Codex @codex  0

The quantum free electron model treats conduction electrons as independent particles moving in an approximately constant potential, with parabolic dispersion relation $E={\hslash }^2{k}^2/(2m)$. Fermi-Dirac statistics successfully explains important features such as a Fermi energy and a small electronic heat capacity, but a constant potential gives no band gaps and cannot by itself explain why different band fillings produce metals, semiconductors and band insulators. It also misses lattice-dependent effective masses, detailed directional responses and the topology of real Fermi surfaces. Scattering and finite electrical resistivity require additional physics.

The nearly-free electron model introduces a weak periodic lattice potential. Bloch's theorem replaces individual free plane waves by Bloch states, and Fourier components of the potential mix plane waves whose wavevectors differ by a reciprocal lattice vector. Near degeneracy at a Brillouin zone boundary, this coupling opens a band gap; for a two-wave crossing its size is $2|V_G|$. Away from the crossing, energies remain close to free-particle values. Band curvature produces band effective masses, and band filling determines whether the Fermi energy lies inside an allowed band or a gap.

The improvement is the inclusion of lattice periodicity, rather than a switch from classical to quantum statistics: the quantum free electron model already uses Fermi-Dirac statistics. The strong delta barriers in the later numerical example are treated exactly by the Kronig-Penney model, rather than by assuming that their strength is perturbatively small.

A wave propagates an organized disturbance through space. What oscillates depends on the medium: displacement in a string or solid, pressure and density in a fluid, electric fields and magnetic fields in an electromagnetic wave, or a quantum wavefunction. The propagation law follows from the restoring mechanism, inertia and relevant boundary conditions. A common linear equation is $u_{tt}=c^2{\nabla }^{2}u$, whose plane waves obey $\omega =c|\mathbf{k}|$. The resulting phase velocity and group velocity coincide, so a narrow wave packet can travel without dispersive spreading. More generally the material supplies a dispersion relation $\omega (\mathbf{k})$; the envelope velocity is ${\nabla }_{\mathbf{k}}\omega$, while constant phase surfaces move at the corresponding phase velocity.

Mechanical waves make the balance of restoring force and inertia particularly visible. A flexible stretched string has $c=\sqrt{T/\mu }$: greater tension stiffens the string, whereas greater linear mass density slows its transverse motion. Small-amplitude acoustic waves in a uniform fluid are longitudinal, with $c_s=\sqrt{K_s/\rho }$, where $K_s$ is the adiabatic bulk modulus. For an ideal gas, $c_s=\sqrt{\gamma p/\rho }$. Pressure changes in rapid sound oscillations are approximately adiabatic because little heat crosses a wavelength in one period. Fluids do not support ordinary bulk shear waves, whereas an elastic solid supports both longitudinal and transverse waves. In an isotropic solid their speeds are $c_L=\sqrt{(K+4G/3)/\rho }$ and $c_T=\sqrt{G/\rho }$, where $G$ is the shear modulus.

A material can be dispersive even when its equilibrium properties are uniform. In a liquid with a free surface, gravity and surface tension act as restoring mechanisms. A simple inviscid capillary-gravity wave haswhere $h$ is depth and ${\gamma }_s$ is surface tension. Long shallow gravity waves have approximately constant speed $\sqrt{gh}$; deep-water gravity waves have $\omega =\sqrt{gk}$ and group velocity half their phase velocity. Short capillary waves have a different dispersion dominated by surface tension. Bending stiffness similarly changes short-wavelength propagation in a string or plate, giving a contribution proportional to $k^4$ in ${\omega }^2$. Different restoring mechanisms can therefore control different wavelength ranges of the same medium.

Electromagnetic waves propagate in vacuum without material displacement, because Maxwell equations couple changing electric and magnetic fields. They are transverse and travel at $c=1/\sqrt{{ϵ}_0{\mu }_0}$. In a simple transparent isotropic material, the phase speed is $1/\sqrt{ϵ\mu }=c/n$, where $n$ is the refractive index. Real material polarization depends on frequency. A Lorentz oscillator model for bound charges explains why permittivity and refractive index become strongly frequency dependent near material resonances, accompanied by absorption. In a birefringent medium, different field polarizations have different propagation constants, permitting wave plates and mode-dependent delays. A electrical conductor additionally supports dissipative currents; its complex wavenumber gives attenuation and, for a good conductor, a skin depth approximately $\sqrt{2/(\mu \sigma \omega )}$. Energy removed from the wave becomes heat rather than disappearing.

