The original diagram places hard walls at and , and the central plateau on is exactly at the indicated ground-state energy. This equality determines the middle of the requested sketch. In the Time-independent Schrödinger equation,
the central interval has , hence . The ground state can be chosen real and positive inside the walls by the nodeless theorem for a one-dimensional ground state. Reflection symmetry makes it even about , so its linear central segment must be constant.
The hard-wall boundary conditions are . On both outer intervals , so the positive wavefunction has negative curvature and is sinusoidal. Wavefunction matching at a finite potential step requires both and to remain continuous at ; the derivative therefore vanishes where each sinusoidal flank meets the flat middle. A normalized representative is
Each side contributes and the plateau contributes to the squared norm before multiplying by . The corresponding consistency condition is ; a numerical energy is not required for the sketch.
Figure 1.
The positive ground-state wavefunction has sinusoidal flanks and a flat central segment at V equals E
. Details.
Thus the ground state at the top of a central rectangular barrier has no internal nodes, continuous value and slope, and a flat middle, rather than an exponential dip through a classically forbidden region. Multiplication by an overall constant phase changes none of these physical features.
Equation and boundary conditions. The delta potential has strength with units of energy times length, because the Dirac delta function has units of inverse length. The Time-independent Schrödinger equation is
The wavefunction is continuous at the origin. A finite jump in would produce a derivative of a Dirac delta function in , with no corresponding term in this potential. A jump in does produce a delta contribution and is allowed. Integrate through a symmetric interval:
For continuous finite , the right-hand side vanishes as . Consequently
This derivative jump is the boundary condition associated with the attractive delta potential.
Unique bound state. For , write . Away from the origin, . Normalizability excludes exponentials growing at either infinity, leaving
Continuity gives . The derivative jump then becomes . For a nonzero state,
There is exactly one positive value of , so exactly one negative-energy bound state. An odd solution would have ; the allowed decaying exponentials would then both vanish identically. Normalize the even solution using
Choosing the overall phase real and positive gives the bound state in a delta potential:
It peaks at the origin, has a downward cusp there, and decays exponentially on both sides. Its value, but not its slope, is continuous.
Scattering amplitudes and fluxes. For , put and retain as a strength parameter. A unit-amplitude wave incident from the left has
Continuity gives . The jump condition gives
Solving,
The probability current of a plane wave of amplitude is in its propagation direction. Since the asymptotic wavenumber is the same on both sides, reflection probability and transmission probability are just and :
They satisfy , expressing conserved probability current in this real potential.
Figure 1.
The normalized delta-well bound state and reflection/transmission probabilities as attraction increases
. Details.
The right-hand plot uses , proportional to at fixed incident energy. Then rises monotonically from zero to one, while falls from one to zero; they are equal at . Despite the absence of a classical forbidden barrier, an abrupt attractive interaction reflects a quantum wave. Increasing attraction strengthens the derivative mismatch and can approach complete reflection at fixed positive energy. At fixed , increasing incident energy instead makes the well increasingly transparent. The negative-energy bound state and the positive-energy scattering states are different stationary solutions, not an absorptive loss channel.
Reduced radial equation. A spherical harmonic satisfies . Substitute into the Time-independent Schrödinger equation, divide out the angular function, and put . Direct differentiation gives
Multiplication by then gives the Radial Schrodinger equation
Here is the reduced mass, and the extra positive term is the centrifugal potential.
Boundary conditions. At the origin this finite central potential has no point interaction. The physical radial solution is regular there, requiring ; for , a nonzero constant would give and a point-source singularity of the three-dimensional Laplacian. Mere square integrability alone would not remove that singular solution. For a bound state, the radial probability integral is , so the exterior solution must decay and as .
Solutions for zero orbital angular momentum. For and , define
The interior equation is ; excludes the cosine. The exterior equation is ; normalizability excludes the growing exponential. Thus
The constants cannot remain independent once the interface is matched. Since the potential step is finite, both and are continuous at :
Dividing the equations yields
Existence and number of s-wave bound states. Put , , and . Then
The lowest branch lies on . Along it, and increases continuously from to infinity. Therefore a first negative-energy solution exists precisely when , or
Further branches begin at as . Hence the bound-state thresholds of a spherical square well give exactly one negative-energy state when
The upper equality is included: the second branch is then only at , with constant exterior , and is not normalizable. If threshold cases are excluded by convention, the commonly quoted open interval has a strict upper inequality; the physical negative-energy state count at equality is still one.
Deuteron estimate. Using , and gives . At ,
The threshold for a second state is , far above the stipulated depth . Thus this model has no radially excited s-wave bound state.
