Write , where is the inverse temperature, is temperature and is the Boltzmann constant. In the canonical ensemble, each spin configuration has probability . The nearest-neighbor Boltzmann factors multiply, so the spin-chain transfer matrix, in the order , is
Multiplying its entries around the ring and summing over every Ising spin yields the partition function:
The trace implements the periodic boundary conditions; replacing it by an endpoint sum would describe a different partition function. The normalized eigenvectors and corresponding eigenvalues are
The negative eigenvalue is essential for the antiferromagnetic Ising model. Introduce their ratio
The exact finite- partition function and Helmholtz free energy are
For finite , , so for both even and odd . The last term retains the finite-ring effect of geometric frustration.
To insert an Ising spin into this trace, use the diagonal matrix . In the eigenbasis of , it exchanges and , and hence has vanishing diagonal entries. The one-point correlation function is therefore
The same conclusion follows directly from spin inversion symmetry: reversing every Ising spin preserves the energy and the Boltzmann factor while reversing .
For the two-point correlation function, the two insertions divide the ring into paths of and bonds. Thus
In particular, the exact finite-ring antiferromagnetic Ising correlation is
Because the one-point correlation functions vanish, this is also the connected correlation function. It gives and , as required by and exchanging the two paths around the ring. At , distinct Ising spins are independent and for ; is understood separately if a power occurs in the displayed expression.
Write the initial mass density as . The ideal gas law gives pressure , and the sphere has . Here is the Boltzmann constant and is the gravitational constant. First obtain the gravitational potential energy by adding concentric shells. The mass inside radius is , so
In a small contraction at fixed total mass, the gravitational energy released is . The positive work required against the gas pressure is . Equating these gives
Use to eliminate the radius. The uniform-sphere pressure-work collapse criterion is
The units are kilograms: has units , and supplies . At fixed initial and , makes gravity stronger than the pressure-work requirement in this model, allowing contraction.
This is a Jeans mass estimate for homologous contraction of an initially uniform sphere. It is not an exact stability limit for a hydrostatic gas sphere: uniform mass density and uniform temperature would give uniform pressure, rather than the gradient required by hydrostatic equilibrium. The numerical coefficient therefore differs from conventions based on a Jeans instability wavelength or a pressure-confined isothermal sphere. Subsequent contraction also depends on heat exchange; isothermal pressure support during gravitational collapse weakens relative to gravity as the radius decreases.
In Flory–Huggins solution theory, is the volume fraction, is the number of equal-sized lattice segments per chain, is temperature, is the Boltzmann constant, and is the dimensionless Flory interaction parameter. The stated is the mixing Helmholtz free energy per lattice site. The first two terms describe mixing entropy; the last describes the contact-energy contribution.
At fixed and composition-independent ,
Hence the spinodal is
The homogeneous state is locally unstable when . The minimum gives the critical point of a Flory–Huggins polymer solution:
If depends on temperature, the equation converts this result into a temperature–composition boundary.
Here is electric current density, the number density of independently mobile ions, their charge, absolute temperature and the Boltzmann constant. The sum runs over all nearest-neighbour destinations of site , and is the displacement from to . The applied field is , is an attempt frequency, and is the zero-field reaction energy barrier for the indicated jump. With the normalization of the supplied equation,
It has units s; it is not an equilibrium occupation probability. The current formula is the linear-response result of a small field-induced asymmetry in forward and reverse rates, requiring . Use its explicit factor consistently rather than absorbing it into a redefined jump rate.
Let , with the Boltzmann constant, the absolute temperature, and the common equilibrium chemical potential. The conduction band minimum and valence band maximum are and ; their separation is the band gap . The positive parameters in the supplied density of states functions are the band effective masses of electrons and electron holes, not necessarily the bare electron mass.
