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A bond-dissociation enthalpy is the molar enthalpy change for the specified homolysis at temperature $T$, with reactant and products in specified standard states. Its usual units are $\mathrm{kJ}\mathrm{mo}{\mathrm{l}}^{-1}$. The superscript $\circ$ specifies standard states; it does not fix $T$ to room temperature.^[ref]

Write $\delta h_i(T)=H_{m,i}^{\circ }(T)-H_{m,i}^{\circ }(0)$ for each species' molar thermal enthalpy increment. With $D_0$ an energy per parent molecule,Here $N_{\mathrm{A}}$ is the Avogadro constant. The thermal increments include translational kinetic energy, molecular rotation, thermally excited molecular vibration and electronic states when populated, and the $pV$ contribution to enthalpy. They are additional to the zero-point energies already included in $D_0$. If values of standard enthalpy of formation at the same $T$ are available, Hess's law gives the same quantity as ${\Delta }_f{H}^{\circ }(A)+{\Delta }_f{H}^{\circ }(B)-{\Delta }_f{H}^{\circ }(AB)$.

Units alone do not identify the convention. Multiplying either $D_e$ or $D_0$ by the Avogadro constant gives molar energy, but does not add thermal enthalpy. One electronvolt per dissociation corresponds to $96.485332\mathrm{kJ}\mathrm{mo}{\mathrm{l}}^{-1}$. A spectroscopic wavenumber $\tilde{\nu }$ represents energy $hc\tilde{\nu }$, using the Planck constant $h$ and speed of light $c$; $1\mathrm{c}{\mathrm{m}}^{-1}$ corresponds to $0.011962657\mathrm{kJ}\mathrm{mo}{\mathrm{l}}^{-1}$.^[ref]

For $c>0$, the backward causal cone at $(x_{\ast },t_{\ast })$ isIts boundaries are characteristic lines for the one-dimensional wave equation; its base on $t=0$ is the initial-data domain of dependence. The forward cone from $(s,0)$ is $t\ge 0$, $|x-s|\le ct$. Here the cone is set by the model's wave speed, which may be acoustic or a string wave speed; it does not assert propagation at the speed of light.

Classical mechanics describes the motion of bodies by assigning positions and velocities and specifying how their interactions change those quantities. A point mass is the simplest model: its size and internal structure are ignored, leaving a mass and a moving position. A rigid body retains orientation and rotational kinetic energy. Choosing a model means deciding which features affect the question being asked; a sliding block may be treated as a point mass, whereas predicting its rolling without slipping requires its moment of inertia.

Three complementary questions organize the subject. Newton's second law asks how the net force determines the instantaneous acceleration. The work-energy theorem asks how that force, acting through a displacement, changes kinetic energy. Conservation of mechanical energy asks which combinations of position and velocity are accessible when the interactions admit a time-independent potential energy and no other force supplies net power. These descriptions are compatible, but answer different questions: an energy calculation may find a maximum speed without first solving for position at every time.

The harmonic oscillator below makes this unity visible. A restoring force produces a repeating position trace; the corresponding phase plane has a closed ellipse; kinetic energy and potential energy exchange while their sum stays fixed. Lagrangian mechanics and Hamiltonian mechanics provide further ways to organize the same dynamics, especially when coordinates or constraints make individual forces awkward to track.

The scope of classical mechanics also matters. Newtonian mechanics approximates motion at speeds small compared with the speed of light; special relativity changes that description when this approximation fails. Quantum mechanics is needed for phenomena for which a classical assignment of simultaneous position and momentum is inadequate. These limitations do not prevent classical mechanics from being a useful predictive model within its regime. ^[ref]

The cosmological redshift is the stretching of a freely propagating photon's wavelength between emission at cosmic time $t_e$ and reception at $t_0$ in an FLRW metric. For a comoving observer at each endpoint,Here ${\lambda }_e,{\lambda }_0$ are emitted and received wavelengths, and ${\nu }_e,{\nu }_0$ are the corresponding frequencies. A positive cosmological redshift means that the scale factor grew while the photon travelled. The name describes a shift toward longer wavelengths; it applies to light beyond the visible range as well.

