Codex @codex  0

The coulomb is the SI unit of electric charge. A constant electric current of $1\mathrm{A}$ transports $1\mathrm{C}$ in a time of $1\mathrm{s}$; a constant current of $2\mathrm{A}$ for $3\mathrm{s}$ transports $6\mathrm{C}$. The prefix in $1\mathrm{nC}=10^{-9}\mathrm{C}$ explains the much smaller charge scale used in the worked Coulomb's law example. ^[ref]

The unified atomic mass unit and dalton are names for the same mass unit:where the carbon-12 chemical atom is free, at rest, and in its nuclear and electronic ground state. Its conversion to SI mass units is determined experimentally. See The International System of Units (SI), ninth edition, SI Brochure (Table 8, footnote (f), printed p. 146: dalton and unified atomic mass unit).

The degree Celsius has the same size as the kelvin, with a shifted temperature origin: $t/{}^{\circ }\mathrm{C}=T/\mathrm{K}-273.15$. Thus a change of one degree Celsius is a change of one kelvin, but temperature ratios in Carnot's theorem must use absolute thermodynamic temperature.^[ref]

The gravitational constant $G$ sets the strength of Newton's law of universal gravitation. Two point masses $M$ and $m$ a center-to-center distance $r$ apart attract with force magnitudeFor fixed masses and separation, doubling $G$ would double the force. For bodies with spherical symmetry, the same exterior formula follows from the spherical shell theorem; for arbitrary extended bodies, add the attractions of their mass density elements instead. The gravitational constant connects a laboratory attraction to the Newtonian gravitational field controlling a Kepler orbit.

The gravitational constant $G$ and local gravitational acceleration $g$ are different quantities. Applying Newton's second law to a test particle gives $g=F/m=GM/r^2$ for one spherical source. The source's mass and the observer's position change $g$; $G$ remains the same parameter of the law. A local falling-body experiment therefore measures a field, not $G$ alone. On rotating Earth, an instrument fixed to the surface also responds to centrifugal acceleration, while surrounding mass density and altitude change the gravitational contribution.

Dimensional analysis explains the units. Denote the base physical dimensions of length, mass and time by $\mathsf{L},\mathsf{M},\mathsf{T}$. Since force has dimension $\mathsf{ML}{\mathsf{T}}^{-2}$,By contrast, $[g]=\mathsf{L}{\mathsf{T}}^{-2}$ and the standard gravitational parameter $\mu =GM$ has dimension ${\mathsf{L}}^3{\mathsf{T}}^{-2}$. A small numerical value of a dimensional constant depends on the units chosen: it is the resulting force for specified physical masses and separation that conveys the laboratory scale.

NIST's current complete listing givesfor the 2022 CODATA adjustment, the latest adjustment listed when checked on 14 October 2026. Parentheses indicate a standard uncertainty $u(G)=0.00015\times 10^{-11}{\mathrm{m}}^3\mathrm{k}{\mathrm{g}}^{-1}{\mathrm{s}}^{-2}$, approximately $22$ parts per million relative to $G$. The adjustment year is 2022; NIST's May 2024 data update is a different date.^{[ref] [ref]}

For an original scale calculation, stipulate two $1\mathrm{kg}$ point masses separated by $1\mathrm{m}$ and insert this recommended $G$: $F=6.67430\times 10^{-11}\mathrm{N}$. The corresponding acceleration of either mass is $6.67430\times 10^{-11}\mathrm{m}{\mathrm{s}}^{-2}$ at that instant. Reducing the separation to $0.10\mathrm{m}$ multiplies both by $100$. These are ideal model predictions, not observations; their tiny scale explains why stray forces matter.

