Strict positivity throughout phase space is incompatible with compact support. The following calculation uses positive smooth rapidly decaying solutions with all displayed integrals justified; nonnegative cases use the corresponding entropy limits where justified.
Write and use integration over . The two symmetrized weak collision identities are
and
They follow from particle interchange and the angular exchange for elastic collisions. They are the weak identities needed here; no invalid fixed-angle Jacobian is used.
The collision invariants , and obey . Momentum follows from , and energy from . Hence
For the Boltzmann H functional , the spatial transport contribution is a boundary divergence and the term is zero. Set , . The second weak identity with gives the Boltzmann H theorem
Indeed this integrand with its negative sign is for , which is nonpositive. The kinetic H functional decreases; the physical entropy with opposite sign increases.
A first-order phase transition has a discontinuity in a first derivative of the equilibrium free energy, such as the entropy or order parameter. It can have latent heat when the entropy jumps. A continuous phase transition has a continuously vanishing order parameter and no latent heat, with singular higher derivatives and a diverging correlation length. The LG theory compares global minima, not merely the points where a local minimum loses stability.
For the uniform quartic Landau free energy
the equation of state is . At zero field the stable minimum is for , and for . Thus tuning through zero gives a continuous transition. For a fixed , varying through zero instead switches between the two ordered minima and makes jump, giving a first-order phase transition in the conjugate field.
A temperature-like first-order transition can occur at zero field when and a positive sextic term stabilizes the potential. Write . Stationarity of a nonzero phase gives , while equality with gives . Solving these two conditions yields
The order parameter jumps from zero to . At this point
so the competing stationary points are genuinely global minima. This phase coexistence condition differs from the spinodal points and , which mark loss or creation of local stability, not equilibrium coexistence.
If the symmetry permits a cubic term , a positive quartic coefficient does not preclude a first-order transition. For with , stationarity and coexistence give and . This is the first-order transition in a cubic-quartic Landau potential; the symmetry restriction on the expansion is therefore part of the prediction.
Work in a translation-invariant pure thermodynamic phase, and write to distinguish inverse temperature from the order-parameter exponent. The connected correlation function is
Away from criticality in the massive scalar order channel, it decays exponentially, possibly multiplied by an algebraic factor. An exponential correlation length is defined by when that limit exists. At a continuous transition diverges and the critical decay is algebraic. In an ordered symmetric mixture, a nondecaying contribution can remain; selecting a pure branch prevents confusing it with connected critical fluctuations.
Let and . Differentiating the partition function with the energy term gives the correlation-function susceptibility sum rule
If the source is instead the dimensionless , the explicit inverse-temperature factor is absent. In continuum physical coordinates the lattice sum is approximately .
Choose a normalized blocking kernel such that , replacing the sum by an integral for continuous variables. A deterministic example is a product of delta functions imposing that each coarse variable equals the average of spins in a block of sites, with its field normalization included consistently. Define the effective Boltzmann weight by
Kernel normalization makes the blocked partition function exactly equal to the original. Its coarse-grained variables retain the long-distance observables through their defining relation to the original fields. An exact RG step generally generates all symmetry-allowed operators; keeping only a small coupling set is an approximation, not an exact closure assumption. The geometrical coarse lattice has
so its physical volume is unchanged. A subsequent coordinate rescaling may restore the numerical lattice spacing to its initial value, which is the equivalent rescaled-coordinate convention.
Here define as free energy per lattice site, . Exact partition-function invariance gives
Because multiplies the identity operator, a blocking step has , where is the generated constant per blocked site. With this implies
The identity-operator contribution to renormalization-group free energy includes the eliminated modes' entropy, connected vacuum terms and field-measure normalization. It cannot be discarded when calculating an absolute free energy, even though it cancels out of normalized correlation functions.
There is a useful convention behind the word “singular” in this inhomogeneous equation. After removing , still contains a regular coupling-dependent background. If and , then the genuinely nonanalytic part obeys . Thus the printed inhomogeneous representative and homogeneous singular scaling below are consistent after background subtraction. At resonances or marginal points this subtraction may leave additive or multiplicative logarithms; a strictly homogeneous pure-power form is then qualified accordingly.
