Photoprotection Created 2026-10-20 Updated 2026-11-05
Processes limiting light-induced damage when absorbed excitation exceeds safe photochemical use. Energy dissipation, regulated electron flow and repair have complementary roles.
Photosynthesis Created 2026-10-06 Updated 2026-10-20
Photosynthesis captures light energy and transforms it into chemical forms that a biological cell can use. In plants, algae and cyanobacteria, this supports carbon fixation: incorporation of carbon from carbon dioxide into chemical compounds used to build living material. Capturing light and incorporating carbon are distinct processes coupled through metabolism. See OpenStax Biology 2e, 8.1: overview of photosynthesis.
For oxygenic photosynthesis, a simplified net equation writes a six-carbon sugar, glucose, as the representative product:
This is net stoichiometry, not a one-step mechanism. A worked bookkeeping check counts six carbon chemical atoms, twelve hydrogen chemical atoms, and eighteen oxygen chemical atoms on each side: the product side has six oxygen chemical atoms in the sugar and twelve in molecular oxygen. The light label supplies energy, not additional chemical atoms.
Crucially, the released molecular oxygen comes from water, not carbon dioxide. Cancelling water made and consumed in different steps hides this distinction in the net equation. The Calvin cycle supplies a net three-carbon triose phosphate, such as glyceraldehyde 3-phosphate, for subsequent sugar synthesis; it does not directly export glucose. See OpenStax Biology 2e, 8.2: light-dependent reactions and OpenStax Biology 2e, 8.3: using light energy to make organic molecules.
Figure 1. . Original schematic of oxygenic photosynthesis. Solid blue arrows trace selected material transfers; dashed orange arrows show energy transfer and the coupling through ATP and NADPH. These carriers are also molecules, not pure energy. Arrows omit intermediate chemical reactions and do not specify rates or yields. Details.
The useful achievement is connecting incoming light to both usable energy and new biological material. ATP is an immediate energy currency; NADPH supplies electrons for synthesis; carbon dioxide supplies the carbon incorporated into carbohydrates. These roles are complementary. Conservation of energy still holds: photosynthesis transforms energy, never creates it, and some absorbed energy is dissipated as heat. A plant also carries out cellular respiration, including in biological cells that perform photosynthesis. Gas exchange reflects both processes. Oxygenic photosynthesis remains central to interpreting terrestrial molecular oxygen as an atmospheric biosignature gas. See OpenStax Biology 2e, 8.3: photosynthesis and respiration.
Photosynthetic control Created 2026-10-20 Updated 2026-11-05
Photosynthetic control refers to regulation of electron flow, especially lumen-pH-dependent restriction at the cytochrome b6f complex. Slowing electron delivery can protect downstream acceptors from excessive reduction.
Photosystem Created 2026-10-20 Updated 2026-11-05
An organized light-harvesting and reaction-center assembly supporting photosynthetic energy conversion.
An antenna transfers excitation to a reaction centre, where charge separation initiates electron transfer. This distinguishes capture of a photon from conservation of its energy in a redox reaction. In oxygenic photosynthesis, two photosystems act in a connected electron-transfer chain. [ref]
Photosystem I Created 2026-10-20 Updated 2026-11-05
Photosystem I is a light-driven reaction-centre complex in oxygenic photosynthesis. Excitation supports electron transfer to acceptors including ferredoxin; the balance between linear and cyclic routes affects reductant and ATP supply.
Photovoltaic effect Created 2026-10-18 Updated 2026-10-20
The photovoltaic effect is the production of an electric potential difference or an electric current by photon absorption in a material or device. In a semiconductor, absorbed photons generate electrons and electron holes; asymmetric transport and selective collection can maintain distinct quasi-Fermi levels and deliver electrical power to a load. An equilibrium built-in potential alone supplies no continuous electrical power.
Pi electron 2026-10-20
An electron occupying a pi-type molecular orbital. In a conjugated planar molecule, the pi subspace is commonly built from p orbitals perpendicular to the molecular plane; its electron population excludes the sigma framework.
