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In 1977, H. Jeff Kimble, Mario Dagenais, and Leonard Mandel excited a dilute sodium atomic beam with a resonant dye laser. Apertures restricted the observed atoms; a microscope objective collected fluorescence perpendicular to both beams. A beam splitter sent the collected light to two photomultipliers. Shaped pulses drove the start and stop inputs of a time-to-digital converter; its delay histogram rose away from zero delay, indicating photon antibunching. Turning the atomic beam off measured scattered-laser backgrounds. More than one contributing atom and scattered light limited the comparison with an ideal isolated two-level system; the paper explicitly treated corrections.^[ref]

A simple reason for suppressed immediate re-emission is visible in an ideal two-level system. After spontaneous emission, the atom is in $|g⟩$. Its emission operator ${\sigma }_{-}=|g⟩⟨e|$ obeys ${\sigma }_{-}^2=0$, so two instantaneous emissions are impossible. Excitation must rebuild the excited-state population before another emission. This argument explains the zero-delay idealization; the actual photon counting record additionally depends on collection, background, timing, and the number of contributing atoms.

A retroreflector returns incident light approximately toward its source. Corner-cube arrays make the lunar laser ranging round trip possible.

Wilhelm Conrad Röntgen's 1895 first communication describes an induction coil driving an evacuated gas-discharge tube, enclosed in black cardboard in darkness. A paper screen coated with barium platinocyanide showed fluorescence even with its uncoated side facing the tube, visible two metres away. The covering excluded ordinary illumination.^[ref]

He interposed materials: a thousand-page book transmitted; $1.5\mathrm{mm}$ lead was practically opaque. A stepped stack of foil produced a photographic plate record. Different materials were not equivalent at equal density and thickness. Photographic plates checked visual observations while remaining covered against ordinary illumination.^[ref]

Section 14 lists photographs of hand bones, wire on a bobbin, boxed weights, an enclosed compass, and a lead-painted door. It does not identify the hand's owner. Magnetic deflection moved the cathode ray impact point and thus the source, without bending the emerging X-rays. Their nature remained unsettled.^[ref]

The observations belong to 1895; the contemporary English translation appeared in Nature on 23 January 1896.^[ref] The experimental logic separates production, transmission and detection. A visibly opaque covering can transmit X-rays; fluorescence then converts deposited energy into visible light. A shadow measures a difference between paths through an object, rather than a direct view of its surface. Neither a screen's brightness nor photographic darkness alone measures an absolute X-ray energy or establishes the X-ray attenuation law below.

A rotary encoder converts shaft rotation into a readout of angle or changes in angle. The PS-2120A uses interruptions of a light beam to encode shaft motion; its product specification gives 4000 divisions per revolution. That count is a resolution specification, not a guarantee of the precision of an inferred angular acceleration or moment of inertia. ^[ref]

The ruby pressure scale converts a shift of a ruby fluorescence spectral line into pressure. Excitation light produces a fluorescence emission spectrum; fitting its $R_1$ line gives a wavelength ${\lambda }_{R_1}$. The reference ${\lambda }_{R_1,0}$ must be measured or assigned at specified reference pressure and temperature. The difference $\Delta \lambda$ is an observable; interpreting it as pressure requires a pressure calibration and suitable stress conditions.

The original 1972 report found sharp $R_1,R_2$ emission shifting toward lower photon energy as pressure increased; it tentatively associated broadening with nonhydrostatic conditions.^[ref] In use, excitation rejection, a calibrated wavelength axis and a fitted background matter because leakage or background can move an apparent peak. A brighter trace improves counting statistics but does not alone establish a correct pressure scale.

For a rigidly rotating prescribed vacuum path, use spatial coordinates attached to the apparatus and laboratory time $t$. At a path point $\mathbf{r}$, the local apparatus velocity is $\mathbf{v}=\mathbf{\Omega }\times \mathbf{r}$. A light displacement has instantaneous laboratory displacement $d\mathbf{r}+\mathbf{v}dt$, up to the common rotation of the spatial axes. The null condition is thereforeWrite $d\ell =|d\mathbf{r}|$. To first order in $|\mathbf{v}|/c$, the positive root isReversing the path reverses the dot product term but leaves the leading path-length term unchanged. Subtract the two return times and use the scalar triple product identity:This is a line integral version of the Sagnac area law; the vector area identity also follows from Stokes theorem. For a mirror-defined polygon the actual ray paths move slightly as the mirrors rotate; the stationary optical path at zero rotation gives the same first-order result. The prescribed-path calculation is an idealization, not an exact finite-speed formula for every moving-mirror layout.