A renormalization-group fixed point satisfies . Diagonalizing the linearized map gives scaling coordinates . For increasing coarse-graining length, defines a relevant operator, an irrelevant operator, and a marginal operator, whose fate needs nonlinear analysis. Here the are logarithmic scaling exponents: the eigenvalues of the discrete Jacobian matrix are , not the numbers themselves. The critical surface is the stable manifold flowing into the critical fixed point after every relevant scaling field is tuned to zero. A repulsive renormalization-group trajectory leaves the fixed point along relevant directions and flows toward a different long-distance phase.
Figure 1.
Linearized renormalization-group flows in a zero-field slice and the relevant-field plane
. Details.
For the requested two relevant fields, take and , with . Ignoring nonsingular irrelevant corrections and choosing a total blocking scale , the homogeneous singular free-energy density obeys
Choose so the renormalized thermal field is . This proves
Metric factors and regular analytic redefinitions of the scaling fields only change amplitudes. Likewise , so at the correlation-length critical exponent is . Two thermal derivatives of give the heat-capacity critical exponent , proving the hyperscaling relation
Two field derivatives also give ; one field derivative gives , and using to set the blocking scale on the critical isotherm gives . These statements assume that no dangerously irrelevant coupling makes the scaling function singular as it is removed. In particular the naive hyperscaling form need not describe the quartic ordered phase above four dimensions, where its stabilizing quartic coupling is dangerously irrelevant. That restriction reconciles this derivation with the mean-field exponents and Question 3.
The scaling form of the connected correlation function is in the continuum long-distance regime. For , tends to a finite nonzero constant. For , it decays exponentially with a possible algebraic prefactor; an isolated massive pole gives the familiar Ornstein--Zernike correlation function tail with a temperature-dependent amplitude. Exponential decay is the essential feature; the same critical algebraic power need not remain the exact large-distance prefactor.
Using the susceptibility sum rule and spherical integration gives
For and an ordinary exponentially decaying scaling function the integral tends to a finite constant: it converges at zero because is finite, and at infinity because of the exponential decay. Microscopic distances add a regular background. Thus , establishing the Fisher scaling relation
For a continuous field, field scaling and anomalous dimension give
This field renormalization is additional to the canonical engineering factor . It makes . Invariance of the uniform source coupling then gives , agreeing with the susceptibility exponent above. With a convention , the fixed-point choice is ; the sign of the logarithmic derivative depends on this stated convention.
An acoustic analogy is an exact rearrangement of the fluid equations into a chosen linear propagation operator acting on an acoustic variable, with everything left over placed on the right as effective forcing. The rearrangement becomes a sound-prediction method only after a reference medium, boundary conditions and approximations to the forcing are specified. In particular, a right-hand-side term need not represent independently generated sound.
Use Einstein summation convention and write . Differentiating the continuity equation in time and taking the divergence of the momentum equation eliminates :
Set and . Since , the constant has zero Laplacian. The prescribed reference mass density and reference speed of sound are independent of time, so
Combining the two identities gives
Only conservation of mass and conservation of momentum have been used; no equation of state or energy equation was needed. Spatial variation of creates no omitted derivative in this identity, because it multiplies a time derivative. The double divergence of the momentum flux tensor has the structure of an acoustic quadrupole.
For a localized flow, choose the reference fields to match the stationary surrounding medium: and outside the flow, with chosen so there. A uniform surrounding fluid permits ambient constant mass density and adiabatic sound speed, giving the familiar homogeneous wave equation. A nonuniform surrounding fluid calls for its actual stationary reference profiles, extended sensibly through the flow region. This makes the acoustic variable vanish in the unperturbed exterior and minimizes artificial contrast terms. In a uniform isentropic exterior the leading acoustic relation also makes vanish to first order. In a stratified exterior, propagation and entropy-advection effects can remain in , as the next part demonstrates.