The electron occupation is the Fermi-Dirac distribution . The appropriate statistical factors are for electrons and for electron holes. In a nondegenerate semiconductor, and , so the Boltzmann approximation gives
For the conduction band, set and then . The supplied integral yields
For the valence band, set to obtain
The effective density of states factors include the two spin states already present in the supplied density of states functions. Multiplication cancels the chemical potential and gives the semiconductor mass-action law
Here is the intrinsic carrier concentration. Equality additionally requires an electrically neutral intrinsic semiconductor. The product law also applies to an equilibrium doped semiconductor while both populations remain nondegenerate. The derivation assumes parabolic energy bands, the stated spin degeneracy, and a single common chemical potential.
Let be the gas density and the total gravitating mass. For a spherically symmetric gas in hydrostatic equilibrium, radial force balance is
Using the ideal gas law , with constant mean molecular weight , differentiate the product rather than setting constant:
Substitution and cancellation of give the cluster hydrostatic mass estimator
Here is the Boltzmann constant, denoted in the question. The prefactor has units of mass; a pressure decreasing outward makes the bracket negative and the inferred mass positive. For an isothermal gas with , this reduces to . The density in the logarithmic derivative is the gas density, not the total density. A varying or nonthermal pressure would require the corresponding extra terms.
The vertical hydrostatic equilibrium equation balances the gradient of the total pressure against gravity. In a thin disk with Keplerian rotation, expanding the central gravitational field about the midplane gives vertical acceleration , so . Disk self-gravity is neglected in this approximation.
The flux-gradient equation is local thermal balance: the upward radiative flux increases with height because differential rotation dissipates energy. For a Newtonian effective dynamic viscosity , the volumetric heating rate is , which becomes for Keplerian rotation. The symbol here is dynamic viscosity, not kinematic viscosity; the latter is .
The radiative diffusion equation applies to an optically thick medium in local thermodynamic equilibrium. Its diffusion coefficient is , and the equilibrium radiation energy density is . Hence
The minus sign means energy flows down the temperature gradient. Here is the Stefan-Boltzmann constant, the opacity per unit mass, and the speed of light. Constant Thomson scattering opacity is the adopted transport approximation; local thermodynamic equilibrium is an additional assumption behind the radiation equation of state.
Finally the equation of state adds ideal gas gas pressure and isotropic radiation pressure . The Boltzmann constant is , and is the mean mass per gas particle. Both contributions supply the total pressure entering vertical hydrostatic equilibrium.
Write , with the Boltzmann constant. For independent Ising spins, the one-site partition functions on the two sublattices are and . Differentiating each logarithm with respect to its local field gives
At , the two sublattices experience opposite fields, so spin reversal combined with sublattice exchange leaves the Hamiltonian invariant and gives .
For the antiferromagnetic Ising model, take sites, equal sublattice sizes and neighbors per site. There are bonds counted once. The two-sublattice Ising mean-field approximation expands each bond as
and drops only the product of fluctuations. Summing the remaining terms gives
The printed constant omits ; for a total Hamiltonian with unnormalized spin sums, this factor is necessary. Applying the independent-spin calculation now gives
The mean-field approximation is favored by large coordination number: averaging many neighbors reduces local relative fluctuations. The size of critical fluctuations still has to satisfy the Ginzburg criterion; high dimension is a reason for validity, not permission to discard every correlation in every regime.
Antisymmetric solutions and the transition. At , putting makes both equations reduce to . A zero-field continuous transition concerns as well: nonzero explicitly selects the staggered sign and rounds this critical bifurcation. Put . The graphical intersections of and give only for . For there are additionally two nonzero intersections : on , is strictly concave, initially increases, and is negative at , so there is exactly one positive root. Spin reversal supplies the negative root. The origin becomes unstable in the staggered direction, whereas the nonzero roots have and are stable. Expanding about the bifurcation gives
Thus turns on continuously, with and order-parameter critical exponent .
Figure 1.
Antiferromagnetic mean-field graphical solutions and continuous onset of staggered magnetization
. Details.
