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For thin-layer chromatography, define the TLC retardation factor using distances along the development direction:The origin coordinate is $y_0$; use the centre of a resolved spot and a front marked at the end of development. Both distances begin at the origin, never at the plate bottom. The ratio is dimensionless. An immobile spot has $R_f=0$; a spot at the front has $R_f=1$, where separation from other fast components may be poor. This distance ratio is distinct from the chromatographic partition coefficient and from a column retention time.

For an original stylized plate, choose absolute vertical coordinates $y_0=1\mathrm{cm}$, $y_{\mathrm{front}}=11\mathrm{cm}$, $y_A=4\mathrm{cm}$ and $y_B=8\mathrm{cm}$ above the plate bottom. The solvent distance is therefore $10\mathrm{cm}$, while the spot distances are $3\mathrm{cm}$ and $7\mathrm{cm}$:Using $4/11$ or $8/11$ would wrongly include the unused centimetre below the origin. These chosen positions do not represent measured pigments or the protocol's plate dimensions.

The TLC retardation factor depends on the sample, chromatographic stationary phase, eluent composition, and temperature; plate handling and development conditions must also match when comparing runs. The moving wet front and possible surface adsorption require their own transport assumptions. The equilibrium mobile fraction $f_m$ in the chromatographic partition coefficient model is not unconditionally equal to $R_f$; even that model depends on the phase volume ratio. Coincident TLC retardation factors alone never prove chemical identity.

In static thermal equilibrium, the local temperature times the stationary lapse is constant. Energy measured locally redshifts to conserved Killing energy by that same lapse; requiring a single equilibrium Boltzmann exponent gives the relation. The Killing vector field normalization fixes the constant but not the ratio of temperatures at different locations.

A torsion balance measures a weak torque by suspending a body from a thin fiber and reading its twist angle. The fiber supports the body's gravitational weight while permitting rotation about the suspension axis. In the range of linear elasticity, a twist $\theta$ in radians, measured from the untwisted reference orientation, produces a restoring torqueThe torsion constant $\kappa$ sets the sensitivity. At static equilibrium with an applied torque ${\tau }_{\mathrm{ext}}$ and no other axial torque, ${\tau }_{\mathrm{ext}}=\kappa \theta$. A perpendicular force $F$ at lever arm $a$ therefore gives $\theta =aF/\kappa$. The torsion balance measures a turning effect: a force whose line of action passes through the suspension axis gives no axial torque. The Cavendish torsion balance is the gravitational application; Coulomb's law supplies an electrical one. ^[ref]

The original schematic separates two ways of reading the same torque. In deflection operation the top attachment stays fixed and the body rotates. In null operation the experimenter rotates the top attachment by $\alpha$ while returning the body's laboratory angle $\beta$ to its original value. If the initially untwisted configuration has $\alpha =\beta =0$, the fiber twist is $\theta =\beta -\alpha$, not $\beta$ alone. ThusFor a positive applied torque, holding $\beta =0$ requires $\alpha =-{\tau }_{\mathrm{ext}}/\kappa$. Keeping the body at the same angle keeps the lever arm and source geometry fixed, making comparison of different applied forces easier. Either readout still requires a calibrated torsion constant and a stable reference orientation.

An illustrative calculation shows the amplification: with $a=0.050\mathrm{m}$, $F=2.0\times 10^{-9}\mathrm{N}$, and $\kappa =1.0\times 10^{-8}\mathrm{N}m/rad$, the applied torque is $1.0\times 10^{-10}\mathrm{N}\mathrm{m}$ and the equilibrium twist is $0.010\mathrm{rad}\simeq 0.573^{\circ }$. These are stipulated values, not measured data. Reducing the torsion constant tenfold increases this twist tenfold, provided the fiber remains in its calibrated linear elasticity range. The cost is a slower response, explained by the oscillation period in torsion constant.

