Reflections from the two film surfaces interfere with propagation phase plus the relative reflection phase. Reflection from a lower to a higher refractive index contributes a phase reversal. For a higher-index film surrounded by air there is one relative reversal, hence
Thickness or angle variation therefore produces fringes or colours under broadband illumination. An antireflection coating between indices instead uses, at normal incidence, and : the two reflected amplitudes then cancel at the design wavelength. Absorption, polarization, unequal amplitudes and multiple reflections determine the full contrast.
Let the first ray reflect at the upper surface and the second traverse the film, reflect below, and emerge at a laterally displaced point. Its internal round-trip geometric length is , but the external path to a common outgoing wavefront must also be included. The lateral separation is , whose projection along the external ray is . The net optical path difference is therefore
using Snell's law . Multiplying by the vacuum wavenumber gives
For the usual index ordering , including the stated later value , both reflections are towards higher refractive index and both reverse the electric-field sign. Their relative reflection phase is therefore zero; is also their total relative phase modulo . A different index ordering or polarization-dependent reflection phase would require that additional term.
In thin-film interference, coherent beams reflected at the two faces of a transparent film overlap. Let the film have refractive index , thickness , and internal ray angle , determined by Snell's law. For vacuum wavelength , the propagation part of the relative phase is
Although the internal round-trip ray length is , the two emergent rays must be compared on the same outgoing wavefront. Subtracting their external lateral path contribution gives the effective optical path difference , explaining the cosine rather than its reciprocal.
Reflection also changes phase. At normal incidence in lossless positive-index media, the electric-field Fresnel equations give : reflection towards higher index reverses sign, whereas reflection towards lower index does not. If the two interfering reflections differ by one such phase reversal, their total relative phase is modulo . Then reflected maxima and minima obey
If there are zero or two reversals, the conditions interchange. These bright/dark conditions assume overlapping beams with adequate temporal optical coherence; complete cancellation further requires equal amplitudes. In transmitted light, a lossless complete film has complementary intensity variations because reflected plus transmitted power is conserved.
For multiple internal reflections at normal incidence, summing the geometric series gives the exact film reflection amplitude
This includes both the amplitude mismatch and repeated-beam interference. A normal-incidence antireflection coating on substrate index can cancel reflection at one wavelength when and : both interface reflections reverse sign and the film's round-trip propagation adds , with equal interface amplitudes. A varying thickness or angle selects different maxima for different wavelengths, producing the colours of transparent films in white light. Broad bandwidth and large incidence angles generally prevent perfect cancellation across all wavelengths.
For independent small uncertainties interpreted as standard deviations, propagation of uncertainty gives
The angular uncertainty is in radians. Since , the allowed angular contribution to the fractional uncertainty of the numerical aperture is only . Therefore
The uncertainty in the refractive index already contributes . If the quoted errors instead mean strict worst-case bounds, first-order absolute errors must be added rather than added in quadrature; that convention would require . The result uses the usual independent statistical-error convention.
Temperature changes affect measurements through several routes. Thermal expansion changes lengths and alignments; temperature-dependent resistance and refractive index change electrical and optical calibrations; temperature differences between dissimilar junctions generate Seebeck effect voltages. These slow environmental changes are distinct from unavoidable equilibrium thermal fluctuations and Johnson-Nyquist noise. A useful strategy identifies the coupling to the measured signal before choosing a remedy.
Reduce environmental coupling by enclosing the apparatus against drafts, using thermal insulation and radiation shields, isolating heat sources, and minimizing dissipated power. A vacuum enclosure suppresses convection but leaves thermal conduction and thermal radiation paths to control. A large heat capacity reduces rapid temperature excursions. In a simple thermal model with heat capacity and thermal conductance to a reservoir, the relaxation time is , so adequate settling time is necessary after changing the apparatus. A temperature sensor close to the sensitive element and stable negative feedback heating or cooling can regulate its temperature; poorly placed sensors or excessive feedback gain can leave gradients or cause oscillations.
Electrical thermal noise has the classical low-frequency one-sided voltage power spectral density
for a resistor measured over a flat bandwidth without significant loading. More generally replace by the effective noise bandwidth. Lower temperature or narrower bandwidth reduces the noise, and resistance choices must account for source loading and the amplifier's own voltage and current noise. A lock-in amplifier uses modulation and narrowband detection to reject much low-frequency drift and out-of-band noise, while thermal noise inside the accepted band remains. Temperature stabilization does not remove equilibrium fluctuations.
