No measured normalization of the neutral-hydrogen column-density distribution, ionizing field or gas temperature is supplied, so the paper's formulas do not determine numerical densities on their own. With observational data and suitable ionization corrections, the high-redshift Lyman-alpha forest gives a total gas density of order a few relative to today's critical density, comparable to the cosmological baryon density – for . The conclusion is that a large fraction of baryons at reside in diffuse ionized gas, rather than that every baryon has been individually accounted for. Schaye's analysis and Kim and collaborators' survey support that interpretation under their stated gas and ionizing-background assumptions.
The neutral-gas reservoir traced predominantly by damped Lyman-alpha systems is much smaller, of order in the same convention. It is broadly comparable in order of magnitude to today's luminous stellar matter, whose cosmic stellar mass density is a few , but exact comparisons depend on cosmology, helium correction and which stellar components are counted. Storrie-Lombardi, McMahon and Irwin's neutral-gas census finds especially close comparison with present stellar disks. Most high-redshift gas is ionized; the smaller neutral reservoir has a mass of roughly the same order as today's visible stellar population. This comparison does not imply that the measured neutral reservoir alone simply becomes all present-day stars: gas accretion, recycling, ionization changes and outflows continue during galaxy evolution.
The neutral gas density from an absorption distribution is comparatively robust for high columns where the hydrogen is mostly neutral, but saturated lines, dust-obscured quasars, incomplete surveys and small numbers of rare high-column systems affect the integral. The ionized gas density from an absorption distribution has additional systematic uncertainty in the cosmic ionizing background, temperature, absorber depth, helium treatment and small-scale density inhomogeneity. At low columns, line blending and incompleteness matter; at high columns, attenuation makes an optically thin ionization correction invalid. A single power law extrapolated outside the measured column range can also produce a misleading mass integral. Hot gas, molecular gas and gas missed by the selected absorption population are not included automatically. These are observational and modelling qualifications to a baryon census, not failures of the column-mass accounting itself.
Use natural units and the unreduced Planck mass . Neutrino decoupling occurs when the weak interaction rate falls below the Hubble parameter. The weak-decoupling temperature estimate equates the given rate with the radiation-era expansion rate:
Here counts the effective number of relativistic energy degrees of freedom, and the Fermi constant is . The omitted reaction-rate coefficients make this an order-of-magnitude estimate: decoupling occurs at a temperature of order one MeV.
The charge-conserving channel is , together with . The positron sign in the printed neutron-capture channel violates electric charge conservation. Chemical equilibrium requires . Negligible lepton chemical potentials therefore give . Since neutrons and protons are nonrelativistic particles, their Maxwell-Boltzmann distribution gives
Both nucleons have two spin states, and their masses agree closely in the prefactor. Thus neutron-proton chemical equilibrium implies
The heavier neutron is suppressed by a Boltzmann factor.
For the deuterium equilibrium abundance, retain the paper's convention ; the positive nuclear binding energy is . Chemical equilibrium of gives because the equilibrium photon chemical potential vanishes. Using the nonrelativistic Maxwell--Boltzmann number density for each species and dividing gives
Here and . With the baryon-to-photon ratio , the photon number density , and , , this becomes
In this convention counts nuclei, so its contribution to the fraction of baryons in deuterium is .
The deuterium bottleneck explains why helium-4 formation waits until is far below . At higher temperature, there are vastly more photons than baryons; even the dilute energetic tail can destroy newly formed deuterium. A crude estimate balances against one, giving for of order . The power-law factors in the deuterium equilibrium abundance and the nuclear reaction rates refine this estimate. Once stable deuterium accumulates, further reactions can efficiently place nearly all surviving neutrons into helium-4.
Write at the onset of nuclear burning. Each helium-4 nucleus requires two neutrons and contains four baryons. Neutron-limited helium synthesis therefore gives the primordial helium mass fraction
For a realistic rough cosmological weak freeze-out estimate, is about and free-neutron decay after freeze-out reduces it to about , giving roughly one quarter of the baryonic mass in helium-4. The survival relation that conserves baryon number is ; the corresponding is .