The dot product explains the geometry: only the projection of the oriented vector area along the angular velocity contributes. A planar loop whose normal vector is perpendicular to $\mathbf{\Omega }$ has zero leading delay. For repeated traversals with the same orientation, the signed vector areas add; oppositely oriented lobes can cancel even when the total unsigned area is large. Equal perimeter alone does not imply equal response. A constant translational velocity contributes nothing to this leading closed-path line integral, since ${\oint }_{C}d\mathbf{r}=0$.

The Sagnac effect is a difference in return times, or an associated interference fringe displacement, for light sent in opposite directions around a closed optical path in a rotating apparatus. The light leaves one beam splitter, travels around the same loop in opposite senses, and returns to the rotating beam splitter and readout. For a slowly rotating apparatus in flat spacetime, the leading laboratory arrival-time difference isHere $c$ is the vacuum speed of light, $\mathbf{\Omega }$ is the apparatus's angular velocity relative to an inertial frame, and $\mathbf{A}$ is the vector area oriented by the chosen positive direction around the closed curve $C$. With positive rotation about the upward normal vector, the counterclockwise beam is labelled $+$ and arrives later. Reversing rotation, or reversing the orientation convention alone, changes the sign of $\Delta t$.

The surprise is that a small loop can reveal its rotation by comparing two beams locally, even though each local vacuum speed of light measurement gives $c$. A rotating reference frame is not a single inertial frame: a beam must catch the moving receiver after a full circuit. The Sagnac area law makes this difference a practical way to measure angular velocity, while the Relativistic Sagnac delay on a circular ring distinguishes laboratory coordinate time from the receiver's proper time.

A Sagnac interferometer uses a beam splitter to send light with optical coherence around a common closed optical path in opposite directions, then recombines the beams to read their phase difference. Mirrors or a guiding path define the loop; the source, beam splitter, loop and readout rotate together in the basic experiment. A small relative beam tilt makes spatial interference fringes whose displacement reveals a change of phase difference. At one fixed output, a photodetector can instead record the corresponding change in light intensity.

Arthur Leonard Schawlow's 1981 lecture describes an external-cell arrangement: a beam splitter makes opposed beams, an optical chopper interrupts the pump, and a lock-in amplifier reads the probe detector with the chopper reference. Pump-on reduces absorption and raises the detector signal; scanning the laser finds the narrow resonance. Its first application used iodine; pressure and laser jitter limited the resolution.^[ref]

For an original detector model, let $P_0$ be the probe power reaching a photodetector without sample attenuation and let ${\tau }_{\mathrm{off}},{\tau }_{\mathrm{on}}$ be the sample's probe optical depths. After subtracting a stable detector background, the transmitted powers areA positive synchronous change means less probe photon absorption, provided incident probe power is stable and scattered pump light is excluded. For small optical-depth changes the fractional signal is approximately ${\tau }_{\mathrm{off}}-{\tau }_{\mathrm{on}}$. A lock-in amplifier's voltage also depends on gain, reference phase and chopping waveform; it is not automatically this dimensionless ratio.

Useful controls are blocking the pump, detuning far from the feature, reversing or adjusting beam alignment, and repeating the scan at several pump light intensities. Frequency calibration, sample pressure, transit through the beams and laser frequency fluctuations must be assessed separately. Nearly opposed beams leave a residual Doppler shift: for wave vectors ${\mathbf{k}}_1,{\mathbf{k}}_2$, the simultaneous-resonance condition gives $2\delta =({\mathbf{k}}_1+{\mathbf{k}}_2)\cdot \mathbf{v}$. Exact opposition removes this transverse sensitivity in the first-order model.

Scalar diffraction theory approximates light by one complex field satisfying a scalar wave equation. Aperture propagation is represented by an integral of secondary contributions, with vector polarization of waves and detailed electromagnetic edge conditions suppressed. The approximation is useful for many apertures large compared with wavelength, but is not an exact substitute for Maxwell equations at arbitrary apertures.