Being a constant of a physical law does not make the numerical value exact. The SI fixes the numerical values of seven defining constants, including the speed of light and Planck constant; $G$ is determined experimentally. Exact unit definitions still require physical realizations with measurement uncertainty: calibrating a length or a mass does not become error-free.^[ref]

The SI unit of absorbed dose.^[ref]

The International System of Units defines a common system for expressing physical quantities. Its base units include the kelvin for thermodynamic temperature; derived units combine them to describe quantities such as force and energy.^[ref]

The International Temperature Scale of 1990 is a practical scale for reproducible temperature measurements. Its assigned reference points and interpolation procedures approximate thermodynamic temperature. A calibrated standard platinum resistance thermometer transfers this scale over specified intervals; it does not define the modern kelvin.^[ref]

The joule is the SI unit of energy, work, and heat. One newton of force acting along one metre of displacement does one joule of work. The relation $1\mathrm{J}=1\mathrm{N}\mathrm{m}$ makes mechanical and electrical transfers comparable in the same energy unit. ^[ref]

In magnetostatics, an ideal infinitely long solenoid is a cylindrical sheet of circumferential surface current density $K=nI$. It has negligible winding advance, no magnetic core, and no imposed external magnetic field. Choose positive electric current to produce magnetic field along $+z$. In this ideal model the interior magnetic field is uniform and axial, $B={\mu }_{0}nI$, and the exterior magnetic field is zero; ${\mu }_0$ is the vacuum permeability. For a finite, closely wound air-core coil, the same result is an approximation well inside the coil, several radii from either end. Air is treated as having the magnetic permeability of vacuum. ^[ref].

For a short proof, the translational and rotational symmetries of the ideal cylindrical current sheet, together with the Biot-Savart law, give an axial magnetic field. Ampère's law on rectangles wholly outside makes that axial exterior value independent of radius; the condition of no imposed magnetic field makes it zero at infinity and hence everywhere outside. Rectangles wholly inside similarly show that the interior value is independent of radius. Now choose an Amperian loop with axial length $s$, one long side inside and the other outside. The transverse sides are perpendicular to the magnetic field, so their contributions to the line integral vanish. The loop crosses $ns$ turns of the winding, givingHere $s$ is the integration-path length, not the whole coil length $\ell$. An Amperian loop surrounding both sides of the winding encloses equal and opposite electric currents; zero net circulation alone would not prove zero magnetic field at every exterior point.

For the $1000$-turn, $0.50\mathrm{m}$ coil with electric current $I=0.50\mathrm{A}$, the long-solenoid approximation givesThis illustrative calculation uses vacuum permeability ${\mu }_0\approx 1.256637\times 10^{-6}H/m$, a rounded value, not an exact constant. Since the 2019 redefinition of SI, vacuum permeability is determined experimentally.^[ref] Doubling $I$ doubles the ideal magnetic field; doubling $N$ at fixed $\ell$ does the same. Increasing $\ell$ while keeping $N$ fixed decreases $n$ and hence the ideal magnetic field.

Molar mass turns a weighed sample into a count of specified particles. For a pure chemical substance with specified chemical formula and isotopic abundances, its molar mass iswhere $m$ is the sample mass and $n$ its amount of substance. The SI unit is $\mathrm{kg}\mathrm{mo}{\mathrm{l}}^{-1}$; the common laboratory unit is $\mathrm{g}\mathrm{mo}{\mathrm{l}}^{-1}$, with $1\mathrm{g}\mathrm{mo}{\mathrm{l}}^{-1}=10^{-3}\mathrm{kg}\mathrm{mo}{\mathrm{l}}^{-1}$. Equal values of amount of substance correspond to equal counts of specified entities, but heavier entities give greater masses.

Combining this definition with molecular count and amount of substance givesThe Avogadro constant is exact under the modern definition of the mole. The mass $M/N_{\mathrm{A}}$ is the mean mass per specified entity; if isotopes differ within the sample, individual molecules need not all have that mean mass.^[ref]

Specify what $n$ counts: water molecules, hydrogen chemical atoms, and oxygen chemical atoms give different values of amount of substance for the same sample. For a mixture, dividing total mass by total amount of substance of its chosen entities gives a composition-dependent mean. A polymer sample can contain many chain molar masses; its number-average molar mass and weight-average molar mass answer different averaging questions. Relating either to degree of polymerization also requires a unit-mass convention and end-group accounting.

The molar mass constant converts relative atomic mass or relative molecular mass into molar mass. It is approximately $1\mathrm{g}\mathrm{mo}{\mathrm{l}}^{-1}$. Its SI numerical value is determined experimentally: the exact Avogadro constant multiplies an experimentally determined unified atomic mass unit in kilograms. Treating $M_{\mathrm{u}}$ as exactly $1\mathrm{g}\mathrm{mo}{\mathrm{l}}^{-1}$ is therefore an excellent elementary-calculation approximation, rather than a defining equality of the modern SI.^[ref]

The newton is the SI unit of force:This combines the units of mass and acceleration in Newton's second law. ^[ref].

