Coefficient of kinetic friction Created 2026-10-14 Updated 2026-10-20
The coefficient of kinetic friction is the dimensionless quantity for sliding contact with positive normal force in the ideal kinetic friction model. It characterizes the pair of contacting surfaces and their condition. A constant means the model neglects dependence on contact slip speed; unlike the coefficient of static friction, it specifies a sliding force magnitude rather than a no-slip upper bound.
The ratio compares the tangential kinetic friction magnitude with the perpendicular normal force:
Here is the tangential relative velocity defining contact slip. Both numerator and denominator have the same physical dimension, so the coefficient of kinetic friction has no units. It belongs to a contact pair under specified conditions, rather than to one material alone. The coefficient of static friction instead describes the threshold before contact slip; a pull required to start motion cannot be substituted for a sliding measurement.[ref]
As an original model example, stipulate and gravitational acceleration . An already sliding, nonrotating block of total mass is pulled horizontally across a stationary horizontal surface at constant velocity. With no other vertical force, Newton's second law gives . Zero horizontal acceleration then requires a pulling force . Doubling the total mass to gives and . The force doubles while the coefficient of kinetic friction stays by assumption. These numbers are model predictions, not observations or a calibration for a particular material pair.
Figure 1.
Original horizontal sliding model: a 2 kg block has balanced forces at constant speed with a stipulated kinetic friction coefficient of 0.30
. Details.
A constant coefficient of kinetic friction is useful because one ratio can summarize many loads, as tested by load dependence of kinetic friction. It is an empirical approximation over a stated range of normal forces, speeds and surface conditions. It implies no universal independence from speed or apparent contact area: a change of face or sliding regime can change the result. Temperature, wear and lubrication are further conditions to report. Newton's second law still applies when the constant-coefficient approximation fails.[ref]
Coefficient of performance Created 2026-10-14 Updated 2026-10-18
For the cyclic two-side energy balance in refrigerator, define the dimensionless cooling and heating coefficients by
This identity applies even to irreversible machines, provided both coefficients refer to the same operating point, work input and boundary with no additional energy transfer or storage. It does not compare two separately operated appliances. Unlike thermal efficiency of a heat engine, a COP can exceed one: its numerator counts heat moved, including energy taken from another region. [ref]
To obtain temperature-only bounds, impose stronger assumptions: a cyclic machine exchanges heat only with two ideal thermal reservoirs maintained at uniform, fixed absolute thermodynamic temperatures , and receives work through an ideal input carrying no entropy. Include the machine and the heat transfer interfaces in the entropy production accounting. Because its own entropy returns to its initial value each cycle, the Second law of thermodynamics gives
Combining this inequality with gives
Equality requires a reversible thermodynamic process for the entire cycle and its contacts, as in a reversed Carnot cycle. These are Carnot's theorem bounds independent of the working substance. Use kelvin values, not degree Celsius readings, in the numerators; the temperature difference can be expressed in either unit. [ref] [ref]
The diagram fixes and sets , so the reversible bounds are and . The stipulated machine with and satisfies both. Its reservoir entropy production per cycle is . Increasing the temperature lift at fixed lowers both bounds. Equivalently, delivering fixed needs at least
These expressions reveal why a small temperature lift is attractive. Their divergence as is an ideal reversible limit, not a promise of infinite heating or cooling power. For finite heat transfer rates, the working fluid must be colder than the cold bath and hotter than the hot bath; these contact differences produce entropy and increase the internal temperature lift. Dissipative compression and the pressure-reducing restriction of vapor-compression refrigeration supply further departures from reversibility. Thus bath temperatures set an outer bound, not a prediction of real COP. [ref]
Coefficient of thermal expansion Created 2026-10-07 Updated 2026-10-20
The volumetric coefficient of thermal expansion is the fractional volume increase per temperature increase at fixed pressure and composition:
The mass density form requires fixed mass . Its units are ; is another notation for this coefficient. For small temperature changes at fixed pressure,
For a finite change in a single thermodynamic phase, integrate the possibly varying coefficient: . A constant-coefficient approximation gives an exponential, while the displayed linear formula additionally requires .
For an ideal gas at fixed particle number,
Integrating recovers the exact fixed-pressure thermal expansion ratio . Combining expansion with isothermal compressibility gives the local response of any smooth simple compressible system of fixed composition,
The ratio has units . For the one-mole ideal gas state in isothermal compressibility, it is : a increase at fixed volume raises the pressure by about . Maxwell relations identify this same ratio as the entropy slope with respect to volume and give .