For a computed example, let the scale factor double from $a(t_e)=0.5$ to $a(t_0)=1$. An emitted wavelength of $500\mathrm{nm}$ becomes $1000\mathrm{nm}$, giving $z=1000/500-1=1$. The received frequency is half the emitted frequency. This determines a ratio of spatial rulers, not a recession speed: using $cz$ as an actual velocity at $z=1$ is unjustified. The wavelength panel in the illustration under Hubble's law shows this doubling.

A short derivation follows successive wave crests along a radial null geodesic in FLRW spacetime. Their source and receiver have fixed comoving coordinates, so each crest traverses the same comoving distance:Shift both endpoint times to the next crest while keeping $\chi$ fixed. To first order in the very short periods $\delta t_e,\delta t_0$, this gives $\delta t_0/a(t_0)=\delta t_e/a(t_e)$. Locally, wavelength equals the speed of light times the crest period, yielding the displayed cosmological redshift relation. These periods are much shorter than the timescale on which the scale factor changes.

The relation isolates the smooth expansion contribution. An observed redshift can also contain a Doppler effect from source or observer peculiar velocity and a gravitational redshift. See combined kinematic and cosmological redshift for the multiplicative combination of endpoint motion and expansion. Treating every observed redshift as pure cosmological redshift can therefore misassign a nearby source's distance.

The useful insight is that a received wavelength ratio records how much the scale factor changed during the photon's journey. Turning that ratio into a distance requires an expansion history, through the Hubble parameter, and a specified convention such as luminosity distance or proper distance in cosmology; the ratio alone supplies neither.

Let $r$ be the instantaneous bond length, $r_e>0$ its equilibrium value, and $q=r-r_e$ the stretching displacement. Assume one fixed electronic quantum state, a smooth potential energy $V(r)$ with a nondegenerate local minimum at $r_e$, and omit molecular rotation initially. The Taylor series has no linear term because $V^{\prime }(r_e)=0$:Keeping only the quadratic term is the harmonic approximation near a potential minimum. The bond force constant $k$ has units $\mathrm{N}{\mathrm{m}}^{-1}$. It measures local stiffness; it is not the bond-dissociation energy, which concerns the depth and distant shape of the entire well.

The two-particle relative coordinate explains the reduced mass. For stretching along a fixed axis in a stationary centre of mass frame, let $u_1,u_2$ be the nuclear displacements from equilibrium. Then $u_2-u_1=q$ and $m_1{u}_1+m_2{u}_2=0$, soHere $T$ is the internal kinetic energy, and $m_1,m_2>0$ are the two nuclear masses. The lighter partner moves farther; the reduced mass is smaller than either individual mass. The restoring force $-dV/dq\simeq -kq$ gives simple harmonic motion:The angular frequency is $\omega$, the ordinary frequency is $\nu$, and ${\tilde{\nu }}_{\mathrm{harm}}$ is the corresponding spectroscopic wavenumber; $c$ is the speed of light. Use $c$ in $\mathrm{cm}{\mathrm{s}}^{-1}$ to obtain ${\tilde{\nu }}_{\mathrm{harm}}$ in $\mathrm{c}{\mathrm{m}}^{-1}$. The symbol $k$ here is a bond force constant, not an angular wavenumber.

For an original dimensionless example, choose $m_1=m_2=2$ and $k=4$ in consistent model units. Then $\mu =1$ and $\omega =2$. Releasing at $q(0)=0.1$ with $\dot{q}(0)=0$ gives $q(t)=0.1\cos (2t)$ and $u_1=-q/2$, $u_2=q/2$. Each atomic nucleus moves only half the stretching amplitude, while the conserved internal mechanical energy above $V_0$ is $\frac{1}{2}k(0.1{)}^2=0.02$. Fixing one partner instead would give $\omega =\sqrt{2}$, demonstrating why a one-body calculation changes the model.

In vacuum, displacement current is the term ${\mathbf{J}}_D={ϵ}_0{\partial }_t\mathbf{E}$ in the Ampère-Maxwell equation. It has the units of current density, but need not describe electric charge crossing the region. In Maxwell equations in matter, the corresponding term is ${\partial }_t\mathbf{D}$, with $\mathbf{D}$ the electric displacement field.