At rest, all time derivatives and advective terms vanish. The continuity equation and the stated energy equation are then identities, while the momentum equation reduces to . The reference state need not have uniform mass density or entropy. Assume smooth positive reference pressure and mass density, and retain only first-order perturbations.
The linearized continuity equation, momentum balance and adiabatic energy relation are
The perturbation of multiplies a vanishing reference material derivative, so it does not enter at first order. Differentiate the last equation in time, then substitute the linearized momentum equation:
Expanding the divergence yields the stratified acoustic pressure equation
For a perfect gas, . Put . Then
Thus the divergence-form stratified acoustic pressure equation is
This is homogeneous linear propagation through the static medium, including its inhomogeneity. In the acoustic analogy of part (a), has no first-order contribution when viscosity is neglected and the reference velocity is zero. Nevertheless the chosen left-hand operator lacks the gradient terms in the genuine propagation equation. Those effects must consequently appear in . They describe propagation of an existing disturbance, rather than an independent source. Since reference-field choices also change the division between the operator and forcing, cannot be identified unambiguously with newly generated noise. Its presence in the right-hand side is a consequence of the chosen analogy, not a source-classification theorem.
Let , with , and set . Direct differentiation gives
The heat equation implies , so the bracket vanishes. Conversely its being independent of can be absorbed into a -dependent multiplicative normalization of , leaving unchanged. This proves the Cole-Hopf transformation with the positive sign appropriate to the negative-flux Burgers convention. Although the algebra works for nonzero , the given forward Gaussian function diffusion kernel and a physical vanishing-viscosity limit require .
Take for the stated Burgers N-wave. Integrating and normalizing the exterior value to one gives
This function is continuous at ; its logarithmic derivative has the specified jumps. Convolution with the heat kernel is positive and solves the heat equation for . Splitting the integral into the exterior baseline and the interior correction yields
Put . Completing the square gives
Changing the interior integration variable to changes its limits to and the Gaussian function width to . The Jacobian and normalization leave the factor . Thus the Cole-Hopf solution for a Burgers N-wave is
Here is the normalized Gaussian function mass of its indicated interval. Its explicit error function representation is
For fixed , the Gaussian function concentrates at as . Consequently
away from the endpoints; at the limit is . The transition layer has width . This is an approximate identity argument, not a uniform step approximation across the endpoints.
For fixed and , both interval masses tend to one, and the exponentially large positive dominates the exterior correction. Its logarithmic derivative therefore gives
For , both interval masses are exponentially small and the weighted interior integral is also negligible, while the exterior contribution tends to one. Therefore in the specified far exterior.
An exponentially weighted Gaussian function tail should not be discarded solely because its unweighted interval mass tends to zero. In fact, comparing the order-one exterior term with gives the sharper inviscid Burgers N-wave fronts , not . Away from these fronts, the vanishing-viscosity limit is
Inside , this follows from the sign of in the exponential. Outside , the constrained Gaussian function maximum lies at an interval endpoint and has negative exponent. The right shock wave's speed is , equal both to the derivative of and to minus half the sum of its two limiting states; the left shock wave is its reflection. This checks consistency with the Rankine-Hugoniot condition and shows that the requested near-center and far-exterior approximations are compatible with the full entropy limit.
For a uniform-density stellar model, and . With zero surface pressure, integrate the stellar hydrostatic equation:
Using the ideal gas equation of state, . Therefore
Equivalently and . The constant mass density is imposed as a structural approximation; a perfect gas can realize it hydrostatically by allowing its temperature and entropy to vary with radius.
The stellar adiabatic exponents are fixed-composition, constant-specific entropy derivatives:
The chain rule gives . Define the pressure derivatives and . The first law of thermodynamics, with , gives
Combining this with on an adiabat gives
Thus the specific-heat ratio is not generally equal to the three stellar adiabatic exponents.