Under the Boussinesq approximation, the small fractional mass density change produces buoyancy while mass density is otherwise treated as constant. A positive temperature excess gives reduced gravity in the convention used in natural ventilation. The coefficient therefore converts a heat budget into a buoyancy budget. The same measurable expansion response supplies entropy changes and heat capacity differences through Maxwell relations, connecting fluid motion to equilibrium thermodynamics.
Cold cathode Created 2026-10-18 Updated 2026-10-20
An emitter that supplies electrons without intentional heating.
Cold field emission gun 2026-10-20
A cold field emission gun produces an electron beam by field emission without the high emitter temperature of a thermal source. A narrow energy spread can improve temporal coherence and high-frequency contrast in cryo-electron microscopy.
Cold-junction compensation converts a reading with reference temperature into the equivalent reading for a chosen standard reference. Define the thermocouple reference function , where means , not absolute zero. Additivity of the definite integral gives
The final inverse function requires a suitable one-to-one calibration interval. A terminal thermometer supplies independently; the raw thermocouple electric potential difference supplies only the difference of the two reference-function values. In general, first converting to a temperature and then adding is wrong, because the thermocouple reference function need not be linear. The SCC-TC manual explicitly adds the reference-equivalent voltage before its final voltage-to-temperature conversion.[ref]
For a stipulated model only, take throughout the interval. No actual material pair is assigned this constant. Because degree Celsius differences have the same numerical size as kelvin differences,
In this model and . Adding the correction produces , whose inverse calibration gives . Applying the zero-reference calibration directly to would instead display .
Now physically change only the reference temperature to , leaving the measuring junction at . The raw reading becomes ; the correction becomes , so the corrected total stays . Physically changing the reference changes the measured electric potential difference. Adding a software correction changes its interpretation and leaves the raw reading intact. If the actual reference is but the software still assumes , this model displays .
Figure 1.
Adding the reference-equivalent voltage before inverting the thermocouple reference function
. Calculated constant-Seebeck coefficient-difference example only. The zero-reference line and the raw-reading line differ by . At , adding that correction takes to . Changing the reference to changes the raw reading and the correction in opposite directions. Real calibration curves need not be straight. Details.
An actual implementation in FP-TC-120 and cFP-TC-120 Operating Instructions by National Instruments (p. 7, Cold-Junction Compensation) uses terminal-mounted temperature sensors, reports their reading as “CJ Temperature”, and enables compensation in temperature mode but not voltage mode. This makes the distinction between a raw voltage readout and a compensated temperature readout observable. The specified reference-sensor range also produces an out-of-range indication: a calculated number outside a supported range is not a validated measurement.[ref]
Cold neutral medium 2026-10-20
The cold predominantly atomic neutral phase of interstellar gas, with characteristic temperatures of order . It is denser than the warm neutral phase at comparable thermal pressure. Its existence depends on radiation, grain heating and atomic-line cooling; one universal density or temperature does not define every environment.
Cold working 2026-10-20
Plastic deformation below the temperature range for substantial concurrent recrystallization. It changes dislocation structure and texture; irradiation and later heating can modify the resulting microstructure.
Let the scale factor grow by from an initially thermal photon distribution. geodesic redshift gives , and conserving photons in corresponding comoving frequency bins gives . Inserting Planck's law leaves the same spectral form at temperature . Total photon-number conservation alone would not prove that the entire radiation spectrum stays Planckian; frequency redshift and collisionless propagation are also required. Absorption, injection or spectral mixing can invalidate this one-temperature argument.
When the solid and liquid have the same pressure, equality of chemical potentials implies . With latent heat of fusion , this gives the displayed slope. If solid is less dense than liquid, raising the common pressure depresses the melting temperature. is absolute temperature. This coexistence-curve derivative differs from a thermomolecular pressure difference between equal-density phases.
Compact phase sectors Created 2026-10-20 Updated 2026-10-31
An XY model orientation takes values on a circle, so a circuit around an excluded defect core can carry integer winding number. Smooth single-valued spin waves cannot change that integer without a core event or boundary crossing. The locally quadratic order-parameter phase action therefore describes a sector, rather than automatically summing every compact-field configuration. Vortex-antivortex unbinding changes the large-distance correlation function and renormalized phase stiffness, even though ordinary long-range order is already absent in two dimensions at positive temperature.