Checking other orbital angular momentum sectors matters before ruling out every excitation. At the first -wave threshold, the regular interior reduced radial function is and the zero-energy exterior function is proportional to . Matching their logarithmic derivatives requires , whose first root is . Hence
Larger only increases the centrifugal potential. Therefore no bound orbital excited states are expected in the specified central square-well model. Its spin dependence and tensor nuclear forces have not been specified; the calculation does not resolve the real deuteron's internal spin structure.
Distinguishable noninteracting particles. Interpret as the same external one-particle potential for each particle; the total potential is . The Time-dependent Schrödinger equation is
Let and , where . Applying to the product multiplies it by . The time derivative of multiplies it by . Thus the proposed stationary product is a solution provided
The tensor product separates the two independent one-particle dynamics.
Identical spin-one-half particles. Identical fermions require antisymmetry under exchange of the complete position-and-spin labels. First take to be distinct orthonormal spatial orbitals, and define
The symmetric spatial state must multiply the antisymmetric spin-one-half singlet state; the antisymmetric spatial state must multiply one of the three symmetric spin-one-half triplet states. The four normalized possibilities, each with the common time factor , are
These are the required product states under fermionic exchange symmetry. If , the antisymmetric spatial combination vanishes. Only the product times the singlet remains, as required by the Pauli exclusion principle. A nonorthogonal pair would require different normalization factors; the displayed assumes an orthonormal stationary-state basis.
Weak repulsive Coulomb interaction. For fixed orbitals , first-order perturbation theory gives spatial energy shifts . Here is the direct interaction energy, while the exchange integral for repulsion strength is
The positivity follows from the positive Fourier transform of the Coulomb kernel. Consequently Coulomb exchange splitting of two orbitals gives
All three triplet spin components remain degenerate for a spin-independent Coulomb interaction. Their antisymmetric spatial factor vanishes at coincidence and reduces close encounters. The inequality is strict when ; for negligible orbital overlap, the splitting may vanish. This comparison fixes one particle in each of the specified orbitals and does not rank singlets with a different orbital occupation.
Spin-zero bosons. For one particle in each of the same distinct orthonormal orbitals, the spin factor is symmetric and bosonic exchange symmetry requires . At coincident positions,
Thus the bosonic coincidence enhancement in two orthogonal orbitals is
These are joint probability densities, or small-detector-volume limits; an exactly specified point has zero probability in a continuous distribution. If both particles occupy the same orbital, the properly normalized product is already symmetric and the corresponding enhancement relative to distinguishable particles in that same orbital is one. The paper's usual factor-two answer presumes distinct orthogonal input orbitals.
Ehrenfest theorem relates the dynamics of quantum expectation values to operator commutators. For a normalized state obeying and a possibly time-dependent observable , differentiate . Using the adjoint Schrödinger equation for the bra gives
Thus
The identity assumes a common domain on which the required products and derivatives are defined.
For , the canonical commutation relation gives and . Therefore
These resemble Hamilton's equations and Newton's second law, but generally . If the state is localized about , a local expansion gives
The classical trajectory equation for the mean is accurate when the force changes little across the wave packet. For a quadratic harmonic potential, is linear and this closure is exact for every state with the relevant finite moments: . This exact classical evolution of the centroid does not eliminate its quantum position uncertainty or make every state a point particle.
The correspondence principle is broader: quantum predictions recover classical ones in an appropriate limit, such as large action compared with and observations that cannot resolve individual quantum levels. It is not the assertion that every large quantum number automatically makes every possible state classical. Delocalized superpositions and interference can remain significant unless the physical preparation and measurement justify a classical description.
A spectral example is useful. For a quantum harmonic oscillator, neighboring levels differ by , giving transition frequency , equal to its classical oscillation frequency. A coherent state makes the connection more concrete: its mean position and momentum oscillate classically while the finite-width Gaussian profile retains its quantum uncertainty. For hydrogenic Bohr levels , transitions between nearby large have , which equals the classical circular orbital angular frequency in that model. Ehrenfest's theorem supplies an exact expectation-value bridge; a classical trajectory follows only when the force can also be evaluated at the mean position.
Set
All are real and . Suppressing a common time quantum phase , choose
The rightmost region has no left-moving term because no wave is incident from the right. The shifted quantum phase convention makes the transmitted amplitude at the second interface.