For the mixture, and . The specific heat capacity at constant volume, obtained by differentiating at fixed mass density, is
Therefore the adiabatic exponents of a monatomic gas-radiation mixture and its specific-heat ratio are
If a relation involving only the exponents is wanted, eliminate from :
For a pure monatomic perfect gas, and . For any calorically perfect gas with constant heat capacities, the same equality holds with its own . In a genuine gas-radiation mixture, , while the exponents are given separately above.
In the radiation limit, and the adiabatic temperature gradient is . This follows independently from photon entropy: a comoving volume has , so an adiabat obeys and . However, is singular in the pure-radiation limit, not . This is the pure-radiation constant-pressure heat-capacity singularity. The equation fixes temperature whenever pressure is fixed, so an ordinary constant-pressure temperature derivative is not available; along the mixture limit and . For photons alone, mass-specific quantities additionally require a material mass label. The often quoted radiation index is its pressure-density adiabatic exponent, not a finite constant-pressure/constant-volume heat-capacity ratio.
For a fixed polytropic index and fixed equation-of-state constant , let be the first zero of the regular Lane-Emden equation solution. A finite-radius model requires such a zero; for the usual nonnegative indices this holds for . The surface radius and mass follow from and :
The last equality integrates the Lane-Emden equation; define the positive Lane-Emden surface mass constant . Substituting gives
The central-density exponents cancel when the required powers are taken. Thus the polytropic mass-radius relation is
It is independent of , with and composition held fixed. For the radius is fixed; for the mass is fixed. These limiting powers need no division by a vanishing exponent.
For , the literal pressure-density power and the supplied expression for are singular. Interpret this case separately as an incompressible planetary interior with constant density. Then , or at fixed density. A weakly compressed rocky body, or a rough uniform-density approximation to Earth, is an example; realistic terrestrial planets are stratified and compressible.
For , . This describes a cold nonrelativistic degenerate electron gas of fixed composition, or a fully convective monatomic ideal gas at fixed entropy. Examples are a nonrelativistic white dwarf, a sufficiently cooled partly degenerate brown dwarf as an approximation, and an approximately fully convective low-mass star for the ideal-gas version. The fixed- scaling is . It must not be applied to an entire main-sequence stellar sequence with different entropies; the entropy dependence of a polytropic mass-radius relation explains the distinction.
The mass-radius curve of solar-composition substellar objects reflects the transition from weak compression to pressure ionization and electron degeneracy pressure, followed by sustained hydrogen burning. A schematic joining representative object classes is:
The illustration is not an age-specific numerical evolutionary model. In particular, ice giants contain much more heavy material than a solar-composition giant, so a single uniform-composition equation of state does not describe the entire joined curve.
Planet/brown-dwarf naming conventions and deuterium burning do not define a universal discontinuity in the mass-radius relation. Composition, age and irradiation move the curves; the hydrogen-burning transition changes the long-term energy source more fundamentally.
The hot-Jupiter radius inflation problem is that some strongly irradiated giant planets have radii much larger than standard age-, mass- and composition-dependent cooling models predict. Greater internal entropy generally means a larger radius at fixed mass. The two broad classes of explanation are retaining existing heat by delaying cooling and depositing additional energy into the deep planet.
  • Enhanced atmospheric opacity slows radiative leakage and keeps the deep interior hot. Required enrichment or persistent cloud opacity must be compatible with composition and spectra; adding heavy material also tends to increase density. Insulation can preserve initial heat but cannot necessarily reinflate an already cooled planet.
  • Layered convection in a giant planet uses a stabilizing composition gradient and double-diffusive layers to reduce heat transport. The needed gradient and layer structure must survive mixing, and their efficiency is model-dependent; very inefficient transport cannot simply be assumed for every planet.
Surface or upper-atmosphere heating that is promptly reradiated need not raise deep entropy. The depth and long-term power budget distinguish an effective inflation mechanism from one that merely changes a photospheric temperature.
