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A photon gas is a collection of photons described statistically as radiation. Here the equilibrium model is homogeneous, isotropic electromagnetic radiation in vacuum at temperature $T>0$: each photon has energy $E=c|\mathbf{p}|=h\nu$, with momentum $\mathbf{p}$ and frequency $\nu$, and there are two independent transverse states of electromagnetic polarization. An absorbing cavity with walls at a common temperature provides a way to establish this thermal equilibrium. The bulk formulas assume cavity dimensions much larger than the typical wavelength $hc/(k_{B}T)$, so the electromagnetic mode density in a box can replace individual cavity modes by a continuum. ^[ref]

The crucial constraint is whether photon emission and photon absorption, or other number-changing processes, can equilibrate the photon population. When they can, photon number is not an independently conserved quantity and the equilibrium photon chemical potential is ${\mu }_{\gamma }=0$. For each polarization and frequency, the mean occupation number then follows the Bose-Einstein distribution:If number-changing processes are ineffective but number-conserving interactions redistribute energy, a constrained Bose-Einstein distribution can instead have $f=[\exp ((h\nu -{\mu }_{\gamma })/(k_{B}T))-1{]}^{-1}$ with chemical potential ${\mu }_{\gamma }\le 0$ fixed by the number constraint. Thus thermal equilibrium with respect to energy exchange alone does not establish ${\mu }_{\gamma }=0$. The zero value can also persist in an already prepared Planck photon distribution during suitable subsequent evolution; continual photon emission is not required to preserve it. ^[ref]

Combining $f$ with the two-polarization density of states, $g_{\nu }/V=8\pi {\nu }^2/c^3$, gives the Planck photon distribution and the spectral photon energy density:Here $B_{\nu }$ is the spectral radiance in Planck's law; $u_{\nu }$ is stored energy density per unit frequency, not outgoing power per area. Their different units are connected by the full-sphere solid angle and the speed of light $c$. The Boltzmann constant is $k_B$, and $h$ is the Planck constant. ^[ref]

The equilibrium equation of state is particularly simple:The radiation constant $a_R$ is the same constant called $a_{\mathrm{rad}}$ in black-body radiation; $\sigma$ is the Stefan-Boltzmann constant. An outline of the energy density calculation substitutes $x=h\nu /(k_{B}T)$ and uses ${\int }_0^{\infty }{x}^3/(e^x-1)dx={\pi }^4/15$. The radiation pressure follows because the angular average of the squared directional component of photon momentum is $1/3$ for isotropy; the thermodynamic derivation of blackbody radiation pressure supplies an independent route. These formulas describe the radiation contribution, not the cavity walls. The isotropic massless relation $p=u/3$ survives a different isotropic spectrum, whereas the coefficient in $u=a_R{T}^4$ requires the zero-chemical potential Planck photon distribution.

For a computed example with stipulated $T=2.725\mathrm{K}$, the photon energy density is $u\simeq 4.17174\times 10^{-14}\mathrm{J}{\mathrm{m}}^{-3}$ and the radiation pressure is $p\simeq 1.39058\times 10^{-14}\mathrm{Pa}$. The photon number density in the International System of Units isHere $\zeta$ is the Riemann zeta function. The mean photon energy differs from the energy at the peak of a spectral curve: counting photons and weighting them by energy emphasize different frequencies. The calculations use the exact International System of Units values of the Planck constant, Boltzmann constant and speed of light. ^[ref]

A motivating observation is the cosmic microwave background spectrum measured by the Far Infrared Absolute Spectrophotometer (FIRAS) aboard COBE. Its apparatus used a polarizing Michelson interferometer, with one input viewing a roughly seven-degree sky patch and the other an internal blackbody. Scanning mirrors changed the optical path length difference; heat-sensitive detectors recorded the varying power, and Fourier transform spectroscopy recovered the spectral difference. Operation outside the terrestrial atmosphere removed atmospheric emission and absorption, while shielding and cooling the optics in a helium cryostat suppressed the instrument's own radiation. ^[ref]

Absolute calibration came from moving an external blackbody into the sky aperture, filling the same beam used for the sky. This was an iron-loaded epoxy absorber shaped as a re-entrant cone. Repeated reflections made it a close approximation to a blackbody, while thermometers supplied its temperature. Mather and colleagues explicitly evaluated reflections, temperature gradients, radiation leaking through the material and leakage around its edge. These are limits on how faithfully the calibrator realizes thermal equilibrium radiation, rather than details that can be eliminated merely by calling it black. ^[ref]