Uniform solutions. At , imposing instead gives . The function has derivative , is negative at and positive at , and consequently has exactly one zero for every positive temperature. At this zero is . Antiferromagnetic exchange opposes uniform polarization, so the uniform branch has no ferromagnetic ordering bifurcation. This does not remove the antisymmetric solutions below , or exclude transitions of staggered order in the full problem at nonzero uniform field. In particular, uniqueness on the diagonal is not uniqueness of all solutions.
Free energy and stability. The appropriate off-shell two-sublattice Ising variational free energy is the energy minus temperature times the independent-spin entropy. Define
There are bonds and spins of each kind, so the free-energy density per site is
Since , stationarity gives
and the analogous equation for ; these are exactly the two mean-field self-consistency equations. On a stationary solution, the identity gives the equivalent on-shell expression
The entropy form must be used to compare off-shell variations; treating this latter auxiliary expression as the variational potential would give spurious stability conclusions.
Using and , gives
This includes the requested quadratic expansion and first-order field terms. The positive quartic coefficient verifies a continuous phase transition in when the staggered quadratic coefficient changes sign at . The uniform quadratic coefficient remains positive.
Susceptibilities and a printed error. On a stable zero-field ordered branch let and . Since the derivative of is , differentiating the two equations with respect to the uniform field gives
Their sum and difference yield
The difference equation is ; stability implies for . Symmetry also explains the zero result: a uniform perturbation changes the two sublattice magnetizations equally to first order, and hence does not linearly change the staggered magnetization. This is a cross response to , not the magnetic susceptibility to the staggered field .
The displayed in the source instead contains . It cannot follow from differentiating the stated equations. A decisive limiting check is : vanishes exponentially and the actual uniform response tends to zero, whereas the printed expression tends to . Above , and the same linear system gives
For comparison, the actual staggered susceptibility is , becoming above . Its divergence, rather than a divergence of the uniform response, detects antiferromagnetic criticality.
Introduce a constant filament bending modulus , which sets the mechanical force scale. The filament has intrinsic curvature of an elastic filament , and its actual signed curvature in a small-slope Monge representation is . To quadratic order one may identify material arc length with in , while
At fixed positive extension force, the mechanical potential is bending energy minus . Replacing by leaves, up to a force-dependent constant,
Its first variation is
The higher-order Euler-Lagrange equation is therefore
For a Fourier transform relation, take a periodic bulk segment, or a long-filament bulk approximation with negligible endpoint contributions; these are necessary boundary conditions because the question specifies no filament end conditions. Using , every nonzero wavenumber obeys
A zero displacement mode is an arbitrary translation. In a periodic representation a constant intrinsic-curvature mode contributes a constant bending cost but no bulk slope, so it does not contribute to the following deficit. The Parseval identity gives
For clarity about finite normalization, on a periodic interval of length define , . Then the equivalent exact quadratic-order formula is
This is force-extension of an intrinsically curved filament, determined by its particular fixed shape rather than by a thermal orientation entropy.
For an ensemble with quenched intrinsic curvature, first minimize each realization and then average the last expression, replacing by its ensemble mean. For stationary bulk disorder, let be the power spectrum, normalized so that its correlation is . The measurable mean deficit per unit projected length is
If the curvature is smooth enough that the second spectral moment is finite, one can take the large-force limit under this integral, obtaining the smooth-curvature high-force extension law
For a stationary ensemble the integral is . Equivalently, the bulk slope is ; a plot of the mean deficit against measures the mean squared intrinsic-curvature gradient, if is known. The law is a smooth-curvature bulk result, not a universal law for every random filament. For example, ideal white intrinsic-curvature disorder with has an infinite second spectral moment; retaining the full integral instead gives in that ideal continuum model.
Endpoint conditions also matter. If each end is moment-free and has no transverse applied force, the natural conditions from the variation are
at each end. These can produce a free-end curvature boundary layer of width . For a constant intrinsic filament curvature , integration of the higher-order Euler-Lagrange equation with zero transverse force gives and hence
The last formula follows by integrating , and tends to , despite the vanishing bulk curvature gradient. Thus a finite free-ended measurement must include or suppress endpoint bending before interpreting a bulk fit.