The rough neutrino decoupling rate by itself does not determine that one-quarter value. Substituting literally into would give and before neutron decay. Neutron-proton chemical equilibrium persists to a lower temperature, approximately -- once the actual conversion rates are included. The rate scaling fixes the MeV scale; accurate abundances need the conversion coefficients and the delay through the deuterium bottleneck. This sequence is described in David Tong's discussion of nucleosynthesis.
Increasing reduces the equilibrium neutron-to-proton ratio, so the primordial helium abundance decreases. Holding the freeze-out temperature and the decay survival factor fixed, the primordial helium response to the neutron-proton mass difference is
For and -- this is about --, a reduction of roughly fifteen percent. A larger also changes neutron decay and detailed weak rates; their quantitative effects require more microscopic information. The sign from the Boltzmann factor is already clear.
Use natural units, assume negligible neutrino chemical potentials, and approximate neutrino decoupling as occurring before electron-positron annihilation in cosmology. At high temperature, weak interactions maintain a common temperature for neutrinos, antineutrinos, electrons, Positrons and photons. Since , the reaction rate eventually loses against expansion. Decoupled relativistic neutrinos then free stream; their momenta redshift as , so their distribution retains a temperature parameter satisfying .
The still-coupled electromagnetic bath receives the entropy of annihilating electrons and Positrons. Its effective number of relativistic entropy degrees of freedom is initially
where the two photon polarizations count as bosonic states and the four electron-positron spin states have the fermion entropy weight . After the pairs disappear, . Cosmological entropy conservation in this coupled bath gives . The three already decoupled neutrino species are excluded from this bath's entropy count. At decoupling , hence
Subsequent expansion preserves this ratio in the idealized history. Residual interactions during annihilation give small corrections to the instantaneous-decoupling approximation. If a relic species later becomes massive, here remains the redshifting momentum-distribution parameter; it need not be its nonrelativistic kinetic temperature.
A single ordinary neutrino species includes one populated neutrino helicity and one antineutrino helicity. For negligible chemical potential, integration of the Fermi-Dirac distribution gives
Therefore the number density of a relativistic neutrino relative to photons, with the antiparticle included, is
The factor is the fermionic number-density weight, distinct from the energy and entropy weight . This relation continues to hold after this species becomes nonrelativistic if its comoving particle number is conserved.
Under the proposed matter-dominated, spatially flat model, the Friedmann equation requires the present relic-neutrino energy density to be approximately the critical density. Using the unreduced Planck mass gives
Thus the critical-density mass of a thermal relic neutrino is
Taking the paper's rounded values, , and , gives
For , this is of order -- with these approximate constants. More precise constants change the coefficient, not the requested mass scale. This mass is much larger than the present momentum scale , validating the nonrelativistic energy density approximation. The result assumes that one thermal relic species dominates the matter density; it is conditional on that model rather than a measurement of a neutrino mass.
Buoyancy and the convective criterion. Consider a small fluid parcel displaced outward by . Assume that sound waves keep its pressure equal to the ambient pressure, while heat exchange is slow enough that its displacement is an adiabatic process. Composition is uniform, so the parcel and its surroundings have the same mean molecular weight. For an ideal gas, , and an adiabatic parcel obeys . If is the pressure change on moving outward, then
The density excess of the parcel at its new location is therefore
If , this excess is negative: the outward-displaced parcel is lighter and accelerates farther outward. A downward displacement similarly continues downward. Conversely, a smaller gradient gives a restoring buoyancy force. The Schwarzschild criterion is thus stability for and instability for , where the adiabatic temperature gradient is . For a monatomic gas,
A composition gradient would require the additional density effect in the Ledoux criterion; it is absent in this calculation.
Opacity and pressure. The supplied opacity is characteristic of a cool hydrogen-rich stellar atmosphere dominated by negative hydrogen ion opacity. Mostly neutral hydrogen can attach electrons supplied by partially ionized metals; bound-free and free-free absorption involving the resulting ions produces a steep positive temperature dependence. The weak density dependence and strong temperature sensitivity can be represented by local power-law fits. At fixed composition the given pressure form is equivalent to , because . This is an approximate fit over the relevant cool-atmosphere regime, not an exact opacity law at all temperatures; molecular opacity or hydrogen ionization eventually changes the regime.
