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For a point electric charge $q$ in a homogeneous medium of permittivity ${ϵ}_1$ beside a plane interface with permittivity ${ϵ}_2$, its potential on the source side is reproduced by a mirrored image charge $q^{\prime }=q({ϵ}_1-{ϵ}_2)/({ϵ}_1+{ϵ}_2)$. The interface has no free surface charge; continuity of tangential electric field and normal electric displacement field fixes this coefficient.

In a grounded conducting enclosure, let the harmonic function $w_j$ equal one on boundary component $j$ and zero on the others. A point charge $q$ at ${\mathbf{r}}_0$ induces total electric charge $Q_j=-q{w}_j({\mathbf{r}}_0)$ on that component. The weighting harmonic function is its harmonic measure.

To prove the identity, let $\varphi$ be the zero-boundary electric potential, so ${\nabla }^2\varphi =-q{\delta }^{(3)}(\mathbf{r}-{\mathbf{r}}_0)/{ϵ}_0$. Green's second identity gives $-q{w}_j({\mathbf{r}}_0)/{ϵ}_0={\int }_{\partial D}{w}_j{\partial }_n\varphi dS$, where $\mathbf{n}$ points out of the vacuum domain into the metal. The electrostatic boundary conditions at a conductor give $\sigma ={ϵ}_0{\partial }_n\varphi$, proving the result. In an unbounded domain require the additional boundary term at infinity to vanish. Between concentric spheres, $w_a(r)=a(b-r)/(r(b-a))$; between parallel planes $z=0,d$, $w_0=1-z/d$ and $w_d=z/d$.

Inorganic phosphate, abbreviated ${\mathrm{P}}_i$, denotes the free phosphate pool in biochemical chemical equations, including ATP hydrolysis. Its constituent chemical species depend on pH and protonation; ${\mathrm{P}}_i$ does not specify a single electric charge or proton count. See the IUBMB recommendations on biochemical reactant pools.

Across an interface with unit normal $\mathbf{n}$ from medium one to medium two, Maxwell equations imply $\mathbf{n}\times ({\mathbf{E}}_2-{\mathbf{E}}_1)=0$, $\mathbf{n}\cdot ({\mathbf{B}}_2-{\mathbf{B}}_1)=0$, $\mathbf{n}\cdot ({\mathbf{D}}_2-{\mathbf{D}}_1)={\sigma }_f$, and $\mathbf{n}\times ({\mathbf{H}}_2-{\mathbf{H}}_1)={\mathbf{K}}_f$. Here ${\sigma }_f$ and ${\mathbf{K}}_f$ are the free surface electric charge and electric current densities.

The axial electric quadrupole moment of an intrinsic nuclear charge distribution, with the origin at its center and the $z$ axis along its symmetry axis:This convention includes electric charge in $Q_0$; a tabulated moment divided by the elementary charge $e$ instead has units of area. For the uniform spheroid, mapping a uniform unit ball to $(ax,ay,cz)$ gives $⟨x^2⟩=a^2/5$ and $⟨z^2⟩=c^2/5$, soThe formula explains the signs in the figure. It measures an anisotropy of the nuclear charge distribution, rather than counting individual nucleons on a surface. An illustrative choice $\eta =\sqrt{8}$ gives $a=R/\sqrt{2}$, $c=2R$ and $Q_0=7Ze{R}^2/5$, while preserving $a^{2}c=R^3$ exactly.

James Rainwater's lecture contrasts measured laboratory electric quadrupole moments with intrinsic moments inferred through Coulomb excitation, including even-even nuclei. Extracting intrinsic shape therefore uses a nuclear model, rather than equating every measured moment to $Q_0$.^[ref]

An iodide is an iodine anion with electric charge $-e$, where $e$ is the elementary charge.

An ion is a chemical atom or a group of chemical atoms with a nonzero net electric charge. A positive ion is a cation; a negative ion is an anion. The whole entity carries the electric charge: a hydronium ion is a group of four chemical atoms with net charge $+e$. This definition agrees with ^[ref].

For an ordinary ion containing only atomic nuclei and electrons, let $N_p$ count all its protons and $N_e$ all its electrons. Each proton contributes the elementary charge $+e$, each electron contributes $-e$, and neutrons contribute zero. ThereforeThe signed integer $z$ is the net electric charge number. Removing an electron increases $z$ by one; adding an electron decreases $z$ by one. Changing the electron count leaves the atomic number, and therefore the identity of the chemical element, unchanged.

For example, a neutral sodium chemical atom has $11$ protons and $11$ electrons. Its cation ${\mathrm{Na}}^{+}$ still has $11$ protons, but only $10$ electrons, so $q=(11-10)e=+e$. A neutral chlorine chemical atom has $17$ protons and $17$ electrons; its anion ${\mathrm{Cl}}^{-}$ has $17$ protons and $18$ electrons, so $q=(17-18)e=-e$. These are particle inventories, not pictures of atomic orbitals. See 2.6 Ionic and Molecular Compounds (§2.6: ions and ionic compounds).