For the freely jointed chain, rigid links have independent orientations, so the restoring force is entropic. Let now denote absolute temperature, and with Boltzmann constant . In the usual three-dimensional chain, a segment at polar angle has force energy . Its angular canonical partition function and the full chain partition function are
Differentiating with respect to yields the exact mean projected displacement
Here is the Langevin function; this is force-extension of a three-dimensional freely jointed chain, in the fixed-force canonical ensemble. At high extension, , so
Thus the smooth quenched-curvature bulk deficit falls as , whereas the three-dimensional freely jointed chain deficit falls as and depends explicitly on temperature. The distinction is mechanical straightening of a fixed intrinsic shape versus orientational entropy; thermal bending fluctuations of a stiff filament have not been included in the first calculation.
If the comparison chain is also restricted to two dimensions, it is a planar freely jointed chain rather than the three-dimensional model. In this case,
The last identity follows directly by differentiating the integral defining ; and are Modified Bessel functions of the first kind. At large the angular weight is proportional to , giving . Consequently : the same inverse-force exponent, with half the three-dimensional coefficient. Both versions assume inextensible links and forces below the regime where the links themselves stretch.
Choose real eigenfunctions with . For positive modes, self-adjointness and integration by parts diagonalize the energy:
At temperature , the canonical ensemble is a product of centered Gaussian distributions. The equipartition theorem, with Boltzmann constant , gives
The resulting thermal covariance of an elastic filament is
For an unnormalized eigenfunction of squared L2 norm , divide its summand by . This normalization factor cannot be absorbed silently into the modal variance.
For clamped boundary conditions at both ends, the inverse of has Green function, for ,
It is cubic on each side of , satisfies the four clamped conditions, has continuous first two derivatives, and has unit jump in its third derivative. Thus , and its eigenfunction expansion is the sum above. In particular,
These finite variances require removal of every zero-energy filament mode. An unconstrained free-free elastic filament can translate and tilt at no energy cost; a torqued-torqued elastic filament can translate. Their unrestricted Boltzmann distributions are not normalizable, so the full displacement variance is undefined. Fix those rigid degrees of freedom before applying the positive-mode formula.
Take a long periodic section of length , or neglect end effects and choose an integer number of wavelengths. The amplitude here is a single real sine amplitude, fixing the normalization of the thermal membrane undulation spectrum. For a lipid vesicle with an axisymmetric membrane deformation, conservation of the enclosed volume gives
The mean radius therefore decreases at second order. This adjustment is essential: fixing the mean radius instead of the volume would miss the unstable term in the fixed-volume capillary spectrum of a cylindrical membrane.
The surface area of an axisymmetric graph is . Expanding for and gives
Multiplication by the membrane tension yields a quadratic potential energy , where
For , the equipartition theorem gives the stable-mode fixed-volume capillary spectrum of a cylindrical membrane
Here is the Boltzmann constant and is the temperature. The cosine amplitude has the same variance and is an independent real coordinate at quadratic order. If instead with , the corresponding positive- complex coefficient has . This is the same thermal membrane undulation spectrum in a different Fourier mode normalization.
For , the cylinder is unstable rather than having a negative fluctuation variance. The quadratic surface area change is negative: a sufficiently long-wavelength modulation reduces area while retaining volume. This is the Rayleigh–Plateau instability, expressed here as pearling of a tension-dominated lipid vesicle. A cylinder supporting such modes has no unconstrained harmonic thermal equilibrium about the uniform state. The uniform radius change is forbidden by fixed volume, and is marginal in the tension-only approximation. The finite length and endpoint constraints determine which nonzero Fourier modes are allowed.
The large membrane tension assumption controls modes with of order one. For large the omitted membrane bending modulus contribution grows approximately as and overtakes the tension term when . Thus the displayed tension-only spectrum requires as well as small amplitudes and a positive stiffness. Close enough to the marginal wavelength, bending corrections must also be retained; their relative scale at of order one is .