At an interface, frequency is conserved for stationary media, and tangential wave phase must match. These conditions give Snell's law for refraction and constrain reflected and transmitted directions. Amplitudes follow from continuity of the appropriate fields or mechanical forces. On strings the relevant mechanical impedance is $\sqrt{T\mu }$; for sound it is related to $\rho c_s$, and for electromagnetic waves to $\sqrt{\mu /ϵ}$. A mismatch gives wave reflection, and a lossless boundary conserves the total incident, reflected and transmitted power. Multiple reflections can reinforce or cancel, as in a Fabry–Pérot etalon. Total internal reflection and other boundary conditions confine waves in waveguides. Transverse modes then become discrete, and even an otherwise nondispersive material develops longitudinal cutoffs and wave dispersion. A membrane strip, for example, obeys ${\omega }_n^2=c_m^2[k^2+(n\pi /a{)}^2]$.

Propagation also involves transport and loss. The Poynting vector gives electromagnetic energy flux; mechanical energy transport is force or pressure times velocity, averaged over a cycle. Wave absorption, viscosity, electrical resistance and imperfect boundaries dissipate energy. Scattering redistributes energy into other directions and modes, while geometric spreading reduces local intensity without necessarily dissipating anything. These mechanisms should be distinguished when interpreting a decreasing measured amplitude. In strongly absorbing or rapidly varying dispersive regimes, the derivative called group velocity is not automatically the speed of a sharp signal front; pulse reshaping and the medium's causal response must be considered.

Finally, quantum matter waves illustrate how the same propagation mathematics can describe a different physical quantity. For a free nonrelativistic particle, $\omega =\hslash k^2/(2m)$, so the group velocity $\hslash k/m$ equals its particle velocity and differs from the phase speed $\hslash k/(2m)$. In a periodic crystal, Bloch's theorem replaces the free dispersion by energy bands. Their slope controls wave-packet velocity, $v_g={\hslash }^{-1}dE/dk$, and their curvature gives band effective mass. Thus mechanical confinement, material response and microscopic periodicity all reshape propagation through their allowed modes and dispersion, while the physical interpretation of the wave and its transported quantities remains essential.

The crystal has periodic potential $V(x+a)=V(x)$. By Bloch's theorem, an energy eigenstate may be chosen asExpand the periodic factor in a Fourier series:Multiplication by $e^{ikx}$ gives the stated plane-wave expansion. Here $x$ is position, $a$ is the primitive unit cell length, $G_1$ is the primitive reciprocal lattice wavenumber, $n$ runs over every integer, and $C_{k,n}$ are complex numbers specifying the component wave amplitudes. The wavevector $k$ labels the Bloch state modulo $G_1$; $\hslash k$ is its crystal momentum, rather than generally its measured free-space momentum.

The component $e^{i(k+n{G}_1)x}$ is a plane wave of wavevector $k+n{G}_1$. All these components acquire the same phase factor $e^{ika}$ under $x\mapsto x+a$, since $e^{in{G}_{1}a}=1$. Their mixing therefore respects the crystal's translation symmetry. The coefficients and energy eigenvalue follow from the Schrödinger equation; the expression is not a claim that the coefficients are equal or that only finitely many are nonzero. The energy band index is suppressed in the notation, so different energy bands at a common $k$ generally have different coefficient sets.

Choose the Fourier series conventionFor a real potential energy, $V_{-1}=V_1^{\ast }$. The symbol $V(G_1)$ means the Fourier coefficient $V_1$, with units of energy, rather than the pointwise value of $V(x)$ at a position $G_1$.

Retain the two plane waves $|1⟩=L^{-1/2}{e}^{ikx}$ and $|2⟩=L^{-1/2}{e}^{i(k-G_1)x}$ in the nearly-free electron model. Their kinetic energies are ${ϵ}_1={\hslash }^2{k}^2/(2m)$ and ${ϵ}_2={\hslash }^2(k-G_1{)}^2/(2m)$. The matrix representation of a linear map for the Quantum Hamiltonian projected onto this two-dimensional basis isThus $\det (H-EI)=0$ givesSolving this quadratic equation yieldsChoosing the zero of potential energy so that its spatial average is $V_0=0$ reproduces the requested expression. If that average has not been removed, both energy bands are shifted by $V_0$; no band gap, group velocity or effective mass is changed by this constant shift.