During sky observations the internal blackbody temperature was adjusted to nearly null the spectral difference, reducing gain and drift errors. Fixsen and colleagues' 1996 analysis used calibrated spectra over wavenumbers $2$ to $21\mathrm{c}{\mathrm{m}}^{-1}$, about $60$ to $630\mathrm{GHz}$. They separated the sky's spatially uniform component, its dipole and Galactic emission, and varied sky cuts and foreground templates as controls. The resulting cosmic microwave background spectrum agreed with a single Planck function, with reported RMS deviations below 50 parts per million of its peak brightness. This is a residual statistic over the analyzed spectrum, not a pointwise relative error bound at every frequency. ^[ref]

The observation motivates using a photon gas as a physical model rather than merely a formal counting exercise. Its interpretation has a clear boundary: agreement with Planck's law constrains departures from an equilibrium spectral shape within the calibrated band and foreground assumptions; it does not directly measure radiation pressure or entropy density of a photon gas. Nor does it establish that today's cosmic microwave background is continually re-equilibrating with matter. A previously thermal spectrum can retain its Planck function shape as expansion of the universe lowers every photon frequency in the same proportion. The usefulness of the model is that one measured spectral temperature, together with its equilibrium assumptions, predicts energy density, radiation pressure, photon number density and entropy density of a photon gas consistently.

Nonrelativistic matter density grows as $(1+z{)}^3$, whereas freely redshifting photon energy density grows as $(1+z{)}^4$. Their equality gives the displayed redshift. Radiation inferred solely from a cosmic microwave background temperature excludes the relic neutrino energy density, so the resulting redshift differs from total matter-radiation equality. Comparing density parameters at one epoch is equivalent to comparing the densities because their common critical-density denominator cancels.

Many ionic crystals have high melting temperatures compared with small molecular solids, because reorganizing their strongly interacting ions costs energy. But melting leaves a dense liquid with interactions; it does not perform the complete separation defining a lattice energy. At fixed pressure, the transition occurs when the Gibbs free energies of the solid and liquid match. The relevant enthalpy and entropy differences both matter, so lattice energy alone is not a universal ordering of melting temperatures. Strong covalent bonds in extended networks can also give high melting temperatures.^[ref]

A physiological effector performs the action that changes the regulated physiological variable. In thermoregulation, sweat glands, changes in skin blood flow, and skeletal muscle shivering contribute different actions. The command, the action and the resulting temperature are three distinct readouts. ^[ref]

A physiological sensor detects a relevant condition and changes a signal. In thermoregulation, temperature-sensitive neurons supply information about internal and skin temperature. Sensing a disturbance and sensing its internal consequence need not be the same operation.

A physiological set point is a reference around which regulation is organized, analogous to a reference signal. An observed average is not automatically a separately encoded target. A range of acceptable values and different response thresholds can be more informative than a single exact number. Negative feedback describes a causal sign; neither perfect constancy nor complete restoration follows from that sign alone.

For core body temperature, circadian rhythms and fever can change the defended level. Thus a response toward the current physiological set point need not restore yesterday's temperature. A drifting target and imperfect tracking of a fixed target are different explanations for a changing readout. ^[ref]

The pKa is the negative base-ten logarithm of the dimensionless acid dissociation constant. A lower pKa means a larger acid dissociation constant and a stronger tendency to donate a proton under the same standard state, solvent, and temperature conventions. The Henderson-Hasselbalch equation places equal weak acid and conjugate base thermodynamic activities at pH equal to pKa. See Flowers et al., Chemistry 2e, the Henderson-Hasselbalch equation.

Take a homogeneous material exhibiting superconductivity in the half-space $z\ge 0$, bounded by vacuum at $z=0$. Fix the temperature below the superconducting transition temperature, take a constant positive London penetration depth ${\lambda }_L$, and assume a local, linear London equation description in a Meissner state. The applied magnetic field is weak enough that it neither nucleates a quantum vortex nor appreciably suppresses the material's superconductivity. Assume translation invariance in $x,y$, no imposed transport electric current, and a tangential boundary magnetic field $\mathbf{B}(0)=B_0\hat{\mathbf{x}}$. Here $B_0$ is the local surface magnetic flux density, equal to the imposed vacuum magnetic field in this infinite planar geometry; it is not automatically the far-away applied value for a finite object.