For the circular phase boundary in a lipid bilayer, the energy is its perimeter times the line tension . Let be the polar angle and write , where the periodicity requires an integer . Fixed enclosed area implies
The perimeter, including the mean-radius change, is
Thus the fixed-area capillary spectrum of a circular boundary, again for a single real sine or cosine amplitude, is
The complex Fourier mode coefficient convention again divides this result by two. The mode is excluded by the fixed-area constraint, so the negative-stiffness interval is not an allowed mode of a closed circular boundary.
At , the zero stiffness is the translation mode of a circular boundary, not a shape instability. Displacing the centre by a small distance changes the radius to first order by or while leaving area and perimeter unchanged. For example, an exactly translated circle has
The higher harmonics complete a true translation mode of a circular boundary. The denominator therefore represents free centre motion: an unconfined domain's centre has no restoring force or finite equilibrium variance in an infinite membrane. Radius fluctuations about a recentered domain omit this mode; external confinement would give it a separate restoring stiffness.
In Landau-Ginzburg theory, use the sextic even Landau potential with a fixed positive stabilising coefficient :
Here is the scalar order parameter, its conjugate magnetic field, and an independent symmetry-preserving control, such as the single-ion coupling in the Blume–Capel model. Thus need not break , whereas does. The Blume–Capel mean-field tricritical parameters are one realization; generally, a tricritical point occurs when
Two controls tune away the quadratic and quartic terms. For , crossing at gives a continuous phase transition; for , the quartic term instead favours a finite- minimum before the origin loses local stability. The sextic term bounds the free energy below. The tricritical point joins the continuous and discontinuous transition loci.
For the symmetric phase diagram, write . A nonzero stationary point obeys . Its free-energy density relative to the origin is . Equality of the two minimum values, together with stationarity, gives
At this phase coexistence point,
so are genuinely degenerate global minima, not just stationary solutions. The spinodal points are for the disordered local minimum and for the appearance of the ordered minima. They are limits of metastability, distinct from the equilibrium first-order phase transition at .
Accordingly, the coefficient equations determining the physical temperature curves are
The simultaneous zeros of and determine and . For the alternative normalization , the same first-order condition is , with . These equations determine the curves implicitly; their slopes in actual coordinates depend on the material-specific coefficient functions.
In three controls , or locally equivalent coordinates, there are tricritical first-order wings. The plane contains a coexistence sheet of the two symmetry-related ordered phases. For it ends on the ordinary critical line ; for it reaches the three-phase line . Two further first-order surfaces extend from that line into and . Across a wing, two minima of the same sign but different magnitudes exchange global stability; the field favours that sign. Each wing ends on an ordinary critical edge where those minima and their intervening maximum merge. The three surfaces and their critical boundaries meet at the tricritical point.
The tricritical wing critical edges follow by imposing at :
Here , confirming an ordinary quartic critical minimum locally. The field scale and the temperature-like displacement both vanish at the tricritical point. If are independent smooth local coordinates in , the following diagram has the same local topology as the physical three-dimensional phase diagram. Its surfaces use exact equal-minimum conditions, as described by tricritical wing coexistence factorization.
Figure 1.
Symmetric transition curves and three-dimensional first-order wings of a sextic Landau potential
. Details.
For the order-parameter critical exponent and critical-isotherm exponent at the tricritical point, set to leading order and take . For , the ordered saddle has , while at the equation of state is . Hence the tricritical mean-field critical exponents are
These are mean-field critical exponents. Below the tricritical upper critical dimension they need not be the interacting exponents, and at that dimension logarithmic corrections can accompany the powers. Along a generic path with the quartic term is subleading in the tricritical balance; a path keeping fixed instead approaches ordinary critical behaviour.