Oberlin College's documented demonstration heats a cube internally with a bulb and compares polished aluminium, dull aluminium, black-painted and white-painted faces at the same temperature. The apparatus includes a thermopile and a digital meter. Its preparation specifies 20 minutes of preheating and heater setting 6; these are instructions, not measured outcomes. The thermopile supplies the electrical readout for the relative thermal radiation comparison. Cover it between readings: otherwise detector warming changes its reference temperature. The account reports little difference between painted black and white faces and a larger contrast between shiny and painted faces. The comparison motivates a surface-dependent emissivity and shows why visible color alone is insufficient.[ref]
Equal source temperature is the principal control: it holds the Stefan–Boltzmann law factor fixed. For a sharper comparison, also hold detector distance, viewing angle, viewed area and surrounding temperatures fixed, and record a covered-detector baseline. These are additional diagnostic controls. Under those assumptions, a changed readout can reveal changed directional emissivity averaged over the detector's wavelength response. The demonstration supplies neither an absolute calibration nor a scan over all directions and wavelengths; it therefore does not directly measure total hemispherical emissivity or establish the fourth-power law. Comparing cooling rates would additionally require separating convection, thermal conduction and heat capacity effects, as in net radiative heat exchange.
A hotter stellar core can favor a higher-barrier route despite fewer catalyst nuclei. To isolate this competition, prescribe a local hydrogen burning toy model at fixed mass density , with reference and
Choose and , rounded barrier parameters for a proton pair and proton capture on nitrogen-14. These prescribe the temperature dependence, while the following freely chosen heating normalization incorporates effective nuclear factors and deposited energy:
Here is hydrogen mass fraction, is CNO mass fraction, and is an arbitrary positive unit of stellar energy-generation rate. For and , the reference ratio is by construction. It is not a measured solar ratio. The CNO cycle bottleneck is represented by one effective rate, without evolving the existing proton-proton chain branches or catalyst network.
At , the logarithmic temperature slopes are and . The larger Coulomb barrier gives a steeper fractional response. Because these slopes change with temperature, this example retains the exponential rather than extending two fixed power laws. Writing and gives
provided the bracket is positive. With the chosen composition, . Reducing to at unchanged shifts it to . For , this catalytic route supplies no heat in this model. These are local toy crossovers: a whole star's luminosity requires integrating its stellar energy-generation rate through its stellar composition profile and stellar structure. Nuclear features, plasma screening and changes of the dominant bottleneck limit the model's extrapolation.
Figure 1.
Chosen pp and CNO heating rates and their composition-dependent crossover
. Original local toy rates at fixed density and hydrogen mass fraction 0.70. The CNO-to-pp ratio at 15 MK is chosen as 0.01 for CNO mass fraction 0.01. Exponential barrier responses give crossovers at 20.30 and 23.91 MK for the two catalyst abundances. These are model curves, not stellar measurements or a fitted solar model. Details.
For convective contraction with power-law opacity at fixed stellar mass and opacity normalization, and . Eliminating gives . Thus a larger mean molecular weight moves the track to larger effective temperature at a given luminosity, with . Contraction decreases both temperature and luminosity for this particular opacity exponent.
Compressibility Created 2026-10-14 Updated 2026-10-31
Compressibility measures how readily a sample's volume decreases when its pressure increases. For a simple compressible system with fixed particle number and composition, specify the constraint :
Here denotes pressure, also written elsewhere. The minus sign makes compressibility positive on a mechanically stable equilibrium branch. Its units are inverse pressure, ; its reciprocal is the constrained bulk modulus, measured in pascal units. Holding temperature fixed gives isothermal compressibility; holding entropy fixed gives isentropic compressibility along an isentropic process. The latter describes a reversible adiabatic compression, since an irreversible adiabatic process can increase entropy. [ref]
For an ideal gas, the ideal gas law and the reversible ideal-gas adiabat give, at the same equilibrium state,
Here and are the whole sample's heat capacity at constant pressure and heat capacity at constant volume, and is the heat capacity ratio. Constant is required for the finite-path formula . Reversible adiabatic compression raises the temperature, making the pressure rise more steeply than in an isothermal compression. Thus keeping entropy fixed makes the gas harder to compress locally. For a classical monatomic gas at , , so and ; the corresponding values of the bulk modulus are and .
For a smooth, stable single thermodynamic phase at positive temperature, Maxwell relations also imply
where is the coefficient of thermal expansion. The ideal gas result is one example of this broader link between mechanical and thermal responses. The equality is possible when and the other responses remain finite. These formulas compare equilibrium partial derivatives, rather than arbitrary fast or dissipative compression histories. [ref]
The ratio of compressional to shear elastic wave speeds. Composition, cracks, temperature and fluid saturation all affect it.
Compton cooling by the cosmic microwave background Created 2026-10-07 Updated 2026-10-14
Hot electrons can transfer energy to cosmic microwave background photons through Compton scattering. For a fixed electron fraction and electron temperature well above the radiation temperature, the optically thin gas cooling time scales approximately as . Its volume loss scales with electron density, not with , because the radiation density is independent of local gas density. The process tends toward the radiation temperature; it heats rather than cools electrons colder than that radiation.