For a bounded, decaying interior solution, the London equations, magnetostatic Ampère law and Gauss's law for magnetism giveThe solution isAt one London penetration depth the magnetic field is $e^{-1}\simeq 0.368$ of its surface value; at five it is $e^{-5}\simeq 0.00674$. There is no finite depth where this exponential is exactly zero. The differential equation excludes the growing exponential through the deep-interior boundary condition. A constant normal component cannot decay in this geometry: Gauss's law for magnetism would require ${\partial }_z{B}_z=0$. A perpendicular applied magnetic field on a finite plate therefore requires a different spatial problem.^[ref]

Astronomy and Astrophysics 571, A16. temperature and lensing-potential analysis under the standard cosmological model and tested extensions. This precedes the January 2015 examination; it is distinct from the February 2015 parameter release.

For photons in thermal equilibrium at temperature $T$, Planck's law gives the photon number density per frequency interval. In terms of the Planck function, it is $dn/d\nu =4\pi B_{\nu }(T)/(ch\nu )$, hence

Planck's law gives the spectral radiance of an ideal blackbody in thermal equilibrium at absolute temperature $T>0$. It predicts how much power is carried in each small frequency or wavelength interval, per projected area and per solid angle. The whole curve is determined by $T$: no material-specific parameter enters this ideal Planck function.

Writing $\nu$ for frequency in hertz and $\lambda$ for wavelength in metres, the two forms of the Planck function areHere $h$ is the Planck constant, $k_B$ the Boltzmann constant, and $c$ the speed of light in vacuum. Their exact values in the International System of Units are $h=6.62607015\times 10^{-34}\mathrm{J}\mathrm{s}$, $k_B=1.380649\times 10^{-23}\mathrm{J}{\mathrm{K}}^{-1}$, and $c=299792458\mathrm{m}{\mathrm{s}}^{-1}$. ^[ref]

The units matter: $B_{\nu }$ is measured in $\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}\mathrm{H}{\mathrm{z}}^{-1}$, whereas $B_{\lambda }$ is measured in $\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}{\mathrm{m}}^{-1}$. Both are spectral radiance, rather than radiant exitance or energy density. To report $B_{\lambda }$ per micrometre, multiply its per-metre value by $10^{-6}$; a micrometre-wide interval is $10^{-6}$ metres wide.

For a computed example, at $T=6000\mathrm{K}$ and $\lambda =0.500\mu \mathrm{m}$, the exponent is $hc/(\lambda k_{B}T)\approx 4.79592$. Substitution into Planck's law gives $B_{\lambda }\approx 3.17569\times 10^{13}\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}{\mathrm{m}}^{-1}$, or $3.17569\times 10^7\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}$ per micrometre. At the same wavelength, the illustrative temperatures $3000\mathrm{K}$ and $4500\mathrm{K}$ give $2.60268\times 10^5$ and $6.37793\times 10^6$ in the latter units. These are ideal predictions for stipulated temperatures.

The key change of variables is $\nu =c/\lambda$. Corresponding positive intervals carry the same power, so $B_{\lambda }d\lambda =B_{\nu }|d\nu |$ andEqual-width wavelength intervals have unequal widths in frequency; the factor $c/{\lambda }^2$ compensates for this. Merely replacing the horizontal-axis labels of $B_{\nu }$ by $c/\nu$ does not produce $B_{\lambda }$. This explains the frequency and wavelength peaks of Planck's law.