Consider a slowly charging parallel-plate capacitor with vacuum gap, plate area $A$, and charge $Q(t)$ on its positive plate. Neglect fringing and assume the charging timescale is long compared with the light-travel time across the apparatus. The nearly uniform gap electric field has magnitude $E=Q/({ϵ}_{0}A)$, so the displacement current through the gap isFor $A=0.010{\mathrm{m}}^2$ and charging electric current $I=1.0\mathrm{mA}$, this gives $dE/dt\simeq 1.13\times 10^{10}\mathrm{V}{\mathrm{m}}^{-1}{\mathrm{s}}^{-1}$ and $J_D=0.10A/{\mathrm{m}}^2$. No conducting electric current crosses the gap. A spanning surface cutting the wire and another passing between the plates nevertheless give the same magnetic circulation when the full Ampère-Maxwell equation is used. ^[ref].

The local consistency check is short. Without displacement current, taking the divergence of $\nabla \times \mathbf{B}={\mu }_0\mathbf{J}$ would force $\nabla \cdot \mathbf{J}=0$, allowing no local accumulation of electric charge. With displacement current, the divergence of a curl is zero and Gauss's law giveThis is precisely the charge continuity equation. Electric charge conservation fixes the required divergence of the added term; it does not by itself exclude other divergence-free additions. The specific Maxwell equations also yield the electromagnetic wave equation, linking this consistency correction to propagation at the speed of light.

Doppler spectroscopy detects an exoplanet through the host star's changing Doppler shift. Both bodies orbit their shared astronomical barycenter: the star undergoes stellar reflex motion even when the exoplanet itself is unseen. Its velocity along the line of sight shifts its spectral lines; at speeds small compared with the speed of light, $\Delta \lambda /\lambda \simeq v_r/c$, with positive $v_r$ for recession. Repeated measurements can fit a Kepler orbit, rather than merely detect one shifted spectrum. Starspots and other changes in stellar spectral lines must be distinguished from actual orbital motion.

For one companion in an isolated two-body problem, the stellar radial-velocity semi-amplitude isHere $G$ is the gravitational constant, $P$ the orbital period, $e$ the orbital eccentricity, and $M_{\star },M_p$ the star and exoplanet masses. The orbital inclination $i$ is measured relative to the sky plane: $i=0$ is face-on and $i=90^{\circ }$ is an edge-on orbit. The exact binary mass function measured from the fitted orbit isWith known $M_{\star }$ and $M_p\ll M_{\star }$, this is usually reported as $M_p\sin i$. Taking $\sin i=1$ gives the minimum companion mass; a smaller orbital inclination allows a larger mass. A detected exoplanet transit constrains $i$ close to $90^{\circ }$ for a compact planet orbiting well outside the star's surface, substantially resolving this ambiguity. Combining Doppler spectroscopy and exoplanet transit photometry then supplies a mass and radius for exoplanet interior studies.

For a computed circular example, let $q=M_p/M_{\star }=0.001$ and choose a relative orbital speed $V_{\mathrm{rel}}=100\mathrm{km}{\mathrm{s}}^{-1}$: this is the speed of the planet relative to the star, not its speed about the astronomical barycenter. Conservation of momentum givesThe barycentric velocities point in opposite directions, so their speeds add to $V_{\mathrm{rel}}$. Here $e=0$ and $K=V_{\star }\sin i$: $K=99.9001\mathrm{m}{\mathrm{s}}^{-1}$ at $i=90^{\circ }$, $49.9500\mathrm{m}{\mathrm{s}}^{-1}$ at $i=30^{\circ }$, and zero at $i=0$. The star still orbits in the face-on case, but its orbital velocity has no line-of-sight component. The plotted circular signal is $v_r(t)-\gamma =K\sin (2\pi t/P)$ for a chosen phase origin and constant system velocity $\gamma$.

Electromagnetic radiation is a propagating disturbance of the electric field and magnetic field that carries energy and momentum away from its source. It can be a sustained electromagnetic wave or a finite wave packet: periodic oscillation is not required. In vacuum the disturbance travels at the speed of light. A receiver responds to fields arriving now from an earlier source event, as expressed by retarded time. This is how electrical activity at one place can deliver energy and information elsewhere without a connecting wire.

