Past exam of the physics B course of the University of Cambridge 2011 Paper 2 Section A A1 Solution 2026-10-20
For the entropy balance of a thermostatted resistor, electrical work becomes heat . At fixed temperature the resistor has no net change of thermodynamic state; it exports this heat to its thermostat. Treating the electrical supply as a source of work,Entropy is produced by Joule heating even though it does not accumulate in the resistor. Additional entropy production inside a nonideal power supply is outside the specified model.
Past exam of the physics B course of the University of Cambridge 2011 Paper 2 Section B B8 Solution 2026-10-20
Insert and into the given identity. For a linear, time-independent, nondispersive medium, and , givingThe divergence theorem then yieldsThe left side is outward electromagnetic power flow. The current term is power delivered to matter, becoming Joule heating for an Ohmic conductor, and is the change in stored electric plus magnetic energy. The minus sign says outward flux reduces stored energy unless supplied locally.
Follow the drawing's coordinates: lower strip at , upper strip at , current along in the upper strip and back along the lower. The wording “both strips lie in the -plane” must mean parallel to that plane, since the drawing separates them in . Neglect the side and end fringes using . Then and the top-strip potential is , while the lower strip is equipotential at zero.
The harmonic function matching those two surfaces isIndeed , and it has the required potentials at . ThusThe two current sheets reinforce their magnetic field between the strips; its direction follows the right-hand rule. The Poynting flow in resistive parallel strips follows from their cross product:Power flows along the gap towards the load and upwards into the resistive strip. Across a transverse area , falls from to . The upper surface receives , exactly the strip's heating; the ideal lower strip receives none. In the charge-free gap, , consistent with a static field and no local dissipation. The small longitudinal electric field cannot be discarded if this upward energy transfer is to be represented.
Past exam of the physics B course of the University of Cambridge 2012 Paper 1 Section B B9 Solution 2026-10-20
Use peak-amplitude phasors with time factor and . Faraday's law of induction and the Ampere-Maxwell law giveIn the good-conductor limit , take the root with positive attenuation into the slab:The real physical field is . A thick slab excludes a returning wave from its rear face. The skin depth is the electric-field amplitude decay length; the intensity decay length is .
Faraday's law of induction fixes . The surface impedance of a good conductor and the complete transmitted magnetic field are consequentlyThe sign of the imaginary part belongs to the stated time convention. Average the Poynting vector using complex conjugation and the factor one half appropriate to peak phasors:As an independent energy check, , the mean Joule heating per unit volume.
Ohm's law gives and . Hence the averaged Lorentz force per unit volume isIntegrating through the illuminated half-space gives the positive inward radiation pressureFinally let be the vacuum wave impedance. Tangential-field boundary conditions at normal incidence give the electric-amplitude reflection coefficient . Since ,Here by surface energy balance. Combining the leading formulas gives , the nearly perfect-reflector limit. The displayed reflection expansion also assumes a good conductor relative to the incident vacuum wave, .
Past exam of the physics B course of the University of Cambridge 2012 Paper 2 Section C C11 Solution 2026-10-20
Capacity convention. The printed equation requires to be volumetric heat capacity, in . If “specific heat capacity” means per unit mass instead, the storage term is and both denominators in the printed equation must contain . This distinction is fixed by dimensions.
For a fixed material region , conservation of thermal energy gives the heat balance with volumetric heat generation,Use the divergence theorem, and constant coefficients. Since the region is arbitrary,The heat source is power per volume, while is thermal conductivity rather than thermal diffusivity.
For uniform electrical conductivity and imposed current, current density is and Joule heating is . A long, steady, cylindrically symmetric wire therefore satisfiesIntegration gives . Regularity at makes , and the surface condition fixes the remaining constant. Thus the Joule-heated cylindrical wire hasHere denotes the printed radial coordinate and avoids confusing it with mass density. The centre is hotter by .
For the air boundary, the internal flux at is . Equate this to . The Newton cooling of a Joule-heated wire givesMultiplication by circumference verifies that surface loss per length equals , the electrical power per length. The full air-cooled profile uses this surface temperature plus the same parabolic interior excess, assuming constant material properties and negligible end losses.
