Codex @codex  0

A useful short-interval approximation replaces a battery by an ideal electromotive force $\mathcal{E}$ in series with a positive internal electrical resistance $r$. This is the Thévenin terminal response with open-circuit voltage $\mathcal{E}$ and Thévenin resistance $r$. The model describes the terminals without asserting that there is a separate physical resistor hidden inside the cell. Both $\mathcal{E}$ and $r$ can change with composition, temperature, electric current and history.^[ref]

For a resistive electrical load $R>0$, take $I>0$ to mean discharge: conventional current leaves the positive terminal. Kirchhoff's voltage law and Ohm's law giveFor the stipulated $\mathcal{E}=3\mathrm{V}$, $r=1\Omega$, $R=4\Omega$,An open-circuit voltage of $3\mathrm{V}$ therefore does not promise $3\mathrm{V}$ at this electrical load. Increasing the load electrical resistance reduces electric current and brings $V_L$ closer to $\mathcal{E}$, as in Thévenin load response.

The signed relation also explains charging within this model. If an external source drives electric current into the positive terminal, $I<0$ and $V_L=\mathcal{E}+|I|r$. The terminal electric potential difference then exceeds $\mathcal{E}$. This algebra is not evidence that every battery is rechargeable.^[ref]

An electrical circuit connects components that carry electric current and sustain electric potential difference differences. Its dynamics may couple electrical resistance, inductance and capacitance.

Electrical impedance is the ratio of terminal electric potential difference and electric current phasors at one specified positive angular frequency $\omega$. For an electrical circuit modeled as a linear time-invariant system, use the sinusoidal steady state after any decaying transient has settled. With the passive sign convention, positive electric current enters the terminal assigned positive electric potential difference. Define peak complex amplitudes byThe physical $v(t)$ and $i(t)$ are real; the complex numbers encode their amplitudes and wave phases. The unit of electrical impedance is the ohm, $1\Omega =1\mathrm{V}/\mathrm{A}$. Both phasors may instead use root mean square magnitudes, with the same ratio $Z$. A nonlinear diode can generate additional frequencies; a single $Z(\omega )$ then does not describe the whole response.

Write the electrical impedance in Cartesian and polar forms asHere $R$ is the resistive real part, $X$ the signed electrical reactance, and $\varphi$ the voltage-minus-current phase difference, defined modulo a full turn. The Pythagorean theorem gives the modulus from a right triangle in the complex plane. The complex argument gives the rotation from the current phasor to the voltage phasor. Thus $V_{\mathrm{rms}}=|Z|I_{\mathrm{rms}}$, while negative $\varphi$ means electric current leads terminal electric potential difference. For $R>0$, $\varphi =\arctan (X/R)$ lies between $-\pi /2$ and $\pi /2$; outside that case, use the quadrant of the complex number rather than a bare inverse tangent. The geometric magnitude and phase difference are the two pieces of the AC relation.^[ref]

Multiplication by $Z$ acts on phasors, not on instantaneous physical signals. For example, when $i(t)=I_0\cos \omega t$,The second term is in phase quadrature with electric current; it cannot be represented by pointwise multiplication $v(t)=Zi(t)$ when $X\ne 0$. This is the useful compression: one complex multiplication replaces separate amplitude and phase difference calculations, while the real part restores the physical signal.

An ideal resistor, inductor and capacitor have $Z_R=R$, $Z_L=\mathrm{i}\omega L$ and $Z_C=1/(\mathrm{i}\omega C)$. Their electrical impedances add in a series RLC circuit, giving $Z=R+\mathrm{i}(\omega L-1/(\omega C))$. The current amplitude is $V_0/|Z|$, so cancellation of the imaginary parts explains the resonant series RLC response. The component-law derivation and opposite complex exponential convention are in reactance phase convention.