Use a matched reference or differential bridge to reject common environmental changes. Keep junctions isothermal and choose matched materials to reduce thermoelectric offsets. For a resistance measurement, reversing a small test current separates a stable offset from the wanted voltage:
Reversal must be fast enough that the offset stays approximately fixed, with enough settling time and sufficiently little self-heating. Recording the sample temperature permits a measured calibration slope to correct a signal to a reference temperature; the correction's calibration and thermometer uncertainties must be propagated. Independent white noise fluctuations decrease under averaging, whereas correlated temperature drift may not decrease as the inverse square root of the number of readings. Temperature records and repeated reference measurements help distinguish the two.
A Michelson interferometer splits a collimated beam at a partially reflecting beam splitter. Two mutually perpendicular arms reflect from mirrors and recombine at the same beam splitter; the superposed returning beams produce interference fringes at the detector. Translate one mirror along its arm while holding the other fixed.
Figure 1.
Original Michelson geometry for measuring wavelength by counting fringes while one mirror moves
. Details.
If that mirror moves a measured distance , the round-trip optical path difference changes by in air, approximated as vacuum. Every change of one wavelength moves one complete bright-dark-bright fringe cycle past a fixed detector point. Count such cycles to obtain
Use a spectral line selected with a suitable optical filter, and count many interference fringes to reduce the fractional uncertainty of the distance and count. Keep the two arms within the source's optical coherence length and maintain overlap and alignment. If the vacuum wavelength is required for an arm filled with air of known refractive index , the corrected relation is at stable .
Draw the Fabry–Pérot etalon with parallel mirrors and an incident beam making internal angle with their normal. Every emerging transmitted contribution has undergone one more internal round trip than its predecessor.
Figure 1.
Successive transmitted paths and a common outgoing wavefront for a tilted beam in an air-gap etalon
. Details.
The extra internal path is , but successive contributions leave at laterally separated points, a distance apart. Comparing their phases on the same outgoing wavefront subtracts the path projection . Their net optical path difference in air is
Hence, in the reflection-phase convention implicit in the supplied transmission formula,
For a gap of refractive index , replace by and use the vacuum wavelength. Coating reflection phases can add a round-trip offset; the expression above assumes that offset is absorbed in the resonance order, or is zero modulo as in the stated ideal model.
A waveguide confines the transverse structure of a wave while permitting propagation along a chosen route. It can deliver energy to a distant receiver without the same geometric spreading as an unguided beam, protect a signal from unwanted coupling, and select transverse normal modes. It also makes propagation paths and coupling to devices more controllable. Confinement does not eliminate wave absorption or scattering loss, and it can introduce wave dispersion and cutoff frequencies of a membrane waveguide or corresponding cutoffs for other wave types.
Two examples are an optical fiber, which guides light by its core-and-cladding refractive index structure, and a hollow electromagnetic waveguide used to carry microwaves between a source and an antenna. A duct for acoustic waves is a further example. Each uses different material and boundary conditions, but the common idea is controlled transverse confinement.
A wave propagates an organized disturbance through space. What oscillates depends on the medium: displacement in a string or solid, pressure and density in a fluid, electric fields and magnetic fields in an electromagnetic wave, or a quantum wavefunction. The propagation law follows from the restoring mechanism, inertia and relevant boundary conditions. A common linear equation is , whose plane waves obey . The resulting phase velocity and group velocity coincide, so a narrow wave packet can travel without dispersive spreading. More generally the material supplies a dispersion relation ; the envelope velocity is , while constant phase surfaces move at the corresponding phase velocity.
Mechanical waves make the balance of restoring force and inertia particularly visible. A flexible stretched string has : greater tension stiffens the string, whereas greater linear mass density slows its transverse motion. Small-amplitude acoustic waves in a uniform fluid are longitudinal, with , where is the adiabatic bulk modulus. For an ideal gas, . Pressure changes in rapid sound oscillations are approximately adiabatic because little heat crosses a wavelength in one period. Fluids do not support ordinary bulk shear waves, whereas an elastic solid supports both longitudinal and transverse waves. In an isotropic solid their speeds are and , where is the shear modulus.