Past exam of the physics B course of the University of Cambridge 2013 Paper 1 Section B B8 Solution 2026-10-20
For a moving loop, Faraday's law of induction is , where is the local wire velocity, , and the oriented boundary and surface follow the right-hand rule. For a fixed loop the motional term vanishes. Lenz's law is the minus sign: the induced response opposes the change of linked flux, not necessarily the applied field itself.
Let increase downhill and choose positive current to produce an uphill magnetic force. The normal component of the imposed field is , so the changing external flux is . With initially zero current and no resistance, conservation of flux linkage gives . The rod feels gravity vertically downward, a rail reaction normal to the slope, and magnetic force of magnitude horizontally uphill. Its downhill component is ; its normal component presses the rod into the rails, giving .
The inductive oscillation of a sliding rod on inclined rails follows fromThe magnetic force is not itself parallel to the rails. Defining and , release from rest givesThe first stop occurs at ; the rod then returns and oscillates between and . At the force is zero but the speed is maximal. Mechanical potential energy is reversibly exchanged with kinetic energy and ; a perfectly conducting circuit provides no damping.
For the resistive long-time drift of an inductive sliding rod, with loop resistance , useJoule heating damps the transient oscillation. On sufficiently long rails the asymptotic motion is steady sliding, not permanent rest:The zero-resistance model has persistent oscillations; its late-time limit cannot be interchanged with taking . These results assume , smooth contacts, negligible rod self-inductance and constant geometry.
Past exam of the physics B course of the University of Cambridge 2015 Paper 1 Section A A4 Solution 2026-10-20
The varying magnetic flux through the ring induces an electromotive force by Faraday's law of induction. Its direction follows Lenz's law. With solenoid current , ring current , ring self-inductance , electrical resistance , and mutual inductance ,The ring sits in a nonuniform magnetic field: coupling decreases above the solenoid, so and with a common orientation for the two windings. For , the in-phase part of the induced ring current is negative:Thus alternating-current induction levitation can balance the ring's weight when . A falling mean lifting force with height supplies vertical stability. In the strongly inductive limit the two currents are almost opposite: the ring repels the solenoid during both half cycles. Finite self-inductance matters; an ideal purely resistive loop would carry a current exactly in quadrature with and give zero average force in this model. The source supplies the Joule heating in the real ring, and any mechanical work while it rises.
Past exam of the physics B course of the University of Cambridge 2015 Paper 1 Section B B9 Solution 2026-10-20
Choose the guide axis as , with and . The electric field is along , parallel to the walls' dimension. Take a homogeneous lossless nonmagnetic dielectric with relative permittivity , ideal conducting walls, and time dependence . The lowest transverse electric mode of a rectangular waveguide isAt , this tangential electric field vanishes. At the electric field is normal to the wall; a nonzero value is supported by surface electric charge and violates no conducting boundary condition. The field has zero divergence. The associated normal magnetic field also vanishes at each wall, as verified below. The fundamental sine across the wider dimension minimizes the nonzero transverse wave number; is not a physical propagating mode of a hollow simply connected guide.
Below the waveguide cutoff frequency , put with to select decay for . The evanescent transverse electric mode in a rectangular waveguide then hasFor the fixed frequency in the question,The decay length increases monotonically and diverges as ; its formal limit at is . At the mode is at cutoff, with zero axial wave number. For , is real and the mode propagates without axial attenuation in this ideal lossless model. There is no real finite evanescent decay length to continue beyond cutoff. The paper's graph notation denotes the same as its preceding formula.
From Faraday's law of induction, . Writing givesThus vanishes on the walls and vanishes on the walls, meeting the normal magnetic boundary conditions. The fields also satisfy . For real the physical fields are , , and .
The time-averaged Poynting vector isAll products are imaginary because the electric field and magnetic field are in quadrature. A single decaying evanescent wave stores reactive energy without transmitting average power into a semi-infinite lossless guide. A finite below-cutoff section can transmit power when both independent evanescent solutions are present; that is a different boundary-value problem.
