The laws of black-hole mechanics establish the classical analogy with thermodynamics. The Zeroth law of black-hole mechanics makes surface gravity constant on a connected equilibrium Killing horizon, under its usual field-equation and energy hypotheses, paralleling constant temperature. For neighboring stationary Einstein–Maxwell solutions, the First law of black-hole mechanics is
This parallels plus work terms; denotes energy in units. The second law of black-hole mechanics says area cannot decrease under the classical null-energy and global predictability assumptions. The third law of black-hole mechanics is unattainability: regular finite physical processes satisfying its hypotheses cannot drive to zero. It parallels unattainability of absolute zero, not a universal assertion of zero extremal entropy.
Classically a hole absorbs without emitting, so the analogy alone does not identify a measured temperature. Quantum Hawking radiation supplies , with and future-horizon normalization at infinity. Comparing the area terms in the first laws gives the Bekenstein-Hawking entropy
up to a conventionally fixed additive constant. In ordinary units it is . Entropy scales with area, not interior volume.
For the massless scalar in quantum field theory in curved spacetime, global hyperbolicity ensures well-posed Cauchy evolution. The conserved Klein-Gordon inner product is
Its current has zero divergence by the wave equation, making it slice-independent with appropriate boundary behavior. Positive frequency relative to the asymptotic past and future Minkowski times defines complete bases , with , and vanishing mixed products. Expand the field as
Continuous labels replace sums by integrals; wave packets avoid artificial normalization infinities. Particle creation by a nonstationary spacetime occurs when evolution mixes frequency signs through a Bogoliubov transformation:
The inner product gives and . For the initial vacuum annihilated by all , . Thus nonzero negative-frequency mixing makes the in-vacuum non-vacuum for final observers. The vacuum state in a stationary spacetime depends on its positive-frequency splitting; this is not inconsistent with deterministic mode evolution. A unitary implementation on one fixed infinite-mode Fock space further needs the Hilbert–Schmidt condition on .
For collapse forming a Schwarzschild black hole, a late outgoing ray traced back to past null infinity obeys the Hawking exponential ray map
Pulling back gives for . Its past Fourier transform has both frequency signs. For and damping , the Gamma function evaluates the Fourier integrals as
As , the two denominator arguments approach , so . Thus the thermal ratio of Hawking Bogoliubov coefficients is . Together with the bosonic normalization difference, this yields . Potential scattering adds a greybody factor:
The collapse state has outgoing flux at future infinity without an incoming thermal bath and is regular for infall. It is not the eternal-hole equilibrium state. Horizon-entering modes complete the future basis; tracing over their correlated partners gives the approximately thermal exterior state. The collapsing geometry is not literally Minkowskian everywhere in the far future: asymptotically flat null-infinity modes are the relevant application of the earlier in/out construction.
Emission reduces the isolated hole's mass. Schwarzschild temperature is proportional to , giving the negative heat capacity of a Schwarzschild black hole: losing energy makes it hotter. Dimensional estimates give luminosity proportional to and evaporation time proportional to , with species and greybody factors determining coefficients. Area may shrink because quantum stress violates the energy assumptions of Hawking's area theorem. The generalized second law instead concerns , incorporating radiation entropy and preventing ordinary thermodynamic violations by disposal of entropy into a hole.
Pair correlations also distinguish thermal reduced states from the complete pure state. The black hole information paradox asks whether complete evaporation preserves quantum information: an exactly thermal final exterior with no remaining partners would appear inconsistent with unitary pure-state evolution. The semiclassical calculation controls late-time flux, not the Planck-scale endpoint, and does not itself settle this question. Quantum emission gives the temperature–entropy identification physical meaning; generalized entropy replaces the classical area alone when radiation back-reacts.
The laws of black-hole mechanics initially relate geometric quantities in a way resembling thermodynamics. Hawking radiation supplies a physical temperature: in units , while displaying ,
The Hawking temperature is measured with the stationary time normalized at infinity. The radiation's thermal occupation factor is physically observable; propagation to infinity also introduces greybody factors, so the distant spectrum need not be a perfect blackbody spectrum at every frequency.
The Zeroth law of black-hole mechanics says that surface gravity is constant on a stationary Killing horizon under its standard hypotheses. Through the Hawking temperature, this becomes uniform equilibrium temperature. The First law of black-hole mechanics is
Using identifies its area term as . Integrating gives the Bekenstein-Hawking entropy, up to an additive constant. Thus is the energy, the angular and charge terms are work terms, and the geometrical law is the ordinary thermodynamic first law with a fixed entropy normalization.
The second law of black-hole mechanics, or Hawking's area theorem, gives nondecreasing area in the classical setting with the requisite energy and predictability assumptions. It corresponds to increasing Bekenstein-Hawking entropy. Semiclassical black-hole evaporation can decrease the area: the classical null energy condition need not hold for the quantum expectation of the stress-energy tensor. The appropriate extension is the generalized second law, that does not decrease, with the exterior entropy and its renormalization treated consistently. Hawking's temperature identification motivates this law; thermality alone does not prove every form of it.
The third law of black-hole mechanics is the unattainability, by an admissible finite physical process, of zero surface gravity. With Hawking temperature it becomes unattainability of absolute zero. It is not the assertion that an extremal black hole has vanishing entropy: its area can remain nonzero when .
For a Schwarzschild black hole, and , giving and . Their product satisfies , explicitly checking the first law. Quantum radiation turns the temperature and entropy in the mechanical analogy into physical thermodynamic quantities.
Classically, the laws of black-hole mechanics have the same form as the laws of thermodynamics, but this could have been only a formal analogy. Hawking radiation makes it physical: a stationary black hole emits approximately thermal radiation with
so surface gravity is proportional to genuine temperature.
The correspondence is:
matches the first law of thermodynamics and fixes the Bekenstein-Hawking entropy
A real Hawking temperature therefore identifies horizon area as thermodynamic entropy and turns the geometric laws into thermodynamic laws.
For discrete states of energy , the canonical partition function is
For a classical continuous system the sum is replaced by the appropriately normalized phase-space integral, including the Gibbs factor for identical particles.
It packages the equilibrium probabilities and hence all canonical thermodynamics. In particular,
and .