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An electron occupying a pi-type molecular orbital. In a conjugated planar molecule, the pi subspace is commonly built from p orbitals perpendicular to the molecular plane; its electron population excludes the sigma framework.

A plasma is a gas of mobile charged particles whose collective electromagnetic response is important to its dynamics. It commonly contains ions and electrons, and may also contain a neutral component: complete ionization is not required. A multi-species fluid description has current density $\mathbf{J}={\sum }_s{q}_s{n}_s{\mathbf{u}}_s$. The relative motion of the species can matter even when a single-fluid magnetohydrodynamics approximation describes the large-scale dynamics.

A resistance thermometer using platinum as its sensing material. It provides the temperature readout in the saturation-pressure equilibrium measurement.

Transduction turns electrical resistance into a temperature indication. A uniform wire has $R={\rho }_{\mathrm{el}}\ell /A$, with electrical resistivity ${\rho }_{\mathrm{el}}$, length $\ell$, and cross-sectional area $A$. Stronger atomic vibrations at higher temperature scatter electrons more, increasing platinum's electrical resistivity; impurities and crystallographic defects also contribute.^[ref]

A small known electric current $I$ and measured electric potential difference $V$ give $R=V/I$ through Ohm's law; a resistance bridge can instead compare the element with a reference resistor. Inverting the calibrated response then gives the sensing element's temperature. This makes electrical readout convenient, but the platinum resistance thermometer lead resistance error, resistance thermometer self-heating, and resistance thermometer immersion test explain why a stable display alone is insufficient. The gas thermometer supplies a contrasting route through an equation of state; the saturation-pressure equilibrium measurement shows why a trustworthy independent temperature readout matters.

A p-n junction joins regions of a semiconductor with opposite majority charge carriers: electrons on one side and electron holes on the other. It provides the junction modeled by the Shockley diode equation.

Near an unbiased p-n junction, diffusion leaves exposed ionized donor impurities and acceptor impurities. Their electric field opposes further majority-carrier transfer. At thermal equilibrium, drift and diffusion balance; there is no net electric current. Forward bias reduces the barrier to carrier injection; reverse bias enlarges it. A heavily doped tunnel diode adds a different transport route, quantum tunnelling, that the ordinary Shockley diode equation omits.

A polar covalent bond shares electrons unequally, as in hydrogen chloride.

The word “polar” qualifies the sharing within a covalent bond; it does not require complete transfer of an electron or an isolated cation–anion pair. In $A^{\delta +}-B^{\delta -}$, the signs identify the relatively electron-poor and electron-rich ends, while $\delta$ leaves the amount unspecified. A neutral Lewis structure can give both chemical atoms zero formal charge and still correspond to a polar covalent bond: equal division of the bond pair is a formal allocation, whereas bond polarization concerns the actual electron density.

Local and molecular descriptions answer different questions. Calling one chemical bond a polar covalent bond does not establish that the whole molecule is a polar molecule. Combine the bond dipoles with the molecular geometry, then check for molecular dipole cancellation. This lets a short electronegativity comparison explain a local tendency without confusing it with the observable electric dipole moment of the whole molecule.

Consider a parent atomic nucleus at rest. Write its signed nuclear polarization along a fixed axis $\hat{\mathbf{z}}$ as $P=⟨J_z⟩/(I\hslash )$, where $I\hslash$ is its maximal spin component. Let $\theta$ be the angle of the emitted electron momentum to that axis and let $\beta =v/c$. Use $\mathcal{P}$ for the parity operator, so it is not confused with $P$.

For an axially symmetric leading-dipole model, retain a constant and the term linear in the polarization vector $\mathbf{P}=P\hat{\mathbf{z}}$. Rotational symmetry makes the directional term proportional to $\mathbf{P}\cdot \hat{\mathbf{p}}$. Define its dimensionless coefficient as $A\beta$. At fixed electron energy the relative intensity and normalized probability density function per solid angle are thereforeThe factor $\beta$ is the conventional separation of the speed dependence; rotational symmetry alone does not determine that dependence or $A$. The coefficient $A$ contains the decay dynamics. This leading model omits higher angular terms and detailed recoil and radiative effects. A partially oriented higher-spin ensemble can also have alignment that is not specified by its vector nuclear polarization alone.

The unit-integral condition follows without any model of a detector:Thus $f$ has unit angular average, while the probability density function in the polar angle alone contains the Jacobian determinant factor:In particular, $f$ itself is neither a normalized probability density function in $\theta$ nor a detector count. Positivity on $-1\le u\le 1$ gives $|a|\le 1$.

Under full spatial reflection, $\mathbf{p}\mapsto -\mathbf{p}$ but $\mathbf{J}\mapsto \mathbf{J}$. The latter follows already for orbital angular momentum from $\mathbf{r}\times \mathbf{p}\mapsto (-\mathbf{r})\times (-\mathbf{p})=\mathbf{r}\times \mathbf{p}$; spin has the same axial vector transformation. Hence $\mathbf{P}\cdot \hat{\mathbf{p}}$ is a pseudoscalar, and $\cos \theta \mapsto -\cos \theta$. If parity conservation held for this model, equal probabilities for the inverted process would force $a=0$. Conversely, $a=0$ in an unpolarized sample proves nothing about $A$.

Integrating over the two hemispheres gives a useful original check:Choose $A=-0.8$, $P=0.5$, and $\beta =0.75$, so $a=-0.3$. Then the forward and backward hemisphere probabilities are $0.425$ and $0.575$, and their counting asymmetry is $-0.15$. These are chosen teaching values, not measured values from the Wu experiment. At a single energy, the angular shape determines the product $AP\beta$; it cannot separately determine $A$ without a polarization calibration.