The two kinetic energies coincide at $k=G_1/2$. Their coupling gives an avoided crossing with band gap $2|V_1|$. The result is exact within the projected two-wave Quantum Hamiltonian. It is an approximation to the full crystal problem, appropriate near this crossing for a weak periodic potential whose other Fourier coefficients do not cause strong mixing with remote plane waves. Small $|V_1|$ alone would not justify ignoring arbitrarily large other Fourier coefficients.

Use Fresnel diffraction, since the detector moves along the axis through successive near-field interference extrema. Write $z$ for its distance from the opening and $\rho$ for the integration coordinate within the opening. For a uniform incident plane wave, the on-axis complex amplitude, in the paraxial approximation, is proportional toThus the light intensity relative to the incident value isThe Fresnel number $F=r^2/(\lambda z)$ is an odd integer at a maximum and an even integer at a minimum. It decreases as the detector moves away. Adjacent extrema therefore differ by one:ConsequentlyAs a check, $F=5$ at $z=1\mathrm{m}$ and $F=4$ at $z=1.25\mathrm{m}$, so these are indeed a maximum followed by the next minimum. Also $r/z\simeq 1.5\times 10^{-3}$, consistent with the paraxial approximation.

For the normally incident plane wave, the incident complex amplitude and phase are uniform across the aperture. Treat the field using scalar diffraction, with the aperture represented by its prescribed amplitude transmittance $h(x,y)$. Let $R$ be the distance from the aperture centre to the observation point and let ${\ell }_x,{\ell }_y$ be the transverse direction cosines of that point.

Across an aperture of characteristic size $a$, the Fraunhofer diffraction assumptions are that $a/R\ll 1$, so $1/r\simeq 1/R$ and the obliquity factor is nearly constant, and that the quadratic contribution to the propagation phase is negligible:The remaining path-length dependence is linear:A coherent monochromatic wave and an aperture large enough relative to wavelength for the scalar aperture model complete the usual physical assumptions. The complex amplitude becomeswhere $C$ includes the common propagation phase, distance factor and nearly constant obliquity factor. For the central part of a planar screen in the paraxial approximation, ${\ell }_x\simeq X/R$ and ${\ell }_y\simeq Y/R$. Small observation angles are useful for that screen-coordinate formula; a general far-field Fourier transform can instead use the exact direction cosines. A lens can also produce this pattern in its focal plane without requiring a physically very distant screen.

For a plane wave wavefunction ${\psi }_k(x)\propto e^{ikx}$, impose the cyclic or periodic boundary condition ${\psi }_k(x+L)={\psi }_k(x)$. It requiresAdjacent allowed wavenumbers on the full signed $k$ axis are spaced by $\Delta k=2\pi /L$. Ignoring spin, the density of states per unit $k$ is consequentlyBoth positive and negative $k$ are included in this density. It is not yet the density per unit magnitude $|k|$, which has an extra factor of two away from zero. In $d$ independent dimensions the same periodic boundary conditions give one spatial state per $k$-space cell of measure $(2\pi /L{)}^d$.

For a plane wave propagating along $\hat{\mathbf{k}}$ in vacuum, Maxwell equations give $\mathbf{B}=\hat{\mathbf{k}}\times \mathbf{E}/c$, with $\mathbf{E}\perp \hat{\mathbf{k}}$. HenceTaking $E=E_0\cos (\mathbf{k}\cdot \mathbf{r}-\omega t)$, the period average of the squared cosine is $1/2$. ThusThe fields are in phase, so the travelling-wave energy flux never reverses. The peak amplitude convention is essential; using a root-mean-square electric field would remove the factor $1/2$.

In charge- and current-free vacuum, Maxwell equations reduce toTaking a curl and using $\nabla \times \nabla \times \mathbf{E}=\nabla (\nabla \cdot \mathbf{E})-{\nabla }^2\mathbf{E}$ givesand the same wave equation for $\mathbf{B}$. For a plane wave $\mathbf{E}=\mathrm{Re}[{\mathbf{E}}_0{e}^{i(\mathbf{k}\cdot \mathbf{r}-\omega t)}]$, $\omega =ck$, $\mathbf{k}\cdot {\mathbf{E}}_0=\mathbf{k}\cdot {\mathbf{B}}_0=0$ and ${\mathbf{B}}_0=\hat{\mathbf{k}}\times {\mathbf{E}}_0/c$. Thus the fields are transverse, mutually perpendicular and in phase; polarization describes the electric-field trajectory at a fixed point.

