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For the separated stationary state, restore its time factor $e^{-iEt/\hslash }$. Away from radial nodes, the quantum phase is $S=k\varphi -Et/\hslash$, up to a constant $0$ or $\pi$ where the real radial function has fixed sign. The guidance equation in plane polar coordinates therefore gives the Bohmian circulation of an angular-momentum eigenstateThe direction is $\hat{\mathbf{\varphi }}$ for $k>0$ and $-\hat{\mathbf{\varphi }}$ for $k<0$; the velocity is zero for $k=0$. Each admissible trajectory is a circle:The orbital angular momentum along the trajectory is $m{r}_0{v}_{\varphi }=\hslash k$. The origin or any zero-amplitude circle is excluded from this local formula. For the real degenerate superposition constructed above, the spatial quantum phase is constant on each nodal sector, so its Bohmian mechanics velocity is instead zero. Thus the circular motion is a conclusion about the separated angular-momentum eigenstate, not an arbitrary energy eigenstate.

The rotational invariance of a central-potential Hamiltonian allows a simultaneous eigenstate of energy and the two-dimensional orbital angular momentum $L_z=-i\hslash {\partial }_{\varphi }$. For a separated wavefunction $F(r)G(\varphi )$, the Laplacian in polar coordinates givesThe $\varphi$ term must be a constant; write $G^{\prime \prime }/G=-k^2$. The angular eigenfunctions can be chosen as $e^{ik\varphi }$. Single-valuedness under $\varphi \mapsto \varphi +2\pi$ imposes $e^{2\pi ik}=1$, hence $k\in \mathbb{Z}$. The radial equation in the separation of a two-dimensional central-potential eigenstate isFor a real central potential and the usual real self-adjoint radial boundary conditions, the radial equation admits a basis of real solutions: real and imaginary parts of a complex solution obey the same equation and boundary conditions. Choose a real normalized radial eigenfunction. Since the plane area element in plane polar coordinates is $rdrd\varphi$, the normalization isThis establishes the intended separated simultaneous eigenstate form. It is not the form of every stationary state. The radial equation depends on $k^2$, so the $k$ and $-k$ sectors have the same energy. For $k\ge 1$, their normalized superpositionis a single-valued stationary state with that energy but is not a single angular exponential. Quantum degeneracy is precisely why separation of variables selects a convenient eigenstate basis rather than all vectors in an energy eigenspace. The printed assertion needs this qualification. The printed polar-coordinate aid also labels a gradient component tuple as a divergence; the gradient used below is the two-dimensional vector $\hat{\mathbf{r}}{\partial }_r+\hat{\mathbf{\varphi }}{r}^{-1}{\partial }_{\varphi }$.

The squared sine has integral $a$ over the interval of length $2a$, since it contains an integer number of half-wavelengths. A real positive phase convention therefore givesInside the infinite square well, the Time-independent Schrodinger equation is $-{\hslash }^2{\psi }_n^{\prime \prime }/(2m)=E_n{\psi }_n$. The wavenumber is $\pi n/(2a)$, soThe stationary states vanish at both walls and form an orthonormal basis of the square-integrable state space. A common arbitrary phase on each basis function does not alter any energy or measurement probability.

The Parseval identity for the orthonormal stationary-state expansion is ${\sum }_{n\ge 1}|c_n{|}^2=\Vert \psi {\Vert }^2=1$. Splitting the amplitudes into even and odd indices givesMultiply by ${\pi }^2/3$ to obtain the requested identity. Its integer constants areThe series converges absolutely, since both parity contributions are $O(p^{-2})$. This derivation uses the normalization of the prepared state and completeness of the well stationary states, rather than a separate summation trick.

For a finite potential energy discontinuity, the stationary state $\psi$ and its first derivative are continuous at $a$. Integrating the Time-independent Schrodinger equation across a shrinking interval about $a$ gives continuity of ${\psi }^{\prime }$; a jump in $\psi$ would produce a distributional derivative incompatible with a finite potential energy.

For $E>V_0$, put $k=\sqrt{2mE}/\hslash$, $q=\sqrt{2m(E-V_0)}/\hslash$ and use unit incident amplitude:There is no wave incident from the right. The matching equations $1+r=t$, $k(1-r)=qt$ give $r=(k-q)/(k+q)$ and $t=2k/(k+q)$. Comparing reflected and incident probability currents gives the reflection coefficientThe transmitted fraction is $T=(q/k)|t{|}^2=4kq/(k+q{)}^2$, so $R+T=1$.