For a geometrically thin atmosphere take the surface gravity of a star to be constant, . Combining with gives hydrostatic equilibrium in optical depth,
The grey atmosphere relation gives . With negligible external pressure, , integration yields
An imposed nonzero external pressure would add ; the boundary assumption is what fixes the integration constant here.
The factor in parentheses is . Hence
The grey-atmosphere convection onset with eighth-power temperature opacity occurs when this reaches , so
The radiative continuation below this boundary would be unstable. Efficient convection instead keeps the deeper star approximately adiabatic.
Matching to the convective interior. Write . Eliminating density using the ideal gas law gives
at fixed composition. Since is a fixed number, the matching temperature is proportional to , while the matching pressure satisfies . Consequently
The polytropic mass-radius relation for index gives . Raising the matching relation to the ninth power and using therefore gives
Finally the Stefan–Boltzmann law yields the Hayashi relation with eighth-power temperature opacity,
Composition and the opacity normalization are fixed in this comparison. The entropy coefficient is spatially constant in each convective model, but need not be the same for stars with different masses or radii.
Thermal energy versus electrostatic repulsion. The mean translational kinetic energy of one nonrelativistic thermal proton is
Using the center-to-center touching separation , the Coulomb barrier estimate is
Thus . Using rather than as the rough interaction distance doubles the estimate but leaves the conclusion unchanged. Typical solar thermal energies are far below the classical barrier. The two essential ideas are the high-energy tail of the thermal distribution and quantum tunnelling through the Coulomb barrier: neither a mean-energy estimate nor a sharp classical cutoff describes the reacting population.
For two equal-mass protons, let be their relative speed. In the center-of-mass frame each has speed , so their total collision energy is
Here is the reduced mass, not the stellar mean molecular weight.
In the low-energy, nonresonant approximation, the geometrical quantum-wave factor in a collision cross-section is proportional to the squared de Broglie wavelength, hence to . The slowly varying short-range reaction probability is absorbed into ; for proton–proton fusion it also includes the small weak-reaction probability. The rapidly varying exponential is the quantum tunnelling probability. For a Coulomb potential , its leading semiclassical exponent is
The integral follows from ; its dimensionless integral is . A finite nuclear radius modifies the short-distance factor absorbed into . In this convention : it is a penetration-energy scale, distinct from the classical contact energy .
Thermal averaging and pair counting. Each proton samples collision partners with number density and collision flux , so its collision rate is . Multiplying by the number of protons counts each identical pair twice. The thermonuclear reaction rate is therefore
The relative speed of two independent thermal protons has a Maxwell-Boltzmann velocity distribution with reduced mass . Changing variables with gives the normalized energy density
Substituting and the collision cross-section causes the energy powers to cancel:
The Gamow peak and its Gaussian width. Set . It diverges at either endpoint and has its unique minimum where
Thus the energy called in this question is the Gamow peak energy,
In the stellar tunnelling regime ,
This establishes the requested hierarchy in its physical regime; it is not an inequality valid at arbitrary temperature.
At the minimum, and . Hence
The Gaussian standard deviation is , small compared with when . Extending the lower endpoint to relative to the peak then gives
Combining this with the thermal prefactor yields the Gaussian approximation to a nonresonant thermonuclear rate,
At fixed reactant density and fixed , comparison with the requested temperature form gives
The constant here has dimensions of temperature; it is not inverse temperature. Resonances, plasma screening or variation of would require corrections to this particular approximation.
Mechanical balance and equipotentials. Let be the Newtonian gravitational potential and the cylindrical distance from the rotation axis. For rigid angular velocity , a fluid element at rest in the rotating frame has no Coriolis acceleration. The centrifugal acceleration is , so hydrostatic equilibrium becomes
Using the Poisson equation for gravity and gives
On any regular connected equipotential surface, every tangent displacement satisfies and therefore . Locally , with . This makes a function of as well. Equivalently, taking the curl of the hydrostatic equation gives . Thus and are constant on each surface. The last conclusion follows from the modified Poisson equation; it does not constrain the magnitude of the first derivative to be constant there.