A concrete laboratory experiment is PASCO's Coulomb balance: level its counterbalanced rod, discharge both conducting spheres, and set the unloaded zero. Charge the spheres at maximum separation; switch off the charging supply. Move the second sphere to a known center separation $R$, then turn the suspension dial until the rod returns to its index mark. Record the dial change and $R$, recharge, and repeat at several separations. The manual recommends a draft-free room, clean insulating supports, and recharging before each reading: leakage, especially in humid conditions, otherwise changes the electric charges during the sequence. At close separations the conducting spheres redistribute charge, so the point charge approximation needs correction. ^[ref]

For constant electric charges and a fixed perpendicular lever arm, the Coulomb's law prediction is $|\theta |\propto R^{-2}$. Plotting the logarithm of twist magnitude against the logarithm of separation gives $\log |\theta |=\text{constant}-2\log R$, so the predicted slope is $-2$. Absolute force measurement additionally needs the torsion constant; comparing ratios can eliminate it if it remains stable. Repeating a reference separation between other settings distinguishes a separation effect from a changing signal. A declining reading at the reference separation would invalidate the assumption of unchanged electric charges, even if a distance plot looks smooth.

The historical electrical example is Coulomb's first memoir of 1785. His apparatus enclosed a suspended needle with a small ball and a second ball; an adjustable head twisted the suspension. After charging the balls by contact, he reported angular separations $36^{\circ }$, $18^{\circ }$, and $8.5^{\circ }$ with head settings $0^{\circ }$, $126^{\circ }$, and $567^{\circ }$. The total twists were approximately $36^{\circ }$, $144^{\circ }$, and $576^{\circ }$: fourfold restoring torque accompanied approximately halved separation. These are his reported observations, not data from our diagrams. ^[ref] A precise reconstruction must use center distances and the changing lever arm, rather than identify angular separation exactly with distance; Alberto A. Martínez's replication explicitly analyzes that geometry. ^[ref]

Sensitivity also exposes changes of the apparatus itself. Fleischer and colleagues' cryogenic torsion balance used a temperature-controlled enclosure to reduce vacuum-vessel top-plate temperature fluctuations to approximately $\pm 0.01\mathrm{K}$, limiting changes in suspension geometry from thermal expansion. They used a mild bake-out near $40^{\circ }\mathrm{C}$ to speed initial fiber relaxation and reduce slow zero motion. Their optical readout compared the pendulum mirror with an internal reference mirror to reject shared optical motion. Room-temperature thermal radiation entering through the optical opening heated the pendulum; a cold filter reduced that load. The authors could not directly measure the pendulum's temperature without disturbing it, and explicitly distinguished the cold shield's temperature from the body's. Cooling therefore requires checking the actual noise and thermal environment, rather than assuming that the fiber and body share the shield's temperature. ^[ref]

A useful control strategy is to record unloaded readings and temperature before and after each signal sequence, recalibrate the torsion constant under the same conditions, and compare forward and reverse settings. The algebra of torsion balance zero drift shows precisely which offsets such comparisons can cancel. A fine angular scale alone does not establish a small measurement error.

The torsion constant, or torsional spring constant, is the positive restoring torque per unit twist angle of a complete suspension in its linear elasticity range:Its SI unit is $\mathrm{N}m/rad$. The minus sign describes restoration toward the untwisted orientation. The derivative specifies a local stiffness if the response is not globally linear; using one constant over a finite range additionally requires a straight calibration curve. Return to the same zero after unloading tests recoverable elastic deformation; repeat loading in both directions to check whether the response depends on its previous loading. Staying below permanent deformation is necessary, but does not alone prove proportionality between torque and twist.

For an ideal uniform circular wire of length $\ell$, radius $r$, and shear modulus $G_s$, the filament torsional stiffness is $C=G_s{J}_p$, with polar second moment of area $J_p=\pi r^4/2$. Uniform twist gives $\theta /\ell$ as the twist per unit length, soHere $U$ is stored elastic energy. Doubling the wire's radius multiplies the ideal torsion constant by $16$; doubling its length halves it. This explains why a long thin fiber is useful for weak torque measurement. The formula assumes linear elasticity with uniform material and circular section; it does not calibrate arbitrary ribbons, clamps, or a compound suspension. Within this ideal model, the equipartition theorem predicts an equilibrium thermal mean-square angular displacement $⟨{\theta }^2⟩=k_B\mathcal{T}/\kappa$, where $k_B$ is the Boltzmann constant and $\mathcal{T}$ the uniform absolute temperature. A softer suspension magnifies both the signal and its thermal fluctuations.