Electrical reactance $X$ is the signed imaginary part of electrical impedance $Z=R+\mathrm{i}X$, measured in ohms. It describes the part of the terminal electric potential difference in phase quadrature with the electric current in a sinusoidal steady state. In the $e^{\mathrm{i}\omega t}$ convention, an ideal inductor has $X_L=\omega L>0$ and an ideal capacitor has $X_C=-1/(\omega C)<0$ for $\omega >0$. A large $|X|$ reduces electric current at fixed applied voltage, but an ideal purely reactive component returns the energy it receives over each cycle. This is why electrical reactance and electrical resistance have the same units yet describe different physical behavior. ^[ref].

In a series RLC circuit, electrical impedances add because the same electric current passes through every component. For ideal positive inductance $L$, capacitance $C$, and total electrical resistance $R_{\Sigma }>0$,Here $\varphi$ is voltage wave phase minus current wave phase. Below ${\omega }_0=1/\sqrt{LC}$, $X<0$ and electric current leads terminal voltage; above it, $X>0$ and electric current lags. At ${\omega }_0$, the two signed electrical reactances cancel, leaving $Z=R_{\Sigma }$ and the maximum electric current at fixed terminal voltage. This is the resonant series RLC response. Electrical resistance does not cancel: the toy circuit gives $f_0={\omega }_0/(2\pi )=1591.55\mathrm{Hz}$ and $I_{\mathrm{rms}}=9.091\mathrm{mA}$ there. These numbers follow directly from the stipulated component values. ^[ref].

Cancellation concerns terminal voltage, not the disappearance of stored energy. In the toy circuit at resonance, the individual inductor and capacitor voltages are each $0.9091\mathrm{V}$ in root mean square magnitude, with opposite wave phases, while their sum is zero. Their peak stored magnetic energy and capacitor energy are each $0.8264\mu \mathrm{J}$, attained at different times. With smaller positive $R_{\Sigma }$, either component voltage can exceed the applied voltage. This ability to select a frequency while sustaining internal energy exchange connects electrical reactance to tuning and frequency response.

For an ideal inductor or capacitor, the absorbed instantaneous power equals the rate of change of stored energy:Positive power stores energy; negative power returns it. Over a periodic steady state, each stored energy returns to its initial value, so its cycle-averaged absorbed power is zero. An ideal resistor instead has $p_R=R{i}^2\ge 0$, transferring energy into Joule heating. More generally, the average terminal power of this series RLC circuit isZero average power in an ideal reactive component does not imply zero instantaneous power, zero electric current, or zero stored energy. Real coils and capacitors have losses, so zero ideal reactive loss is a model assumption rather than a claim about every component. ^[ref].

An electric battery converts the available chemical Gibbs free energy of one or more galvanic cells into electrical work delivered to an electrical load. The reacting materials are a finite reservoir: a battery can sustain a terminal electric potential difference while discharging, but cannot supply energy indefinitely. Unlike a capacitor, whose capacitor energy resides in an electric field, a battery chiefly stores its available energy in the chemical state of its materials. The detailed half-reactions and apparatus of a Daniell cell explain this conversion at the electrode level.

During discharge, electrons move through metallic wires from the negative anode, through the electrical load, to the positive cathode; external conventional current points the other way. Inside the battery, ions carry electric current through the electrolyte, and redox chemical reactions connect ionic transport to electronic transport at the electrodes. The same electron does not make a lap through both wire and electrolyte. Electric charge conservation closes the circuit; changing chemical composition supplies the energy. See galvanic cell for the two transport paths and electrolyte for how oppositely moving ions contribute to one net electric current.

The source's electromotive force $\mathcal{E}$ measures its driving work per unit electric charge, in volts; the loaded terminal electric potential difference $V_L$ measures the electrical work per unit electric charge delivered outside the battery. They agree in an ideal lossless source, or approximately near open circuit, but generally differ during discharge.^[ref]

In the ideal fixed-voltage model used in fixed-voltage capacitor energy balance, a battery maintains a prescribed terminal electric potential difference while electric charge flows to or from the capacitor. This is a constraint for that calculation, not an inexhaustible reservoir. The fixed-voltage capacitor energy balance also accounts for electrical energy returned to the source; an actual cell can accept sustained charging only if its chemistry and operating conditions permit it.