For uniform composition, an equation of state determines uniquely at fixed in the usual stellar regime. For the gas-plus-radiation equation, the derivative with respect to is positive. Hence , and the opacity and radiative conductivity are also functions of .
Surface flux and the requested sketch. Define , positive for the outward radiative flux. Then
On an outer equipotential surface, is constant and the outward normal is parallel to . Its effective gravity is , so . The Stefan–Boltzmann law gives the radiative gravity-darkening law,
A rapidly rotating star is oblate. Centrifugal support reduces the effective gravity near the equator, which is therefore cooler and dimmer; the poles are hotter. The original sketch below uses a subcritical Roche model of a uniformly rotating star to show this geometry and the corresponding temperature variation. The material temperature on an interior equipotential is not the same quantity as the emergent effective temperature defined by surface flux.
Figure 1.
Oblate rotating star with hot poles, cool equator and radiative gravity darkening
. Details.
Why purely local radiative balance fails. Differentiating the flux gives
On one equipotential, and the proposed source are all constant, but generally varies with latitude. Unless or there is another special cancellation, no single value of can match this flux divergence at all points on the surface. This is the radiative-equilibrium obstruction in a rotating barotropic star. Slow stellar meridional circulation can transport heat to compensate; it is distinct from abandoning hydrostatic balance at leading order.
Integrated energy balance with circulation. The steady continuity equation is . Combining the entropy–enthalpy relation with hydrostatic balance gives
Integrate the energy equation over and apply the divergence theorem:
Uniform composition makes constant on the enclosing equipotential, and is constant there by definition. Pull out of the last integral; the remaining net mass flux is zero by steady continuity. Thus the equipotential luminosity conservation with stellar circulation is
This does not require pointwise on : inward and outward circulation may cancel in the net mass flux.
Finally, is constant on and the divergence theorem applied to the effective potential gives
Therefore . Since ,
The mass is the mass enclosed by this surface, not necessarily the total stellar mass. The denominator is positive for the regular hydrostatic surfaces used here; near loss of centrifugal confinement the assumed stellar model must be reconsidered. The derivation uses slow circulation, retaining hydrostatic/equipotential thermodynamics to leading order while allowing a nonzero advective heat flux.
A spatially uniform pressure is a useful leading approximation when the sound speed makes the acoustic crossing time much shorter than the radiative cooling and thermal conduction times. The motions must remain at low Mach number, and gravity and other stresses must be negligible. Sound then redistributes pressure before appreciable thermal evolution occurs. Small pressure corrections can still drive the slow motion; imposing exactly zero pressure gradient in the full momentum equation at every order would be a stronger assumption.
The equation of state gives the specific internal energy of an ideal gas as . With , the continuity equation is . Differentiating therefore yields
Insert this into the internal energy equation, whose compressional term is , and use spatially uniform pressure, so . The result is
For temporally constant pressure put , so the mass density is . The continuity equation now gives . Multiplication of the last equation by , with , gives
This is the isobaric conductive cooling in mass coordinates transformation before changing coordinates.
There is a boundary assumption implicit in the proposed Lagrangian coordinate. For a mass integral from a fixed origin, integration of the continuity equation gives
Thus is material when the base mass flux vanishes, as appropriate for the stationary cold reservoir below. If the origin permits mass flux, replace by ; this corrected label has zero material derivative. In a material mass coordinate, and . In particular
The conduction coefficient therefore becomes , with the same as the cooling coefficient. With , the equation is
In the hot gas there is no volumetric radiative cooling. The initial temperature is uniform and the cold boundary introduces no finite mass length. The remaining nonlinear diffusion equation is invariant under , with the same temperature scale. Its natural similarity solution is therefore
The far-field condition also recovers the initial temperature at every fixed as . Substitution gives the ordinary differential equation
For , this reduces to . Integrating first for gives . The two boundary conditions fix , hence the error-function isobaric cooling front is
Here the error function has normalization , as printed in the original PDF; the converted TeX's is incorrect. The following original sketch shows the temperature profiles. The cooling layer broadens as , and at fixed positive mass label the temperature falls as time increases, while the remote hot gas remains at .
