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An operator implementing a symmetry of quantum states and observables. The ordinary spatial symmetries considered in molecular spectroscopy are unitary and commute with the Hamiltonian. More generally, an antiunitary symmetry such as time reversal needs its corresponding treatment.

If two pure quantum states overlap by $(1/\sqrt{2}{)}^{1/n}$, their $n$-copy states have overlap $1/\sqrt{2}$. Each block spans an effective qubit, with orthonormal basis $e_0={\Psi }_1$ and $e_1=\sqrt{2}{\Psi }_2-{\Psi }_1$. Applying the two-block PBR exclusion measurement for zero and plus uses $2n$ independently prepared copies. A common single-copy ontic overlap of positive mass remains positive under this finite tensor power.

Coauthor of the Pusey-Barrett-Rudolph theorem.

Consider an original hypothetical atom with a lower angular momentum multiplet $F=1$, $m=-1,0,+1$, and one opposite-parity excited level $F^{\prime }=0,m^{\prime }=0$. Stipulate that all spontaneous emission returns to these three lower quantum states, with no other decay channel. This is an isolated four-state model, not the actual sodium or rubidium D-line structure. In particular, the physical rubidium cell above contains multiple hyperfine structure levels.

The electric-dipole selection rule permits $\Delta F=-1$ here; ${\sigma }^{+}$ absorption with $\Delta m=+1$ excites only $m=-1$. Decay from $F^{\prime }=0$ has three equal integrated branching probabilities $b_{-}=b_0=b_{+}=1/3$: rotational symmetry gives equal squared Clebsch-Gordan coefficients. The emitted photons carry the three permitted angular momentum projections; equal integrated branching does not imply equal intensity in every observation direction. Thus $m=0$ and $m=+1$ are both dark. The chosen beam cannot prepare a unique pure $m=+1$ state.

Let $R\ge 0$ be the absorption rate of an atom in $m=-1$, and let $\Gamma$ be the excited-state spontaneous emission rate, both in inverse seconds. Assume $R,\gamma \ll \Gamma$, negligible stimulated emission, and no maintained quantum coherence between sublevels. Eliminating the short-lived excited population gives normalized lower populations $p_{-}+p_0+p_{+}=1$ to this approximation. At each scattering event the atom leaves $m=-1$ with probability $2/3$; the remaining $1/3$ simply returns it there.

Model depolarizing collisions and other population relaxation by resets to the unpolarized distribution at rate $\gamma \ge 0$. The rate equations areThis relaxation prescription assumes that Zeeman splitting is small compared with thermal energy, so the unpolarized distribution approximates thermal equilibrium. It is not an energy-independent relaxation law at arbitrarily low temperature.

Every transfer has a nonnegative rate: optical transfers $-\to 0$ and $-\to +$ each have rate $R/3$, and relaxation transfers between each distinct pair have rate $\gamma /3$. These define a continuous-time Markov chain. The three derivatives sum to zero, and at $p_i=0$ the corresponding derivative cannot be negative. Hence the model conserves population and preserves nonnegative populations. Optical cycles that return to $m=-1$ contribute to scattering even though they cause no net population transfer.

The time-evolution operator maps an initial quantum state to its state at a later time. For a time-independent Hamiltonian operator $H$, it is the unitary operator $U(t)=e^{-iHt/\hslash }$.

More generally, write $|\psi (t)⟩=U(t,t_0)|\psi (t_0)⟩$. The time-evolution operator obeysFor a constant self-adjoint Hamiltonian operator, $U(t,t_0)=\exp [-iH(t-t_0)/\hslash ]$. With zero as the initial time, this gives the group law $U(t+s)=U(t)U(s)$. Successive evolution is reversible; a measurement followed by conditioning on an outcome is a separate operation described by projective measurement.

For a time-dependent Hamiltonian operator, the defining equation is $i\hslash {\partial }_{t}U(t,t_0)=H(t)U(t,t_0)$. In finite dimension, a continuous Hermitian $H(t)$ still gives unitary time evolution, sinceThe solution is a time-ordered exponential, with later factors acting on the left. One may replace it by $\exp [-i{\int }_{t_0}^{t}H(s)ds/\hslash ]$ when $[H(s),H(s^{\prime })]=0$ at all times; independently changing pulse axes generally requires time ordering.^[ref]

Topological quantum matter has robust low-energy properties controlled by global topology rather than local order parameters.