A material can be dispersive even when its equilibrium properties are uniform. In a liquid with a free surface, gravity and surface tension act as restoring mechanisms. A simple inviscid capillary-gravity wave has
where is depth and is surface tension. Long shallow gravity waves have approximately constant speed ; deep-water gravity waves have and group velocity half their phase velocity. Short capillary waves have a different dispersion dominated by surface tension. Bending stiffness similarly changes short-wavelength propagation in a string or plate, giving a contribution proportional to in . Different restoring mechanisms can therefore control different wavelength ranges of the same medium.
Electromagnetic waves propagate in vacuum without material displacement, because Maxwell equations couple changing electric and magnetic fields. They are transverse and travel at . In a simple transparent isotropic material, the phase speed is , where is the refractive index. Real material polarization depends on frequency. A Lorentz oscillator model for bound charges explains why permittivity and refractive index become strongly frequency dependent near material resonances, accompanied by absorption. In a birefringent medium, different field polarizations have different propagation constants, permitting wave plates and mode-dependent delays. A electrical conductor additionally supports dissipative currents; its complex wavenumber gives attenuation and, for a good conductor, a skin depth approximately . Energy removed from the wave becomes heat rather than disappearing.
At an interface, frequency is conserved for stationary media, and tangential wave phase must match. These conditions give Snell's law for refraction and constrain reflected and transmitted directions. Amplitudes follow from continuity of the appropriate fields or mechanical forces. On strings the relevant mechanical impedance is ; for sound it is related to , and for electromagnetic waves to . A mismatch gives wave reflection, and a lossless boundary conserves the total incident, reflected and transmitted power. Multiple reflections can reinforce or cancel, as in a Fabry–Pérot etalon. Total internal reflection and other boundary conditions confine waves in waveguides. Transverse modes then become discrete, and even an otherwise nondispersive material develops longitudinal cutoffs and wave dispersion. A membrane strip, for example, obeys .
Propagation also involves transport and loss. The Poynting vector gives electromagnetic energy flux; mechanical energy transport is force or pressure times velocity, averaged over a cycle. Wave absorption, viscosity, electrical resistance and imperfect boundaries dissipate energy. Scattering redistributes energy into other directions and modes, while geometric spreading reduces local intensity without necessarily dissipating anything. These mechanisms should be distinguished when interpreting a decreasing measured amplitude. In strongly absorbing or rapidly varying dispersive regimes, the derivative called group velocity is not automatically the speed of a sharp signal front; pulse reshaping and the medium's causal response must be considered.
Finally, quantum matter waves illustrate how the same propagation mathematics can describe a different physical quantity. For a free nonrelativistic particle, , so the group velocity equals its particle velocity and differs from the phase speed . In a periodic crystal, Bloch's theorem replaces the free dispersion by energy bands. Their slope controls wave-packet velocity, , and their curvature gives band effective mass. Thus mechanical confinement, material response and microscopic periodicity all reshape propagation through their allowed modes and dispersion, while the physical interpretation of the wave and its transported quantities remains essential.
A bubble is a thin water layer surrounded by air. At a locally flat patch, let its thickness be , its refractive index be , and the internal angle of refraction be . The two principal reflected light contributions are the reflection at the first surface and the contribution that enters the layer, reflects at its second surface and leaves again. The first reflection, from lower to higher refractive index, introduces a phase shift; the second does not. Their optical path difference is , so their phase difference is, modulo ,
where is the vacuum wavelength. Constructive interference in reflected light therefore occurs approximately when
Destructive interference occurs at . In the weak-reflection approximation, the reflected light intensity at each wavelength is proportional to . This is a smooth spectral filter, with broad maxima and minima: it does not select three pure wavelengths corresponding to display primaries. Ordinary illumination contains many visible wavelengths, and the eye combines their remaining contributions through color vision. The result is a mixture of colours, often pastel or desaturated.
The layer thickness varies over the bubble because of drainage and flow; the bubble's curvature also changes the local angle of refraction and the viewed optical path difference. The spectral filter therefore changes continuously across the surface and in time. Very thin regions become dark because the two reflected contributions nearly cancel across the visible optical spectrum. Thin-film interference explains both the changing colours and this dark limit.
Figure 1.
Two reflected paths through a thin film and the broad spectral filtering that produces mixed colours
. Details.
The ray sketch shows a local patch and is not to scale. The plotted curves use a chosen constant at normal incidence and illustrative thicknesses; they show the spectral filter rather than calibrated perceived colours.