Figure 1.
Isobaric conductive cooling profiles at increasing scaled times
. Details.
For , the magnitude of the heat flux into the cold reservoir is
Although the thermal conductivity tends to zero there, the physical temperature gradient diverges: their product has this finite limit. The stationary reservoir has no incoming advective energy flux and radiates the conducted energy immediately. Since , the radiated power per unit area is
Thus the requested exponent is . The initial divergence is the usual idealization of an instantaneous temperature discontinuity in a diffusion equation.
Use the relative potential and integrate the stated, untruncated Maxwell-Boltzmann velocity distribution over . The normalization cancels its three Gaussian integrals:
The gravitational potential sign reverses under the relative-potential convention, so the spherical Poisson equation for Newtonian gravity is
Also , with . Differentiating the density relation yields
An ideal gas with constant temperature has . Its hydrostatic equilibrium equation is precisely the same when
Together with the same enclosed-mass equation, central density and boundary conditions, this proves the isothermal stellar and gas density equivalence. In dimensionless terms, and obey with in both systems.
This calculation uses the distribution as printed for all velocities. Imposing an additional cutoff at positive relative energy changes the integral to , where , and no longer gives an exactly isothermal gas profile. An untruncated self-gravitating isothermal sphere also needs an outer modification for finite total mass. The function here is the error function. Finally, the half-line Gaussian integral printed in the note lacks a factor: the correct value is .
The density-weighted mean kinematic viscosity is
using . Under the preceding rescaling, let
Uniqueness of the universal dimensionless solution makes a positive numerical constant independent of . Hence
For Keplerian rotation, . The constant-opacity gas-pressure disk viscosity law is therefore
The particular scaling convention changes the representation of but not this physical law. Its nontrivial powers come from balancing viscous heating, diffusive cooling and vertical support together, rather than assuming a fixed temperature or thickness.
Work at one radius and write . Use the surface density to fix the mass density normalization and introduce the height scale
Choose the dimensionless variables
The pressure and temperature scales make the hydrostatic and ideal gas equations parameter-free. The flux scale fixes the heating coefficient at , and the choice of makes the diffusion coefficient unity. Direct substitution gives the universal ordinary differential equations
For example, the dimensionless coefficient in the temperature equation is .
Let the upper free surface be at , so its physical semithickness is . Midplane symmetry and the radiative-zero disk surface conditions give
The last condition is precisely . The unknown surface position and the two positive midplane values are determined as part of the normalized boundary value problem. Symmetry makes even and odd; already follow from the equations and are not additional independent boundary conditions.
The zero conditions do not mean zero surface flux. Integrating the heating equation gives . Near a regular surface with finite outgoing flux, dividing the hydrostatic equation by the temperature equation yields . Thus , and , so mass density also vanishes. The apparent singular quotient in the diffusion equation has a finite regular limit. All boundary conditions and equations are independent of the physical parameters: this is homologous vertical structure of a constant-opacity alpha disk.
The first equation is vertical hydrostatic equilibrium: the upward pressure gradient balances the central mass's vertical gravitational force. For , the point-mass acceleration is , where Keplerian rotation gives . The disc's self-gravity and vertical inertia are neglected.
The second equation is local thermal balance. The divergence of the vertical radiative flux equals viscous dissipation. In the convention of this alpha disk, , and the dominant Keplerian shear has . Therefore
The radiative flux increases from zero at the symmetric midplane to a positive outgoing value at the upper surface. Radial heat transport, thermal advection and rapid storage of thermal energy are excluded from this local balance.