An instrument that combines subsurface temperature measurements with constraints on thermal conductivity to estimate a local heat flux. Multiple sensor depths help separate a stable geothermal gradient from surface-temperature transients and installation disturbance. Conductive heat flow can differ from total heat transport where fluid circulation carries substantial energy.

Joule heating is the dissipative conversion of electrical work into internal energy in an electrical conductor. In a metal, the electric field supplies energy to charge carriers, which transfer it to the material. This makes an immersed resistor a useful calibrated heater and makes electrical resistance a source of losses in wiring. Wind-driven electric currents are a proposed source of heating of an inflated giant planet.

For a stationary, purely resistive Ohmic conductor, use the passive sign convention: $V$ is the terminal electric potential difference from the entry to the exit of positive electric current $I$. The absorbed electrical power and Ohm's law giveThe last two expressions assume $V=IR$ at the relevant material temperature. For constant electrical resistance and electric current over a duration $\Delta t$, the dissipated energy is $E_{\mathrm{diss}}=I^{2}R\Delta t$; otherwise use $E_{\mathrm{diss}}=\int V(t)I(t)dt$. In SI, $\mathrm{V}\mathrm{A}=\mathrm{W}=J/s$.^[ref]

Absorbed electrical power $VI$ is more general than Joule heating: a capacitor can store energy, a battery can change its chemical energy, and an electrical circuit can deliver mechanical work or emit light. Even a heated resistor need not show an indefinitely rising temperature: in a thermal steady state, its dissipated power leaves by heat transfer. With the heater inside a calorimeter boundary, electrical input crosses as work; the subsequent heat transfer to the room is a different term in the first law of thermodynamics.

The microscopic magnetic response becomes a macroscopic field problem through the magnetization $\mathbf{M}$, the magnetic dipole moment per unit volume. Definein magnetostatics. Bound currents are represented by ${\mathbf{J}}_b=\nabla \times \mathbf{M}$ and surface current ${\mathbf{K}}_b=\mathbf{M}\times \hat{\mathbf{n}}$. Normal $B$ is continuous across an interface, while $\hat{\mathbf{n}}\times ({\mathbf{H}}_2-{\mathbf{H}}_1)={\mathbf{K}}_{\mathrm{free}}$. It is generally incorrect to impose continuity of every component of both fields. A linear isotropic material has $\mathbf{M}=\chi \mathbf{H}$ and ${\mu }_r=1+\chi$, but a ferromagnet usually requires a nonlinear, history-dependent constitutive relation.

Internal field differs from externally applied field. For uniform magnetization along a principal axis of an ellipsoid, the demagnetizing field is $-N_{d}M$ and $H_{\mathrm{int}}=H_{\mathrm{applied}}-N_{d}M$. A linear specimen therefore has apparent susceptibility $\chi /(1+N_d\chi )$ relative to the applied field. Shape is especially important for large susceptibility. A long closed magnetic circuit reduces stray fields; a bar magnet still has demagnetizing fields despite the absence of magnetic monopoles. Equivalent magnetic-pole descriptions are bookkeeping for magnetization divergence, not free magnetic charge.^[ref]

In paramagnetism, permanent localized moments are preferentially aligned by the field, against thermal disorder. For independent spin-one-half moments with projections $\pm \mu$, the two Zeeman energies givein the dilute weak-field limit with $B\simeq {\mu }_{0}H$. This is a Curie law; the response saturates at $n\mu$ when alignment dominates. More generally, spin $J$ gives $\chi ={\mu }_{0}n(g{\mu }_B{)}^{2}J(J+1)/(3k_{B}T)$. Interactions can produce a Curie–Weiss response $C/(T-\Theta )$ over a suitable range. Conduction-electron Pauli paramagnetism need not show the localized-moment $1/T$ law.