One sodium chloride formula unit accounts for one ${\mathrm{Na}}^{+}$ cation and one ${\mathrm{Cl}}^{-}$ anion, whose net electric charges sum to zero. Ordinary solid sodium chloride is an extended arrangement of ions, rather than discrete $\mathrm{NaCl}$ molecules. This is a useful distinction: a neutral material can contain charged constituents, and its chemical formula tells us their ratio without claiming that each pair is a separate molecule.

Ion bookkeeping connects chemistry to electric current: moving ions can transport electric charge, while stationary ions cannot supply a transport current density. In electrochemistry, both signs of ions can contribute to the same conventional current. An ion opposing a fixed electric charge is called a counterion.

An ion channel is a membrane protein that provides a selective pathway for ions across a cell membrane. An open pore permits passive transport down the relevant electrochemical gradient; it does not supply the free energy for uphill transport as a pump involved in active transport does. Two things are needed for a net electric current: an available pathway and an electrochemical potential difference. Opening a pore alone need not produce a net electric current. See Ion Channels and the Electrical Properties of Membranes.

The selective permeability of an ion channel depends on interactions between its pore and the passing ions, not simply on a hole's diameter. Some ion channels strongly favor potassium over sodium; others admit several kinds of positively charged ions. Thus selective does not necessarily mean exclusive to one ion species. See Purves et al., Neuroscience, 2nd edition (2001): molecular structure of ion channels and the mixed-channel example in Purves et al.: principles derived from studies of the neuromuscular junction.

Gating is the opening and closing of an ion channel's pathway. A voltage-gated ion channel responds to membrane potential; an ionotropic receptor can respond to a bound ligand. Gating changes the available electrical conductance, while the electrochemical gradient supplies the drive for passive transport. For a fixed reversal potential in the simple model below, opening more identical ion channels increases the magnitude of the electric current at a fixed nonzero drive, without choosing its sign independently of membrane potential. The two-state ion-channel gating model describes how the open fraction can change. See the Alberts reference above.

For a worked approximation, hold an open population's electrical conductance at $g=10\mathrm{nS}$ and its reversal potential at $E_{\mathrm{rev}}=-80\mathrm{mV}$. Use $V=V_{\mathrm{inside}}-V_{\mathrm{outside}}$ for membrane potential and inward-positive conventional current:At $V=-100,-80,-60\mathrm{mV}$, respectively, the electric currents are $+200,0,-200\mathrm{pA}$, since $1\mathrm{nS}\times 1\mathrm{mV}=1\mathrm{pA}$. Positive electric current means net positive electric charge entering, or net negative electric charge leaving; it does not mean that every ion moves inward. For a pore passing only positive ions, the three results mean net inward passage, no net passage, and net outward passage. These stipulated values describe an illustrative Ohmic approximation, not measured properties of a particular ion channel; see reversal potential for the current plot and limitations.

The useful connection is between a molecular gate and a controllable electric current. A ligand can change electrical conductance through an ionotropic receptor, or membrane potential can change it through a voltage-gated ion channel, connecting recognition and electrical signaling. In a historical landmark, Erwin Neher and Bert Sakmann reported currents from individual ion channels in frog muscle membranes in 1976. See Neher and Sakmann, Single-channel currents recorded from membrane of denervated frog muscle fibres, Nature 260, 799–802 (1976).

The net displaced electric charge associated with a change in channel conformation, inferred by integrating the ion-channel gating current after subtracting unrelated currents. It is distinct from the electric current itself and from charge carried through the open pore.

The concentration-based ionic strength is $I_c=\frac{1}{2}{\sum }_i{c}_i{z}_i^2$, where $c_i$ is each dissolved ion's concentration and $z_i$ its signed electric charge number. It has the same units as $c_i$; some formulas instead use the dimensionless ratio $I_c/c^{\circ }$. All dissolved ions contribute, including those that balance the electric charge of a buffer solution's conjugate base. Ionic strength helps describe the interactions represented by activity coefficients. See Hippler and Metcalfe, activity coefficients and dimensionless ionic strength.

An ion trap confines an ion using electromagnetic fields, allowing repeated interrogation of the same particle. The name also covers related traps for an electron. A Paul trap uses an oscillating electric quadrupole field; a Penning trap combines a static electric quadrupole field with a static magnetic field. Confinement creates time to measure an energy level, frequency or magnetic dipole moment; it does not itself cool the particle or identify its internal quantum state.

The obstacle is Earnshaw's theorem. In a charge-free neighbourhood the static electric potential $\Phi$ obeys Laplace's equation, ${\nabla }^2\Phi =0$. For a particle of fixed nonzero electric charge $Q$, the potential energy $Q\Phi$ is also a harmonic function. The maximum principle for harmonic functions excludes a strict interior minimum. For a quadratic example, the Hessian matrix has zero trace; it cannot have three positive eigenvalues. A static purely electric field therefore cannot supply three-dimensional stable confinement of a free point electric charge. Time variation in a Paul trap, and the velocity-dependent Lorentz force in a Penning trap, change the assumptions of this argument.