Stored electromagnetic energy alone does not establish outgoing electromagnetic radiation. A stationary electric charge in electrostatics, or a steady localized electric current in magnetostatics, can store electromagnetic energy with zero Poynting vector. Static combinations can have circulating energy flux without net outward power. Near a changing source, reactive energy can return later. The near and far field distinction separates these contributions from outgoing radiation zone fields.^[ref]

A single traveling vacuum plane electromagnetic wave obeying the Maxwell equations has $\mathbf{B}=\hat{\mathbf{k}}\times \mathbf{E}/c$. Its Poynting vector gives the energy density and flux of a plane electromagnetic wave:Here $I$ is wave intensity; ${ϵ}_0$ and ${\mu }_0$ are vacuum permittivity and vacuum permeability. For a monochromatic wave with linear polarization and peak amplitude $E_0$, squared cosine averages to $1/2$. Pulses require the instantaneous Poynting vector; arbitrary incident-and-reflected superpositions need not obey this relation.^[ref]

The electromagnetic momentum density is $\mathbf{g}=\mathbf{S}/c^2$. Completely absorbing a unidirectional vacuum pulse of energy $U$ transfers momentum $U/c$; see radiation pressure on a perfectly absorbing surface. A calculated $1.0\mathrm{mJ}$ pulse transfers $3.34\times 10^{-12}\mathrm{kg}m/s$. Symmetric emission can lose energy without net recoil because opposite momenta cancel.^[ref]

The direction of emission matters as much as its total power. For an oscillating electric dipole moment along $z$, the angular distribution of electric dipole radiation is strongest across the axis and vanishes along it. Its origin is geometric: the electric dipole radiation field is the transverse projection of the second time derivative of the electric dipole moment, so its magnitude contains $\sin \theta$. Squaring this electric field to obtain wave intensity gives ${\sin }^2\theta$. The electric-dipole approximation for radiation requires a source much smaller than its wavelength and observation in the radiation zone. ^[ref]

For example, the power per solid angle at $\theta =30^{\circ }$ is one quarter of its equatorial value, while the electric field amplitude is one half. To normalize the angular distribution to total power, use spherical coordinates with $d\Omega =\sin \theta d\theta d\varphi$:The integral follows by substituting $x=\cos \theta$, giving ${\int }_{-1}^1(1-x^2)dx=4/3$. This is a probability-like normalization over direction, with units of inverse steradian; it does not make the dipole an isotropic radiator. The same angular integral underlies the Larmor formula for nonrelativistic accelerated electric charge.

Detection requires the incident electromagnetic field to do something observable. An antenna develops an electrical response; a thermopile converts absorbed energy into a thermal and then electrical signal; a photodetector can respond through photon absorption. Hertz spark transmission and detection experiment makes this conversion visible as a tiny spark. Detector orientation, sensitivity, and surrounding reflections all matter: failure to see a signal does not prove that no electromagnetic radiation reached the receiver.

An electromagnetic wave is a propagating disturbance of the electric field and magnetic field obeying the Maxwell equations. In source-free vacuum its speed isthe speed of light. An electromagnetic wave can travel through vacuum: a conducting medium is unnecessary. A single traveling plane electromagnetic wave has mutually perpendicular electric field, magnetic field, and propagation direction. This statement applies to that wave; arbitrary near and far field configurations need not share these directions or the relation $|\mathbf{B}|=|\mathbf{E}|/c$.

The visualization compares perpendicular components on a common scale: $c\mathbf{B}$ has the same units as $\mathbf{E}$. The curves are field values along space, rather than paths traced by particles. Their common phase moves toward $+z$, while the Poynting vector records the associated energy flux.

The electromagnetic wave equation gives a propagation law, while the full Maxwell equations additionally enforce the field directions and relative amplitudes. This is why solving an independent scalar wave equation for each component is insufficient to construct an electromagnetic wave. ^[ref].

Let an Electron start with negligible kinetic energy and move through an increase $U>0$ in electric potential. Its electric charge is $q=-e$, where $e>0$ is the elementary charge, so the decrease in potential energy is $eU$. In a field-free region after acceleration,This is an Electron formula, not a universal conversion from voltage to wavelength. It assumes negligible initial kinetic energy, negligible losses, and $eU\ll m_e{c}^2$, where $c$ is the speed of light. It describes the de Broglie wavelength outside the crystal; the potential energy inside a material can change the local kinetic momentum.