An actual teaching experiment in LM-0300 Fabry Perot Spectrum Analyser by Walter Luhs, §§3.1.1–3.1.2, prepares a green laser beam by aligning it near and far along a rail, then centring back-reflected light from adjustable curved mirrors. An actuator using piezoelectricity moves one mirror. A screen first displays interference fringes; a focusing optical lens and photodiode then replace the viewing arrangement. The oscilloscope records the photodiode signal and the piezo drive reference on separate channels, using the latter as its trigger. Alignment and mirror separation are adjusted to suppress extra transverse normal modes; source temperature and drive electric current are controlled. Repeated peaks calibrate the scan using the appropriate free spectral range, and their spacing divided by their full width at half maximum estimates finesse.^[ref]

This experiment uses a confocal curved-mirror cavity, whose repeated peak families can have spacing $c/(4d)$ in air; it must not be calibrated blindly with the parallel-mirror $c/(2d)$. Extra transverse normal modes can mimic source features. A finite measured peak width bounds source sharpness only after instrumental broadening is considered; it does not determine the source's intrinsic width by itself.^[ref]

For an independent ideal scan calculation, hold a narrow laser wavelength fixed and vary the parallel-mirror gap $d$ at normal incidence. Advancing one resonance order requires $\Delta d=\lambda /(2n)$. If $d$ changes uniformly over the measured interval, the time between repeated peaks divided by their full width at half maximum in time equals finesse. The cancellation of scan rate follows from $d(t)=d_0+vt$: both peak spacing and peak width are divided by the same $|v|$. It fails if the scan rate changes appreciably over that interval. A practical control in the University of Washington's motor-driven flat-mirror experiment is to check that successive peaks are equally spaced before using the time axis this way; its handout also warns that table strain and aggressive low-pass filtering alter the trace.^[ref]

A brief flash of light produced when an energetic particle deposits energy in a material. Counting resolved flashes can count individual incident particles; this differs from atmospheric scintillation.

Consider an original, explicitly normalized model of primary coma, rather than a prescription for a particular optical lens. Let $(u,v)$ be Cartesian coordinates in a circular optical pupil divided by its radius $a$, with $u^2+v^2\le 1$. Let $h=\alpha /{\alpha }_0$ be a signed small field angle divided by an arbitrary positive reference angle. With polar coordinates $u=\rho \cos \theta$, $v=\rho \sin \theta$, prescribe the wavefront errorHere $W_0$ is an arbitrary positive optical path difference scale, not a measured error. The cubic optical pupil dependence and linear field dependence are the classical Seidel form.^[ref]

In the paraxial approximation, light ray direction errors follow the transverse gradient of wavefront error. For a reference sphere a distance $L$ from the exit optical pupil in a uniform image medium of refractive index $n$, the corresponding image-error scale is $s=L{W}_0/(na)$. Choose image-error coordinate signs so the normalized displacement is $\nabla w$; reversing the convention reverses the plotted orientation. Image coordinates below are errors relative to the ideal image of this particular object point, rather than positions of different objects:The partial derivatives explain the asymmetry: opposite optical pupil points $(u,v)$ and $(-u,-v)$ land together, rather than on opposite sides of the ideal image. For $h>0$, every $X$ is nonnegative, while $Y$ can have either sign. The figures stipulate this single wavefront error, omit other optical aberrations and diffraction, and assign no instrument dimensions.

For a ring of fixed optical pupil radius $\rho$, the double-angle formulas for trigonometric functions giveThus each ring maps into a circle of radius $|h|{\rho }^2$ whose centre is displaced by $2h{\rho }^2$. Doubling $\rho$ quadruples both sizes; for $h=1$, the edge ring has centre $(2,0)$ and radius $1$, while the half-radius ring has centre $(1/2,0)$ and radius $1/4$. Superposing these displaced circles produces the comet-like envelope.

For uniform irradiance over the circular optical pupil, equal area samples give an equal-weight geometrical image. Its centroid is $(h,0)$ because $⟨u^2⟩=⟨v^2⟩=1/4$ and $⟨uv⟩=0$. Moving the coordinate origin to that centroid translates the image; it does not remove its asymmetric shape. Adding a linear term to $w$ likewise translates all light rays equally. These origin choices must be distinguished from changing the optical aberration itself.