For $0<E<V_0$, write $\kappa =\sqrt{2m(V_0-E)}/\hslash$ and retain only the decaying right-hand solution $t{e}^{-\kappa (x-a)}$. Matching gives $r=(k-i\kappa )/(k+i\kappa )$, which has modulus one. The evanescent wave carries no transmitted probability current. At $E=V_0$, the bounded right-hand solution is constant and matching again gives $r=1$. ThusClassically, a particle is wholly transmitted for $E>V_0$ and wholly reflected for $E<V_0$; there is no classical partial reflection above the step. At the threshold it has zero right-hand speed and no transmitted flux, a marginal case requiring a convention about motion exactly on the discontinuity. The quantum result approaches $R=0$ as $E/V_0\to \infty$.

The Time-dependent Schrodinger equation for the one-dimensional Quantum harmonic oscillator isA stationary state has $\Psi (x,t)=\psi (x)e^{-iEt/\hslash }$, so cancellation of the common time factor gives

SetThe equation becomesWith $\psi =f(y)e^{-y^2/2}$,and hence $f$ obeys the Hermite differential equation

If $f$ is monic of degree $N$, the coefficient of $y^N$ in this equation is $ϵ-1-2N$. It must vanish, soWriting $f={\sum }_{k=0}^N{a}_k{y}^k$ gives the recurrenceThe coefficient of $y^{N-1}$ first gives $a_{N-1}=0$, and the recurrence preserves parity. If $N$ is even, every odd coefficient vanishes, so $f$ is an even function. The Gaussian factor is also even; therefore the stationary state $\psi$ has even parity.

For a wavefunction $\Psi (x,t)$, the probability density and probability current areMultiply the Schrodinger equation by ${\Psi }^{\ast }$, multiply its complex conjugate by $\Psi$, and subtract. The real potential energy terms cancel, leavingwhich is the probability continuity equation ${\rho }_t+j_x=0$.

For a stationary state, ${\rho }_t=0$, so $j_x=0$ and $j$ is constant in space. A normalizable wavefunction has vanishing current at spatial infinity, forcing this constant to be zero. By contrast the nonnormalizable plane wavehas stationary density $|A{|}^2$ and nonzero currentwhen $k\ne 0$.

A stationary state has the formFor a time-independent quantum observable $Q$, the global phases cancel in the expectation value:It is therefore independent of time.

For the infinite square well,The possible energy measurement results arewith respective Born rule probabilities $|c_1{|}^2$ and $|c_2{|}^2$. Normalization gives $|c_1{|}^2+|c_2{|}^2=1$.

At time $t$,The required matrix elements areConsequentlywhere the angular frequency isFinally, $2|c_1{c}_2|\le |c_1{|}^2+|c_2{|}^2=1$, so

For a one-dimensional wavefunction,The probability continuity equation isFor a stationary state $\psi (x,t)=\varphi (x)e^{-iEt/\hslash }$, the probability density is independent of time, so ${\partial }_{x}j=0$ and the probability current is constant in space.

For the plane waveone obtainsThis is a momentum eigenstate with momentum $p=\hslash k$ and, when it satisfies the free Schrodinger equation, energy $E={\hslash }^2{k}^2/(2m)$. Its constant density and current describe a spatially uniform beam carrying probability in the sign of $k$. It is not a normalizable wavefunction, so it represents an idealized state rather than a localized particle.

The probability density and probability current areFor a stationary state, $\psi (x,t)=\chi (x)e^{-iEt/\hslash }$, so $\rho =|\chi {|}^2$ is independent of time. The continuity equation then gives $\partial J/\partial x=0$. Hence

For a plane wave $A{e}^{i(kx-Et/\hslash )}$, the probability current isThe incident amplitude is one and the transmitted amplitude is $T$, soThis is the transmission probability for quantum tunnelling. In the stationary state, $\partial \rho /\partial t=0$, so the continuity equation makes the net current independent of position. The reflected current therefore supplies the remainder:

Only odd stationary states contribute, and for $j=2n+1$ their squared coefficients are $128/[{\pi }^2(j^2-16{)}^2]$. Since $E_{av}/E_1=16$, substitution givesso $B=8$.

$\rho =|\psi {|}^2$ and $j=(\hslash /m)\mathrm{Im}({\psi }^{\ast }{\psi }_x)$. Schrödinger’s equation and its conjugate give ${\rho }_t+j_x=0$; a stationary state has $j_x=0$. Continuity of $\psi ,\psi \prime$ at $0,a$ and matching plane waves giveso $F=1/3$ and $G=a\sqrt{3m}/\hslash$. Transmission is minimised when $G\sqrt{U_0}=\pi /2+n\pi$, i.e. $U_0=(\pi /2+n\pi {)}^2/G^2$.

An energy and orbital angular momentum eigenstate for a real two-dimensional central potential can be chosen with integer $k$ and real radial function $f$. Its radial equation isQuantum degeneracy permits other stationary states, including $f(r)\cos (k\varphi )/\sqrt{\pi }$, which are not single angular exponentials. Separation of variables supplies a basis rather than describing every superposition in a degenerate eigenspace.