The pascal is the SI unit of pressure:For a uniform normal force of $10\mathrm{N}$ over area $0.02{\mathrm{m}}^2$, the pressure is $500\mathrm{Pa}$. The unit expresses a force per area, rather than the total force alone. ^[ref].

The SI unit used for equivalent dose and effective dose. Sharing dimensions with the gray does not make the quantities interchangeable.^[ref]

A steradian is the solid angle subtended at a sphere's center by a patch of surface area $R^2$. The whole sphere subtends $4\pi \mathrm{sr}$. In the SI, the steradian has unit one; retaining its symbol identifies a solid angle, just as radians identify an angle. A dimensionless quantity still needs its physical meaning specified.^[ref]

Temperature labels thermal equilibrium: two internally equilibrated bodies have the same temperature when contact permitting only heat exchange produces no net heat transfer. The zeroth law of thermodynamics makes the comparison transitive. If bodies A and B separately reach thermal equilibrium with the same thermometer without appreciably disturbing either body, they agree with each other. This is what lets a gas thermometer compare a metal block with water, despite their different internal energies and heat capacities. Insulation alone makes no such comparison: it can prevent heat transfer between bodies at different temperatures. ^[ref]

The zeroth law of thermodynamics establishes equality comparisons, but does not choose a numerical scale. Thermodynamic temperature supplies an absolute scale consistent with Carnot's theorem and entropy. For a simple compressible system at thermodynamic equilibrium with fixed particle number $N$ and composition,Here $U$ is internal energy, $S$ is entropy, and $V$ is volume; the second equality assumes the derivative can be inverted. Temperature is a thermodynamic conjugate variable to entropy and belongs to the intensive and extensive thermodynamic quantities as an intensive quantity. Its partial derivative tells us how much internal energy must change per unit change of entropy under the stated constraints. More general systems require their other mechanical and material variables to be held fixed too. ^[ref]

For an infinitesimal quantity $\delta Q>0$ of heat transferred from A to B, with no work or matter exchange, the equilibrium entropy changes giveFor ordinary positive temperatures, spontaneous heat transfer from $T_A>T_B$ increases total entropy; thermal equilibrium has $T_A=T_B$. This comparison uses changes in entropy, rather than the total internal energy contained in either body. A small hot object can have less internal energy than a large cool one. See entropy maximization under thermal contact for the equilibrium criterion and negative temperature for the special case of bounded energy spectra.

Express absolute thermodynamic temperature $T$ in kelvin, and a Celsius reading $t_C$ in degree Celsius:The offset is exact: $300\mathrm{K}$ corresponds to $26.85{}^{\circ }\mathrm{C}$, and $400\mathrm{K}$ to $126.85{}^{\circ }\mathrm{C}$. Their absolute temperature ratio is $4/3$; dividing their Celsius readings gives a different number. Thus gas thermometer pressure ratios and Carnot's theorem require thermodynamic temperature. The modern SI definition of the kelvin fixes the Boltzmann constant $k_B=1.380649\times 10^{-23}\mathrm{J}{\mathrm{K}}^{-1}$; a reference bath realizes or transfers the scale rather than defining that constant.^[ref]

Temperature is not universally the mean kinetic energy of a particle. In a classical, nonrelativistic ideal gas at thermal equilibrium, the equipartition theorem gives the mean translational kinetic energy relative to the gas's bulk motion:Here $m$ is particle mass, $\mathbf{v}$ its velocity, and $\mathbf{u}$ the mean flow velocity. In this regime, different particle masses at the same temperature have equal mean translational kinetic energies but different characteristic speeds. A moving gas can also carry bulk kinetic energy without being hotter in its rest frame. Internal molecular modes and quantum statistics require further care; the equipartition theorem has classical assumptions, whereas the equilibrium entropy definition applies more widely. ^[ref]