Pierre Hohenberg Created 2026-10-20 Updated 2026-11-05
A theoretical condensed matter physicist who, with Walter Kohn, established a foundation of density functional theory in 1964. Their variational principle expresses the ground-state energy of interacting electrons through the electron density, making a three-dimensional quantity central to a many-particle problem.[ref]
His 1967 work also ruled out the relevant finite-temperature long-range order in one- and two-dimensional bosonic and fermionic systems under the theorem's assumptions. This helps explain why dimensionality matters when discussing Bose-Einstein condensation.[ref]
Piers Coleman Created 2026-10-20 Updated 2026-11-05
Piers Coleman studies strongly interacting electrons, particularly heavy fermions and the Kondo lattice. In these materials, coupling between mobile electrons and local magnetic moments can produce coherent low-energy quasiparticles with a very large effective mass. His theoretical exposition connects the screening of one magnetic moment in the Kondo effect with collective behavior in a lattice of such moments. The competition with magnetic interactions helps organize questions about magnetism, superconductivity and the breakdown of the heavy-electron state.[ref]
Figure 1.
Portrait of Piers Coleman
. Pierscoleman, 3 December 2018. CC BY-SA 4.0, via Wikimedia Commons. Source.
Plasma (physics) Created 2026-10-13 Updated 2026-10-20
A plasma is a gas of mobile charged particles whose collective electromagnetic response is important to its dynamics. It commonly contains ions and electrons, and may also contain a neutral component: complete ionization is not required. A multi-species fluid description has current density . The relative motion of the species can matter even when a single-fluid magnetohydrodynamics approximation describes the large-scale dynamics.
Plasma wave 2026-11-05
A plasma wave is a collective disturbance of charged particles and electromagnetic fields in a plasma. Restoring forces can involve charge separation, magnetic tension or pressure, producing different branches rather than one universal wave speed.
For a cold unmagnetized electron fluid with effectively stationary neutralizing ions, electrostatic density oscillations have electron plasma frequency . Displacing electrons creates an electric field that pulls them back; inertia produces oscillation. Measuring that frequency therefore constrains electron density. Thermal motion, magnetic fields and collisions modify the dispersion and damping, and must be included when the cold-fluid assumptions fail.
Platinum resistance thermometer Created 2026-10-14 Updated 2026-10-20
A resistance thermometer using platinum as its sensing material. It provides the temperature readout in the saturation-pressure equilibrium measurement.
Transduction turns electrical resistance into a temperature indication. A uniform wire has , with electrical resistivity , length , and cross-sectional area . Stronger atomic vibrations at higher temperature scatter electrons more, increasing platinum's electrical resistivity; impurities and crystallographic defects also contribute.[ref]
A small known electric current and measured electric potential difference give through Ohm's law; a resistance bridge can instead compare the element with a reference resistor. Inverting the calibrated response then gives the sensing element's temperature. This makes electrical readout convenient, but the platinum resistance thermometer lead resistance error, resistance thermometer self-heating, and resistance thermometer immersion test explain why a stable display alone is insufficient. The gas thermometer supplies a contrasting route through an equation of state; the saturation-pressure equilibrium measurement shows why a trustworthy independent temperature readout matters.
P-n junction Created 2026-10-18 Updated 2026-10-20
A p-n junction joins regions of a semiconductor with opposite majority charge carriers: electrons on one side and electron holes on the other. It provides the junction modeled by the Shockley diode equation.
Near an unbiased p-n junction, diffusion leaves exposed ionized donor impurities and acceptor impurities. Their electric field opposes further majority-carrier transfer. At thermal equilibrium, drift and diffusion balance; there is no net electric current. Forward bias reduces the barrier to carrier injection; reverse bias enlarges it. A heavily doped tunnel diode adds a different transport route, quantum tunnelling, that the ordinary Shockley diode equation omits.
Polar covalent bond Created 2026-10-13 Updated 2026-10-20
The word “polar” qualifies the sharing within a covalent bond; it does not require complete transfer of an electron or an isolated cation–anion pair. In , the signs identify the relatively electron-poor and electron-rich ends, while leaves the amount unspecified. A neutral Lewis structure can give both chemical atoms zero formal charge and still correspond to a polar covalent bond: equal division of the bond pair is a formal allocation, whereas bond polarization concerns the actual electron density.
Local and molecular descriptions answer different questions. Calling one chemical bond a polar covalent bond does not establish that the whole molecule is a polar molecule. Combine the bond dipoles with the molecular geometry, then check for molecular dipole cancellation. This lets a short electronegativity comparison explain a local tendency without confusing it with the observable electric dipole moment of the whole molecule.
Polarized beta-decay angular distribution Created 2026-10-18 Updated 2026-10-20
Consider a parent atomic nucleus at rest. Write its signed nuclear polarization along a fixed axis as , where is its maximal spin component. Let be the angle of the emitted electron momentum to that axis and let . Use for the parity operator, so it is not confused with .