Use inverse temperature , reserving without a subscript for the critical exponent. Write ; each undirected bond occurs once, so the number of bonds is . In the mean-field theory of the Ising model, write each Ising spin as and neglect the product of fluctuations:
The resulting independent-spin statistical Hamiltonian is
The constant corrects the double counting of interaction energy. The Ising spin sums now factorize and can all be evaluated:
This is the approximate partition function at an assumed mean field; equilibrium fixes self-consistently. The corresponding Ising auxiliary mean-field free energy is
Its equilibrium value gives the mean-field Helmholtz free energy in the imposed field. Away from a stationary point its parameter is an assumed field variable, not necessarily the actual mean Ising spin of that independent-spin distribution.
For the full small- expansion at fixed , set and . Differentiating gives successive derivatives , , , and at . Therefore
At zero field, spin inversion symmetry eliminates odd powers and this simplifies to
The quadratic coefficient changes sign and the quartic coefficient is positive at
Thus the zero-field mean-field prediction is a continuous, continuous phase transition: the stable zero spin magnetization develops two symmetry-related nonzero minima continuously below .
Both requested routes give the same mean-field self-consistency equation. First, the one-spin expectation in the effective field is
Second, differentiating the Ising auxiliary mean-field free energy gives
whose stationary condition is precisely that mean-field self-consistency equation. Choose its stable, lowest-free-energy branch rather than every algebraic solution.
An equally useful mean-field approximation parametrizes the trial distribution by its actual mean Ising spin. Its probabilities are , giving the Bragg-Williams free energy of the Ising model
This energy-minus-entropy function has expansion
Its stationary equation is , again equivalent to the mean-field self-consistency equation. The two functions differ away from equilibrium, but agree on stationary branches: for and , the entropy bracket equals . Their small- coefficients therefore need not agree at arbitrary temperature; at they have the same leading critical quartic coefficient . This distinction prevents confusing the auxiliary-field expansion with the physical-magnetization variational expansion.
For the order-parameter critical exponent, expand the equation of state at :
On a nonzero stable branch,
Hence . The spontaneous magnetization is understood by selecting a branch with an infinitesimal field after the thermodynamic limit; a finite symmetric sample has zero exact zero-field mean Ising spin.
For the magnetic susceptibility per site, define with in energy units. Implicit differentiation gives
Above , and . Below , evaluated on a selected ordered branch, the expansion of gives . Thus the magnetic-susceptibility critical exponent is on both sides, with different amplitudes. At , the equation of state becomes
so the critical-isotherm exponent is . These are mean-field critical exponents, not a claim that neglecting fluctuations gives the exact Ising transition in every dimension.
Take a homogeneous comoving cell of physical volume and total entropy . At vanishing chemical potential, the reversible first law of thermodynamics reads
For an extensive equilibrium system, the thermodynamic Euler relation is . At this gives
The supplied pressure identity verifies consistency directly: implies
The thermodynamic Euler relation fixes the additive normalization that a differential identity alone would leave undetermined.
For adiabatic cosmological expansion, the cosmological perfect-fluid continuity equation gives , while . Hence
This proves cosmological entropy conservation in the stated perfect-fluid approximation. Kinetic equilibrium alone does not guarantee adiabatic evolution: entropy injection, dissipative stresses or out-of-equilibrium reactions would require additional source terms. Those effects are implicitly excluded in this calculation.
During the cannibal phase of a decoupled sector, cosmological entropy conservation and the leading result of part (c) give
Differentiating and using yields logarithmic cooling during cannibalism:
Here absorbs the entropy normalization, and the logarithmic expression is a large- asymptotic relation. With fixed visible entropy degrees of freedom the photon bath has . Thus for the scalar particles cool much more slowly than the photons and become relatively hotter.
The physical reason is that converts rest-mass energy into kinetic energy of the remaining particles. Elastic scattering distributes this energy, offsetting much of the cooling caused by expansion. The total comoving entropy remains constant; the number density does not merely dilute as . This explanation applies only while number-changing chemical equilibrium persists. If those reactions freeze out, an isolated number-conserving nonrelativistic gas instead has under adiabatic expansion, which is faster cooling than the photons. The paper supplies no rates, so that transition time cannot be determined.