The skin effect also gives exponential field decay, but in a good metal has both real and imaginary parts and there is a real inward mean Poynting vector. That flux supplies Joule heating . Here attenuation comes from geometric cutoff in a lossless region, with no conductivity and no dissipative power sink; exponential decay alone does not establish absorption.
Past exam of the physics B course of the University of Cambridge 2015 Paper 2 Section B B7 Solution 2026-10-20
Displacement current makes Ampère's law compatible with charge conservation. The macroscopic Maxwell equations areTaking the divergence of the last equation and using Gauss's law gives . Omitting would wrongly require the conduction current to be divergence free during charging. The displacement-current density has current-density units, but need not represent free charges crossing a region.
The surface independence of Ampère circulation during capacitor charging illustrates the need directly. A surface spanning the circuit can cut the wire or pass between the plates. For ideal parallel plates, andThe corrected circulation of is independent of that surface choice. Free conduction current stops at a plate; displacement current supplies the gap contribution.
In vacuum the two time-dependent curl equations support waves. Taking a curl of Faraday's law in a source-free region yieldsThe corresponding magnetic equation is identical. For a plane wave, and . The fields carry energy through the Poynting flux. Dropping displacement current everywhere would remove these freely propagating solutions.[ref]
In a metal, conduction and displacement compete. For a uniform ohmic material with , constant , and transverse waves,Use . The dispersion relation and conduction-to-displacement current ratio areWhen , with : fields are screened within a skin depth and energy is dissipated by Joule heating. This quasistatic limit neglects displacement current locally compared with conduction; it does not invalidate the full Maxwell law. At sufficiently high frequency, conductivity and permittivity are frequency dependent, so a constant- approximation must be replaced by a material model.
In an unmagnetized cold plasma, electron inertia gives a cutoff. With immobile ions and negligible collisions, and give . For the transverse wave cutoff in a cold unmagnetized plasma, combining this carrier current with vacuum displacement current givesTransverse waves propagate above and are evanescent below it. The group velocity is even though the phase velocity exceeds . The cold model also has longitudinal charge-density oscillations at , distinct from transverse light waves. Collisions add damping, and pressure or magnetic fields modify these simple dispersions. To avoid carrier-current double counting in effective permittivity, once the carrier response is included in it must not be counted a second time as a separate conductivity. Displacement current therefore connects circuit continuity, vacuum radiation, conductor screening and plasma propagation within one consistent field theory.[ref]
Electromagnetism by David Tong. Sections 7.6.2–7.6.3: conductors, plasma frequency and longitudinal plasma oscillations
Past exam of the physics B course of the University of Cambridge 2016 Paper 1 Section B B8 Solution 2026-10-20
Use peak phasors with time dependence , real positive electrical conductivity , and absolute permeability . Ampère-Maxwell equation and Faraday equations giveso . The sign of the imaginary term follows from the stated time convention. For a transverse plane wave in a homogeneous conductor,In the good-conductor limit, choose the root that decays into :The electric phasor and physical field are consequently and , as required. Tangential boundary matching sets ; it need not equal the incident amplitude.
Faraday's law fixes the magnetic field, including its phase:For real and , this means , with other components zero. The time-averaged Poynting vector isThe energy entering a thin slab exceeds that leaving it by per unit volume, givingDirectly, and at each time. Therefore is exactly this loss. The factors one half use peak rather than root mean square phasors; amplitude decays over , while intensity decays over .
For a cold collisionless unmagnetized plasma, electron inertia gives and real . Above the plasma frequency the wave propagates without this resistive attenuation. Below it, a semi-infinite plasma supports an evanescent field with electric and magnetic components in quadrature and zero mean inward energy flux: the incident energy is reflected, not absorbed as Joule heating. electron kinetic energy is reversibly stored, so the nondispersive dielectric field-energy formula alone is incomplete. Collisions introduce a real dissipative electrical conductivity and can produce absorption.[ref]
Oscillations and Waves by Richard Fitzpatrick. Section 9.7, equations 9.36–9.53, evanescence, phase quadrature and unit reflectance
Past exam of the physics B course of the University of Cambridge 2018 Paper 1 Section B B8 Solution 2026-10-18
Effective permittivity. Use peak phasors with time dependence . The Ampere-Maxwell law isThe conductive contribution to complex permittivity is thereforeHere is the source's effective relative permittivity, not just the real part of a complex response. The positive imaginary term is the loss sign appropriate to this time convention.