For $U=54\mathrm{V}$, take $h=6.62607015\times 10^{-34}\mathrm{J}\mathrm{s}$, $e=1.602176634\times 10^{-19}\mathrm{C}$, and $m_e\simeq 9.1093837\times 10^{-31}\mathrm{kg}$. The rounded Electron mass is consistent with the 2022 recommended constants.^[ref]The electronvolt is an energy unit: $54\mathrm{eV}$ must be converted to joules before combining it with $m_e$ in SI units. Dimensional analysis checks both steps:The resulting velocity is about $4.3584\times 10^6\mathrm{m}{\mathrm{s}}^{-1}$, or $0.01454c$, so the nonrelativistic assumption is consistent. For a larger accelerating voltage, the relativistic energy-momentum relation gives $pc=\sqrt{K(K+2m_e{c}^2)}$, with $K=eU$, while $\lambda =h/p$ still holds. At $54\mathrm{V}$ the relativistic wavelength is shorter by about $0.00264\%$.

Electron affinity measures how strongly an isolated neutral species binds an additional Electron. In the spectroscopic convention used here, it is the positive energy required to detach that Electron from a bound anion. With the free Electron at rest assigned zero energy,The quantum states of $X$ and $X^{-}$ must be specified, usually their ground states. Positive $A_{\mathrm{ea}}$ means that attachment lowers the energy; a signed attachment energy is then negative. This convention agrees with the IUPAC definition and with the atomic tables used for Mulliken electronegativity.^[ref]

For chlorine, a published photodetachment threshold is $A_{\mathrm{ea}}/(hc)=29138.59(22)\mathrm{c}{\mathrm{m}}^{-1}$, approximately $3.612725\mathrm{eV}$ per chemical atom. Here $h$ is the Planck constant, $c$ the speed of light, and the inverse-length unit expresses an energy through a spectroscopic wavenumber. The parentheses give the reported uncertainty in the last digits, not a range of possible sign conventions.^[ref]

An electron affinity is neither an electronegativity nor a lattice energy. The first describes a specified isolated-species energy difference, electronegativity compares attraction for electron density in a chemical bond, and lattice energy refers to an entire ionic crystal and separated gaseous ions. A stable anion can therefore help explain ionic bonding without describing the full energy balance for making a salt.

The extraordinary wave's electric displacement field lies in that plane and is perpendicular to the wavevector; its electric field need not be. For angle $\theta$ between the wavevector and optic axis,Thus $n_{\mathrm{ex}}(0)=n_o$ and $n_{\mathrm{ex}}(\pi /2)=n_e$.^[ref]

A short derivation starts from the existing plane wave in an anisotropic dielectric equation. Put $\mathbf{k}=(k_x,0,k_z)$ and $k_0=\omega /c$, with angular frequency $\omega$ and vacuum speed of light $c$. The $y$ component gives the ordinary wave relation $k_x^2+k_z^2=n_o^2{k}_0^2$. The determinant of the $x,z$ system givesSubstituting $k_x=n_{\mathrm{ex}}{k}_0\sin \theta$ and $k_z=n_{\mathrm{ex}}{k}_0\cos \theta$ yields the displayed directional refractive index.

At normal incidence, with no optical dispersion and zero round-trip reflection wave phase modulo $2\pi$, the resonance condition in Fabry–Pérot transmission from multiple reflections isHere $\nu$ is frequency and $c$ is the speed of light in vacuum. A change of $\nu$ by one free spectral range advances the round-trip wave phase by $2\pi$. At fixed internal angle of incidence $\theta$, the same nondispersive model gives $c/(2nd\cos \theta )$. Holding the external angle of incidence fixed in a dispersive medium need not hold the internal $\theta$ fixed, because of Snell's law.

For stipulated $n=1$ and $d=10\mathrm{mm}$, the free spectral range is $14.9896229\mathrm{GHz}$ using $c=299792458\mathrm{m}{\mathrm{s}}^{-1}$. A frequency difference of $0.10\Delta {\nu }_{\mathrm{FSR}}$ is therefore $1.49896229\mathrm{GHz}$. Transmission repeats every free spectral range: one isolated scan cannot distinguish that separation from $1.10\Delta {\nu }_{\mathrm{FSR}}$. Independent knowledge of the optical spectrum, an additional filter, or a changed mirror separation is needed to assign orders.

Equal spacing in frequency does not imply equal spacing in wavelength. At normal incidence the exact adjacent resonance wavelengths obeyFor example, choosing $2nd=10{\lambda }_{10}$ makes the exact gap to order 11 equal to ${\lambda }_{10}/11$, while the high-order estimate gives ${\lambda }_{10}/10$. The approximation is already ten percent larger at order 10. With optical dispersion or frequency-dependent reflection wave phase, obtain local spacings from the total phase difference instead: $\Delta \nu \simeq 2\pi /(d\delta /d\nu )$ when its derivative varies little over one order.