Work first in units . Black-hole thermodynamics starts with the laws of black-hole mechanics. For a connected stationary regular Killing horizon, the Zeroth law of black-hole mechanics makes its surface gravity constant when the Einstein field equations and dominant energy condition hold. This parallels uniform equilibrium temperature. For neighboring stationary asymptotically flat four-dimensional Einstein-Maxwell black holes, the First law of black-hole mechanics is
where is the horizon angular velocity and its electric potential relative to infinity. The last terms are rotational and electromagnetic work, analogous to the work terms in . The second law of black-hole mechanics, expressed by Hawking's area theorem, makes the total future horizon area nondecreasing for classical matter obeying the null energy condition and global assumptions such as strong asymptotic predictability. The third law of black-hole mechanics is an unattainability statement: subject to the usual regularity assumptions, the weak energy condition, and a bounded stress-energy tensor, no finite physical process reduces the surface gravity of a regular horizon to zero. It does not assert that extremal black holes have zero area or zero entropy.
Classical geometry alone fixes an analogy, not a nonzero physical temperature. Quantum field theory supplies Hawking temperature . Comparing the area term of the first law with gives for nonextremal holes, and hence the standard Bekenstein-Hawking entropy. Restoring physical constants,
Here restored is the physical acceleration surface gravity and is the squared Planck length. The first-law comparison determines the area coefficient, leaving an additive entropy constant unspecified; the displayed formula is the usual convention. Its area scaling, rather than ordinary volume scaling, signals that the available thermodynamic degrees of freedom of a gravitating system are constrained by the horizon geometry.
Particle production explains the quantum input. For a real scalar field obeying the massless covariant wave equation, the Klein-Gordon inner product on solutions is
The wave equation makes its current divergence-free, so the product is independent of a Cauchy hypersurface when the boundary flux vanishes. Use suitably normalized wave packets or the appropriate continuum distributions. Asymptotic past and future Minkowski spacetimes give preferred positive-frequency solution mode bases and , normalized by , and . Between those regions, a nonstationary geometry generally has no preferred positive-frequency splitting.
The mode bases are related by a Bogoliubov transformation,
The last identities follow from conservation of the Klein-Gordon inner product and are the canonical identities for a bosonic Bogoliubov transformation. Expanding the field in either complete basis and extracting its positive-frequency coefficient gives
Thus the state annihilated by every has
This particle number from Bogoliubov coefficients is nonzero when time evolution mixes positive and negative frequencies. It describes one state as vacuum in the early particle basis and populated in the late basis; it does not require an arbitrary choice of a vacuum at each intermediate time. For a finite implementable transformation the state remains a squeezed pure quantum state. In infinitely many modes, a common unitary bosonic Fock space implementation requires additional conditions, such as the beta map being a Hilbert-Schmidt operator; finite wave packet observables need not share every global divergence of an ideal continuum calculation.
For gravitational collapse, the future is not globally Minkowski: it contains a black hole. The relevant late out-basis includes modes reaching future null infinity together with modes entering the future event horizon. Modes on infinity alone are not a complete Cauchy basis. Nevertheless the same mode-mixing calculation determines the outgoing particle flux. Near a nonextremal horizon, the logarithm in the tortoise coordinate converts regular early null coordinates into the Hawking exponential ray map
where is the early affine null coordinate and is late retarded time at infinity. Backward propagation of a late outgoing mode gives a factor for . Its positive- and negative-frequency Fourier integrals differ by analytic continuation around the logarithmic branch. With a convergence regulator they reduce to
Taking gives the thermal ratio of Hawking Bogoliubov coefficients, . Combining this with the canonical normalization yields the bosonic occupation . Late-time wave packets turn formal continuum coefficients into a finite number flux.