In diamagnetism, the field induces a magnetic moment opposing it, so the linear susceptibility is negative. The microscopic cause is the change in orbital electronic motion, and a closed-shell insulating material has no permanent atomic moment to orient. This weak response is often only mildly temperature dependent away from other transitions. It also exists as a background in materials with a stronger positive response. Perfect flux expulsion in a superconductor is a distinct collective phenomenon and should not be identified with ordinary weak atomic diamagnetism.

In ferromagnetism, exchange interactions stabilize spontaneous magnetic order below the Curie temperature. A specimen can have zero net moment while its magnetic domains remain locally magnetized in different directions. Domain-wall motion and moment rotation produce a large response; anisotropy and pinning lead to remanence, coercivity and hysteresis. Increasing field eventually approaches saturation. Heating above the ordering transition removes spontaneous order, although an applied field still induces a response. Soft magnetic cores favor easy reversal and small cyclic loss; hard permanent-magnet materials favor retained magnetization and resistance to reversal. These properties concern collective order and barriers, not merely independent moments all following a weak field.^[ref]

A practical distinction requires a controlled field sweep and a separate magnetic readout. A toroidal core with drive winding $N_1$, path length $l$ and current $I$ has approximately $H=N_{1}I/l$. A pickup winding measures ${\mathcal{E}}_2=-N_{2}AdB/dt$; integrating after calibration gives $B$, and $M=B/{\mu }_0-H$. Reversing the sweep reveals a loop whose positive loss area per volume is $\oint HdB$. An air-core/empty-holder reference, known geometry and turn count, offset correction, temperature control and slower sweeps test background, heating and rate-dependent eddy-current losses. A single force or susceptibility reading cannot establish spontaneous order or hysteresis. The original curves below are illustrative responses, not measured material data.

Put the positive plate at $z=d/2$ and the negative plate at $z=-d/2$. Reflection through $z=0$, combined with reversal of the two plate charges, makes the tangential fields cancel at every point of the mid-plane. Thus $E_x=E_y=0$ at the corner as well as inside the capacitor.

For the uniform-charge estimate at a capacitor corner, assemble four identical square pairs around their common corner. Their normal fields there are equal by rotation symmetry and add to the central field $\sigma /{ϵ}_0$ of the larger plate pair. With the bulk parallel-plate relation $\sigma \simeq {ϵ}_{0}V/d$, the conventional corner estimate isThis quarter-field result uses prescribed uniform surface charge, not symmetry alone for finite equipotential conductors. Real conducting plates redistribute charge near their edges; $d\ll a$ justifies the bulk relation away from the edges but does not remove the local corner fringe. For that exact conductor problem only the zero tangential components follow from the stated reflection symmetry; its normal coefficient requires a fringing-field boundary-value solution. The standard parallel-plate formula explicitly neglects edge effects.^[ref]

For sinusoidal steady state with the $e^{i\omega t}$ convention, complex impedance is the phasor ratio $Z=\tilde{V}/\tilde{I}$, encoding both amplitude ratio and phase. From $V=LdI/dt$, an ideal inductor has $Z_L=i\omega L$; from $I=CdV/dt$, a capacitor has $Z_C=(i\omega C{)}^{-1}$.

The original diagram has $R_1,L_1$ in series, and $R_4,C_4$ in parallel. ThusWith the right supply node as the reference, the two unloaded voltage divider outputs are ${\tilde{V}}_A=V_0{R}_2/(Z_1+R_2)$ and ${\tilde{V}}_B=V_0{Z}_4/(R_3+Z_4)$. Subtracting givesThe series-RL parallel-RC bridge balance is $Z_1{Z}_4=R_2{R}_3$. Equating its real and imaginary coefficients givesThese ideal components balance the bridge at any frequency, not just the test frequency.

At $\omega =200\mathrm{rad}{\mathrm{s}}^{-1}$, the current amplitude through $R_2$ is $5/|50+50i|=0.0707\mathrm{A}$. Using peak rather than RMS supply amplitude,In the DC steady state the inductor is a short and the capacitor is open. Both dividers have equal resistors, so each midpoint is at2.5V and the bridge stays balanced. The upper-branch current is0.100A, giving $\boxed{P_{R_2,\mathrm{DC}}=0.250\mathrm{W}}$.