Static calibration supplies known torques without assuming the unknown interaction being measured. Apply a known perpendicular force $F$ at lever arm $a$, record the change from the unloaded twist, and useSeveral positive and negative settings test proportionality; fit the slope of applied torque against twist and retain a possible intercept. A nonzero intercept must not be silently absorbed into the slope. Convert degrees to radians before reporting $\mathrm{N}m/rad$. PASCO's procedure turns the Coulomb balance on its side and adds small known masses to generate a gravitational weight at the sphere's lever arm, returning the rod to its index mark by turning the dial. Its tabulated coefficient is force per degree: multiply by the lever arm and $180/\pi$ to obtain our torsion constant. ^[ref]

The figure's ideal static calibration uses $\kappa =1.0\times 10^{-8}\mathrm{N}m/rad$: an applied torque of $2.0\times 10^{-10}\mathrm{N}\mathrm{m}$ gives $0.020\mathrm{rad}$. Both signs lie on the same straight line. The plotted points are calculated examples, not experimental observations; they cannot demonstrate a real fiber's linearity.

Dynamic calibration instead measures the oscillation period $T_0$ with known total suspended moment of inertia $I$. For negligible damping, small free oscillations about a fixed reference obey simple harmonic motion:Include the rod, mirrors, and any attachments in $I$ unless their contributions are demonstrably negligible. Keep the applied torque absent or independent of angle. If an external torque has derivative $g_{\tau }=d{\tau }_{\mathrm{ext}}/d\theta$ at equilibrium, linearization gives effective stiffness $\kappa -g_{\tau }$: timing alone then measures that combination, and stability requires $\kappa -g_{\tau }>0$. A constant applied torque merely shifts equilibrium. Non-negligible damping changes the measured period; damped torsional oscillation gives a correction under a specified damping model. Agreement between static and dynamic calibrations is a useful check on the assumed moment of inertia, reference stability, and restoring law, rather than a reason to ignore their assumptions.

Researcher in bacterial gene regulation. Waldminghaus and collaborators investigated the FourU RNA thermometer in Salmonella, linking temperature-dependent RNA structure with control of gene expression.^[ref]

Total hemispherical emissivity integrates over all emitted wavelengths and the outward hemisphere. If ${ϵ}_{\lambda ,\Omega }$ is spectral emissivity resolved by direction, and $B_{\lambda }(T)$ is blackbody spectral radiance from Planck's law, thenIt is a weighted average, not an unweighted mean of surface properties. Even if the wavelength-resolved material response stays unchanged, the Planck's law weighting changes with temperature, so the total ratio can change. Likewise, total radiometric absorptance averaged over radiation from hotter surroundings generally differs from this emission-weighted ratio. Kirchhoff's law of thermal radiation equates matched spectral and directional quantities; it does not equate arbitrary broadband averages.

The tracking error used by the controller is the signed differencebetween the reference signal and the measured output. A positive tracking error means the readout is below the desired value; a negative tracking error means it is above. With exact measurement $y_m=y$, $r=1$ and $y=1.1$ give $e=-0.1$. For a positive-response controlled plant, positive feedback gain in proportional control $u=k_{p}e$ then reduces the plant output. The sign of the controller must also account for the sign of the controlled plant's response: a positive command that reduces the plant output requires a different sign choice. Kantor uses the opposite tracking error convention, $PV-SP$, together with a minus sign in his controller; translating both signs gives the convention here. ^[ref]

Distinguish the controller's tracking error from the physical plant output discrepancy $\epsilon =r-y$. If the readout has constant sensor bias $b$, thenAll four quantities $r,y,y_m,e$ have the same units under dimensional analysis; a sensor bias is expressed in those units too. A readout that is too high by $0.2{}^{\circ }\mathrm{C}$ can make $e=0$ when the physical temperature is $0.2{}^{\circ }\mathrm{C}$ below the goal. Integral action integrates the tracking error it receives; it cannot infer this missing calibration information from that tracking error alone. Thermometer calibration against an independent reference addresses a different problem from tuning a feedback gain.