The energy density and Poynting vector areFor a linearly polarized sinusoid with peak electric amplitude $E_0$, the mean intensity is ${ϵ}_{0}c{E}_0^2/2$. Electromagnetic momentum density is $\mathbf{S}/c^2$; normal absorption produces radiation pressure $⟨S⟩/c$, while ideal retroreflection doubles it. Linear superposition permits interference and standing waves, whose local electric and magnetic fields need not have the traveling-plane-wave equality point by point.

In microscopic SI form, Maxwell's equations couple charge density $\rho$ and current density $\mathbf{J}$ to electric and magnetic fields:Gauss's electric law expresses electric flux from charge and reduces to the inverse-square Coulomb field for a point charge. Gauss's magnetic law gives zero net magnetic flux through every closed surface; magnetic field lines do not begin or end on magnetic monopoles in this theory.

Faraday's induction law says changing magnetic flux produces a circulating electric field. For a fixed loop, its circulation is minus the rate of change of enclosed magnetic flux, explaining the sign of induction and Lenz's law. For example, changing a primary coil's electric current changes the flux through a stationary secondary coil and induces a voltage. A moving wire also has the magnetic part of the Lorentz force on its charges; the fixed-loop field equation and the full motional-emf calculation must be distinguished.

The Ampère-Maxwell law relates magnetic circulation to conduction current and displacement current. The latter is essential around a charging capacitor: a surface cutting the lead and another passing through the gap must predict the same circulation. Taking the divergence givesusing Gauss's electric law. Charge conservation therefore fixes the consistency of the time-dependent equations. In matter, the equivalent macroscopic equations use $\mathbf{D}$ and $\mathbf{H}$, free sources and constitutive relations. The Lorentz force density $\rho \mathbf{E}+\mathbf{J}\times \mathbf{B}$ describes exchange of momentum with charges.

In source-free vacuum, take the curl of Faraday's law and use $\nabla \times (\nabla \times \mathbf{E})=\nabla (\nabla \cdot \mathbf{E})-{\nabla }^2\mathbf{E}$. Both fields satisfyFor a plane wave, $\omega =ck$, $\mathbf{k}\cdot \mathbf{E}=\mathbf{k}\cdot \mathbf{B}=0$ and $\mathbf{B}=\hat{\mathbf{k}}\times \mathbf{E}/c$. The fields are transverse, mutually perpendicular and in phase. Their energy density and energy flux areThis is Poynting's theorem: field energy is transported and can do work on matter. Electromagnetic radiation is a propagating, energy-carrying solution of the coupled electric and magnetic field equations.

A small displacement $\mathbf{u}$ in a homogeneous isotropic elastic solid obeys linear elasticity. With Lamé constants $\lambda ,\mu$ and mass density $\rho$, momentum balance givesA longitudinal plane wave has displacement parallel to its propagation direction and changes local volume. A transverse wave has perpendicular displacement and produces shear. Substitution givesAn ideal fluid has no static shear modulus and cannot support this bulk transverse elastic wave. A thin rod with free lateral surfaces instead supports an extensional long-wavelength mode with speed $\sqrt{E/\rho }$; its transverse contraction changes the effective stiffness, so it should not be identified with the unbounded-solid longitudinal mode.

Stress and displacement boundary conditions produce reflection, transmission, mode conversion and guided waves. Viscoelasticity and scattering can attenuate waves; finite geometry can make guided modes dispersive even when the bulk elastic constants are frequency independent. Wave speed depends on both material stiffness and the allowed deformation.

For a homogeneous isotropic solid with small displacement $\mathbf{u}$, linear elasticity gives ${\sigma }_{ij}={\lambda }_L(\nabla \cdot \mathbf{u}){\delta }_{ij}+2\mu e_{ij}$. Momentum balance becomesA plane wave with displacement parallel to its wavevector is longitudinal, whereas perpendicular displacement is transverse. Writing $K={\lambda }_L+2\mu /3$ for the bulk modulus and $\mu$ for the shear modulus, their bulk speeds areThere are two independent transverse polarizations. The bulk modulus supplies resistance to compression; shear rigidity supplies transverse restoring stress. An ordinary fluid has no static shear rigidity and cannot sustain these propagating bulk shear waves. A thin rod with freely contracting sides instead has longitudinal speed $\sqrt{Y/\rho }$, because its lateral boundary conditions differ from a bulk plane wave. Reflection, refraction and mode conversion occur at interfaces; a free surface also supports Rayleigh waves.