The isoelectric point is the pH at which a specified molecule's mean net electric charge is zero. Different protonation states can still carry nonzero electric charges; their contributions cancel in the average. For the two-step glycine speciation model, this gives $\mathrm{pI}=(\mathrm{p}{K}_{a1}+\mathrm{p}{K}_{a2})/2$. Additional ionizable amino acid side chains require their own chemical equilibrium calculations; averaging every pKa is not a general rule. ^[ref]

Below its isoelectric point, free glycine has positive mean electric charge and an electric field drives it toward the negative electrode; above its isoelectric point, the mean electric charge is negative and the direction reverses. At its isoelectric point the charge-driven contribution vanishes. Diffusion and bulk movement of the chemical solution can still move the sample. Gel electrophoresis applies this charge dependence to separation, although protein size, shape and interactions also affect migration. The pKa values of free glycine do not determine a protein's isoelectric point: its free N-terminus, C-terminus and ionizable amino acid side chains supply a different inventory. ^[ref]

Isotopes of a chemical element have the same atomic number $Z$, hence the same number of protons, but different neutron numbers $N$ and therefore different mass numbers $A=Z+N$. For example, every neon atomic nucleus contains ten protons: neon-20, neon-21, and neon-22 contain ten, eleven, and twelve neutrons, respectively. They occupy one chemical element box in the periodic table, rather than three boxes.

Three labels answer different questions. The chemical element fixes $Z$; the isotope specifies which neutron number accompanies that $Z$; the ion label specifies the net electric charge. Neutral ${}_{10}^{22}\mathrm{Ne}$ and the ion ${}_{10}^{22}{\mathrm{Ne}}^{+}$ both contain ten protons and twelve neutrons; they contain ten and nine electrons, respectively. Ordinary ionization changes the electron count, leaving the isotope unchanged. Changing the neutron number can change nuclear binding energy and the possibility of radioactive decay. Isotopic abundances can help distinguish material sources, while radioactive decay can additionally supply chronological information.

A mass spectrum makes the distinction experimentally visible: a single chemical element can give separate ion peaks at different mass-to-charge ratios. Its bulk atomic weight is a weighted mean governed by isotopic abundances, rather than the location of one compulsory peak. The historical mass spectrograph experiment and the synthetic neon mass spectrum below illustrate these complementary observations.

A physicist.^[ref]

The Thomson charge-to-mass experiment used electric and magnetic deflections of cathode rays to investigate their charged constituents. It determines a charge-to-mass ratio; separating electric charge from mass requires additional information.

In the ideal sinusoidal Josephson junction, the pair electric current and quantum phase obeyHere $e>0$ is the magnitude of the electron electric charge, $\hslash =h/(2\pi )$ uses the Planck constant, and $I_c$ is the junction's superconducting critical current under the specified conditions. Define the signs as follows: positive conventional electric current flows from terminal 2 to terminal 1, and $V$ is the voltage of terminal 2 relative to terminal 1. The Gauge-invariant Josephson phase below fixes the matching orientation of $\varphi$. The DC Josephson effect and AC Josephson effect follow from these relations. ^[ref]

The incremental capacitance associated with changes of electric charge around a p-n junction. Its depletion contribution is often estimated by $C_j\simeq {\epsilon }_{s}A/W$, so an independent junction capacitance measurement can constrain the width $W$ of the depletion region under the model assumptions. Other stored electric charge, including injected minority carriers, can also contribute to a measured terminal capacitance.

The stationary axisymmetric Einstein–Maxwell family of asymptotically flat spacetimes extends the Kerr metric by including electric charge. Its horizon polynomial is the displayed $\Delta$; for $M^2>Q^2+a^2$ the roots are $r_{\pm }=M\pm \sqrt{M^2-Q^2-a^2}$. The outer Killing horizon has area $4\pi (r_{+}^2+a^2)$, angular velocity $a/(r_{+}^2+a^2)$ and electric potential $Q{r}_{+}/(r_{+}^2+a^2)$.

The ${\Lambda }^0$ in the baryon octet is an isospin singlet with strangeness $-1$ and zero electric charge. Its ordinary valence quark content is $uds$.

The lowest Lambda c baryon has valence content $cud$, electric charge $+1$, isospin zero and spin angular momentum $1/2$. Its light pair has antisymmetric flavour and spin zero. This is the charm analogue of the Lambda baryon.

The electrostatic bisector force is laterally anti-restoring, with the positive stiffness coefficient on the right. A spring of tension $T$ and length $\ell$ adds transverse restoring stiffness $T/\ell$ when its fixed support is directly above the charge. The displayed inequality therefore distinguishes actual transverse stability from the saddle of a model with only a vertical spring force. Axial spring stiffness alone does not specify the transverse verdict. At fixed finite support geometry and positive gravitational load, sufficiently small electric charge preserves lateral stability: the destabilizing coefficient tends to zero as $q^2$, while the tension term approaches $mg/\ell >0$. The vertical equilibrium must separately satisfy its own positive-stiffness condition.