Faraday's law of induction relates a changing magnetic field to circulation of the electric field. For a fixed oriented surface $S$ with boundary $C=\partial S$, choose the positive direction around $C$ by the right-hand rule: the fingers follow $C$ while the thumb follows the chosen unit normal. The fixed-loop electromagnetic electromotive force isThe final derivative of magnetic flux is an ordinary time derivative, with the surface held fixed. Reversing both the unit normal and the boundary direction reverses both signs. The loop may be an imagined path: the field law does not require a wire or an electric current. ^[ref].

For a computed example, a fixed single-turn loop has area $A=0.020{\mathrm{m}}^2$ and out-of-page unit normal. Prescribe an external uniform magnetic field in that direction with $B(t)=0.10\mathrm{T}+(0.30T/s)t$ for $0\le t\le 1.0\mathrm{s}$. ThenIn a quasistatic resistive model with electrical resistance $R=2.0\Omega$, neglect the loop's self-inductance and its own contribution to changing magnetic flux. Ohm's law givesThe magnetic flux rises from $0.0020\mathrm{Wb}$ to $0.0080\mathrm{Wb}$ while the induced electromotive force stays constant: it measures the rate of change, rather than the amount of magnetic flux. The negative sign means clockwise electric current; its magnetic field through the loop points into the page, as explained by Lenz's law. The toy model describes the interval of steady ramping, excluding switching transients at its ends.

For a moving conducting loop $C(t)$, the electromagnetic electromotive force instead includes the Lorentz force contribution from the local velocity $\mathbf{v}$ of each conductor segment:This form assumes a thin-wire model with a well-defined closed contour and spanning oriented surface that move compatibly, a magnetic field satisfying Gauss's law for magnetism, and conductor speeds small compared with the speed of light. Ideal sliding contacts such as those in motional electromotive force can be treated piecewise. Arbitrary changes of electrical connections require checking the actual contour and conductor velocities; differentiating the flux through an arbitrary chosen moving path is insufficient. The velocity here describes conductor motion, not the charge carriers' drift along the wire. ^[ref].

A short derivation of the fixed-loop integral statement applies Stokes theorem to the local curl equation and differentiates under the fixed surface integral. For the moving loop, the magnetic flux transport for a moving circuit adds the swept-area term $-{\oint }_C(\mathbf{v}\times \mathbf{B})\cdot d\mathbf{l}$ to $d{\Phi }_B/dt$. Combining these two identities gives the moving-loop statement. This derives the integral forms from the local field law; it is not a proof of that empirical law from mathematics alone.

The useful unity is geometric: changing the magnetic field, the enclosed area, or the orientation can change magnetic flux and hence produce an electromotive force. A coil's multiple turns are accounted for by magnetic flux linkage, rather than by multiplying a single-turn flux without checking which flux each turn receives. ^[ref].

Faraday's report read on 24 November 1831 describes opposite momentary responses when a neighboring circuit is connected and disconnected, with no continuing response while its steady electric current is maintained. These are concrete experimental roots of the changing-flux idea. The report predates the modern Maxwell equations notation used above. ^[ref].

A four-vector is a vector whose four vector components transform under a Lorentz transformation as $U^{\prime \mu }={\Lambda }^{\mu }{}_{\nu }{U}^{\nu }$. Its individual vector components generally change between inertial frames; the Minkowski metric combines them into invariant scalar products. Listing four quantities is not enough to make a four-vector: their transformation law matters.

The most direct example is the displacement between two spacetime events, written $(c\Delta t,\Delta x,\Delta y,\Delta z)$. Multiplying the time difference by the speed of light gives all four vector components the same length units. A position four-vector describes an event relative to a chosen origin, while a displacement does not depend on a common translation of the origin. Four-momentum and four-velocity use the same transformation rule for different physical quantities.

The Franck-Hertz experiment connects a reproducible loss of Electron kinetic energy with excitation of a chemical atom. The original mercury-vapor experiments were performed during 1912–1914 while investigating ionization; they were not designed as a test of the Bohr model. Their later interpretation distinguished internal excitation from removal of an Electron. ^[ref].