The third equation is radiative diffusion, equivalently
It applies to optically thick material, with the opacity per unit mass and the Stefan-Boltzmann constant. Here constant electron-scattering opacity represents Thomson scattering; the formula uses a diffusive, nearly thermal radiation field. Positive upward flux requires temperature to decrease upwards.
The final equation is the ideal gas pressure law, with mean molecular weight in proton-mass units. Writing gives . The pressure is gas pressure because radiation pressure is assumed negligible. The four equations express vertical support, local heating balance, diffusive cooling and the gas equation of state.
For a fixed column density or rest-equivalent-width threshold, the number of ordinary Lyman-alpha forest features per unit redshift generally increases towards higher redshift. Over much of –, a rough description is with an index of order –, dependent on selection; the evolution is much slower at low redshift. Near reionization, blending and widespread opacity make a decomposition into individually detected lines increasingly inappropriate.
First separate physical evolution from geometrical path length. For comoving absorber density and proper interception area , absorber incidence and comoving number density gives
Even a non-evolving population is not constant per unit redshift. Using absorption distance removes this particular geometrical effect.
The remaining redshift evolution of the Lyman-alpha forest reflects several competing processes. Cosmic expansion dilutes the gas; at fixed overdensity, photoionization equilibrium gives , so dilution can move many features below a fixed threshold. The cosmic ionizing background evolves as quasars, stellar sources and ionizing-photon absorption evolve; a decline of its intensity at late times partly offsets dilution. Photoheating changes temperature and radiative recombination, while gravitational instability redistributes gas into denser structures and hot shocked phases and changes its velocity field. Thus evolving line counts are not a direct count of conserved clouds; the density, thermal state, radiation field, geometry and observational selection must all be accounted for. The high-redshift increase and its physical interpretation are documented in the forest observations and models.
Near the background quasar, the quasar proximity effect typically reduces the number and strength of Lyman-alpha forest features relative to regions farther along the sightline. It is an ionization effect, not evidence that the quasar lies in an empty region. At fixed gas density and temperature, photoionization equilibrium gives
If the unperturbed neutral-hydrogen column-density distribution is , , detecting a column above now requires its unperturbed column to exceed . Integrating that distribution shows that the number above threshold is reduced by . This supplies an explicit model for the decline of line counts.
The known quasar luminosity estimates its photoionization rate at proper separation :
These expressions assume unattenuated, steady, isotropic quasar emission and a specified ionizing spectrum. Fitting the measured suppression as a function of separation determines the ratio and hence constrains the cosmic ionizing background. A weaker background gives a larger region in which the quasar dominates. For fixed background spectral shape, this constrains its specific intensity near the Lyman limit system ionization edge, not an arbitrary spectral function. The proximity-effect estimator of the ionizing background is biased if the host gas is overdense, the quasar's past luminosity differs from its observed luminosity, its radiation is anisotropic, or systemic-redshift errors distort the inferred separation; absorption between source and gas also changes . These effects explain why the method needs environmental and source modeling, as discussed in the proximity-effect measurements.
The primordial light-element abundance determination uses minimally processed material and estimates its residual processing rather than directly observing the universe at a few minutes old.
For deuterium, high-redshift, low-metallicity quasar absorption systems resolve isotope-shifted D I lines from the H I Lyman series. The deuterium feature is displaced by about from hydrogen; fitting several transitions and the velocity components distinguishes genuine deuterium from an unrelated hydrogen blend. The ratio of the inferred columns estimates D/H after the ionization and component structure are checked. Low metallicity minimizes stellar destruction, giving a representative primordial ratio of roughly .
For helium-4, helium and hydrogen recombination-emission lines in metal-poor H II regions of nearby dwarf galaxies give a mass fraction. Several lines constrain temperature, electron number density and corrections for collisional excitation, ionization structure, radiative transfer and underlying stellar absorption. Extrapolation of helium enrichment against metallicity towards zero metallicity estimates , approximately –, corresponding to helium/hydrogen by number near .
For helium-3, the approximately GHz hyperfine line of in Galactic H II regions probes the abundance, with ionization and nebular structure corrections. Stellar production and destruction make its primordial value hard to extract; a characteristic abundance near relative to hydrogen is compatible with standard nucleosynthesis but is not a comparably clean primordial measurement.