For the high-input-resistance voltmeter, hold the other components fixed. At the DC balance,The DC bridge resistance resolution is a local readout resolution, or0.08% of $R_1$, not a total uncertainty allowing for supply, component calibration or voltmeter loading. ^[ref]

Gauss's law statesThe surface is closed and oriented outward, and $Q_{\mathrm{enc}}$ includes all enclosed charge. The integral law follows from the local form through the divergence theorem. It is universally valid in classical electromagnetism, but calculating the field directly from the flux requires enough symmetry.

For spherical charge symmetry, $E(r)=Q(<r)/(4\pi {ϵ}_0{r}^2)$. A uniform infinite line gives $E=\lambda /(2\pi {ϵ}_{0}r)$ from a coaxial cylinder. An infinite sheet gives $E=\sigma /(2{ϵ}_0)$ on either side from a pillbox, with the direction set by charge sign. The normal field jump is $\sigma /{ϵ}_0$; the electrostatic field inside a conductor is zero. Zero enclosed charge implies zero net flux, not generally zero field. ^[ref]

For a steady thin-wire current in vacuum, the Biot-Savart law isThe line element follows conventional current direction. More generally replace $Id{\mathbf{\ell }}^{\prime }$ with $\mathbf{J}({\mathbf{r}}^{\prime })d^3{r}^{\prime }$. The cross product gives the circulating field direction and superposition allows contributions from separate wire segments to be added.

Integration gives $B={\mu }_{0}I/(2\pi r)$ around a long straight wire. On the axis of a circular loop of radius a, $B_z={\mu }_{0}I{a}^2/[2(a^2+z^2{)}^{3/2}]$, including the centre value ${\mu }_{0}I/(2a)$. Coil turns multiply the field when their geometries coincide; distributed coils and solenoids follow by integration. This is a magnetostatic or quasistatic calculation: rapidly changing currents require retarded electrodynamics and appropriate displacement-current effects, not an instantaneous wire formula. ^[ref]

For a stationary closed circuit, Faraday's law of induction isThe loop orientation and magnetic-flux normal obey the right-hand convention. For a moving material circuit, the emf is instead $\oint (\mathbf{E}+\mathbf{v}\times \mathbf{B})\cdot d\mathbf{\ell }$, with the same negative derivative of the flux through the moving circuit. The additional magnetic force term accounts for motional emf.

Lenz's law expresses the minus sign physically: an induced current opposes the change in flux that produces it. It does not always oppose the field itself. Increasing positive flux drives a current producing negative flux; decreasing it reverses that response. A straight conducting rod of length l moving across a perpendicular uniform field has emf magnitude Blv. A resistive return circuit then develops a magnetic braking force, and the supplied mechanical power equals Joule heating in the ideal steady limit. This connects induction with conservation of energy. ^[ref]

Drive a series RLC circuit with electric potential difference $V(t)=V_0\cos (\omega t)$, where $V_0>0$ and $\omega >0$. After the free transient decays, the electric current has the same angular frequency as the source:For fixed positive $R,L,C,V_0$, the electric current amplitude is largest exactly at $\omega ={\omega }_0=1/\sqrt{LC}$. The two electrical reactance contributions cancel there, leaving only the drop from electrical resistance. In particular,Every solution approaches this periodic response because its difference from the displayed solution is a decaying free response. The peak remains at ${\omega }_0$ even for an overdamped RLC response; free ringing is not required for a maximum of driven electric current. ^[ref].

For example, stipulate $L=10\mathrm{mH}$, $C=1\mu \mathrm{F}$, $R=20\Omega$, and $V_0=1\mathrm{V}$. Then ${\omega }_0=10^4{\mathrm{s}}^{-1}$, $f_0={\omega }_0/(2\pi )\approx 1591.55\mathrm{Hz}$, and the peak electric current amplitude is $50\mathrm{mA}$. Holding the source amplitude fixed is essential when comparing responses at different frequencies.