A motivating apparatus/model comparison is Park, Martin, Kelly and Hedengren's temperature-control laboratory: two TIP31C heaters with attached TMP36GZ sensors and heat sinks, an Arduino, a power supply, and a USB-connected computer. The readout converts sensor voltage to temperature; software records that measured output while specifying heater commands from $0$ to $100\%$. For the single-heater test, one command changes in steps and the other heater stays off. Parameters are fitted to one run, then a different command sequence tests predictions without feeding measured temperatures into the simulation. The authors observe that their richer thermal model predicts the response better than the approximation with a single time constant and a delayed control input, especially after command changes. The real sensor has its own thermal lag. They also repeat the same command profile at different ambient temperatures and find changes in the response, motivating ambient-condition reporting. This experiment measures a command-to-readout response, not independently the exact heater temperature or delivered power. ^[ref]

The lesson for tracking error is to record three traces during a tracking test: the reference signal, the measured output, and the applied control input. Their first difference is the tracking error; a model prediction minus a readout is instead a model discrepancy. In a proposed comparison of proportional control and proportional-integral control, keep the initial temperature, ambient conditions, heater limits, and target changes fixed; run the second heater separately as a known control disturbance. Independent thermometer calibration is needed to assess physical accuracy. These are suggested controls, not additional experiments claimed for the paper. A sensor's lag, measurement noise, actuator saturation, and changed ambient conditions can all invalidate conclusions drawn from the ideal first-order model.

Transition state theory relates an elementary reaction's rate constant to a Gibbs energy of activation. The Eyring expression used in the catalyst example assumes every passage counted at the transition state succeeds. More generally, a factor accounting for unsuccessful passage multiplies it. Comparing barriers alone gives the quoted speedup only when the remaining prefactors agree. Free-energy profiles can depend on temperature, so the example's values at $300\mathrm{K}$ do not determine a temperature curve. See the IUPAC Gold Book: transition state theory.

A low-mean molecular weight hydrogen-helium envelope can add a large radius while adding a small fraction of the mass. The exoplanet transit photometry radius is the altitude where tangential optical depth becomes order unity, so temperature, opacity, and exoplanet clouds can move the measured radius above the deep material radius. Atmospheric loss and cooling change this contribution over time.

For a dilute classical ideal gas whose atoms carry independent nondegenerate internal levels $0,ϵ$, the canonical partition function factorizes into translation and $(1+e^{-\beta ϵ}{)}^N$. The upper-level probability is $p=(1+e^{\beta ϵ}{)}^{-1}$. Taking two derivatives of its logarithm gives the title sum of independent variances. The internal contribution freezes exponentially at low temperature and tends to $N{ϵ}^2/4$ at high temperature. The translational classical result cannot be continued through quantum degeneracy without changing the model.

Four-terminal sensing tests a conducting connection between the voltage contacts. A magnetometer instead tests the sample's magnetic response. These measurements provide complementary constraints: the first is sensitive to a continuous path, while the second also depends on screening geometry and preparation history.

For transport, define $V_{ab}$ between the inner contacts and use the reversed-electric current estimator from four-terminal sensing. Contact separation excludes drive-contact drops, but does not eliminate a drifting thermoelectric effect, Joule heating or an unrepresentative path through part of the specimen. Repeat at smaller electric currents and compare results at the same sample temperature. A finite-current result refers to that electric current and its relation to the path's superconducting critical current.

For magnetism, distinguish cooling in zero applied magnetic field and then applying it from the Field-cooled Meissner experiment. Record the applied magnetic field, background and sample geometry when interpreting magnetization or magnetic susceptibility. A transport short does not establish full Meissner effect screening throughout the specimen. Conversely, flux pinning in a type-II superconductor can make the field-cooled magnetic response differ from ideal complete expulsion. Even a large shielding signal is not automatically a direct measure of the superconducting phase fraction: a connected outer screening region can surround nonsuperconducting material.

For equal thermal properties and bounded travelling profiles on two deep half-spaces, the solid temperature is $T_m$ and the liquid profile is exponential. The Stefan condition requires $L=c_p\Delta T$. This balances the latent heat of solidification with warming of the initially supercooled liquid.

For $F=F_0+b(T-T_c)M^2+d^{\prime }{M}^6$ with $b,d^{\prime }>0$, the ordered minimum has $M^4=b(T_c-T)/(3d^{\prime })$. Its singular free energy is $-2b^{3/2}(T_c-T{)}^{3/2}/\sqrt{27d^{\prime }}$. Twice differentiating in temperature gives the displayed ordered-side heat capacity singularity, with mean-field critical exponent $\alpha =1/2$. This path keeps the quartic coefficient tuned to zero; a generic path with a positive quartic term instead crosses over to the ordinary quartic result.