A Schwarzschild black hole has , so this spectrum has . The exterior curvature potential partly reflects the outgoing modes. Its transmission probabilities are the greybody factors, giving, for one massless scalar species in the stationary late-time approximation,
Thus the horizon temperature is universal, while the spectrum received at infinity is not a perfect featureless blackbody radiation spectrum. The derivation assumes the near-horizon quantum state inherited from a regular collapse vacuum and ignores rapid backreaction over the timescale of the packets. Exponentially blueshifted precursor frequencies indicate the usual short-distance assumption in the semiclassical calculation, not an independently demonstrated quantum-gravity description of the endpoint.
The outgoing positive energy flux drives black-hole evaporation. At leading order for a large isolated Schwarzschild black hole, area scales as and temperature as , giving and a lifetime of order , with the coefficient depending on species and transmission factors. Its negative heat capacity of a Schwarzschild black hole, , means that it heats up as it loses mass and cannot be in stable canonical equilibrium with an unlimited thermal reservoir. The approximation fails when quantum-gravitational scales are reached and does not fix whether the endpoint is complete evaporation, a remnant, or something else.
Area loss does not contradict the classical area theorem, because the quantum stress-energy tensor need not obey the classical null energy condition; negative horizon energy accompanies the positive outgoing flux. The appropriate thermodynamic statement is the generalized second law, involving . Finally, Hawking radiation raises the black hole information paradox: if a pure quantum state completely evaporates into an exactly thermal mixed quantum state and its partners disappear, the result conflicts with ordinary unitary time evolution. Early outgoing radiation can be mixed simply because of its entanglement with interior modes while the complete state remains a pure quantum state; that fact alone is not information loss. Resolving the fate of all correlations through the evaporation endpoint requires more than the leading semiclassical flux calculation.
Assume a single-phase ideal gas mixture in a closed parcel, with common temperature , total pressure , and molar species amounts . Define and volume mixing ratios , so . Ideal mixing makes partial pressure .
For a pure ideal species, , with molar volume . At fixed temperature, integration from standard pressure gives
The same logarithmic composition term follows from the ideal mixing entropy . Extensivity gives . Hence the Gibbs free energy of an ideal-gas mixture is
Equivalently, write each standard chemical term as , using molar enthalpy and entropy. For zero abundance the limit defines the extensive expression continuously.
The fractions alone do not specify the extensive Gibbs free energy: the total amount or an equivalent elemental inventory must also be fixed. Moreover, in a chemically closed reacting system need not remain constant; for example, hydrogenation of carbon monoxide changes the total molecular count while conserving atoms. Minimization is therefore over species amounts subject to elemental constraints, rather than over fractions with an artificially fixed molecular count. Nonideal gases require activities or fugacities; condensates contribute separate phase terms.
Assume the planet and present-day Jupiter have the same mass, comparable composition and initial cooling normalization, and both can be described by the supplied power-law planetary cooling over the relevant ages. Take the age of present-day Jupiter to be and the young planet's age to be . The normalization cancels:
The 5-AU orbit is used to regard stellar irradiation as modest compared with a hot-Jupiter orbit; the ratio is specifically intrinsic cooling, not the sum of intrinsic and reradiated luminosity. Initial entropy and irradiation can change the assumed normalization, so this estimate is not independent of formation conditions.
Such a young self-luminous giant is a favourable target for near-infrared exoplanet direct imaging. The increased intrinsic luminosity improves its contrast with the host star, and a wide physical orbit is more readily separated on the sky than a hot-Jupiter orbit. Two essential observing considerations are:
Thus direct imaging of a nearby young system, with sufficient angular resolution and contrast, is the natural discovery method, subject to the actual stellar brightness and instrumental limits.
Hot-Jupiter radius inflation is the excess radius of many irradiated gas giants relative to standard cooling models of the same mass, composition and age. A young gas giant starts with high entropy and a large radius, but ordinarily contracts through Kelvin-Helmholtz contraction. An old inflated object must either retain that thermal reservoir unusually well or receive power that affects the deep interior.