For a cold, unmagnetized, collisionless plasma, take an equilibrium electron density , electrons of mass and charge , and approximately stationary ions. Use fields proportional to . The electron displacement satisfies
Its electric polarization is , hence the cold collisionless plasma dielectric response
The negative susceptibility arises from the inertial electron response, rather than a restoring force binding an electron to a particular atom.
A transverse electromagnetic wave then obeys
For , the plasma supports propagation, with refractive index . The phase velocity is greater than , while the group velocity is ; their product is , and no superluminal signal is implied. Below the plasma frequency, the bulk wavenumber is imaginary and the field is evanescent. A sufficiently thick plasma largely reflects such radiation in the lossless model.
Including an electron momentum-relaxation rate replaces the denominator by :
Its imaginary part describes absorption with the stated time convention. Finite electron temperature also produces plasma screening of slowly varying electrostatic fields, with . That spatial, longitudinal screening problem is distinct from simply taking in the cold transverse-wave formula. Magnetic bias, ion motion and kinetic resonances require more general dielectric responses.
Electromagnetic waves drive mobile charges in a conducting medium. Their current changes both the phase and attenuation of the wave. A description in terms of a real, frequency-independent refractive index is therefore generally insufficient: the material response and the propagation constant are complex and frequency dependent.
Use phasors proportional to , with and for a passive medium. In a homogeneous, isotropic, linear material, let represent the permittivity associated with bound-charge electric polarization, the magnetic permeability and the mobile-charge conductivity. The macroscopic Maxwell equations give
For a transverse plane wave, taking another curl yields
This division of the response avoids counting mobile electrons both in and in . Define the complex refractive index . For a nonmagnetic medium, . Its real part determines the phase variation, while the positive optical extinction coefficient gives amplitude attenuation and intensity attenuation . The amplitude penetration length is
A simple microscopic explanation comes from the Drude model. Let electrons of charge , mass and number density move against an effectively stationary positive background. Collisions relax their mean velocity at rate :
Consequently
With a vacuum-like bound-charge background, this gives
Its imaginary part is positive for positive , consistent with dissipation under the chosen phasor convention. Real materials can require an effective electron mass, a nontrivial bound-charge response, or additional absorption associated with the electronic band structure.
A plasma is a conducting ionized medium with mobile electrons and ions, approximately neutral on large scales because of plasma screening. For the electron-frequency transverse waves considered here, the heavy ions can often be treated as stationary. In a dilute weakly collisional plasma, , so
For , is real in this collisionless model and the wave propagates. Its phase velocity is , while its group velocity is ; their product is . A phase crest exceeding does not imply superluminal information transport. For , the refractive-index square is negative and
The transmitted field is evanescent rather than a traveling bulk wave. A sufficiently thick collisionless plasma reflects such radiation without Ohmic absorption. Collisions make the response complex and permit absorption. This accounts for a plasma cutoff and, qualitatively, the reflection of some radio frequencies by ionized atmospheric layers. The simple model describes transverse waves; plasmas also support longitudinal collective modes.
In a metal, positive ions usually form a crystal lattice. Mobile conduction electrons occupy states described by the electronic band structure and normally form a degenerate Fermi gas. The conduction-electron density is usually much higher than in a dilute gas plasma. Thus its plasma frequency is commonly in the optical or ultraviolet range, rather than the lower radio-frequency values possible in dilute plasmas. Electron scattering from the lattice, defects and other excitations gives a finite relaxation rate. The distinction is not that every plasma is collisionless and every metal collisional: the controlling ratio for either material is , together with its carrier density and bound-charge response.
At sufficiently low frequency, , the metal's conductivity is approximately real, . In a good conductor the conduction current dominates the displacement current, . The wave equation then gives
For example, a tangential electric field varies as
The current is therefore concentrated within a few skin depths of the surface: this is the skin effect. As frequency increases within this regime, . In a wire whose radius greatly exceeds , only a thin outer region carries appreciable alternating current, increasing the effective resistance. In a conducting shield, the same penetration suppresses the field transmitted through a sufficiently thick wall.
The Poynting theorem identifies the loss as Joule heating. The cycle-averaged heating density for a complex conductivity is
The wave impedance is . For incidence from vacuum at normal incidence, the electric reflection amplitude is , where . A good conductor has small and therefore strong reflection, while the part of the incident power entering it is dissipated over the skin depth.