The penetrating electric wave. Combine this equation with Faraday's law of induction. In a uniform source-free medium the transverse phasor satisfiesFor a good conductor of electrical conductivity , , so . The root which decays into isChoose the surface phasor amplitude real. Taking the real part of givesThe skin depth is an amplitude-decay distance in metres.
The magnetic wave and phase. The curl of an -polarized field varying in is in the direction. Since ,ThusThe phase sign follows the specified convention. Equivalently the surface impedance of a good conductor is .
How the fields differ from those in vacuum. The two metal fields have the same exponential envelope and spatial period , but their phase arguments differ by .
Original normalized electric and magnetic field profiles inside a good conductor at one instant, showing their common decay envelope and quarter-of-a-right-angle phase difference
. Details. An individual travelling wave in the lossless exterior has no attenuation, real wave impedance and in-phase electric and magnetic fields. The exterior total field also includes the reflected wave and may show interference, so it need not share that simple phase relation everywhere. At the interface the tangential fields match; is the field just inside the metal, not necessarily the incident amplitude. A good conductor reflects strongly and its wave impedance is much smaller than the vacuum impedance.
Average inward energy flux. For peak phasors, the Poynting vector averaged over a cycle is . The fields giveConsequently the constant in the question isThe flux is in the direction and has units .
Local energy conservation. The Poynting flux and local heating in a skin layer satisfyThe decrease becomes Joule heating in each layer. The Poynting theorem includes this transfer from field energy to the metal; averaged electromagnetic energy storage has zero time derivative in the periodic state, so no energy is lost from the complete balance.
An electrical transformer transfers alternating electrical power between windings through a shared changing magnetic flux. A core with large magnetic permeability confines most of the flux, so both windings link approximately the same flux . Faraday's law gives induced electromotive forcesFor an ideal electrical transformer, negligible winding resistance and leakage flux imply the terminal-voltage magnitude ratioThe relative phase depends on the winding sense and terminal convention. At a loaded secondary, Lenz's law makes the secondary current oppose the flux change. The primary draws an additional current which approximately cancels the secondary magnetomotive force: in magnitude when the magnetizing current is negligible. Consequentlyfor a resistive load, using root mean square values. More generally the ideal device conserves instantaneous power, with the appropriate current signs. A load impedance appears at the primary as , enabling impedance matching and electrical isolation.
For sinusoidal flux, gives . At a given supply voltage, reducing frequency increases the required peak flux and can drive the core into magnetic saturation. Real losses include winding Joule heating, magnetic hysteresis, eddy currents and leakage flux; a laminated core suppresses eddy-current loops. A steady direct current produces no continuing secondary electromotive force, while its small winding resistance can allow a damaging primary current after switching transients.
Past exam of the physics B course of the University of Cambridge 2019 Paper 1 Section B B6 Solution 2026-10-18
Induction and its sign. The Maxwell-Faraday equation is . For a fixed loop, Stokes theorem givesThis is Faraday's law of induction. The orientation of the surface normal and positive circulation are linked by the right-hand rule. The minus sign is Lenz's law: the induced current's linked flux opposes the imposed flux change, rather than reinforcing it.
The inductive current. Let the loop normal make angle with the applied field, with positive current defined by that normal. The external magnetic flux is . With negligible electrical resistance, the circuit equation is , so total linked flux is constant. For zero initial trapped flux,The printed result needs this initial-flux assumption; in general an additional constant current is allowed. The units are amperes because a weber divided by a henry is an ampere.
Current and forces at one instant. Take along and , so relative to the chosen normal. The loop magnetic dipole moment therefore has a component opposite the applied field. Each wire element experiences Lorentz force . Opposite sides have equal and opposite forces, giving zero net force in the uniform field but a nonzero couple.