The central question is which quantum states can be joined by a smooth change of a local Hamiltonian while keeping a nonzero bulk spectral gap. A Chern insulator makes this question concrete: two band insulators can have different integer Chern numbers, forcing a gap closure between them. The Haldane phase supplies a one-dimensional example in which a protecting symmetry matters. These are distinct from intrinsic topological order, with its anyons and topology-dependent ground-state degeneracy. The Berezinskii–Kosterlitz–Thouless transition concerns a separate mechanism involving vortices; topology organizes more than one kind of physical phenomenon.

Let orthonormal energy eigenvectors be ${\Psi }_1,{\Psi }_2$, and let a measured observable have eigenvectors $v_{+}=\cos \alpha {\Psi }_1+\sin \alpha {\Psi }_2$ and $v_{-}=-\sin \alpha {\Psi }_1+\cos \alpha {\Psi }_2$. If the initial quantum state is $v_{-}$, unitary time evolution multiplies each energy component by $e^{-it{E}_j/\hslash }$. Its amplitude in $v_{+}$ is $\sin \alpha \cos \alpha (e^{-it{E}_2/\hslash }-e^{-it{E}_1/\hslash })$. The Born rule gives the displayed probability. The energy gap fixes the oscillation frequency, while the angle between the measurement and energy bases fixes its amplitude. Energy degeneracy or coinciding bases makes the transition probability vanish.

An internal qubit uses two distinguishable electronic or hyperfine structure quantum states, denoted $|g⟩,|e⟩$. The ion's centre-of-mass motion has a different Hilbert space. In one approximately harmonic direction, a number state $|n⟩$ has energy $E_n=\hslash \nu (n+1/2)$, where $\nu$ denotes a motional angular frequency, not ordinary frequency. The tensor product of quantum systems gives $|g,n⟩$. Cooling towards $n=0$ prepares motion; it does not automatically prepare the internal qubit. Nor does the ground state mean a stationary point particle: zero-point energy and position spread remain.

For several ions, Coulomb forces couple their displacements into collective normal modes. Each selected normal mode has its own quantum harmonic oscillator number states, while each ion retains internal qubit states. A pulse addressing one ion can change a shared mode. This supplies a route to correlations between distant internal quantum states; it also makes residual motional excitation and unwanted excitation of other normal modes relevant. A single-ion pulse calculation alone establishes no experimental multi-ion quantum gate performance.

Trapped-ion quantum control prepares an ion's internal quantum state, couples it to quantized motion with laser pulses, and measures the result through state-dependent fluorescence. Its appeal is access to both a controllable two-level system and a quantum harmonic oscillator in one apparatus.

Confinement, preparation, control and readout solve different problems. The Paul trap's RF electric field confines the ion through its RF-averaged trapping potential; it still produces Paul trap micromotion. Doppler cooling and resolved sideband cooling reduce motional excitation. Optical pumping selects an internal quantum state. A coherent pulse then changes amplitudes, while electron shelving converts an internal population into a detectable stream of photons. A bright/dark count by itself does not reveal a quantum superposition's relative phase; an additional controlled rotation before detection can make that phase affect the measured population.

A tunnel diode is a p-n junction with sufficiently heavy semiconductor doping on both sides to make a thin depletion region and permit substantial interband tunnelling. The neutral regions are degenerate semiconductors. Its distinctive forward current-voltage characteristic contains a peak followed by a valley: over part of the curve, increasing the applied electric potential difference decreases the electric current. The Esaki tunnel-diode experiment made this behavior experimentally concrete.

The useful quantity is the local slope, not the ratio of total voltage to total electric current. With conventional electric current $I$ entering the positive-voltage terminal, defineNegative differential resistance means $g_d<0$, hence $r_d<0$ where defined. A forward operating point can still have $V>0$, $I>0$ and absorbed power $VI>0$. A small voltage increase then gives a negative current increment; this does not make the total electric current negative or turn the device into an unlimited source of energy. The external supply sets the operating point and supplies the energy available for an electronic amplifier.

An original idealized construction explains the shape. Put the n-type semiconductor on the left and the p-type semiconductor on the right. Take $q>0$ as the elementary charge and $V=V_p-V_n$. Increasing forward bias lowers the right-hand electron energy levels relative to the left. Denote the two reservoir electrochemical potentials by ${\mu }_n,{\mu }_p$, so that ${\mu }_n-{\mu }_p=qV$. At zero temperature, occupied left-hand conduction band states extend up to ${\mu }_n$; empty right-hand valence band states start at ${\mu }_p$. For transfer conserving electron energy, the available interval isIt is nonempty only when its upper endpoint exceeds its lower endpoint. Both an occupied initial quantum state and an empty final quantum state must exist at the same energy. The Pauli exclusion principle prevents transfer into an already occupied final quantum state.