For finite potential steps and equal mass, wavefunction matching at a finite potential step requires continuity of both and . Explicitly,
A discontinuous wavefunction would introduce an inadmissible singular kinetic term, while integrating the stationary Schrödinger equation across a finite step shows that the derivative cannot jump. These conditions also keep the probability current continuous, so a finite interface neither creates nor destroys probability. The derivative rule would need modification for a delta-function potential or a different effective mass; neither occurs here.
The infinite wall imposes , and the wavefunction vanishes for . The even full-oscillator ground state fails this boundary condition; the lowest admissible state is the positive-half restriction of the odd first excited state. Multiplying by restores normalization because half its probability originally lay on either side.
With , the half-harmonic oscillator ground state is
It rises from zero at the wall, reaches its wave-amplitude maximum at , and decays to zero as . It is positive throughout the interior of the allowed region, with no interior node, as required for its ground state. The wall need not make the derivative continuous with the forbidden half-line.
Figure 1.
Half-oscillator ground state and the full-oscillator states after removing the wall
. Details.
The Hamiltonian operator is
Since multiplication by commutes with multiplication by , part (b) gives . Similarly . Substituting into part (c) gives Ehrenfest theorem:
Thus the mean momentum changes according to the mean force, and the derivative of mean position is mean velocity. These exact quantum equations resemble Hamilton's classical equations, but generally differs from . The classical point-particle equation for the center is exact for potentials at most quadratic and is an approximation for a localized packet when the force varies little across it. A spatially broad packet in a nonlinear potential need not follow a classical trajectory. Even where its center follows classical motion, its width and measurement uncertainties remain quantum properties.
Assume independent normally distributed angle errors with known standard deviation . The relevant chi-squared test uses the sum of squared standardized residuals,
For the model through the origin, the predictions and residuals, expressed in milliradians, are
Consequently . There are statistical degrees of freedom. The upper-tail P-value is approximately ; equivalently the value greatly exceeds the critical value . The zero-intercept model is strongly rejected under the stated errors.
For the alternative linear regression, minimize . Setting both partial derivatives to zero gives the normal equations, whose solution is
For these data , , and . This yields
The new predictions are , with residuals . Therefore
The affine model is compatible with the data. Allowing for its additional fitted parameter, the decrease has a chi-squared distribution with one statistical degree of freedom under the nested zero-intercept hypothesis, corresponding to . Thus the model with a fitted intercept provides the better description, rather than merely lowering the residual by adding a parameter.
With the measurement variance treated as known, the coefficient uncertainties are
Hence , about standard deviations above zero. A positive constant systematic error in the angular zero, or an additional nearly constant torque, could account for it. Its presence is evidence against the ideal zero-intercept model; four points alone do not identify the physical cause uniquely. A calibration error in only rescales the inferred gravitational constant and cannot remove this residual pattern.
Using the fitted slope after allowing for this offset would give , with the period and slope errors combined in quadrature. This is conditional on the constant-offset model.
The symmetry is electromagnetic reciprocity applied to mutual inductance. For thin closed circuits in vacuum, the magnetic vector potential generated by circuit B is
Stokes theorem converts the magnetic flux through circuit A into its magnetic vector potential circulation. Dividing by gives Neumann's mutual-inductance formula,
The dot product and separation are unchanged by interchanging A and B, so
Each has units . The winding orientations must be used consistently to determine the common sign. The same reciprocity holds in ordinary linear reciprocal magnetic media; it is not an unrestricted statement about biased nonreciprocal materials. Equivalently, a reversible magnetic energy function has equal mixed derivatives with respect to the two currents.
Following the moving fluid. The Eulerian velocity field assigns a velocity to each position. A fluid particle satisfies , so the chain rule gives the material derivative, also called the convective derivative,
Even in steady flow a particle can accelerate because it moves between regions with different velocity. For example, flow around a curved obstacle changes direction despite . Mass conservation is
For a constant-density incompressible fluid, .
Euler equations for an inviscid fluid and Bernoulli's equation. Neglect viscosity and take the body force per unit mass to be . Newton's second law for a fluid element gives
For steady flow, dot with displacement along a streamline. The tangential component of is the derivative of along that line. For constant density, integration gives
In uniform gravity, . Thus pressure, kinetic energy per unit mass and gravitational potential energy per unit mass exchange along a streamline. For a barotropic compressible fluid, replace by . Different streamlines need not have the same Bernoulli constant.
Vorticity and potential flow. Vorticity is . A small fluid element rotates locally with angular velocity after its deformational part is separated. The vector identity
gives for steady constant-density inviscid flow. Thus an irrotational region has one common Bernoulli constant on each connected region. In a simply connected irrotational domain, introduce a velocity potential . Incompressibility then gives Laplace's equation, . For unsteady irrotational flow,
An impermeable stationary wall fixes , but ideal potential flow does not enforce no slip. In a multiply connected domain, irrotational flow may still have nonzero circulation around an excluded vortex core, so a globally single-valued potential requires care.
