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The heat capacity at constant pressure is $C_p=(\delta Q/\partial T{)}_p=T(\partial S/\partial T{)}_p$ for reversible heat input. The enthalpy is $H=U+pV$, so $dH=TdS+Vdp$. Along an isobar this gives $\boxed{C_p=(\partial H/\partial T{)}_p}$.

For a simple system of fixed composition, the first law of thermodynamics andgiveThusEquality of mixed derivatives gives the Gibbs free-energy Maxwell relation

The heat capacity at constant volume and heat capacity at constant pressure areRegarding $S$ as a function of $T,V$ and differentiating along a constant-pressure curve givesThe Maxwell relation from the Helmholtz free energy isTherefore the difference between constant-pressure and constant-volume heat capacities is

Along the liquid-gas phase coexistence curve, the molar Gibbs free energies agree. Differentiating $G_{\mathrm{l}}=G_{\mathrm{g}}$ along the curve givesHence the Clausius-Clapeyron relation iswhere $L=T(S_{\mathrm{g}}-S_{\mathrm{l}})$ is the molar latent heat.

If $V_{\mathrm{g}}\gg V_{\mathrm{l}}$ and the gas is ideal, then $V_{\mathrm{g}}=RT/P$, soFor constant $L$, integration yieldswhere $P_0$ is constant over the range in which the approximations apply.

Heat enters only during the constant-pressure step, so the heat capacity at constant pressure givesThe positive magnitude of the heat rejected during constant-volume cooling isBecause the working gas returns to its initial state, the thermodynamic cycle has zero net change in internal energy and $W=Q_1-Q_2$. Its thermal efficiency is therefore