Original top view of the loop's vertical sides at positive applied field; dots and crosses show vertical current, and the force pair increases the angle between normal and field
. Details. The horizontal top and bottom wire segments also experience equal and opposite vertical forces. They cancel without adding torque about the vertical rotation axis; the displayed force pair supplies that torque.
Average torque. Since , its generalized component for increasing is . Substitution givesand, using ,The orientation torque on a flux-conserving loop drives its normal away from the field for the stated initial angle. Its magnitude has units joules, or newton metres.
Free motion with large inertia. Write for the mechanical moment of inertia. If its orientation changes little during each field cycle, the slow equation is , with effective potentialThe stable orientation is , where the loop plane contains the applied field. Released from rest between and , the loop accelerates toward that orientation, overshoots and librates around it. In the leading averaged, undamped model its turning angles are and . It does not settle without a dissipative mechanism. For small librations the squared angular frequency is .
Negligible inductance and finite resistance. Now the current is proportional to the induced electromotive force, not to the flux. Including slow rotation,The rotational damping of a resistive loop in an oscillating field follows fromAt fixed orientation, the first term alternates at and has zero mean. The loop can therefore rock slightly, but there is no leading mean aligning torque like that in the inductive case. Slow rotation giveswhich opposes motion and produces Joule heating. Initial-phase transients can initiate motion, and the instantaneous torque is not zero. This description retains the large-inertia, slow-motion approximation; it does not assert an exact stationary solution at every starting angle.
Past exam of the physics B course of the University of Cambridge 2019 Paper 1 Section B B7 Solution 2026-10-18
The integral field equation. The Ampere-Maxwell law is . Apply Stokes theorem to any fixed oriented surface bounded by the chosen contour:The added displacement current is required for compatibility with electric charge conservation. Taking a divergence and using gives .
Field geometry. Choose the upper plate positive and let increase upward. In the long-plate, slow-discharge approximation, . Conventional wire current runs downward from the positive plate. The magnetic field intensity circulates clockwise as viewed from above. The Poynting vector points radially toward the resistive wire.
Original meridional section of the discharging capacitor; electric field and wire current point down, magnetic field circles the wire, and electromagnetic energy flows inward
. Details. Wire and displacement currents. The capacitance and discharge law areBecause decreases, points upward, opposing the downward wire current. Through a disk of radius between the plates its magnitude isThe effective downward current enclosed by the circular contour is therefore . The Ampere-Maxwell law givesThis is the magnitude; with the stated coordinates, . The factor expresses cancellation between conduction and displacement currents. The approximation requires distances outside the thin wire and away from detailed electrode-edge fields.
Energy flux and power. Since ,Its units are watts per square metre. Integrating over the cylinder's side area , the signed outward power is negative:There is no leading axial flux through the cylinder's ends in this ideal field geometry.
Where the energy goes. The Poynting flux in a centrally discharged parallel-plate capacitor carries field energy through the dielectric space into the resistor, where it becomes Joule heating at rate . Inside radius the stored electric energy isHenceThe resistor receives the inward flux from outside that cylinder plus the field energy released inside it. As approaches the wire radius, essentially all its power arrives as radial electromagnetic flux. Over the whole capacitor, . The Poynting theorem thus accounts for the complete discharge without treating energy as transported only along the conducting wire. High resistance makes the quasistatic electric-field approximation and neglect of changing magnetic energy consistent.
Past exam of the physics B course of the University of Cambridge 2021 Paper 2 Section A A5 Solution 2026-10-18
For charge sharing between distant connected spheres, use the standard approximation that the spheres are sufficiently far apart for mutual electrostatic effects to be negligible, and that the wire adds negligible capacitance. The capacitance of an isolated conducting sphere is . ThusThe initial charges are . Connecting the spheres allows charge to flow until their potentials are equal. Charge conservation givesThe initial and final electrostatic energies are and . Their difference becomes Joule heating in the resistive wire:Numerically,The resistance determines how fast this happens, not the final energy difference. Sufficient damping suppresses sustained charge-current oscillations; the calculation also neglects energy radiated away. At finite sphere separation the capacitance matrix would be needed, and the radii and initial potentials alone would not specify an exact correction.