For example, uniform two-dimensional flow past a circular cylinder has outside . Its normal velocity vanishes at the cylinder, and its surface tangential velocity is . Bernoulli's equation predicts a symmetric pressure distribution and zero drag. This is D'Alembert's paradox: the assumptions omit the viscous boundary layers, separation and wake responsible for real drag.
For an incompressible fluid of constant kinematic viscosity , the curl of the motion equation gives
The first term stretches and tilts vortex lines; the second diffuses vorticity. In two-dimensional incompressible inviscid flow the stretching term is absent and vorticity is carried with the fluid. In a three-dimensional inviscid flow it can be amplified by stretching. Density gradients not parallel to pressure gradients provide an additional source in a general compressible fluid.
Viscous flow. A Newtonian fluid's shear stress is proportional to rate of strain. For constant viscosity and incompressibility the Navier-Stokes equation is
with dynamic viscosity and kinematic viscosity . At an ordinary solid wall, the no-slip boundary condition sets fluid velocity equal to the wall velocity. Viscosity transfers momentum between neighbouring layers and converts mechanical energy into heat; unlike the pressure force, its shear contribution depends on velocity gradients.
For plane Couette flow between plates , with the upper plate moving at , the steady solution is , with shear stress . For pressure-driven flow through a pipe of radius , a constant pressure gradient gives the parabolic Poiseuille profile
The Reynolds number compares convective inertia with viscous force. Small Reynolds number often permits the Stokes-flow approximation; large Reynolds number can produce thin boundary layers and, under suitable conditions, turbulence. It does not justify neglecting the wall conditions. Bernoulli's inviscid constant is generally not conserved along a viscous streamline, and pipe flow instead shows a pressure loss corresponding to dissipation.
For the usual hollow rectangular electromagnetic waveguide, let the propagation axis be and the interior be , . A transverse magnetic polarization has and . At a perfect conductor wall the tangential electric field vanishes. Since is tangential to all four side walls, it satisfies a homogeneous Dirichlet boundary condition around the rectangle.
Separating the transverse Helmholtz equation therefore gives the transverse magnetic mode of a rectangular waveguide
A zero value of either index makes identically zero, rather than producing a nonzero field uniform along that direction. The transverse electric and magnetic fields of this TM family are obtained from transverse derivatives of , so they also vanish. Thus both TM indices must be nonzero: neither nor exists in this rectangular hollow-guide model. In contrast, transverse electric modes obey a Neumann boundary condition on and may have one zero index. The claim is about this waveguide geometry, not all possible guides.
Let the particle have mass , and assume its force is derived from a time-independent potential energy during the stated interval. Differentiation gives
For , choose a branch on which is real. Conservation of energy is the quickest integration of Newton's second law:
The additive constant is arbitrary. For instance, the displayed expression applies directly for , and , without raising a possibly negative to a fractional power. Its derivative gives along the trajectory, as required. The second term has units of kinetic energy because has units .
For , the velocity is constant, so the potential energy is constant on the visited interval; the expression above reduces to such a constant. For , or , the particle is stationary: the trajectory only fixes to vanish at its position and does not determine the potential energy elsewhere. These exceptional cases cannot determine a unique nonconstant function.
Magnetic field and force. A steady electric current produces a magnetic field. In vacuum the Biot-Savart law gives
The Lorentz force on the charge carriers transfers force to the material carrying them. The resulting force on a current element of another circuit is , or, for a continuous current distribution, the magnetic force per unit volume is .
For two long parallel straight wires a distance apart, Ampère's law gives . Therefore
The force is attractive for parallel currents and repulsive for opposite currents, by the cross product rule. Its units are . This approximation neglects wire thickness and end effects; a complete circuit includes its return current. Element-by-element forces need not form an isolated Newton's-third-law pair, but complete stationary circuits have balanced mutual forces when the entire system is included.
Energy description. For two linear coupled circuits the magnetic energy is
Here is a mechanical coordinate and the signed mutual inductance. At prescribed currents, the generalized force is if the self-inductances do not vary. This positive derivative is obtained from magnetic coenergy, or by including the electrical sources' work; differentiating with a minus sign at fixed currents would omit that source work. At prescribed flux linkages the force instead equals the negative derivative of stored magnetic energy with those linkages fixed. The geometry thus determines both inductance and mechanical force.