In a linear, nondispersive, lossless medium, the field energy density and energy flux areThe Poynting theorem follows by dotting the two curl Maxwell equations with the other field and subtracting:The right-hand side is power transferred from the field to free charges. In vacuum the energy density is ${ϵ}_0{E}^2/2+B^2/(2{\mu }_0)$.

Static electric or magnetic fields store energy even though their time derivatives vanish. Static Poynting flow occurs because static crossed fields can also have a nonzero Poynting flux: for example, a steady current-carrying coaxial line has radial electric and azimuthal magnetic fields, carrying energy along the line toward the load. Time independence therefore does not imply zero energy flow.

For phasors whose real parts represent the physical fields,For a travelling plane wave in vacuum the electric and magnetic contributions are equal and $⟨S⟩=c⟨u_{\mathrm{em}}⟩$. In dispersive matter the simple macroscopic energy formula needs modification to include the material response; it is not a universal formula for plasma energy.^[ref]

Displacement current makes Ampère's law compatible with charge conservation. The macroscopic Maxwell equations areTaking the divergence of the last equation and using Gauss's law gives $\nabla \cdot {\mathbf{J}}_f+{\partial }_t{\rho }_f=0$. Omitting ${\partial }_t\mathbf{D}$ would wrongly require the conduction current to be divergence free during charging. The displacement-current density ${\partial }_t\mathbf{D}$ has current-density units, but need not represent free charges crossing a region.

The surface independence of Ampère circulation during capacitor charging illustrates the need directly. A surface spanning the circuit can cut the wire or pass between the plates. For ideal parallel plates, $Q={ϵ}_{0}AE$ andThe corrected circulation of $\mathbf{H}$ is independent of that surface choice. Free conduction current stops at a plate; displacement current supplies the gap contribution.

In vacuum the two time-dependent curl equations support waves. Taking a curl of Faraday's law in a source-free region yieldsThe corresponding magnetic equation is identical. For a plane wave, $\mathbf{k}\cdot \mathbf{E}=\mathbf{k}\cdot \mathbf{B}=0$ and $\mathbf{B}=\mathbf{k}\times \mathbf{E}/\omega$. The fields carry energy through the Poynting flux. Dropping displacement current everywhere would remove these freely propagating solutions.^[ref]

In a metal, conduction and displacement compete. For a uniform ohmic material with ${\mathbf{J}}_f=\sigma \mathbf{E}$, constant $ϵ,\mu$, and transverse waves,Use $e^{i\mathbf{k}\cdot \mathbf{r}-i\omega t}$. The dispersion relation and conduction-to-displacement current ratio areWhen $\sigma \gg \omega ϵ$, $k\simeq (1+i)/\delta$ with $\delta =\sqrt{2/(\mu \sigma \omega )}$: fields are screened within a skin depth and energy is dissipated by Joule heating. This quasistatic limit neglects displacement current locally compared with conduction; it does not invalidate the full Maxwell law. At sufficiently high frequency, conductivity and permittivity are frequency dependent, so a constant-$\sigma$ approximation must be replaced by a material model.

In an unmagnetized cold plasma, electron inertia gives a cutoff. With immobile ions and negligible collisions, $m_e\dot{\mathbf{v}}=-e\mathbf{E}$ and $\mathbf{J}=-n_{e}e\mathbf{v}$ give $\sigma (\omega )=i{n}_e{e}^2/(m_e\omega )$. For the transverse wave cutoff in a cold unmagnetized plasma, combining this carrier current with vacuum displacement current givesTransverse waves propagate above ${\omega }_p$ and are evanescent below it. The group velocity is $c\sqrt{1-{\omega }_p^2/{\omega }^2}<c$ even though the phase velocity exceeds $c$. The cold model also has longitudinal charge-density oscillations at ${\omega }_p$, distinct from transverse light waves. Collisions add damping, and pressure or magnetic fields modify these simple dispersions. To avoid carrier-current double counting in effective permittivity, once the carrier response is included in ${ϵ}_{\mathrm{eff}}$ it must not be counted a second time as a separate conductivity. Displacement current therefore connects circuit continuity, vacuum radiation, conductor screening and plasma propagation within one consistent field theory.^[ref]