A polymerization-active site is the reactive location that enables the next chain-growth propagation step. In the schematic$M$ is one free monomer molecule, $j$ is the chain's degree of polymerization in incorporated monomeric units, and the star marks the polymerization-active site. The site's reactive character survives the growth step, although the chemical atoms carrying it can change. The star is not an extra unit, a literal particle, or necessarily a positive or negative electric charge. Actual reaction mechanisms can involve an unpaired electron, a cation, an anion, or a metal-associated site; the abstract notation does not identify which. ^[ref]

For bookkeeping below, each linear active chain has exactly one polymerization-active site. This is a stipulated model, not a property of every chain polymerization: a chain can have several reactive sites, and a reversibly inactive chain can remain capable of future growth. Count currently active sites separately from all chains capable of later reactivation.

The positron is the positively charged antiparticle of the electron.

Positronium is the electromagnetic bound state of an electron and a Positron. Their equal masses give reduced mass $m_e/2$, half the hydrogenic Rydberg binding scale and approximately twice the electron-proton separation of hydrogen. Its spin singlet and triplet differ in hyperfine energy; annihilation also affects their physical lifetimes and splitting.

An electron annihilation operator restricted to the no-double-occupancy sector of the t-J model. It removes a spin-$\sigma$ electron only when the opposite-spin site occupation vanishes. The corresponding creation operator cannot create a doubly occupied site. These projected operators do not obey the unrestricted canonical on-site fermion algebra on all states.

The proton is the positively charged spin-one-half baryon found in atomic nuclei. Its mass is approximately $1836$ times the electron mass.

Unintended exposure near a written feature caused by electron scattering in the resist and substrate. The deposited-energy distribution is broader than the incident probe, requiring dose or geometry correction for dense and isolated patterns.

A p-type semiconductor has more mobile electron holes than electrons; it can nevertheless be electrically neutral overall.

A radio wave traversing a dilute cold plasma has a group velocity that depends on its frequency. In the ideal unmagnetized limit, the dispersion relation is ${\omega }^2=c^2{k}^2+{\omega }_p^2$, where ${\omega }_p$ is the angular plasma frequency. For $\omega \gg {\omega }_p$, differentiate to obtain $v_g=c\sqrt{1-{\omega }_p^2/{\omega }^2}$, then expand $1/v_g$ to first order. The excess travel time over a vacuum path isHere $f=\omega /(2\pi )$ is ordinary frequency, $e$ is the magnitude of the elementary charge, $m_e$ is the electron mass, ${ϵ}_0$ is the vacuum permittivity, $n_e$ is electron number density, and $c$ is the speed of light. This approximation neglects magnetic corrections, collisions and multipath scattering; its positive sign means lower frequencies arrive later.

A planar six-membered aromatic ring with nitrogen at opposite ring sites. Its molecular point group is the D2h point group. The six ring $p_z$ atomic orbitals form a six-electron conjugated system; the in-plane nitrogen lone pairs are outside this $\pi$ basis.

The electronic contribution to differential capacitance arising from a change of chemical potential as particles are added. For noninteracting electrons at zero temperature, it is $e^2$ times the density of states of the whole sample at the Fermi energy. The quantum capacitance of a graphene cone gives a worked example.

An electric field normal to a semiconductor quantum well shifts the electron and hole confinement energies and displaces their envelopes in opposite directions. The exciton optical transition usually redshifts and its oscillator strength falls as their overlap decreases. In a symmetric unbiased well the permanent dipole $p_0$ vanishes, so the leading weak-field shift is quadratic. This optical shift includes confinement and binding changes; it is not solely a change in exciton binding energy.

A quantum dot confines electrons and electron holes in all three spatial directions, producing discrete energy levels. A semiconductor island surrounded by a larger-band gap material is one realization. Its optical excitation and electron-hole recombination depend on confinement, Coulomb interactions and electric-dipole selection rules.

Filling a degenerate orbital shell produces a larger addition energy for the next electron. In a circular two-dimensional harmonic potential, shell $q=n_x+n_y$ has $q+1$ orbitals and capacity $2(q+1)$ including spin. Cumulative closed-shell occupancies are $(q+1)(q+2)=2,6,12,20,\dots$. Charging and orbital contributions must be separated, and anisotropy or exchange can split the ideal shells.

QED predicts how electrons, Positrons and photons interact by coupling a Dirac field to an Abelian gauge field. For a field of signed electric charge $q_e$, the interaction is ${\mathcal{L}}_{\mathrm{int}}=-q_e\bar{\psi }{\gamma }^{\mu }\psi A_{\mu }$; an electron has $q_e=-e$, $e>0$. Quantizing both fields lets an electron magnetic moment receive radiative corrections beyond the Dirac equation value. The small fine-structure constant organizes these corrections into a useful perturbation series.

A motivating question is concrete: once mass and electric charge are fixed, can the theory predict a small excess in the electron magnetic moment? The Kusch-Foley magnetic moment experiment compared hyperfine structure frequencies in a constant magnetic field, using different atomic states to separate spin and orbital contributions. Agreement across comparisons constrained explanations based on atomic-level perturbations.^[ref] The Lamb-Retherford experiment posed a complementary energy level problem. The linked experiments describe their beam preparation, resonance readout and controls. Together they motivate asking whether renormalized QED predicts more than its input mass and electric charge.