For lithium-7, the approximately Å Li I absorption doublet in warm, old, metal-poor halo stars gives a photospheric abundance after stellar-atmosphere and effective-temperature corrections. The Spite plateau suggests an initial number ratio of order if depletion is small; transport below the photosphere, nuclear destruction and atmosphere systematics can lower the measured value relative to the birth abundance. Standard Big Bang nucleosynthesis at the deuterium- and microwave-background-favored baryon density instead predicts several , roughly in exam-era calculations. This discrepancy is the cosmological lithium problem, not a measurement of an independently adjustable primordial lithium parameter.
The approximate values deliberately represent exam-era orders of magnitude rather than a claim of current precision; the contemporary abundance assessment discusses the inference and tensions.
For a moderately faster cosmic expansion that still permits efficient nuclear burning, the hydrogen mass fraction is smaller, since cooling from cosmological weak freeze-out to helium formation takes less time, fewer free neutrons decay into protons, and more surviving neutrons enter helium-4. If the change also affects cosmological weak freeze-out, its higher freeze-out temperature leaves a larger initial neutron-to-proton ratio and reinforces the helium increase. The conclusion assumes efficient neutron-limited helium synthesis: an unspecified arbitrarily rapid expansion could instead outrun the nuclear reactions, so the nuclear-burning qualification of the helium expansion-rate response prevents an unconditional assertion.
Let and use a fixed arbitrary material subvolume in the reference configuration, with outward unit normal . The reference mass density is time independent. The global momentum conservation law is
The divergence theorem, differentiation under the integral, and arbitrariness of give
The global conservation of energy law includes both internal energy and kinetic energy:
Here is outgoing heat flux per reference area. Localizing gives
Subtract the scalar product of the local momentum conservation law with . Since , this proves the Lagrangian internal energy balance
For positive temperature , the global entropy inequality is
Its local excess is a nonnegative production density . Expanding the divergence of proves the Lagrangian entropy inequality in the requested equality form:
No constitutive assumption on the heat flux was needed for these balance identities.
For the reference-configuration jump balances, make the orientation convention explicit. Write and let point from the minus side to the plus side. Let be the actual interface speed in direction . A signed level function with the plus side obeys on the interface. For , the singular time derivative is ; the singular reference divergence of is . Thus a local conservation law bounded sources has the Rankine-Hugoniot condition
This is also the shrinking moving-pillbox calculation of the global law: finite volume supplies have no surviving surface term.
To match the displayed positive-sign momentum jump in the paper, use its speed parameter as , so the interface travels in direction . Assuming continuous and no surface force or energy supply, the jump laws are then
and, from ,
The last inequality is nonnegative entropy production concentrated on the interface. Temperature and flux in the entropy term are the traces on their respective sides; one cannot take a common temperature outside the jump unless it is continuous.
If is instead defined as the interface speed in direction , all three terms above acquire a minus sign. In particular the printed positive-sign momentum formula requires the opposite speed convention; changing just the order of the jump does not remove this convention issue. If reference density is discontinuous, replace by the jump of the complete conserved density.
An equivalent internal-energy jump follows by subtracting the kinetic-energy jump using , where :
The averaged traction appears because ; using a one-sided traction would generally be incorrect.
Universality means that systems with different microscopic interactions can have the same asymptotic critical behaviour. Under renormalization-group flow, irrelevant microscopic differences shrink, and systems whose critical flows approach the same renormalization-group fixed point belong to one universality class. Important determinants are spatial dimension, order-parameter symmetry and number of components, the range of interactions and any additional relevant constraints. Microscopic Bravais lattice shape alone does not normally change the short-range scalar universality class.
Critical exponents, properly normalized scaling functions and certain dimensionless amplitude ratios are universal within a universality class. For example, the universal specific-heat amplitude ratio compares the two singular amplitudes above and below the transition, canceling their common normalization factors. Scaling functions require choices of thermal, field and length metric factors before comparisons between microscopic systems make sense. The critical temperature, critical field, Bravais lattice spacing, individual correlation-length and magnetic susceptibility amplitudes, and analytic free-energy backgrounds are not generally universal. Thus two models can share critical exponents without sharing their transition temperature or the absolute size of their response.