For the original diagram, choose arbitrary energy units with $E_{c,n}=-0.5$, ${\mu }_n=0$, ${\mu }_p=-u$ and $E_{v,p}=0.5-u$, where $u$ is $qV$ in those units. The available interval has widthThus $L(0.25)=0.25$, $L(0.50)=0.50$, $L(0.70)=0.30$, and $L(1.15)=0$. Initially forward bias opens a transfer window; further forward bias closes it by moving the right-hand valence band edge below the left-hand conduction band edge. This is a state-counting illustration, not a formula for a measured electric current.

For reverse bias, the transfer direction changes: occupied right-hand valence band states can feed empty left-hand conduction band states. In the same construction, $u=-0.70$ opens the interval $0<E<0.70$ for this reverse transfer. A narrow depletion region allows a large reverse quantum tunnelling electric current at small electric potential difference, whereas the ordinary Shockley diode equation predicts only a small reverse saturation electric current before diode reverse breakdown. At zero biasing, equal reservoir occupations give zero net electric current; quantum tunnelling does not require a net equilibrium flow.

A finite-temperature refinement replaces sharp occupation cutoffs with the Fermi-Dirac distribution. An illustrative weak-transfer expression isHere $\mathcal{W}\ge 0$ describes allowed initial/final quantum states and their coupling, and $f_n,f_p$ are Fermi-Dirac distributions with the respective electrochemical potentials. The occupation difference follows by subtracting the reverse transfer factor from the forward one: $f_n(1-f_p)-f_p(1-f_n)=f_n-f_p$. An overlap interval alone does not determine $\mathcal{W}$: transmission probability, density of states, crystal momentum selection and phonons can matter. A complete germanium calculation is more demanding than multiplying two constant density of states factors. At larger forward bias, ordinary carrier injection and diffusion supply a rising current branch even after direct band overlap is lost.

A normalized quantum state $\chi =\sqrt{q}{\psi }_1+e^{i\eta }\sqrt{1-q}{\psi }_2$ in two orthonormal energy eigenstates returns to its original one-dimensional measurement subspace with probabilityThis follows by applying unitary time evolution to each energy eigenstate, then the Born rule. The relative phase $\eta$ cancels from the return amplitude. Degenerate energies make the probability identically one.

Take an isolated two-level system, or a spin one-half qubit, with Pauli matrices ${\sigma }_x,{\sigma }_z$. Let ${\sigma }_z|0⟩=|0⟩$ and ${\sigma }_z|1⟩=-|1⟩$. The initial and final Hamiltonian operators areThe energy gaps are ${\Delta }_i,{\Delta }_f$. Prepare the initial ground state $|0⟩$, with energy eigenvalue $-{\Delta }_i/2$. A final orthonormal eigenbasis isDirect matrix multiplication gives $H_f|g_f⟩=-{\Delta }_f|g_f⟩/2$ and $H_f|e_f⟩=+{\Delta }_f|e_f⟩/2$. The unchanged initial quantum state is $|0⟩=c|g_f⟩-s|e_f⟩$. Its new probability amplitudes are the inner products $c,-s$; the Born rule gives $p_g=c^2,p_e=s^2$. The angle between the real amplitude vectors is $\theta /2$, whereas the Hamiltonian axis on the Bloch sphere rotates through $\theta$.

At $\theta =\pi /3$, $c=\sqrt{3}/2$ and $s=1/2$, so the final energy measurement gives $-{\Delta }_f/2$ with probability $3/4$ and $+{\Delta }_f/2$ with probability $1/4$. At $\theta =0$ the initial ground state remains the final ground state; at $\theta =\pi$ it is the final excited energy eigenstate. These statements are about the new energy labels, not an instantaneous physical rotation of the quantum state.

If a trial quantum state is dominated by two energy eigenstates of distinct energies $E_a<E_b$, then its Rayleigh quotient is approximately their probability-weighted mean. Rearranging that mean gives the displayed relative admixture. Neglected states must make small contributions to the energy numerator as well as to wavefunction normalization; small probabilities alone need not suffice if their energies are large.