For the Blume–Capel model, take ferromagnetic , count each nearest-neighbour bond once and use hypercubic coordination . The nearest-neighbour direction sum in the printed Hamiltonian is understood implicitly. In a ferromagnetic mean-field approximation, write and replace the interaction by its self-consistent single-site field . The single-site partition function and variational free-energy density are
The first term prevents double counting the interaction energy. Differentiation gives the mean-field self-consistency equation
Set and , the occupied-spin probability at . Expanding the single-site logarithm yields
The nontrivial simultaneous quadratic and quartic zeros require and , hence . At those values the sixth-order coefficient is , so the degeneracy is a stable tricritical point. The mean-field tricritical parameters are
This is a mean-field result, not a dimension-independent exact lattice transition temperature. The Boltzmann constant is kept explicit in this lattice calculation.
For the Rayleigh-Jeans spectrum of a finite blackbody disk, the Rayleigh-Jeans law replaces by . Here is the Planck constant and the Boltzmann constant. The multitemperature blackbody disk therefore has
For example, setting makes its frequency-independent coefficient proportional to the finite dimensionless integral
Although the exact effective temperature vanishes at the inner edge, the very narrow cold rim where the Rayleigh-Jeans law fails makes a negligible contribution in this limit. More formally, after dividing the integrand by , the inequality bounds it by , so dominated convergence justifies the result even at that edge.
At large radius, , and the contribution per logarithmic interval is . The outer disk dominates the low-frequency emission because its much greater area outweighs its lower effective temperature.
For intermediate frequencies use the allowed power-law approximation to the effective temperature and introduce
Then
so
The lower limit is much smaller than one and the upper limit much larger than one. Extending them to zero and infinity leaves a constant: near zero the integrand behaves as , and at infinity it decays exponentially. Hence the intermediate spectrum is
This is the one-third spectrum of a multitemperature disk. Much of the emission comes from radii where is of order , moving inward as the frequency rises. With the exact inner-edge profile, a broad intermediate interval also requires frequency well below ; the supplied approximation captures its slope away from the hottest annuli.
In the vertical equations, denotes dynamic viscosity, while is the mean molecular weight in units of the proton mass . The symbol denotes the Boltzmann constant. For the intended hydrostatic equilibrium calculation, put with , , and set . Dividing the hydrostatic equation by and integrating from the symmetric midplane gives
The specific enthalpy vanishes at the free surface. Hence the polytropic vertical structure in stellar gravity is
On , the ideal gas relation gives and ; the vacuum extension sets outside. The formula needs for a finite positive semi-thickness and assumes the harmonic vertical gravity remains valid through this height.
There is a genuine inconsistency if all four printed structure equations are imposed literally with and finite positive opacity: radiative diffusion then requires , whereas the polytropic temperature above has a nonzero gradient away from the midplane. The intended result is valid for the hydrostatic polytropic equation of state with the radiative closure replaced or neglected, for example an adiabatic opaque limit. It is not an exact simultaneous solution of the stated finite-opacity radiative system. With that radiative system and a nonvacuum ideal gas, instead gives an isothermal solution
which has no finite free surface. For , constant and constant would force constant density, contradicting hydrostatic balance on a nontrivial vertical interval. This is the zero-radiative-flux obstruction for a polytropic ideal gas.
Assume for stability. With equal quadratic coefficients and , the internal symmetry is the full orthogonal group . In two dimensions at positive temperature, with short-range interactions, the Mermin-Wagner theorem forbids spontaneous symmetry breaking of this continuous symmetry. Thus in both phases in the infinite system; a nonzero average order parameter does not distinguish them.
Instead measure the correlation function
The low-temperature phase has quasi-long-range order and algebraic correlations; the high-temperature phase has a finite correlation length and exponential correlations. More precisely,
A finite order parameter amplitude allows . Its long-distance Goldstone-mode effective free energy is . Restoring the Boltzmann constant and using the renormalized phase stiffness, the thermal phase fluctuations give
The Berezinskii–Kosterlitz–Thouless transition separates vortex-antivortex binding from unbound vortex defects. At the boundary, the universal stiffness jump gives and . The low-temperature phase stiffness is nonzero; it vanishes at long distances in the disordered phase. The exact transition location is fluctuation dependent and cannot be obtained just by setting the bare to zero.