At high enough frequency that , a metal's free-electron response also approaches the collisionless plasma form. The low-frequency formula must not simply be extrapolated into that regime. Real optical behavior additionally depends on the electronic band structure and transitions between bands. Both plasmas and metals are therefore described by the same electromagnetic response framework, but their relevant densities, scattering rates and frequency regimes differ.
An incident electromagnetic wave generally produces reflected and transmitted waves because the two media have different electromagnetic response. Consider a flat interface between homogeneous, linear, lossless media with permittivities and magnetic permeabilities . Their wave speeds and wave impedances are
For each plane electromagnetic wave, . With no free surface charge or current, the interface conditions for electromagnetic fields require continuous tangential and normal . Equality of the phase at every point on the boundary gives equal angular frequencies and tangential wavevectors. Hence the reflection angle equals the incidence angle and Snell's law is
where and each angle is measured from the normal.
At normal incidence use the same tangential axis for all electric amplitudes. The two independent boundary equations are
Solving gives the amplitude Fresnel equations
For nonmagnetic media, these become and . Reflection into a medium of larger refractive index therefore reverses the electric amplitude's sign at normal incidence.
The normal Poynting vector determines the reflected and transmitted fractions of incident power. At normal incidence,
It is the power fractions, rather than the squared electric amplitudes alone, that add to unity.
At oblique incidence separate transverse electric polarization (, electric field perpendicular to the incidence plane) from transverse magnetic polarization (, electric field in that plane). For nonmagnetic media, writing and , the Fresnel equations are
Here choose a common direction and, for each ray, the direction as . This makes the reflected basis reverse its tangential direction at normal incidence, explaining why the displayed then has the opposite sign to . Physical reflectance is independent of this sign convention. For either polarization with propagating transmission,
For polarization, zero reflection occurs at the Brewster angle . If , incidence above the critical angle for total internal reflection produces an evanescent field in total internal reflection and for an isolated lossless interface. A lossy second medium requires complex response coefficients and an absorption term in the energy balance.
Reflection and central spot. At a boundary from lower to higher refractive index, the near-normal electric-field reflection coefficient is negative, . This gives a wave phase reversal on reflection from the glass plate through the air film. Reflection at the lens's glass-to-air underside has no such reversal. These are consequences of the Fresnel equations for the reflected electric field.
At ideal contact the film thickness is zero, so the two reflected contributions have zero geometrical optical path difference but a relative phase reversal. They produce destructive interference, and the central spot is dark. This conclusion concerns the film reflection; other lens surfaces can add a weak background.
Rings and their radii. At radial distance , let the air thickness be . The two relevant rays reflect at the upper and lower film interfaces. The lower reflection accumulates an extra round-trip optical path length , plus the relative reflection shift. As increases away from contact, alternating constructive and destructive thin-film interference forms Newton's rings. At near-normal incidence, a bright ring satisfies
The extended source can illuminate these localized film fringes: each incident contribution interferes with its own two reflected paths; unrelated source points need not be mutually coherent.
For the spherical lens surface, geometry gives , so . Since , . Combining the equations yields
The bright ring is the first bright ring around the dark contact point.
Curvature from ring diameters. Writing , subtract the squared diameters to eliminate the unknown initial order:
Using SI units,
Liquid-filled film. With film refractive index , still smaller than both glass indices, there remains exactly one relative reflection phase reversal. The round-trip optical path length is now , so
Here is the illuminating vacuum wavelength, approximately its air value, rather than its shorter value inside the liquid. The ring labelled therefore has diameter
Filling the gap contracts each ring radius by at fixed order and curvature.
The Huygens-Fresnel principle constructs a new wavefront as the envelope of secondary wavelets emitted by points on an earlier wavefront. Let the phase velocities in the two media be and , with refractive indices evaluated at the light's fixed frequency.
Figure 1.
An original secondary-wavelet construction of refraction at a plane interface
. Details.
For refraction from secondary wavelets, let point of the incident wavefront reach the interface first. A second point reaches the interface at after time , so . During the same interval, the secondary wavelet centered on advances radius into the second medium. The refracted wavefront is tangent to this wavelet, hence ; also because a ray is normal to its wavefront in these isotropic media.