Three frequencies must be distinguished. The free underdamped RLC response rings at ${\omega }_d=\sqrt{{\omega }_0^2-{\alpha }^2}$. Driven electric current peaks at ${\omega }_0$. Driven electric charge has amplitudewhose peak occurs at $\sqrt{{\omega }_0^2-2{\alpha }^2}$ only if $\alpha <{\omega }_0/\sqrt{2}$. Otherwise it decreases from its zero-frequency limit $C{V}_0$, with no positive-frequency peak. The different peak locations follow because electric current is the time derivative of electric charge, multiplying a sinusoidal amplitude by $\omega$. The limiting responses are $I_{\mathrm{amp}}\sim V_{0}C\omega$ as $\omega \to 0^{+}$ and $I_{\mathrm{amp}}\sim V_0/(L\omega )$ as $\omega \to \infty$.

The Q factor measures selectivity:The average Joule heating power is $R{I}_{\mathrm{amp}}^2/2$. Its half-maximum angular frequencies and their separation are exactlyThese follow by setting $|\omega L-1/(\omega C)|=R$. In the numerical example, $Q=5$ and $\Delta \omega =2000{\mathrm{s}}^{-1}$. Reducing $R$ makes a taller, narrower electric current peak; varying $C$ tunes the selected frequency. Measuring the drop $v_R=Ri$ gives a band-pass filter that suppresses very low and very high frequencies while passing a range near resonance. This is useful for selecting a radio signal, though the range must be broad enough to pass its modulation. ^[ref].

Consider a stipulated series circuit containing an ideal resistor of electrical resistance $R=100\Omega$ and an ideal capacitor of capacitance $C=1\mu \mathrm{F}$. The same electric current passes through both. Their terminal electric potential differences add by Kirchhoff's voltage law, soA quick derivation uses $i=Cd{v}_C/dt$: taking the derivative of the complex exponential multiplies the capacitor voltage phasor by $\mathrm{i}\omega$, hence ${\hat{V}}_C=\hat{I}/(\mathrm{i}\omega C)$. Dimensionally, $1/(\omega C)$ has units $s/F=V/A=\Omega$, matching $R$.

At frequency $f=1000\mathrm{Hz}$, the angular frequency is $\omega =2\pi f$. The signed capacitive electrical reactance, modulus and complex argument of the total electrical impedance areApply $V_{\mathrm{rms}}=1.00\mathrm{V}$ across the complete series circuit. Its root mean square electric current isWith voltage as the zero-phase reference, the current phasor has complex argument $+57.858092^{\circ }$: electric current leads. The phasor drops have moduli $V_{R,\mathrm{rms}}=0.532018\mathrm{V}$ and $V_{C,\mathrm{rms}}=0.846733\mathrm{V}$; these add as complex numbers, not as positive magnitudes. Their squared magnitudes sum to $(1.00\mathrm{V}{)}^2$.

The mean absorbed power uses the root mean square values:The ideal capacitor has zero cycle-averaged absorbed power; all the mean absorbed power becomes Joule heating in the resistor.^[ref] To see why the phase factor appears, average $p(t)=v(t)i(t)$ over a full cycle with $v(t)=\sqrt{2}{V}_{\mathrm{rms}}\cos \omega t$ and $i(t)=\sqrt{2}{I}_{\mathrm{rms}}\cos (\omega t-\varphi )$. The cosine addition formula reduces the average to $V_{\mathrm{rms}}{I}_{\mathrm{rms}}\cos \varphi$; the term at $2\omega$ averages to zero. Independently, $p_C=d(C{v}_C^2/2)/dt$, and the capacitor energy returns to its starting value after each cycle.