Use peak phasors with time dependence $e^{-i\omega t}$, real positive electrical conductivity $\sigma$, and absolute permeability ${\mu }_a=\mu {\mu }_0$. Ampère-Maxwell equation and Faraday equations giveso ${ϵ}^{\prime }=ϵ+i\sigma /(\omega {ϵ}_0)$. The sign of the imaginary term follows from the stated time convention. For a transverse plane wave in a homogeneous conductor,In the good-conductor limit, choose the root that decays into $z>0$:The electric phasor and physical field are consequently ${\tilde{E}}_x=E_0{e}^{(i-1)z/\delta }$ and $E_x=\mathrm{Re}[E_0{e}^{i(z/\delta -\omega t)-z/\delta }]$, as required. Tangential boundary matching sets $E_0$; it need not equal the incident amplitude.

Faraday's law fixes the magnetic field, including its phase:For real $E_0$ and $\psi =z/\delta -\omega t$, this means $H_y=E_0{e}^{-z/\delta }(\cos \psi -\sin \psi )/(\omega {\mu }_a\delta )$, with other components zero. The time-averaged Poynting vector isThe energy entering a thin slab exceeds that leaving it by $-d⟨N_z⟩/dz$ per unit volume, givingDirectly, $\mathbf{J}=\sigma \mathbf{E}$ and $\mathbf{J}\cdot \mathbf{E}=J^2/\sigma$ at each time. Therefore $⟨J^2/\sigma ⟩=\sigma |{\tilde{E}}_x{|}^2/2$ is exactly this loss. The factors one half use peak rather than root mean square phasors; amplitude decays over $\delta$, while intensity decays over $\delta /2$.

For a cold collisionless unmagnetized plasma, electron inertia gives $\tilde{\sigma }=i{ϵ}_0{\omega }_p^2/\omega$ and real ${ϵ}^{\prime }=1-{\omega }_p^2/{\omega }^2$. Above the plasma frequency the wave propagates without this resistive attenuation. Below it, a semi-infinite plasma supports an evanescent field with electric and magnetic components in quadrature and zero mean inward energy flux: the incident energy is reflected, not absorbed as Joule heating. electron kinetic energy is reversibly stored, so the nondispersive dielectric field-energy formula alone is incomplete. Collisions introduce a real dissipative electrical conductivity and can produce absorption.^[ref]

The Poynting vector is the electromagnetic energy flux density,In vacuum it equals $\mathbf{E}\times \mathbf{B}/{\mu }_0$. For a linear nondispersive medium with time-independent constitutive coefficients, Maxwell's equations and the identity $\nabla \cdot (\mathbf{E}\times \mathbf{H})=\mathbf{H}\cdot \nabla \times \mathbf{E}-\mathbf{E}\cdot \nabla \times \mathbf{H}$ give Poynting's theorem,The source term is work done by the fields on free charges; for an Ohmic conductor it is the positive local Joule heating rate $\sigma E^2$. Integrating over a volume states that loss of stored field energy plus outward energy flow equals energy transferred to matter. In dispersive media, such as a plasma, material motion contributes to stored energy and the simple nondispersive expression cannot be used indiscriminately.

For a vacuum plane wave, $B=E/c$ and $\mathbf{E}$, $\mathbf{H}$ and the propagation direction form a right-handed triad. With real peak field $E_0$, the time-averaged wave intensity isMore generally, complex peak amplitudes give $⟨\mathbf{S}⟩=\frac{1}{2}\mathrm{Re}({\mathbf{E}}_0\times {\mathbf{H}}_0^{\ast })$. Along a transmission line, the cross-section integral of the longitudinal Poynting vector is the transmitted electrical power $VI$. Energy flows through the electromagnetic fields in the surrounding dielectric, even though the conductors guide the currents.