The model's full transverse extent is $3|h|$ along $X$ and $2|h|$ along $Y$. Halving the field angle halves the blur, and reversing it reverses the pattern about the ideal image. This isolates why coma matters for an optical camera's usable field of view: collecting more light does not ensure that off-axis points remain compact. Near diffraction-limited resolution, a physical optics calculation of the point spread function is needed instead of interpreting the geometrical tip as an infinitely sharp image.^[ref]

MIT's guide uses an illuminated vacuum photodiode, with collecting anode positive relative to the emitting cathode. A transimpedance amplifier gives $V_1=R_{F}I$; a multimeter reads its mean. The fluctuation path rejects below $100\mathrm{Hz}$, adds roughly tenfold voltage gain, then nominal hundredfold preamplification and a $1$–$50\mathrm{kHz}$ band-pass filter; the readout measures root mean square voltage. With diode bias off, a sinusoid at the test port calibrates $g(f)$. Restore bias, retain gain settings, vary lamp brightness, and repeat both readings. The guide warns about overload; it supplies a procedure, not measured results.^[ref]

The inference can be expressed without relying on nominal passband edges. Let $g(f)$ denote the calibrated voltage transfer after the $R_F$ conversion, so $K(f)=R_{F}g(f)$ and define $\mathcal{K}={\int }_0^{\infty }|K(f){|}^{2}df$. Under independent arrivals and an unchanged additive background,The slope of voltage variance against mean electric current can therefore estimate $q$. A free intercept accounts for a constant background; forcing the line through zero generally biases the slope. The root mean square readings must have their mean removed and then be squared. Subtracting two root mean square amplitudes does not subtract independent variances. Estimate the variance from successive records; averaging the waveforms first would suppress the fluctuation being measured.

Additional controls sharpen this interpretation. Block the light with detector bias, temperature, and gain unchanged; this preserves dark current and electronics while removing photocurrent. Repeat this dark comparison between illumination settings to check drift. If independent dark arrivals have mean magnitude $I_d$ and illuminated arrivals add $I_{\mathrm{ph}}$, their spectra add: $2q(I_d+I_{\mathrm{ph}})$. Subtracting the unchanged dark variance isolates $2q{I}_{\mathrm{ph}}\mathcal{K}$. This subtraction model assumes unchanged transfers and independence; switching off bias for gain calibration is a different control and need not preserve the dark background.

Vary measured $I_{\mathrm{ph}}$ rather than assuming lamp knob position is proportional to photocurrent. Check collection versus bias to identify a range where incomplete collection is negligible; a space charge limited tube can correlate transfers. Verify that the transimpedance amplifier remains linear and that its frequency response is unchanged over the illumination range. Changing signal bandwidth should change the excess variance through $\mathcal{K}$; compare inferred input spectra in several bands. Correlated fluctuations of the light source can add a contribution scaling approximately as $I_{\mathrm{ph}}^2$, while an electronics floor can hide the linear term at small electric currents. A fitted line over a short range alone does not establish independent transfers.

The gain calibration must include the same detector-to-readout path used for noise, or explicitly supply any omitted transfer. Detector capacitance, finite collection time, amplifier voltage and current noise, thermal electrical noise, pickup, clipping, and finite recording precision limit the inference. Current-dependent electrical impedance or heating can make a background current-dependent too. Since $\mathcal{K}$ contains squared gain, a small fractional error in gain produces approximately twice that fractional error in the predicted variance scale. Knowing a nominal gain and two cutoff settings is insufficient.

Single-slit diffraction is the spreading of light transmitted by one slit. Consider an ideal rectangular slit of width $a$, illuminated normally by a uniform plane wave with a single wavelength $\lambda$ in the surrounding medium. This monochromatic wave has uniform wave amplitude and equal incident wave phases across the slit, providing the required optical coherence. In the scalar Fraunhofer diffraction model, the normalized angular wave intensity isHere $\theta$ is measured from the forward normal in the plane across the slit width. The sinc function uses the unnormalized convention $\mathrm{sinc}u=\sin u/u$. The limit makes the central value one. This ideal envelope neglects additional direction-dependent propagation and detector factors; near the forward direction it describes the normalized screen irradiance. ^[ref].

The noncentral zeros satisfyThe restriction follows from the range of the sine of a real angle. The first minima have $\sin \theta =\pm \lambda /a$ when $\lambda /a\le 1$. If $a<\lambda$, this model has no noncentral zero in the forward hemisphere; equality puts the first zeros at grazing directions, outside the small-angle approximation and off any finite perpendicular screen. ^[ref].

For $0<\lambda /a<1$, define the central width as the separation between the two first minima. Its angular width and its width on a perpendicular screen areThe angular approximation uses radians and requires $\lambda /a\ll 1$; the screen approximation uses $y\approx L\theta$. The tangent relation is exact straight-line geometry, even though the underlying Fraunhofer diffraction field is approximate. This width is distinct from the full width at half maximum.