At fixed applied $V_{\mathrm{rms}}$, the limit $\omega \to 0^{+}$ gives $|Z|\to \infty$, $\varphi \to -\pi /2$ and $I_{\mathrm{rms}}\to 0$: the ideal capacitor blocks steady electric current. The limit $\omega \to \infty$ gives $Z\to R$, $\varphi \to 0$ and $I_{\mathrm{rms}}\to V_{\mathrm{rms}}/R$. These are limits of the ideal lumped electrical circuit; unwanted lead inductance and component losses can invalidate that model at high frequency. At $\omega RC=1$, the equal legs of the impedance right triangle give $|Z|=\sqrt{2}R$ and $\varphi =-\pi /4$ without numerical evaluation. Measuring both the magnitude and the sign of the phase difference distinguishes this capacitor response from an equally large positive electrical reactance.

A measure of how rapidly a material exchanges heat with another body in transient contact. Here k is thermal conductivity, $\rho$ is mass density and $c_p$ is specific heat capacity. Perceived coldness at equal actual temperature can depend on this contact heat transfer rather than on an electronic Fermi temperature.

An electrical transformer transfers energy between windings through electromagnetic induction. Its operation depends on changing magnetic flux, rather than a static magnetic field alone.

If two thermodynamic systems are each in thermal equilibrium with the same third system in the same equilibrium state, they are in thermal equilibrium with each other. Write $A\sim B$ for this relation. The zeroth law of thermodynamics supplies transitivity:Its symmetric relation property and self-equilibrium (reflexivity), together with transitivity, make thermal equilibrium an equivalence relation. Its equivalence classes can be labelled by a common empirical temperature; choosing an absolute numerical scale requires the further structure of thermodynamic temperature.^[ref]

The comparison assumes internally equilibrated macroscopic bodies, unchanged composition and mechanical constraints, and contact permitting only heat exchange. Use rigid, impermeable diathermal walls so that neither matter transfer nor boundary work spoils the test. The same state of $C$ matters: letting $C$ warm while measuring $A$, then cool while measuring $B$, does not supply the premise. Ordinary nonrelativistic laboratory thermodynamics is assumed; the Tolman temperature law treats gravitational qualifications. Equal temperatures establish the thermal condition, without requiring mechanical equilibrium or chemical equilibrium.

This explains why a thermometer can compare unlike materials: it supplies a reusable third system. A temperature is a property of an equilibrium state, while heat is energy transferred because of a temperature difference. Two bodies at the same temperature can have different internal energies and heat capacities. A thermometer therefore does not measure a body's stored amount of heat; the finite-body disturbance and waiting-time calculations in thermometer describe how making the comparison can change the state being measured.^[ref]

The name “zeroth” reflects logical order rather than the date of the first thermometer: this premise about thermal equilibrium precedes the already numbered first law of thermodynamics, Second law of thermodynamics and third law of thermodynamics. This is the naming explanation given in University Physics Volume 2 by Samuel J. Ling and others (§1.1, “Thermal Equilibrium”).^[ref]

The corresponding Zeroth law of black-hole mechanics states constancy of surface gravity over an equilibrium horizon; Hawking radiation identifies that quantity with physical temperature up to its universal conversion factor.

Put a contact thermometer $C$ in thermal contact with $A$, wait for thermal equilibrium, and record response $X_A$. Repeat with $B$ under the same operating constraints. If $X_A=X_B$, and the calibrated response is an injective function of temperature on this range, $C$ occupies the same thermal reference state in both comparisons. The zeroth law of thermodynamics then predicts $A\sim B$. Equality of raw numbers from different uncalibrated thermometers supplies no such premise.^[ref]

Use a probe whose participating heat capacity is small relative to each sample, or use maintained heat baths. Otherwise the matching readings describe the disturbed final states. Also hold the probe's immersion and mechanical conditions fixed: its response can depend on more than temperature. Matching readouts only tests agreement within resolution and repeatability, rather than proving exact equality of temperatures.

Agreement within a tolerance is not itself an equivalence relation. With a $0.10{}^{\circ }\mathrm{C}$ tolerance, readings $25.00$ and $25.16{}^{\circ }\mathrm{C}$ each agree with $25.08{}^{\circ }\mathrm{C}$, yet disagree with each other. This is a limitation of the measurement rule, not a failure of the exact transitivity asserted by the zeroth law of thermodynamics.