A short derivation uses the Boltzmann distribution for a single electromagnetic mode with thermal energies $nh\nu$, $n=0,1,\dots$. Put $q=e^{-h\nu /(k_{B}T)}$. The geometric series gives $Z={\sum }_{n\ge 0}{q}^n=(1-q{)}^{-1}$ and mean thermal energy $h\nu q/(1-q)$. The electromagnetic mode density in a box, including both independent polarization of an electromagnetic wave states of a photon, is $8\pi {\nu }^2/c^3$ per volume per unit frequency. Multiplication gives spectral energy density $u_{\nu }=8\pi h{\nu }^3/[c^3(e^{h\nu /(k_{B}T)}-1)]$; isotropy gives $B_{\nu }=c{u}_{\nu }/(4\pi )$. This counts thermal excitation energy, excluding zero-point energy. ^[ref]

Planck's law connects quantum mechanics to a measurable radiation curve. Its small-$h\nu /(k_{B}T)$ limit is the Rayleigh-Jeans law, $B_{\nu }\approx 2k_{B}T{\nu }^2/c^2$; its large-$h\nu /(k_{B}T)$ limit is the Wien approximation, $B_{\nu }\approx (2h{\nu }^3/c^2)e^{-h\nu /(k_{B}T)}$. The suppression at high frequency makes the total energy density finite. Integrating the curve gives the Stefan–Boltzmann law, while locating its peak gives Wien's displacement law. Thus one formula predicts both the spectral shape and the total emission.

The spectral energy distribution of a planetary nebula combines hot central-star radiation, nebular free-free/free-bound/two-photon continua, recombination and collisionally excited lines, infrared dust emission and sometimes molecular emission. Ionizing-photon supply, gas thermal/ionization balance, density, composition, geometry and extinction determine their relative strengths. A line-dominated broad-band flux is not by itself a continuum temperature measurement.

A planetary surface energy balance equates absorbed short-wave radiation and heat supplied from below with reflected short-wave radiation and emitted long-wave radiation. With incident flux $F_r$, Bond albedo $\alpha$, conductive upward flux $F_c$, and emissivity $ϵ$,

For blackbody star and planet observed at one common wavelength sufficiently long for the Rayleigh-Jeans law to hold for both,This follows by substituting $B_{\lambda }=2c{k}_{B}T/{\lambda }^4$ in the thermal eclipse depth. A radiative flux ratio alone does not determine the radius without a planetary brightness temperature and a stellar temperature. Spectral peaks interpreted with Wien's displacement law must refer to $F_{\lambda }$, not $F_{\nu }$ or $\lambda F_{\lambda }$.

A resistance thermometer using platinum as its sensing material. It provides the temperature readout in the saturation-pressure equilibrium measurement.

Transduction turns electrical resistance into a temperature indication. A uniform wire has $R={\rho }_{\mathrm{el}}\ell /A$, with electrical resistivity ${\rho }_{\mathrm{el}}$, length $\ell$, and cross-sectional area $A$. Stronger atomic vibrations at higher temperature scatter electrons more, increasing platinum's electrical resistivity; impurities and crystallographic defects also contribute.^[ref]

A small known electric current $I$ and measured electric potential difference $V$ give $R=V/I$ through Ohm's law; a resistance bridge can instead compare the element with a reference resistor. Inverting the calibrated response then gives the sensing element's temperature. This makes electrical readout convenient, but the platinum resistance thermometer lead resistance error, resistance thermometer self-heating, and resistance thermometer immersion test explain why a stable display alone is insufficient. The gas thermometer supplies a contrasting route through an equation of state; the saturation-pressure equilibrium measurement shows why a trustworthy independent temperature readout matters.

A 1998 NIST account describes stirred comparison baths, a reference SPRT with a 30 Hz resistance bridge, and a temperature-controlled $100\Omega$ reference resistor. The test IPRTs used a $1\mathrm{mA}$ current source, a scanner, and an 8½-digit voltmeter. Separate current and voltage leads made each test probe a four-terminal device; readings in both current directions supplied voltage ratios to the reference resistor.^[ref]

Its program bracketed test readings with reference SPRT readings and repeated a block if bath drift was excessive. A check SPRT monitored the system; reference water-triple point measurements checked stability. Sensor depths were matched, and unfamiliar probes underwent immersion tests. Ice and water-triple point readings before and after calibration checked changes. Additional points could test the fitted curve. Reported calibration uncertainties excluded transport, subsequent drift, hysteresis, and the user's measurement system. These are controls and limits of that documented apparatus, not an accuracy promise for all platinum resistance thermometers.^[ref]

The inference is a pair: reference temperature from the SPRT, test electrical resistance from the electrical readout. Record measuring electric current, wiring, immersion, and the stated reference scale with each pair. A bath controller's setpoint is not itself the calibrated reference temperature. Returning to a reference and checking intermediate points distinguishes a fitted relation from a reproducible calibration over the intended interval.