For $\lambda =500\mathrm{nm}$, $a=0.1\mathrm{mm}$ and $L=1\mathrm{m}$, the positive first minimum isThe dimensionless far-field parameter is $a^2/(\lambda L)=0.02$. Doubling the slit width to $a=0.2\mathrm{mm}$ gives $W\approx 5.00002\mathrm{mm}$ and parameter $0.08$; both curves below use the Fraunhofer diffraction approximation. Choosing $L=2\mathrm{m}$ halves those parameters and doubles both screen widths.

Each curve is normalized to its own $I_0$; the arrows measure between first minima. The calculation uses $\theta =\arctan (y/L)$ before evaluating the sinc function, rather than replacing $\sin \theta$ by $y/L$. The lower diagram shows the exact screen geometry with the vertical scale enlarged. Normalization removes the change in peak brightness when the slit width changes.

The wave interference explanation is especially simple: divide the slit into equal narrow strips and add their complex amplitudes, rather than their wave intensities. With wavenumber $k=2\pi /\lambda$, the continuous slit givesIntegrating the complex exponential gives the endpoint difference; its continuous value at zero is one. Taking the squared complex modulus gives the stated wave intensity. This is the Fourier transform of an interval indicator expressed in angular coordinates. Feynman's continuous-source argument obtains the same pattern by letting the number of sources tend to infinity. ^[ref].

At the positive first minimum, the wave phases span exactly $2\pi$ across the slit. Every strip in one half has a partner $a/2$ away, with equal wave amplitude and phase difference $\pi$, so the pairs cancel. At $\theta =0$, all the wave phases align instead. ^[ref].

The drawing uses $N=8$ equally weighted midpoint samples $x_j/a=-1/2+(j+1/2)/8$, with $j=0,\dots ,7$. At the first minimum their complex amplitudes are a common rotation of the eight roots of unity, so their head-to-tail polygon closes exactly. This finite sum illustrates cancellation; the continuous integral, rather than eight point sources, defines the slit pattern at general angles. The circle shows the continuous range of wave phases; coloured arrows show the eight samples.

A narrower aperture requires a larger angle to accumulate the cancelling phase difference, so narrowing the slit widens the beam. This is a useful limit on geometrical optics: confining light more tightly at an opening increases its subsequent angular spread. At fixed incident irradiance and slit height, reducing $a$ also reduces transmitted power, exposing a practical balance between diffraction-limited resolution and light throughput. In a diffraction grating, this single-slit diffraction envelope modulates the wave interference between different slits.

A solar cell converts incident light into electrical power through the photovoltaic effect. A semiconductor p-n junction separates and collects photogenerated electrons and electron holes. An ideal illuminated junction has output current densityHere $J_{\mathrm{sc}}$ is the short-circuit current density, $J_0$ is the diode saturation current, and $V_{\mathrm{oc}}$ is the open-circuit electric potential difference. The conversion efficiency is the largest delivered $VJ$ divided by the incident power per unit area; the short-circuit and open-circuit operating points themselves deliver zero power.

Spatial optical coherence compares field samples at different positions, usually across a transverse plane at equal time. Two small openings separated by $d$ sample this correlation: recombine their light with nearly matched travel times and measure interferometric visibility near the central interference fringes. A narrow opening in front of a broad-spectrum lamp can improve transverse spatial optical coherence while leaving its short temporal optical coherence. These are separate controls: narrow spectral selection by itself need not make an extended source spatially coherent. MIT's lecture notes illustrate the two-opening test and these contrasting source preparations. ^[ref].

To isolate source width, stipulate a distant, narrowband source with uniform angular brightness on $-\Theta /2\le \alpha \le \Theta /2$, and mutually uncorrelated emission from distinct source directions. Here $\Theta \ll 1$ is the full angular width in radians, $\lambda$ the common wavelength, and the two openings are separated by $d$ along the same transverse direction as the source extent. Neglect amplitude differences across the openings. Each source direction contributes a phase difference approximately $2\pi d\alpha /\lambda$. Averaging its complex cross term givesThe sinc function is extended continuously to one at $q=0$. The sign convention in the exponential depends on which opening is numbered first; the symmetric model gives the same real result either way. Equal detected single-opening light intensities make the magnitude equal to interferometric visibility. A displaced source center adds a deterministic wave phase, shifting the interference fringes without changing their contrast.