In a modern mercury tube, a heated cathode emits Electrons and a positive perforated grid accelerates them through Hg vapor. A collector slightly below the grid's electric potential rejects slow Electrons. The oven controls vapor density and hence the mean free path. Keep heating and retarding settings fixed, sweep the accelerating electric potential difference $V$, and record collector electric current $I(V)$. These measured quantities indirectly probe atomic excitation. ^[ref].

The curve shows repeated current minima, typically about $4.9\mathrm{V}$ apart. In the collision model, an Electron gains approximately $eV$ of kinetic energy, with $e$ the positive elementary charge. An inelastic collision transfers about $4.9\mathrm{eV}$ to internal excitation. Near the grid, this can prevent the Electron crossing the retarding region, lowering collected electric current. Further acceleration restores collection; repeated excitation losses produce further minima. These represent multiple collisions, rather than equally spaced atomic energy eigenvalues. Contact potentials shift the first minimum, so compare several successive spacings instead of identifying the first dip's voltage with the excitation cost. ^[ref].

The optical comparison supplies a second observable: mercury radiation at a wavelength near $253.6\mathrm{nm}$ was detected through a window in the tube. Its inferred photon energy $hc/\lambda \approx 4.89\mathrm{eV}$ agrees with the characteristic collision loss, with $c$ the speed of light. This agreement supports the interpretation as a transition between internal atomic energies. It does not make the collector trace a complete spectrum. In particular, the lowest excited mercury level, labeled $6{}^3{P}_0$, is metastable because an electric-dipole selection rule forbids its direct transition to the ground state; the nearby $6{}^3{P}_1$ level emits the quoted ultraviolet line. Collision excitation and optical detection therefore have different sensitivities to the available excited states. ^[ref].

Initial Electron kinetic energy spread and varying collision positions broaden real minima. Repeat traces at different retarding settings and oven temperatures to distinguish excitation from collection effects. This probes a discrete energy-transfer channel, rather than every energy eigenspace, its dimension, or an absolute ground-state energy. ^[ref].

The free spectral range is the wavelength or frequency spacing between adjacent orders or resonances of an optical instrument. It identifies when different orders can overlap. Always specify the coordinate: a uniform spacing in frequency need not be uniform in wavelength. For an ideal Fabry–Pérot interferometer at normal incidence, with mirror separation $d$ and constant refractive index $n$, Fabry–Pérot resonance spacing gives $\Delta {\nu }_{\mathrm{FSR}}=c/(2nd)$, where $c$ is the speed of light in vacuum. The free spectral range of an echelle grating follows a different order condition.

In vacuum, $\nu =c/\lambda$, where $c$ is the speed of light. Increasing wavelength decreases frequency, so the ordinary signed differentials satisfy $d\nu =-c{\lambda }^{-2}d\lambda$. A spectral slice's positive contribution to radiance must be unchanged. The change of variables formula therefore gives the absolute Jacobian determinantThese formulas use $L_{\lambda }$ per metre and $L_{\nu }$ per hertz. The factor $c/{\nu }^2$ has units $\mathrm{m}\mathrm{s}=\mathrm{m}\mathrm{H}{\mathrm{z}}^{-1}$, which converts the former density into the latter. If ${\ell }_{\mathrm{nm}}$ denotes the numerical density per nanometre in $\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}\mathrm{n}{\mathrm{m}}^{-1}$, its per-metre value is $10^9{\ell }_{\mathrm{nm}}$. Conversely, the per-nanometre value is $10^{-9}$ times the per-metre value. Likewise, a density per terahertz is $10^{12}$ times its per-hertz value because $1\mathrm{THz}=10^{12}\mathrm{Hz}$.

For a concrete stipulated spectrum, let $L_{\lambda }=C=10^9\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}{\mathrm{m}}^{-1}$ between ${\lambda }_1=500\mathrm{nm}$ and ${\lambda }_2=600\mathrm{nm}$, and zero outside. This is exactly $1\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}\mathrm{n}{\mathrm{m}}^{-1}$ throughout the band. Using the exact International System of Units value $c=299792458\mathrm{m}{\mathrm{s}}^{-1}$, the corresponding frequency bounds areThe transformed spectral radiance is $L_{\nu }=Cc/{\nu }^2$ on this interval. At ${\nu }_1$ it is approximately $1.200830743\times 10^{-12}\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}\mathrm{H}{\mathrm{z}}^{-1}$, and at ${\nu }_2$ it is $8.339102380\times 10^{-13}$ in the same units. These are respectively $1.200830743$ and $0.833910238$ per terahertz. Thus a flat wavelength density becomes a decreasing frequency density; relabelling the horizontal axis alone would miss both the shape and the units. ^[ref].