The Triple-alpha process fuses three helium-4 nuclei into carbon-12 through an unstable beryllium-8 intermediate. Its steep temperature dependence can make helium-shell burning thermally unstable. The resonant triple-alpha temperature sensitivity isolates the role of the Hoyle state, while laboratory evidence for the Hoyle state explains how a particle spectrum tests the required nuclear level.

A triple point is a temperature–pressure pair at which three distinct bulk thermodynamic phases of a one-component substance coexist in thermodynamic equilibrium. In the familiar solid–liquid–gas case, their three phase coexistence curves meet. Other combinations, such as two crystal polymorphs and a liquid, also qualify: “triple” counts thermodynamic phases, rather than states-of-matter categories.

For the same substance, the chemical potential in each thermodynamic phase must agree:There are two independent equality conditions for two controls, temperature and pressure. Generically they select an isolated pair $(T_t,p_t)$; the third pairwise equality follows from the first two. Equivalently, the phase rule gives $F=1-3+2=0$. This counts independent intensive controls, not phase fractions: changing the amounts of the three thermodynamic phases need not change the ideal bulk temperature and pressure, provided all three remain present. Different sets of crystal polymorphs can give different triple points for the same substance.^[ref]

At a liquid-gas critical point, the two fluid thermodynamic phases instead merge, and their mass density difference and latent heat vanish. It is the endpoint of the liquid–gas phase coexistence curve, rather than a meeting of three distinct thermodynamic phases. The regular independent-equality count used for a triple point cannot explain this merger. A triple point can retain finite mass density and entropy differences between all three thermodynamic phases.^[ref]

A triple-point cell turns phase coexistence into a reproducible reference for thermometer calibration. The NIST water-cell demonstration uses a sealed glass vessel containing water of specified isotopic composition and an open central thermometer well. Cooling this well with solid carbon dioxide and alcohol freezes an ice mantle while leaving liquid water and its vapor. The coolant is outside the sealed sample; the sample's vapor space does not communicate with room air.^[ref]

In the actual NIST cell-comparison experiment, newly frozen mantles were compared with an aged reference mantle in a controlled maintenance bath. A warm aluminium rod melted a thin inner layer around the well, allowing the mantle to rotate freely and establishing an ice–water interface close to the sensor. A standard platinum resistance thermometer and a resistance bridge measured the electrical resistance ratio to a calibrated, temperature-controlled reference resistor. Readings at two currents permitted extrapolation to zero electrical power, correcting self-heating; measured immersion depths supplied hydrostatic pressure corrections. Comparing preparations over time tested stabilization rather than assuming freshly frozen ice was ready.^[ref]

The inference is a reproducible fixed-point response for the thermometer, not a direct reading of three chemical potentials. The reference cell anchors the comparison; a water point alone does not determine a thermometer's response at every other temperature. The ideal $F=0$ argument excludes impurity and isotope variation, finite interface effects and unintended heat transfer; real cells also require adequate immersion and stable electrical references. Repeatability is evidence that these effects are controlled, not a reason to omit their uncertainty.

Since 20 May 2019 the kelvin has been defined through a fixed numerical value of the Boltzmann constant. The thermodynamic temperature of the water triple point is consequently a measured quantity with uncertainty, rather than an exact value imposed by the kelvin definition. Its continued use as an assigned reference on the International Temperature Scale of 1990 is a separate convention.^[ref][ref]

The troposphere is the lowest main layer of the terrestrial atmosphere, with weather and generally decreasing temperature with altitude. Local inversions and moist convection complicate a single lapse-rate description.

A researcher who coauthored in situ material creep experiments on a nickel-based single crystal alloy. X-ray diffraction using synchrotron radiation followed the lattice response while the applied stress changed at fixed temperature. Comparing the responses of the matrix and reinforcing regions helped separate load transfer from plastic flow and constrain the motion of dislocations during high-temperature deformation.^[ref]

Daniel Tsui, Horst Störmer and Arthur Gossard reported the effect in 1982. They grew gallium arsenide–aluminium gallium arsenide layers by molecular beam epitaxy, separating the two-dimensional electron gas from its semiconductor doping. They cut Hall bars and made indium contacts. Low-field measurements established number density and charge carrier mobility. A perpendicular magnetic field sweep measured transverse and longitudinal sheet resistivities at several temperatures. Cooling sharpened the plateau near $3h/e^2$ and the longitudinal minimum at filling factor $1/3$; integer plateaus provided an internal comparison. The longitudinal minimum remained finite at the lowest temperature: zero-temperature vanishing was unresolved. This established anomalous transport, without directly measuring excitation electric charge.^[ref]

The two readouts test different statements. A single intersection with $R_H=3R_K$ would also occur on the smooth classical relation $R_H=B/(n_{s}e)$ at $n_{s}h/(eB)=1/3$. A quantum Hall plateau instead persists over a magnetic field interval. Comparing transverse and longitudinal signals helps distinguish that plateau from a contact-placement artefact; the quantum Hall conductivity tensor inversion quantifies the contamination when longitudinal sheet resistivity is nonzero.