Let be the incident and refracted ray angles from the interface normal. They also equal the corresponding acute angles between the wavefronts and the interface. The two right triangles have common hypotenuse , giving
Their ratio eliminates both and :
This is Snell's law. In particular, entering a medium of larger refractive index reduces the ray's angle to the normal. The construction assumes a stationary interface and homogeneous isotropic media with a propagating refracted wave.
Keep the paper's as magnitudes for the two convex faces. With the standard signed-curvature convention measured to the right, the first surface has signed radius and the second . This explains why the requested formula contains a sum of the two reciprocal magnitudes.
Let the axial lens thickness be , and let be the distance from the first vertex to the intermediate focus that its refracted rays would reach without the second surface. The first refraction at a spherical surface gives
At the second face those rays are still converging toward that intermediate focus, so its object distance is negative, , with . Applying the signed spherical-surface equation again gives
In the thin lens limit, . Adding cancels the intermediate-focus terms:
The focal length is the image distance for parallel incident light rays, , hence the lensmaker's equation is
The same surrounding refractive index is assumed on both sides. For this biconvex thin lens has positive focal length. With signed radii , , the equivalent familiar expression is .
Treat the transparent plate as a phase plate at normal incidence. Its extra optical path is . An unchanged interference pattern requires an integer number of full phase cycles:
For full-cycle phase-plate invisibility in an ordinary nontrivial material with , the two smallest are and . If the optically null case is admitted, the first two nondecreasing- values are and . A different allowed range of refractive indices would need to be specified before calling these the absolute smallest possibilities.
In the Lorentz oscillator model, each participating bound electron is displaced by an applied electric field against a restoring force. The model replaces complicated interband transitions by a driven damped harmonic oscillator. If is the electron displacement along the field and the electron charge is , its equation of motion is
Here describes binding and describes loss of coherent motion. For , the complex amplitude is
The induced electric dipole moment is , so the electric polarization amplitude for number density is
Using gives
The paper's is this dimensionless relative permittivity, rather than the absolute permittivity . Independent classes of bound electrons contribute additive susceptibilities, usually with different resonance frequencies and optical oscillator strengths.
Writing separates the response into
At zero frequency the real part is and the imaginary part vanishes. Near resonance the imaginary part has a positive photon absorption peak and the real part changes rapidly, passing through at . Above resonance the real part can become negative when damping is sufficiently weak; at very high frequency it approaches from below while the imaginary part tends to zero. Finite damping removes the undamped divergence.
For a nonmagnetic material take the passive square-root branch , with . A plane wave then has an intensity attenuation coefficient . Thus the imaginary permittivity expresses dissipation, whereas the actual photon absorption coefficient is determined by the imaginary refractive index. The normal-incidence power reflectance is
A large refractive-index mismatch produces wave reflection even without loss. In the undamped model between and , so the field is evanescent and wave reflection is total in a semi-infinite sample. With damping the response includes both wave reflection and photon absorption; a peak in the imaginary permittivity should not simply be identified with a reflectance peak.
To infer the short-wavelength background from , assume weak photon absorption and take the physical semiconductor branch . Then
so
This is an estimate of the valence-electron background in a frequency window above the doped-carrier response and below the effective bound-electron resonance. One reflectance value alone does not determine both parts of a complex dielectric constant. Even for real , a reciprocal-index branch gives the same ; the ordinary background index greater than unity selects the branch used here.
Using the supplied conventional cubic lattice parameter, the participating valence-electron number density is
Using for the stipulated free-electron comparison gives
An angular frequency “in eV” means its quantum energy , not . No doped-carrier effective mass should be inserted into this valence-electron count.
The low-frequency limit of the bound-electron contribution obeys
Consequently
This effective resonance is much larger than the quoted band gap. There is no contradiction: the single oscillator has been assigned the strength of all sixteen participating valence electrons per conventional cell, whereas the band gap is only the lowest interband excitation threshold. A real spectrum distributes optical oscillator strength over many transitions. Equating the oscillator resonance to the lowest threshold would misrepresent the assumed background response. Here “low frequency” means low relative to ; the static response of the doped conducting sample also contains its free carriers.