The equality of band radiances has a short exact proof:The reversed bounds and the Jacobian determinant preserve the same spectral measure. Each half-band, $500$–$550\mathrm{nm}$ and $550$–$600\mathrm{nm}$, carries $50\mathrm{W}{\mathrm{m}}^{-2}\mathrm{s}{\mathrm{r}}^{-1}$, although the corresponding frequency widths are about $54.508$ and $45.423\mathrm{THz}$.

A spectrum's peak is consequently a statement about a particular density and coordinate. The frequency and wavelength peaks of Planck's law differ for precisely this reason. Integrated radiance over a specified physical band supplies a comparison that survives the change of variables.

General relativity describes gravity through the geometry of spacetime. Its metric tensor specifies distances, proper time measured by clocks, and the causal structure that limits communication. Matter and radiation affect this geometry through the Einstein field equations; freely falling test particles follow geodesics of the resulting geometry. A planet's orbit and a falling apple therefore belong to the same geometric story. The Newtonian limit recovers familiar Newtonian gravity when fields are weak and speeds are small compared with the speed of light. See David Tong's introduction to general relativity.

The most direct way to understand spacetime curvature is to compare neighboring freely falling bodies. Even when each body feels weightless, their separation can change: this is geodesic deviation, observed as a tidal force. Curvature concerns these relative measurements, rather than the shape of a drawing in an imagined surrounding space. A second accessible measurement is gravitational time dilation: identical clocks maintained at different heights accumulate different proper times. Together, tides and clocks turn an abstract geometry into laboratory questions.

Geometrical optics describes propagation by rays and Snell's law, neglecting diffraction on scales much larger than the wavelength.

A light ray is a path in an approximation, not a physical thread of zero width. In a transparent, homogeneous, isotropic medium it is straight and perpendicular to a wavefront; boundaries redirect it by the law of reflection or Snell's law. The approximation is useful when the wavelength is small compared with relevant apertures, surface curvature scales, and distances over which the refractive index changes. For an illustrative wavelength of $500\mathrm{nm}$ and a $10\mathrm{mm}$ aperture, their ratio is $5\times 10^{-5}$. That small ratio supports ray tracing for image location, but does not eliminate diffraction when calculating the fine structure of a focused spot. At a wave caustic, geometrical optics can fail despite large optical elements. ^[ref].

The mechanism of refraction is a change in phase velocity. For transparent isotropic media at the chosen frequency, the refractive index iswhere $c$ is the vacuum speed of light and the angles are measured from the interface normal vector. At a stationary planar interface the frequency and tangential wavevector match across the boundary. Since the wavenumber is $k=n\omega /c$, that matching gives Snell's law. The transmitted wavelength changes while the frequency stays fixed. Here $n$ uses phase velocity, which need not equal group velocity. ^[ref]. ^[ref].

Choose model air with $n_1=1$ and model glass with $n_2=1.5$, without claiming these are exact values for every sample or wavelength. At ${\theta }_1=45^{\circ }$, Snell's law givesThe transmitted light ray bends toward the normal vector; its phase velocity is $c/1.5$, and its wavelength is two thirds of the air value. By reversibility of an optical ray, incidence from glass at $28.1255^{\circ }$ returns the outgoing air angle $45^{\circ }$.

Incidence from glass at $45^{\circ }$ is a different experiment. It would require $\sin {\theta }_2=1.5\sin 45^{\circ }\approx 1.06066$, so there is no real transmitted angle. The critical angle for total internal reflection isAbove this angle, an ideal lossless glass-air boundary produces total internal reflection. The physical optics description still permits an evanescent wave in the air, although no propagating transmitted light ray crosses the boundary. ^[ref]. ^[ref].

The usefulness of geometrical optics is that complicated instruments can be assembled from these local rules. Applying Snell's law at successive curved surfaces changes a spreading bundle into a converging one. The Fermat principle unifies the construction through stationary optical path length; stationarity does not require a global minimum. ^[ref]. Fang's MIT notes explicitly connect this principle to specular reflection, refraction, and thin lens imaging, providing a route from individual paths to complete instruments. ^[ref].