Later, 1997 shot noise measurements associated with quantum tunnelling at filling factor $1/3$ tested the excitation electric charge separately, finding $e/3$. That is a different observable from a Hall plateau.^[ref]

A tunnel diode is a p-n junction with sufficiently heavy semiconductor doping on both sides to make a thin depletion region and permit substantial interband tunnelling. The neutral regions are degenerate semiconductors. Its distinctive forward current-voltage characteristic contains a peak followed by a valley: over part of the curve, increasing the applied electric potential difference decreases the electric current. The Esaki tunnel-diode experiment made this behavior experimentally concrete.

The useful quantity is the local slope, not the ratio of total voltage to total electric current. With conventional electric current $I$ entering the positive-voltage terminal, defineNegative differential resistance means $g_d<0$, hence $r_d<0$ where defined. A forward operating point can still have $V>0$, $I>0$ and absorbed power $VI>0$. A small voltage increase then gives a negative current increment; this does not make the total electric current negative or turn the device into an unlimited source of energy. The external supply sets the operating point and supplies the energy available for an electronic amplifier.

An original idealized construction explains the shape. Put the n-type semiconductor on the left and the p-type semiconductor on the right. Take $q>0$ as the elementary charge and $V=V_p-V_n$. Increasing forward bias lowers the right-hand electron energy levels relative to the left. Denote the two reservoir electrochemical potentials by ${\mu }_n,{\mu }_p$, so that ${\mu }_n-{\mu }_p=qV$. At zero temperature, occupied left-hand conduction band states extend up to ${\mu }_n$; empty right-hand valence band states start at ${\mu }_p$. For transfer conserving electron energy, the available interval isIt is nonempty only when its upper endpoint exceeds its lower endpoint. Both an occupied initial quantum state and an empty final quantum state must exist at the same energy. The Pauli exclusion principle prevents transfer into an already occupied final quantum state.

For the original diagram, choose arbitrary energy units with $E_{c,n}=-0.5$, ${\mu }_n=0$, ${\mu }_p=-u$ and $E_{v,p}=0.5-u$, where $u$ is $qV$ in those units. The available interval has widthThus $L(0.25)=0.25$, $L(0.50)=0.50$, $L(0.70)=0.30$, and $L(1.15)=0$. Initially forward bias opens a transfer window; further forward bias closes it by moving the right-hand valence band edge below the left-hand conduction band edge. This is a state-counting illustration, not a formula for a measured electric current.

For reverse bias, the transfer direction changes: occupied right-hand valence band states can feed empty left-hand conduction band states. In the same construction, $u=-0.70$ opens the interval $0<E<0.70$ for this reverse transfer. A narrow depletion region allows a large reverse quantum tunnelling electric current at small electric potential difference, whereas the ordinary Shockley diode equation predicts only a small reverse saturation electric current before diode reverse breakdown. At zero biasing, equal reservoir occupations give zero net electric current; quantum tunnelling does not require a net equilibrium flow.

A finite-temperature refinement replaces sharp occupation cutoffs with the Fermi-Dirac distribution. An illustrative weak-transfer expression isHere $\mathcal{W}\ge 0$ describes allowed initial/final quantum states and their coupling, and $f_n,f_p$ are Fermi-Dirac distributions with the respective electrochemical potentials. The occupation difference follows by subtracting the reverse transfer factor from the forward one: $f_n(1-f_p)-f_p(1-f_n)=f_n-f_p$. An overlap interval alone does not determine $\mathcal{W}$: transmission probability, density of states, crystal momentum selection and phonons can matter. A complete germanium calculation is more demanding than multiplying two constant density of states factors. At larger forward bias, ordinary carrier injection and diffusion supply a rising current branch even after direct band overlap is lost.