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Take a nonrelativistic particle of constant mass $m$ with energy $E>0$, and choose the same zero of potential energy on both sides of a rectangular potential barrier:The equality of the exterior potential energies matters: it gives the same exterior wavenumber $k=\sqrt{2mE}/\hslash$ and makes $T=|t{|}^2$. Here $\hslash =h/(2\pi )$ is the reduced Planck constant. This model has a finite jump in potential energy, no delta potential, and no absorbing term.

For $0<E<V_0$, the Time-independent Schrödinger equation gives the spatial wavefunctionThe full stationary state is $\Psi (x,t)=\psi (x)e^{-iEt/\hslash }$. We set the incident probability amplitude to one and impose no incoming wave from the right; this scattering wavefunction is not a normalizable wavefunction. The tunnelling decay constant $\kappa$ describes exponential decay, rather than an oscillatory wavenumber in the barrier. Both exponential functions are needed on the finite interval: the growing term is not excluded by a condition at infinity.

The wavefunction and its derivative are continuous at each face, giving four linear matching conditions:Their solution supplies the transmission amplitudeA short derivation is to use the two right-face equations to express $A{e}^{\kappa a}$ and $B{e}^{-\kappa a}$ in terms of $t$, then substitute into the left-face equations. Taking the squared modulus gives the rectangular barrier transmission probability.

The Maxwell-Boltzmann distribution describes the random velocities and speeds of particles in a classical ideal gas at thermal equilibrium. Individual particles keep changing velocity through collisions, while the equilibrium probability distribution stays fixed. For one species of particle mass $m$ at positive temperature $T$, the characteristic scale iswhere $k_B$ is the Boltzmann constant. A signed velocity component follows a normal distribution; the nonnegative magnitude follows the Maxwell speed distribution. Their peaks differ because a speed measurement groups together all directions of motion.

Use the gas rest frame, three spatial dimensions, and nonrelativistic particles, with $k_{B}T\ll m{c}^2$ where $c$ is the speed of light. Assume a dilute gas whose interactions between encounters can be neglected in the ideal gas approximation and whose translational motion is classical. A sufficient condition for negligible quantum exchange effects is $n{\lambda }^3\ll 1$, where $n$ is the number density and $\lambda$ the thermal de Broglie wavelength. Diluteness alone does not guarantee thermal equilibrium; the gas must have equilibrated. These are the assumptions behind the classical Maxwell-Boltzmann velocity distribution. ^{[ref] [ref]}

The connection to Maxwell–Boltzmann statistics is the Boltzmann factor for translational kinetic energy, $E_{\mathrm{kin}}=m|\mathbf{v}{|}^2/2$. Normalizing $e^{-E_{\mathrm{kin}}/(k_{B}T)}$ over velocity gives a probability density; an occupation factor $e^{(\mu -E)/(k_{B}T)}$ instead specifies a mean occupation, with chemical potential $\mu$. Their normalizations serve different purposes. ^[ref]

This connects microscopic motion to measurements: a gas thermometer uses the ideal gas law, collisions and the mean free path govern transport, and measurements of spectral lines use thermal Doppler broadening to infer temperature. Each probes a different aspect of the same thermal motion.

In 1860, James Clerk Maxwell presented the component and speed laws in Part I, Proposition IV of Illustrations of the Dynamical Theory of Gases, pp. 22–23. His argument combined independence of the three velocity components with isotropy, and he explicitly compared the component law with the normal distribution of observational errors. Independence is an assumption of that argument; perpendicular coordinate axes alone do not establish it. ^[ref]

Integrating Maxwell–Boltzmann statistics over momentum for nonrelativistic particles of mass $m$, spin-state count $g_s$, and energy $m{c}^2+p^2/(2m)$ gives

For fixed $0<E<V_0$ and $\kappa a\gg 1$, the exact rectangular barrier transmission probability givesThis is the leading term of an asymptotic expansion: the wavefunction amplitude scale is $e^{-\kappa a}$, and the transmission probability scale is $e^{-2\kappa a}$, with an interface prefactor. Increasing width by $\Delta a$ multiplies this approximation by $e^{-2\kappa \Delta a}$. At fixed incident energy, increasing barrier height increases the tunnelling decay constant as $\sqrt{V_0-E}$; heavier nonrelativistic particles also have stronger suppression. For the numerical example in rectangular barrier transmission probability, the approximation gives $0.01397$, compared with the exact $0.01388$.

The regime condition matters. Near $E=V_0$ at fixed width, $\kappa a$ tends to zero and the opaque barrier approximation fails; use the exact threshold value. For $\kappa a\ll 1$, expansion of the hyperbolic sine givesThis tends to one as $a\to 0$ at fixed $E,V_0$, but the condition $\kappa a\ll 1$ alone does not imply nearly perfect transmission if the remaining factor is large. At $E>V_0$, use the oscillatory formula and its scattering resonances, rather than an exponential decay law.