The particle exchange operator $P_{12}$ swaps the complete particle slots, including spin. Its antisymmetric projector is $A_{12}=(I-P_{12})/2$. For orthonormal one-particle states $u,v$, the normalized multiparticle quantum state isBut attempting the same construction with $v=u$ gives the zero vector:The zero vector cannot be normalized to a quantum state. This is exclusion as cancellation of probability amplitudes, rather than a repulsive force. More generally, for normalized $u,v$ the squared norm of the numerator divided by $\sqrt{2}$ is $1-|⟨u|v⟩{|}^2$; the expression has unit norm only when $u,v$ are orthogonal. An overall quantum phase difference between $u,v$ describes the same one-particle state and also gives zero. Pauli explicitly connects exclusion with a vanishing antisymmetric wavefunction.^[ref]

A quantum state on the tensor product of two two-dimensional complex state spaces. A normalized pure state has squared coefficient moduli summing to one. It is a product state exactly when $\alpha \delta =\beta \gamma$, by the two-qubit product-state determinant criterion. The weaker equality of moduli only characterizes independence of the computational-basis outcomes; phases can preserve quantum entanglement despite those independent statistics.

Two localized orbitals coupled by quantum tunnelling and on-site interactions give the smallest Bose-Hubbard model. A symmetric double-well potential with lowest one-particle energies $E_0,E_1$ has $t=(E_1-E_0)/2$ and common diagonal energy $(E_0+E_1)/2$. At fixed total particle number, that common diagonal term is constant. A fixed-number two-mode condensate gives a simple variational method for this model, while stronger interactions can require occupation-correlated trial quantum states.

For self-adjoint operators $A,B$ and a normalized quantum state in their relevant product operator domains, put $u=A\psi$, $v=B\psi$, $z=⟨u,v⟩$. With the inner product linear in its second entry, $⟨C⟩=2\mathrm{Im}z$. The Cauchy-Schwarz inequality givesEquality holds exactly when $u,v$ are linearly dependent and $\mathrm{Re}z=0$. This includes either zero vector; if both vectors are nonzero it is equivalent to $B\psi =i\lambda A\psi$ for real nonzero $\lambda$. Applying this inequality to the centred observables $A-⟨A⟩I$ and $B-⟨B⟩I$ gives the Robertson uncertainty principle.

For a semiprime $N=pq$ with distinct known primes, this quantum state is uniform over the reduced residue classes. With $n$ binary digits in $N$, its fraction among all $2^n$ computational labels is $a=(p-1)(q-1)/2^n\ge 1/4$. An ancilla qubit whose one probability is $1/(4a)$ dilutes the joint good probability to exactly $1/4$. A reversible range-and-greatest common divisor predicate marks the good labels with ancilla qubit one, and a single exact amplitude amplification iteration produces $|{\xi }_N⟩|1⟩$. Known prime factors provide the cardinality; the membership test itself needs only $N$. Polynomial gate complexity presumes ideal one-qubit rotations at the specified amplitudes.

A time-independent Hamiltonian evolves a state by the unitary operator $U(t)=e^{-iHt/\hslash }$.

For a closed quantum system, unitary time evolution changes a quantum state through a unitary operator, preserving norms and inner products. For a time-independent self-adjoint Hamiltonian operator $H$, choose the initial time as zero:Here $\hslash =h/(2\pi )$ is the reduced Planck constant. The same $U(t)$ acts on every initial quantum state; it depends on the Hamiltonian operator and elapsed time, rather than the chosen preparation.^[ref]

The self-adjointness of $H$ makes the exponential a unitary operator. In finite dimension, conjugating its matrix exponential givesThe two exponents commute because both are multiples of $H$. Hence, for any two initial vectors,This short proof explains why normalization survives, why orthogonality of initial vectors survives, and why the transition probability between two states evolved by the same $U$ is unchanged. It does not require that a fixed measurement in quantum mechanics have time-independent probabilities: its measurement basis need not move with the quantum states.

For an unbounded self-adjoint operator, define the exponential through the spectral theorem, rather than assuming that its power series acts on every vector. It is a unitary operator on the entire Hilbert space; the strong Schrödinger equation holds for initial vectors in the operator domain $D(H)$. For a density operator, unitary time evolution reads $\rho (t)=U(t)\rho (0)U(t{)}^{†}$. It preserves eigenvalues and purity of a density operator, but can change its entries in a fixed basis.

The useful distinction is between conserving total probability and conserving each measurement's probabilities. A fixed energy spectrum supplies different ticking rates for different probability amplitudes. Their relative quantum phases can move the Bloch vector and create quantum interference even while every energy eigenstate population stays fixed. Qubit precession under a constant Hamiltonian makes this visible; Ramsey interferometry converts the accumulated relative quantum phase into a population difference that a simple readout can detect.