In a homogeneous linear medium, write $\mathbf{D}=ϵ\mathbf{E}$ and $\mathbf{B}=\mu \mathbf{H}$. Without free charge or current, Maxwell's equations becomeTaking the curl of Faraday's law, using $\nabla \times (\nabla \times \mathbf{E})=\nabla (\nabla \cdot \mathbf{E})-{\nabla }^2\mathbf{E}$, givesTheir plane-wave solutions have ${\omega }^2=k^2/(\mu ϵ)$ and speed $v=1/\sqrt{\mu ϵ}$; in vacuum this is $c=1/\sqrt{{\mu }_0{ϵ}_0}$. For a wave $\mathrm{Re}[{\mathbf{E}}_0{e}^{i(\mathbf{k}\cdot \mathbf{r}-\omega t)}]$, the divergence equations give $\mathbf{k}\cdot {\mathbf{E}}_0=\mathbf{k}\cdot {\mathbf{B}}_0=0$, while Faraday's law gives ${\mathbf{B}}_0=\mathbf{k}\times {\mathbf{E}}_0/\omega$. Thus the fields and propagation direction form an orthogonal triad, with $B_0=E_0/v$.

The two independent transverse electric components allow linear, circular and elliptical polarization of an electromagnetic wave. Their relative amplitudes and phase determine the polarization state. In a lossless nondispersive medium the energy density and energy flux areA travelling plane wave has equal electric and magnetic energy contributions and time-averaged intensity $⟨S⟩=E_0^2/(2Z)$, where $Z=\sqrt{\mu /ϵ}$ is its wave impedance and $E_0$ denotes peak electric-field amplitude. Reflection and refraction follow by imposing the electromagnetic boundary conditions. Frequency-dependent constitutive response introduces dispersion; conductivity introduces attenuation, so the simple real constant-speed result has a specified domain of validity.

Direct differentiation gives ${\psi }^{\prime \prime }/\psi =x^2/a^4-1/a^2$. Inserting this into the Schrödinger equation and separately matching the $x^2$ and constant terms yieldsFor $V_0=m{\omega }_0^2/2$, $a^2=\hslash /(m{\omega }_0)$ and $E=\hslash {\omega }_0/2$. The normalizable Gaussian has no nodes, as expected for the nondegenerate one-dimensional ground state of this confining potential.

The normalization integral is $|C{|}^{2}a\sqrt{\pi }=1$. Choose its irrelevant global phase so thatFor the oscillator ground-state density in a comparison wavelength, choose a free comparison particle with the same total energy. It has $p=\sqrt{2mE}=\hslash /a$, hence comparison wavelength $\lambda =h/p=2\pi a$. ConsequentlyThe bound density is localized on scale $a=\lambda /(2\pi )$, with standard deviation $\lambda /(2\pi \sqrt{2})$, rather than being spatially uniform like the density of a single free plane wave. The comparison does not assign constant free-particle momentum to the bound state; its total energy also includes potential energy.

In vacuum the electric and magnetic field energy densities areFor example, charging a capacitor requires $U={\int }_0^Q(q/C)dq=Q^2/(2C)=C{V}^2/2$. A parallel-plate capacitor with $C={ϵ}_{0}A/d$ and $E=V/d$ then gives $U={ϵ}_0{E}^{2}Ad/2$, identifying the electric field energy density. Similarly an inductor stores $L{I}^2/2$; applying this to a long solenoid yields $B^2/(2{\mu }_0)$ times its interior volume.

Electromagnetic energy is transported by the Poynting vector $\mathbf{S}=\mathbf{E}\times \mathbf{B}/{\mu }_0$. Poynting's theorem,expresses local energy conservation and transfer to matter. In a vacuum plane wave $E=cB$, so the two energy densities are equal and the energy flux has magnitude $c(u_E+u_B)$. For nondispersive linear media the corresponding reversible expressions are $\mathbf{E}\cdot \mathbf{D}/2$ and $\mathbf{B}\cdot \mathbf{H}/2$; they must not be applied unchanged to arbitrary dispersive or hysteretic materials.

Use a stationary wavefunction $\Psi (x,t)=\psi (x)e^{-iEt/\hslash }$ solving the time-independent Schrödinger equation. For energy above the positive step potential, the positive wavenumbers areIncidence only from the left permits a right-moving incident plane wave and a left-moving reflected plane wave for $x\le 0$, but only a right-moving transmitted plane wave for $x>0$:The omitted right-incident component would describe a different scattering experiment. Wavefunction matching at a finite potential step requires continuity of both $\psi$ and $d\psi /dx$ for a finite jump and the same mass on either side:Eliminate $B=C-A$ from the second condition:The first ratio is a transmission amplitude; a transmitted probability current also depends on its different propagation velocity.