Past exam of the physics B course of the University of Cambridge 2021 Paper 2 Section B B7 Solution Created 2026-10-18 Updated 2026-10-20
Electromagnetic waves drive mobile charges in a conducting medium. Their current changes both the phase and attenuation of the wave. A description in terms of a real, frequency-independent refractive index is therefore generally insufficient: the material response and the propagation constant are complex and frequency dependent.
Use phasors proportional to , with and for a passive medium. In a homogeneous, isotropic, linear material, let represent the permittivity associated with bound-charge electric polarization, the magnetic permeability and the mobile-charge conductivity. The macroscopic Maxwell equations giveFor a transverse plane wave, taking another curl yieldsThis division of the response avoids counting mobile electrons both in and in . Define the complex refractive index . For a nonmagnetic medium, . Its real part determines the phase variation, while the positive optical extinction coefficient gives amplitude attenuation and intensity attenuation . The amplitude penetration length is
A simple microscopic explanation comes from the Drude model. Let electrons of charge , mass and number density move against an effectively stationary positive background. Collisions relax their mean velocity at rate :ConsequentlyWith a vacuum-like bound-charge background, this givesIts imaginary part is positive for positive , consistent with dissipation under the chosen phasor convention. Real materials can require an effective electron mass, a nontrivial bound-charge response, or additional absorption associated with the electronic band structure.
A plasma is a conducting ionized medium with mobile electrons and ions, approximately neutral on large scales because of plasma screening. For the electron-frequency transverse waves considered here, the heavy ions can often be treated as stationary. In a dilute weakly collisional plasma, , soFor , is real in this collisionless model and the wave propagates. Its phase velocity is , while its group velocity is ; their product is . A phase crest exceeding does not imply superluminal information transport. For , the refractive-index square is negative andThe transmitted field is evanescent rather than a traveling bulk wave. A sufficiently thick collisionless plasma reflects such radiation without Ohmic absorption. Collisions make the response complex and permit absorption. This accounts for a plasma cutoff and, qualitatively, the reflection of some radio frequencies by ionized atmospheric layers. The simple model describes transverse waves; plasmas also support longitudinal collective modes.
In a metal, positive ions usually form a crystal lattice. Mobile conduction electrons occupy states described by the electronic band structure and normally form a degenerate Fermi gas. The conduction-electron density is usually much higher than in a dilute gas plasma. Thus its plasma frequency is commonly in the optical or ultraviolet range, rather than the lower radio-frequency values possible in dilute plasmas. Electron scattering from the lattice, defects and other excitations gives a finite relaxation rate. The distinction is not that every plasma is collisionless and every metal collisional: the controlling ratio for either material is , together with its carrier density and bound-charge response.
At sufficiently low frequency, , the metal's conductivity is approximately real, . In a good conductor the conduction current dominates the displacement current, . The wave equation then givesFor example, a tangential electric field varies asThe current is therefore concentrated within a few skin depths of the surface: this is the skin effect. As frequency increases within this regime, . In a wire whose radius greatly exceeds , only a thin outer region carries appreciable alternating current, increasing the effective resistance. In a conducting shield, the same penetration suppresses the field transmitted through a sufficiently thick wall.
The Poynting theorem identifies the loss as Joule heating. The cycle-averaged heating density for a complex conductivity isThe wave impedance is . For incidence from vacuum at normal incidence, the electric reflection amplitude is , where . A good conductor has small and therefore strong reflection, while the part of the incident power entering it is dissipated over the skin depth.
At high enough frequency that , a metal's free-electron response also approaches the collisionless plasma form. The low-frequency formula must not simply be extrapolated into that regime. Real optical behavior additionally depends on the electronic band structure and transitions between bands. Both plasmas and metals are therefore described by the same electromagnetic response framework, but their relevant densities, scattering rates and frequency regimes differ.
In magnetostatics Ampère's circuital law is . Its general vacuum version adds on the right. Faraday's law is for a fixed loop. A circular Amperian path around a long straight wire giveswith direction given by the right-hand rule. The force on a wire element is ; its magnitude is and its direction follows this cross product.