Thermometer calibration compares an instrument's response with assigned reference temperatures under specified conditions. In a proposed two-reference procedure, thermalize the sensing part at $T_0$ and $T_1$, record responses $X_0$ and $X_1$, and, only if a linear response is justified over that interval, useAdditional reference temperatures test curvature; returning to the first reference tests drift. A gas thermometer instead obtains its response from an equation of state, with a reference and corrections for its apparatus. In either case, uncertainty in the reference propagates to the inferred temperature. Calibration determines the response relation; it cannot by itself remove the finite-sample disturbance or incomplete thermal equilibrium described in thermometer. A reference established on a practical scale can also differ slightly from true thermodynamic temperature; the BIPM distinguishes the International Temperature Scale of 1990 readings from their thermodynamic counterparts.^[ref]

A triple-point cell turns phase coexistence into a reproducible reference for thermometer calibration. The NIST water-cell demonstration uses a sealed glass vessel containing water of specified isotopic composition and an open central thermometer well. Cooling this well with solid carbon dioxide and alcohol freezes an ice mantle while leaving liquid water and its vapor. The coolant is outside the sealed sample; the sample's vapor space does not communicate with room air.^[ref]

In the actual NIST cell-comparison experiment, newly frozen mantles were compared with an aged reference mantle in a controlled maintenance bath. A warm aluminium rod melted a thin inner layer around the well, allowing the mantle to rotate freely and establishing an ice–water interface close to the sensor. A standard platinum resistance thermometer and a resistance bridge measured the electrical resistance ratio to a calibrated, temperature-controlled reference resistor. Readings at two currents permitted extrapolation to zero electrical power, correcting self-heating; measured immersion depths supplied hydrostatic pressure corrections. Comparing preparations over time tested stabilization rather than assuming freshly frozen ice was ready.^[ref]

The inference is a reproducible fixed-point response for the thermometer, not a direct reading of three chemical potentials. The reference cell anchors the comparison; a water point alone does not determine a thermometer's response at every other temperature. The ideal $F=0$ argument excludes impurity and isotope variation, finite interface effects and unintended heat transfer; real cells also require adequate immersion and stable electrical references. Repeatability is evidence that these effects are controlled, not a reason to omit their uncertainty.

Since 20 May 2019 the kelvin has been defined through a fixed numerical value of the Boltzmann constant. The thermodynamic temperature of the water triple point is consequently a measured quantity with uncertainty, rather than an exact value imposed by the kelvin definition. Its continued use as an assigned reference on the International Temperature Scale of 1990 is a separate convention.^[ref][ref]

Vacuum permittivity is the electromagnetic constant ${ϵ}_0$ in Coulomb's law and the Vacuum Maxwell equations. In classical vacuum, $\mathbf{P}=0$ and the electric displacement field is $\mathbf{D}={ϵ}_0\mathbf{E}$. A material's permittivity includes its electric polarization response; vacuum permittivity supplies the common reference, not a separate adjustable material property. Its SI unit is farad per metre.

For elementary calculations, vacuum permittivity is approximately $8.854\times 10^{-12}F/m$. This is a deliberately rounded value, not an exact decimal or a statement of current measurement precision.^[ref] It sets the scale in Coulomb's law, $F=|q_1{q}_2|/(4\pi {ϵ}_0{r}^2)$ for two stationary point electric charges with separation length $r$ in vacuum, and therefore enters the reference capacitance $C_0={ϵ}_{0}A/d$ of a parallel-plate capacitor.

Since the revised SI took effect on 20 May 2019, the numerical value of vacuum permittivity in SI units is determined experimentally, rather than fixed exactly by the unit definitions. The numerical values of the elementary charge $e$, Planck constant $h$ and speed of light $c$ are fixed exactly. The fine-structure constant $\alpha$ is measured, andwhere ${\mu }_0$ is vacuum permeability. Consequently vacuum permittivity and vacuum permeability have experimental uncertainty, while their product is exact in SI units because $c$ is exact. This is a change in metrological status, not a new material dependence of vacuum permittivity.^[ref]

The volt is the SI unit of electric potential and electric potential difference: $1\mathrm{V}=1J/C$, one joule per coulomb. A positive electric charge of $2\mathrm{C}$ moved through a potential increase of $3\mathrm{V}$ gains $\Delta U=q\Delta \Phi =6\mathrm{J}$ of potential energy; the electric field does $-6\mathrm{J}$ of work. ^[ref].