For an axially symmetric leading-dipole model, retain a constant and the term linear in the polarization vector . Rotational symmetry makes the directional term proportional to . Define its dimensionless coefficient as . At fixed electron energy the relative intensity and normalized probability density function per solid angle are therefore
The factor is the conventional separation of the speed dependence; rotational symmetry alone does not determine that dependence or . The coefficient contains the decay dynamics. This leading model omits higher angular terms and detailed recoil and radiative effects. A partially oriented higher-spin ensemble can also have alignment that is not specified by its vector nuclear polarization alone.
The unit-integral condition follows without any model of a detector:
Thus has unit angular average, while the probability density function in the polar angle alone contains the Jacobian determinant factor:
In particular, itself is neither a normalized probability density function in nor a detector count. Positivity on gives .
Under full spatial reflection, but . The latter follows already for orbital angular momentum from ; spin has the same axial vector transformation. Hence is a pseudoscalar, and . If parity conservation held for this model, equal probabilities for the inverted process would force . Conversely, in an unpolarized sample proves nothing about .
Integrating over the two hemispheres gives a useful original check:
Choose , , and , so . Then the forward and backward hemisphere probabilities are and , and their counting asymmetry is . These are chosen teaching values, not measured values from the Wu experiment. At a single energy, the angular shape determines the product ; it cannot separately determine without a polarization calibration.
Figure 1.
Chosen angular probabilities and detector-efficiency cancellation
. Original model with . The angular probability is distinct from a detector count; opposite hemispheres average the cosine to . Unequal efficiencies and exposures distort individual detector ratios, while a reversal cross-ratio recovers the chosen hemispheric asymmetry. All counts are constructed. Details.
Polarized muon decay Created 2026-10-14 Updated 2026-11-05
For a negative muon with rest-frame spin vector , the leading massless-electron distribution is , where . Its final-spin sum is . The spin vector is axial whereas the electron direction is polar, so their scalar product reverses under parity. Its occurrence demonstrates parity violation by the left-chiral weak charged current.
Polykarp Kusch Created 2026-10-18 Updated 2026-11-05
Polykarp Kusch and Henry Michael Foley measured atomic magnetic resonance frequencies to determine the electron magnetic moment. Different quantum states weight orbital angular momentum and spin contributions differently, allowing ratios of magnetic responses to isolate the spin contribution. The inferred electron spin g-factor differs slightly from two. The Kusch-Foley magnetic moment experiment thus probes a microscopic interaction through accurately counted frequencies, rather than a mechanical measurement of an isolated electron.[ref]
Polymerization-active site Created 2026-10-14 Updated 2026-10-20
A polymerization-active site is the reactive location that enables the next chain-growth propagation step. In the schematic
is one free monomer molecule, is the chain's degree of polymerization in incorporated monomeric units, and the star marks the polymerization-active site. The site's reactive character survives the growth step, although the chemical atoms carrying it can change. The star is not an extra unit, a literal particle, or necessarily a positive or negative electric charge. Actual reaction mechanisms can involve an unpaired electron, a cation, an anion, or a metal-associated site; the abstract notation does not identify which. [ref]
For bookkeeping below, each linear active chain has exactly one polymerization-active site. This is a stipulated model, not a property of every chain polymerization: a chain can have several reactive sites, and a reversibly inactive chain can remain capable of future growth. Count currently active sites separately from all chains capable of later reactivation.
Positron Created 2026-10-05 Updated 2026-11-05
The Positron is the antiparticle of the electron, with equal rest mass and spin but electric charge . It can be created in beta-plus decay or in a sufficiently energetic pair production process.
An electron and Positron can undergo electron-positron annihilation. For the two-photon channel from a pair initially at rest, conservation of momentum requires opposite photon directions and each photon has energy , neglecting binding. Initial motion or a different allowed final state changes that simple picture. Annihilation is conversion of the initial particles' energy into other excitations, not disappearance of conserved energy or charge.
Positronium 2026-10-20
Positronium is the electromagnetic bound state of an electron and a Positron. Their equal masses give reduced mass , half the hydrogenic Rydberg binding scale and approximately twice the electron-proton separation of hydrogen. Its spin singlet and triplet differ in hyperfine energy; annihilation also affects their physical lifetimes and splitting.