Choose the straight-wire current rightward and the square below it, as printed. Its positive magnetic field there is into the page. With an into-page loop normal, the magnetic flux linkage isHere denotes mutual inductance, not a mass. Choose positive coil current to produce an out-of-page field. Then its induced current in the resistance-dominated approximation isThis reproduces the specified sign with the declared orientation. It neglects coil self-inductance, requiring , as implicit in the requested expression.
The nearest side contains N parallel current segments and is at a uniform distance , so its force magnitude isThe two sides perpendicular to the wire have opposite currents and equal magnetic fields at corresponding distances; their forces cancel pairwise. The far side opposes the near-side force and has the smaller field. ThusWhen and have the same sign under the chosen conventions, the near-side coil current opposes the straight-wire current and the total force is away from the wire; otherwise it is toward it. In particular the signed force alternates with . The coil is fixed, so these forces do no mechanical work on it. The mean Joule heating is
In gel sieving of synthetic polymers, gel electrophoresis combines drift under an electric field with size- and conformation-dependent obstruction by a porous matrix. In weak-field free solution, force balance gives and, in a simple effective-charge/effective-friction model, . The mobility is motion relative to the medium, so fluid motion from electro-osmosis must be accounted for separately. This is the operational mobility convention, not a claim that the bare structural charge is always the effective driving charge.[ref]
IUPAC Compendium of Chemical Terminology, fifth edition (Gold Book) by International Union of Pure and Applied Chemistry. entry E02024, electrophoretic mobility: migration speed divided by electric field strength
For a chain with free-draining polymer friction with approximately constant effective electric charge per segment, both charge and friction scale with . The free-solution mobility can therefore become nearly independent of length, making size separation poor. A gel adds steric constraints. Coils smaller than the mesh can pass relatively easily; larger coils require deformation and pore-to-pore rearrangement. A schematic weak-sieving law is , where matrix concentration and retardation coefficient are defined by a calibration; it is not a universal size law.
When a long flexible charged polymer is confined to a tube of available paths, reptation supplies another regime. An additive-friction model gives contour diffusion and renewal time . For ideal large-scale chain statistics, , so centre-of-mass diffusion scales as . With total effective driving charge proportional to , weak-field mobility can then scale as . This assumes screened/ideal large-scale conformations and linear response; strong-field alignment, trapping and nonideal matrices can alter the scaling.
Operationally, load narrow zones of independently characterized synthetic standards and sample into a controlled gel, apply a known field and detect migration positions after a measured time. Compare with a free-solution measurement, vary matrix concentration and field, and control temperature, ionic strength, pH and matrix charge. Larger gel pores or lower matrix concentration usually reduce sieving within a given calibrated material system. Excessive field causes Joule heating and can change conformation and mobility. adsorption or electro-osmotic drift can mimic a size effect; standards should match charge chemistry and topology as well as nominal mass.
Band centres move as while ordinary diffusion gives . Resolution depends on separation of centres relative to band widths, not travel distance alone. A neutral tracer helps identify bulk flow, and multiple concentrations test adsorption or overloading. A mobility or band position does not uniquely determine size without a regime-specific calibration. TODO: biomolecular examples, sample preparation and biological applications are user deferred; the account here concerns synthetic charged polymers only.
Peltier current-reversal experiment 2026-10-18
An actual institutional protocol is CTU's Measurement of characteristics of a Peltier cell. Its cooling run uses a water container, an insulating cap and a current-limited supply; both face temperatures are recorded every minute while electric current is monitored. The apparatus includes a water-cooled exchanger, copper blocks and brass containers. The heating run resets the water near room temperature before reversing polarity. The handout specifies no thermometer type and reports no dataset. Its modular junction geometry is shown separately from the external thermal assembly.[ref]
The following is a proposed quantitative extension. Keep the physical face labels fixed throughout reversal: c denotes the observed object's side and h the exchanger side, even if their actual temperatures change order. Use an independently read thermometer at each thermal contact and log the actual signed electric current and terminal electric potential difference. Maintain reproducible contact pressure and contact layers. A sensor in water measures water temperature, which need not equal the face temperature during a transient; verify mixing and contact equilibration before using it as a face reading. Do not interchange sensor leads when reversing the supply.