The first class is delayed cooling of an inflated giant planet. Two specific mechanisms are increased atmospheric opacity, which makes internal radiation escape less readily, and inhibited interior convection caused by composition gradients, potentially with layered transport. Both slow entropy loss. Stellar irradiation can also maintain an outer radiative blanket, but an appropriate irradiated boundary is already included in many baseline models and does not alone explain every extreme radius.
The second class is heating of an inflated giant planet. Two mechanisms are tidal heating from eccentricity, obliquity or other time-dependent tidal forcing, and Joule heating from wind-driven electric currents in an ionized atmosphere coupled to the magnetic field. Mechanical energy carried inward from atmospheric circulation is another candidate. Heating must be deposited sufficiently deeply and with sufficient power; superficial absorption that is promptly reradiated is not equivalent to deep interior heating. A circular synchronized isolated orbit does not automatically provide a persistent tidal source.
The classes can coexist and are tested through radius-age-irradiation trends, orbital properties and the required energy budget. Merely changing an observed transit altitude by a few atmospheric scale heights is generally distinct from inflating the bulk giant-planet interior.
At fixed mass, three broad controls of a super-Earth-sized body's observed radius are:
Bulk composition, envelope fraction/composition, and thermal/irradiation history are three independent controls. If mass is not fixed, the mass itself is an additional major variable. The label super-Earth does not ensure a rocky composition or an Earth-like atmosphere, and a radius alone does not determine which of these effects dominates.
For a quasistatic spherical star with fixed total mass, the stellar structure equations in radius are
Here is the specific entropy of a moving mass shell, and the entropy term accounts for release or storage of thermal and gravitational energy. In thermal equilibrium it vanishes. An equation of state, opacity, energy-generation law and composition evolution close the equations. The absence of mass loss fixes the outer mass coordinate; it does not require the star to be in thermal equilibrium.
The radiative temperature gradient needed to carry the full luminosity is
Here the actual temperature gradient is . For uniform composition the Schwarzschild criterion says that a radiative layer is stable if , with marginal stability at equality, where the adiabatic temperature gradient is . Use there. If , convection carries some of the flux. Efficient convection gives ; inefficient surface convection needs a transport prescription and can be superadiabatic. For composition gradients, use the Ledoux criterion, with threshold instead. Here , and , using the mean molecular weight .
Above the thin burning shell, take constant luminosity , constant mean molecular weight , ideal-gas pressure with , and the Kramers' opacity law . Then the temperature equation is
To implement the printed assumption that and are all power laws while retaining mass conservation, write , , and . The mass equation gives ; the ideal gas law gives ; hydrostatic equilibrium gives . The diffusion equation gives . Solving this linear system gives the self-gravitating Kramers power-law envelope:
The coefficients can also be matched consistently. If is the core boundary and its enclosed mass,
Radiative transfer fixes the constant luminosity through
whose right-hand side is independent of radius for these exponents. Thus this is a solution of all four envelope equations, not just a dimensional estimate.
Matching the boundary temperature to the isothermal core and extrapolating the idealized power law to the specified photosphere gives
For reference , so the envelope mass is not negligible in this particular solution. The given fixes the core-radius normalization ; a numerical absolute radius needs the unspecified molecular weight. The exponent ratio also gives , so the fully ionized monatomic version of this idealization is convectively stable.
A different common approximation neglects the envelope's self-gravity and sets in the force equation. It cannot obey the exact mass equation with a nonzero density and exactly constant . Under that additional approximation, the same calculation instead gives
This is the constant-core-mass power-law opacity radiative envelope limit, not the full power-law solution with changing enclosed mass. Stating which approximation is used resolves the otherwise different numerical radius ratios.
A compact nearly isothermal core, a thin luminosity-producing shell and a much larger cool envelope describe a shell-burning red giant. The full power-law profile is a deliberately simple model. The Kramers' opacity law and an ionized ideal gas are not reliable at a photosphere; partial ionization, other opacity sources and a convective envelope usually modify real cool giants. The quoted radius ratios are extrapolations within the stipulated model.