\varphi }_{n+1}-{\varphi }_n{)}^2/2+\cdots$. After integrating the angular momenta in the same inverse-energy time coordinate $\tau$, the coupled quantum rotor chain has the fluctuation actionUnit spacing replaces the lattice sum and difference by their continuum limits. The constant energy $-J$ per bond contributes an overall factor $e^{\beta JN}$, suppressed when describing fluctuations. The phase is compact; the Gaussian action describes its smooth sector.

There is an imaginary-time normalization for a coupled rotor chain issue in the printed formula. Factoring out $1/{\hslash }^2$ from the action above places ${\hslash }^{2}J$, not $J$, in its spatial bracket. The printed bracket is therefore correct in $\hslash =1$ units, or with its spatial coefficient redefined as $J_{\mathrm{bracket}}={\hslash }^2{J}_{\mathrm{Hamiltonian}}$. With the same dimensional $J$ as in the Hamiltonian, it lacks that factor.

In physical real time the wave equation is $I{\partial }_t^2\varphi =J{\partial }_x^2\varphi$. The harmonic phase mode of a quantum rotor chain consequently hasThe lattice expression is $\omega (q)=2\sqrt{J/I}|\sin (q/2)|$. The mode is a gapless phase wave analogous to sound in a superfluid, with rotor angular momentum conjugate to its phase. In one dimension this harmonic regime has strong long-distance phase fluctuations rather than true continuous-symmetry long-range order; compact phase slips can change the infrared phase outside the smooth-phase approximation.

Write $\theta =\pi /2-\vartheta$ and $\varphi =\phi$. To quadratic order,After dropping the total derivative $S{\phi }_t$, the quadratic Lagrangian density isIts Euler--Lagrange equations areFor modes proportional to $e^{i(kx-\omega t)}$, nontrivial amplitudes requireThusAt short wavelength the anisotropy is negligible and the quadratic dispersion is that of a conventional ferromagnetic magnon. At long wavelength, easy-plane anisotropy makes the out-of-plane fluctuation the conjugate density of the in-plane phase; eliminating it produces the linear Goldstone sound mode characteristic of a superfluid.

In 1989, William E. Moerner and Lothar Kador reported individual pentacene absorbers in para-terphenyl in Optical detection and spectroscopy of single molecules in a solid by W. E. Moerner and L. Kador (pp. 2535–2538). Different local environments spread photon absorption frequencies; tuning into the sparse wings selected few resonant molecules despite many molecules in the illuminated volume.

Their tunable dye laser focused through a $0.85$ numerical aperture lens onto a $100$–$200\mu \mathrm{m}$ crystal immersed in superfluid helium at $1.6\mathrm{K}$. Frequency modulation accompanied either a $5\mathrm{kHz}$ electric field between coated sapphire disks, detected at $10\mathrm{kHz}$, or a $2\mathrm{MHz}$ quartz shear transducer. An avalanche photodiode measured transmitted-light photon absorption, not fluorescence. Double modulation suppressed residual laser amplitude background.^[ref]

Repeated scans gave the predicted modulated line shape. Blank crystals and off-resonance scans gave background; changing modulation frequency expanded and contracted the feature as predicted. Agreement between both perturbation methods supported the individual-absorber inference. The authors acknowledged out-of-focus molecules and the unlikely alternative of multiple absorbers with exactly coincident frequencies.^[ref]

This is evidence for a selected absorber in a prepared, known chemical substance and host. It does not establish arbitrary unknown molecule identity from one spectral feature, provide an atom-resolved photograph, or count every molecule in the crystal. A measurement sensitive to only a narrow excitation range cannot detect a molecule whose transition lies outside that range. This distinction separates the total particle inventory from the number responding to a particular probe.

Superfluidity is a quantum-fluid response with phase stiffness and flow without viscous dissipation in an appropriate low-speed regime. A superfluid supports a phase-gradient current; defects and excitations can limit that flow. Bose-Einstein condensation concerns macroscopic one-particle occupation and is a distinct criterion: the Gaussian phase stiffness theory can have divergent absolute-phase fluctuations while retaining a cost for gradients.

A gapless mode associated with a canonically paired pair of broken symmetry generators. In an isotropic ferromagnet, the nonzero expectation of $[S^x,S^y]=i{S}^z$ makes two transverse coordinates one dynamical pair, giving one quadratic magnon branch. Broken-generator counting without this pairing would incorrectly predict two independent modes. This contrasts with the linear phase mode of a superfluid.