The strongest separation compares runs at the same , water mass, contact conditions and environment, rather than subtracting arbitrary final temperatures. One option is short initial-rate runs after resetting the whole assembly to a reproducible state. Define as the net power entering the monitored object, inferred from its calibrated effective heat capacity and initial temperature slope. In a simple symmetric model, let include background heat transfer at that state and the dissipated power reaching the object. Thenwhere in the thermoelectric cooling model below. The half-difference and baseline-subtracted half-sum areThe minus sign in the odd part means positive electric current cools the object. The even part has to subtract the zero-current baseline: otherwise heat conduction and ambient exchange remain mixed with Joule heating. Independently measured heat capacity is essential for converting a thermal slope into watts; include the blocks, container and water that actually equilibrate on the measurement timescale.
Useful controls are zero-current drift at several matched temperature differences, equal-magnitude positive and negative electric currents, and repetition of a sequence such as with thermal resets. A calibrated small heater on the object can test the heat capacity and lost-heat correction independently. Check Joule heating in supply leads and contacts, bypass heat conduction through supports and wiring, and ambient convection and thermal radiation. Insulation reduces a leak; it does not establish that it is zero. Measure terminal power at the module boundary so lead losses are not mistaken for module heating.
An odd thermal response supports a reversible current-coupled contribution, but does not by itself locate all of it at one junction: the Thomson effect in nonuniform leads can also be odd. Sensor offsets, unequal current magnitudes, drifting thermal contacts and different junction temperatures during the two runs can contaminate both parts. In particular, heating proportional to is even only when the compared electrical resistance is the same. CTU's qualitative reversal illustrates switching heating and cooling; the matched-state controls above would be needed for a coefficient measurement.
Peltier effect 2026-10-18
The Peltier effect is heat transfer associated with an electric current crossing a junction between materials with different Peltier coefficients. At fixed junction temperature, its contribution changes sign when the conventional current reverses. A junction can absorb heat from its surroundings for one direction and release it for the other. Joule heating, proportional to the square of the electric current, accompanies this transport but does not reverse sign. Consequently, observing a warm device alone does not identify the Peltier effect.
This makes the Peltier effect useful as an electrically controlled heat pump: reversing the supply can switch an object's thermal role without changing any plumbing. In thermoelectric cooling, however, the useful cooling is the junction's absorbed heat minus returning heat conduction and its share of Joule heating. Increasing electric current eventually makes cooling worse. The distinction between transported heat and net cooling is the central practical lesson of the thermoelectric cooler energy balance.
Persistent current (superconductivity) 2026-10-18
A superconducting persistent current is an electric current circulating in a closed path with superconductivity after the external driving electromotive force has ceased. Its associated magnetic field makes the circulation observable without inserting a measuring instrument into the path. This article concerns macroscopic circulation in superconductivity. A finite experiment establishes persistence over its observation window with a stated measurement error, rather than directly observing an infinite lifetime.
The ideal circuit connection is flux conservation in a superconducting loop. In a fixed loop with self-inductance , a single circulating electric current , and externally imposed linked magnetic flux , the lumped circuit approximation givesWhen the electrical resistance vanishes, integrating gives . Removing the external linked magnetic flux therefore changes the circulating electric current; holding it fixed afterwards preserves that electric current. This is a circuit approximation with a specified self-inductance, not a derivation of the microscopic state of superconductivity. For thin paths where the carrier contribution matters, fluxoid and flux quantization in a superconductor supplies the more careful description.
For constant , constant effective electrical resistance , and no changing external linked magnetic flux, the RL circuit instead predictsThis exponential decay follows by separating . A long relaxation time tests extremely small electrical resistance without trying to resolve an equally tiny steady electric potential difference. The stored magnetic energy is , so the same model gives , exactly the Joule heating loss. The finite energy stored in the loop supplies the magnetic readout; the circulating electric current is not a continuously powered source of useful work.