The additional mobile carriers in doped indium antimonide contribute a Drude frequency response, obtained by setting their restoring frequency to zero. At infrared frequencies well below the effective valence resonance, the sum is approximately
At the shorter wavelengths the carrier term is small and approaches the background value. As wavelength increases, the negative free-carrier contribution lowers the real permittivity towards unity. For weak damping, refractive-index matching to vacuum gives the Drude-Lorentz reflectivity minimum at
This minimum is near , not its zero. At the slightly lower screened plasma frequency , the real permittivity crosses zero; at longer wavelengths it becomes negative and the material becomes strongly reflective. Finite damping prevents a perfectly vanishing minimum and rounds the edge. At still lower frequency the large conducting response also drives towards unity.
Figure 2.
Illustrative Drude-Lorentz reflectivity minimum: increasing carrier density shifts the minimum to shorter wavelengths
. Details.
For fixed carrier effective mass and background permittivity, and . The observed shift of the minimum towards shorter wavelength as doping increases is therefore the expected free-carrier trend. The figure is an original model illustration, not a digitization or quantitative fit of the supplied curves; the carrier effective mass, damping and their density dependence have not been specified.
For independent electronic transitions, add the electric dipole moment responses:
The positive constants include electron density and transition atomic oscillator strength. Each term adds an absorption peak to and a dispersive positive-to-negative contribution to , as in the middle row of the figure.
Between well-separated absorption lines, where the medium is transparent, the refractive index generally increases with frequency: , or . This is normal dispersion. Near a resonance the real response turns down with increasing frequency, producing an interval of anomalous dispersion, , accompanied by appreciable absorption. The absorptive and dispersive parts are linked by the Kramers-Kronig relations; the steep variation is not independent of the loss spectrum.
TODO: biomolecular force assays are user-deferred. The following notes cover the generic physical apparatus, calibrated dielectric handles and synthetic attachments only.
In optical tweezers, a tightly focused laser produces a restoring gradient force on a suitable transparent bead. Scattering also transfers momentum along propagation, so a stable three-dimensional trap needs axial as well as lateral restoration. An objective with high numerical aperture, correctly filled entrance pupil, controlled beam polarization and low-aberration sample chamber are practical design elements. Collect transmitted/scattered light with a condenser and measure bead displacement with calibrated imaging or back-focal-plane photodetection. A steerable beam or translation stage sets relative positions; the force signal comes from bead displacement, not commanded stage displacement alone.
Near a stable operating point, use a harmonic optical trap with . For a slowly changing external force, in that coordinate; the optical restoring force is . Calibrate each axis and the range over which its response is linear. Detector sensitivity must also be known: write , with measured detector voltage , offset and position sensitivity in . A spring constant in arbitrary detector units is not a force calibration.
Three complementary physical calibrations are useful. At thermal equilibrium the equipartition theorem gives
This needs an independently calibrated position scale and a variance corrected for drift, detector noise and exposure averaging. In an overdamped Newtonian medium, the optical trap Langevin calibration obeys
Using a one-sided position power spectral density per hertz,
The corner frequency and spectral amplitude test both relaxation and fluctuation size. If drag is known, . The isolated-sphere value must be corrected near boundaries; otherwise measured height dependence can be mistaken for a changed trap stiffness. An independent steady optical trap drag calibration moves fluid past the trapped sphere: . Use small positive and negative speeds to verify slope, offset and force range.
One can also determine position sensitivity without assuming the bulk drag. In a low-frequency sinusoidal-stage optical trap calibration, let the known local fluid velocity amplitude be at drive angular frequency . The coherent bead displacement amplitude is
If the corresponding detector amplitude is , then
After removing the coherent drive line from the thermal record, combine this sensitivity with equipartition theorem to recover , and then infer from . A published calibration combines thermal spectra and stage-driven motion without taking bead drag as an input.[ref]
Controls determine whether these formulas measure the apparatus rather than its noise. Record blocked-light offsets and independent fixed-bead noise; calibrate length with known motion; keep sampling and electronics bandwidth adequate around ; and include exposure filtering and aliasing in a spectral fit. motion blur reduces measured variance and therefore makes naive equipartition theorem overestimate stiffness; additive position noise has the opposite bias. Changing exposure time provides a direct diagnostic.[ref] Check temperature and laser heating, wall separation, bead size and refractive index, alignment and power stability. Repeat after changing power or optical geometry and compare thermal, spectral and drag estimates. For a synthetic force handle, also measure the attachment's compliance and geometry so that bead motion is not automatically identified with its extension.
Figure 1.
Optical trap calibration
. Details.