Let , and suppose with while and remain finite at the transition. Critical exponents describe the leading singular powers: below the transition, , , , , and .
The quartic equation of state immediately gives at zero field below the transition, so . Differentiating with respect to the conjugate field gives , which is above and below; therefore . At , with its real sign, giving . The quadratic correlation function has and critical Ornstein--Zernike correlation function proportional to , giving and .
Finally the minimized potential below the transition is , while it is zero above. Its second temperature derivative is a finite step, so the mean-field heat-capacity critical exponent is . In particular,
These are derived mean-field critical exponents. In the fluctuation-dominated critical region of a phase transition, one instead derives exponents from the scaling eigenvalues of the renormalization-group fixed point, as in the next question. A zero heat-capacity power exponent can also accompany logarithms in other theories, so specifying the power alone does not completely describe that singularity.
A tricritical point occurs when the continuous and first-order transition lines meet. In the symmetric sextic Landau free energy this requires tuning two coefficients, , while stabilizes the potential. For , the zero-field transition lies on and is continuous. For , the coexistence curve is . The order-parameter jump satisfies and shrinks to zero as the tricritical point is approached. The labelled phase diagram below uses as local coordinates; two independent physical controls, such as temperature and composition, can provide these coordinates.
Along the tricritical tuning , the equation of state is . At zero field the ordered solution is , and the critical isotherm has . The inverse magnetic susceptibility is above and below. The minimized singular potential is below, so differentiating twice thermally gives a singularity. These calculations give
The correlation-length and correlation-function exponents follow from the same quadratic gradient term. A generic path with a nonzero positive quartic coefficient instead has ordinary critical behaviour; observing tricritical powers requires the extra tuning. The sextic coupling is marginal in three dimensions, giving tricritical upper critical dimension three and logarithmic corrections there.
Figure 1.
Zero-field sextic Landau phase diagram with continuous and first-order boundaries meeting at the tricritical point, and dashed spinodal limits
. Details.
Let be the observation time and normalize temporarily. In pure radiation domination, and . With , the proper speed is . Put in the preceding integral. Since ,
The small- limit is , the radiation-era particle horizon. For , the ratio is approximately , retaining the distance accumulated while the particle was faster.
There is a normalization qualification: in arbitrary fixed comoving coordinates the distance is , . The expression just derived is also the physical distance at observation. Thus it equals a comoving distance only when is used, as in the preceding part. To express it in today's convention , multiply by . This is the accumulated free-streaming distance in a radiation-dominated universe.
Write , where here is the dimensionless present Hubble constant. The supplied equality redshift gives , and . For the requested dimensionless ratio is
The Hubble rate in this formula is the radiation-era extrapolation used in deriving it. A unique numerical ratio cannot be chosen without .
The printed CMB temperature contains a factor-of-ten error. Its means , whereas the cosmic microwave background temperature in energy units is about , corresponding to . The temperature is supported by NASA's CMB measurements. Using the printed value gives ; using the corrected value gives . For the illustrative choice , so , these give respectively and , and distance-to-Hubble-radius ratios about and . This benchmark is an assumption for the estimate, not an extra parameter supplied by the paper.
For the present-day comoving length, use , the radiation contribution extrapolated to equality. Restoring for the conversion and using gives
For the same benchmark, this is about using the printed temperature and using the corrected temperature, in the prescribed representative-momentum radiation-era model.
At equality matter is no longer negligible, so these are transition-era estimates. The actual total is ; inserting it in the simple normalization would lower the length by , but would not constitute an exact integration through equality. An exact matter-plus-radiation treatment instead replaces the radiation integral by
with in the assumed model. This makes the order-one equality correction explicit. Real neutrino physical momenta in an FRW universe are distributed and their temperature need not equal the photon temperature; the calculation above follows the specified idealization.