Take for the ideal gas. At fixed cylindrical radius, put , where is the Boltzmann constant, the mean molecular weight and the proton mass. Also write . Vertical hydrostatic equilibrium, thermal equilibrium and the ideal gas law require
Consequently, with ,
Integrating from the midplane yields
The polytropic vertical structure in stellar gravity therefore has, for ,
where
This is a polytropic equation of state with polytropic index . For , set ; temperature has no physical gas value in that vacuum. Here is the finite semi-thickness, rather than an exponential disk scale height.
At thermal equilibrium, microscopic reversibility equates the probabilities of a path and its reversed path when both include their Boltzmann distribution initial weights. Denote their endpoint states by , including velocity if needed. Since the Hamiltonian is even under time reversal in classical mechanics,
This detailed balance condition and the energy balance for an autonomous Lagrangian yield
This is the fluctuation-dissipation relation for a Langevin particle: the strength of Gaussian white noise is fixed by the damping and temperature, with the Boltzmann constant.
For an equilibrium coarse-grained variable, the unresolved microscopic states contribute entropy; their statistical weight is encoded in the Helmholtz free energy, rather than in a single microscopic energy. Relative to the same reference measure, , so microscopic reversibility becomes
This extension assumes an equilibrium coarse-grained description with reversible path statistics; externally driven dynamics need not obey this relation.
The chemical potential is the change in internal energy when one particle is added at fixed entropy and volume:
Equivalently, for the Helmholtz free energy.
Let a microstate have energy and particle number . Maximizing the Gibbs entropy subject to normalization and fixed mean values of and is the maximum-entropy derivation of equilibrium ensembles. With Lagrange multipliers , , and , vary
The stationarity equation is . Normalization therefore gives the grand canonical ensemble
Here is the grand canonical partition function and is the Boltzmann constant.
For one fermionic quantum state of energy , the Pauli exclusion principle permits occupation numbers only . Its two grand-canonical weights are and , so its mean occupation is the Fermi-Dirac distribution
For a free nonrelativistic particle, . In a region of area , the number of wave-vector states in the annulus from to , including the two spin angular momentum states, is
Since , the two-dimensional free-electron density of states is constant:
We now use units in which , as in the question. At zero temperature, the Fermi-Dirac distribution is a step function, and hence
At positive temperature the same fixed particle number satisfies the exact relation
Thus
This is the low-temperature particle-number cancellation for constant density of states. Therefore, for , the mean number of particles in the energy interval is
Finally, compare the internal energy with its zero-temperature value. The thermally excited particles above and holes below have equal leading particle numbers, so their terms proportional to cancel. With ,
where the integral follows from the fermion-to-boson thermal integral ratio. Differentiation gives the linear low-temperature heat capacity of a two-dimensional Fermi gas:
The requested power law is therefore linear in , with exponent one.
For a no-slip spherical particle in a Newtonian fluid at low Reynolds number, Stokes law gives . The fluctuation-dissipation theorem then gives the Stokes–Einstein relation . Using the conventional radial Brownian displacement in three dimensions,
Here is the Boltzmann constant, absolute temperature, dynamic viscosity, particle radius and elapsed time. Larger thermal forcing raises diffusion; larger viscous drag reduces it. The formula requires times long relative to momentum relaxation and neglects walls, interactions and external drift.
The word “average” needs a statistic: the vector mean is zero, while the mean radial displacement for Gaussian three-dimensional diffusion is , not . Both scale as . Neither is the total length of a microscopic random path.
After the photon has thermalized, its energy belongs to the macroscopic body's internal energy. The body's heat capacity makes the resulting temperature change negligible. Its equilibrium entropy therefore increases by
The Boltzmann entropy then gives the microstate multiplier from photon absorption:
For scale, explicitly choosing a representative visible wavelength and room temperature gives , or , and a multiplier approximately . These are illustrative choices, not additional supplied data: the exact multiplier depends exponentially on the particular visible wavelength and temperature. The exact Planck constant, speed of light, and Boltzmann constant fix the conversion.[ref]