The strips show $I/(I_1+I_2)=1+g_{12}^{(1)}(0)\cos \varphi$ with equal single-opening light intensities, a common phase difference coordinate $\varphi$ and no single-slit diffraction envelope. At $q=1/2$, contrast is $2/\pi \approx 0.636620$; at $q=1$, it vanishes. At $q=3/2$, the correlation is $-2/(3\pi )\approx -0.212207$: weak fringes return with bright and dark positions exchanged. For $\lambda =500\mathrm{nm}$ and $d=0.5\mathrm{mm}$, the first zero occurs at $\Theta =1\mathrm{mrad}$. This is a calculated example, not an experimental measurement or a universal source-width law.

A proposed source-width control follows directly from this model: illuminate two fixed openings with a distant adjustable luminous slit of full width $w$ at distance $R$, so $\Theta \approx w/R$ under the small-angle approximation, and hold $d$ and the spectral selection fixed. Increasing $w$ overlays more mutually incoherent, displaced interference fringe patterns. Record profiles over several near-central fringes, measure each opening separately and correct intensity imbalance as in first-order optical coherence. Restrict the recorded region so the path difference stays small compared with the optical coherence length, and resolve the fringes with the detector. Real source nonuniformity, finite opening widths and spectral spread modify the stipulated sinc function law. This protocol is a model-based extension of the verified two-opening method, not a claim that the plotted curves were measured.

Thus an extended incoherent source can give locally excellent wave interference when the sampled separation is small, and almost none when it is larger. The useful scale $d\Theta \sim \lambda$ expresses how source extent limits the aperture over which coherent addition is available. The same angular averaging explains why narrowing a source opening can recover visible interference fringes, even without narrowing its optical spectrum.

Spectrophotometry measures received light as a function of wavelength, accounting for the instrument's wavelength-dependent response.

At a smooth mirror with unit normal vector $n$, an incoming unit direction $i$ has outgoing direction $i-2(i\cdot n)n$. Thus the incident and reflected rays make equal angles with the normal.

More precisely, specular reflection redirects each incident light ray into the direction prescribed by the law of reflection, rather than spreading it over many outgoing directions. The incident light ray, reflected light ray, and local normal vector lie in one plane. The surface must be sufficiently smooth on the scale of the wavelength for this model to describe its reflected beam; a visibly flat surface can still scatter light if its microscopic roughness is appreciable. ^[ref].

The displayed formula uses unit vectors $\mathbf{i},\mathbf{n},\mathbf{r}$ and the dot product. It preserves the component parallel to the mirror and reverses the normal component. For a mirror along $y=0$, take $\mathbf{n}=(0,1)$ and $\mathbf{i}=(3/5,-4/5)$. Then $\mathbf{i}\cdot \mathbf{n}=-4/5$ and $\mathbf{r}=(3/5,4/5)$: both directions have vector norm one, and both make an angle $\arccos (4/5)\approx 36.87^{\circ }$ with the relevant normal direction. Replacing $\mathbf{n}$ by $-\mathbf{n}$ leaves the result unchanged.

This same local rule explains a flat mirror's virtual image. For a source at $(0,a)$ above $y=0$, backward extensions of reflected light rays intersect at $(0,-a)$. The light remains above the mirror; its apparent origin lies below it. A curved mirror changes its normal vector from point to point and can instead make reflected light rays converge. The geometry of image formation therefore starts with one simple direction rule. ^[ref].

// Target: optics.bigb

In 1913 Johannes Stark reported that an applied electric field resolved the hydrogen $H_{\beta }$ and $H_{\gamma }$ spectral lines into five components at his instrument's spectral resolving power, viewed perpendicular to the electric field. Three inner components had polarization of an electromagnetic wave perpendicular to the electric field; two outer components had it parallel.^[ref]

In his lecture of 3 June 1920 for the 1919 prize, Johannes Stark describes canal rays emerging through a perforated cathode into the electric field between it and a supplementary electrode. A spectrograph recorded the emitted light. His earlier Doppler effect comparison used a collimator perpendicular to the beam and then along approaching rays. Later beam/electric field reversal changed component intensities.^[ref]

The historical account distinguishes observation perpendicular to the electric field, with five resolved components, from observation parallel to it, with three. These are viewing directions, distinct from the direction of the polarization of an electromagnetic wave.^[ref]

The experimental distinctions matter. Changing the viewing direction tests a Doppler effect contribution; changing the applied electric field tests the Stark effect; analyzing polarization of an electromagnetic wave separates components that may overlap in an unpolarized record. A comparison with the unperturbed spectral line fixes the origin of a displacement. These are different controls, and the earlier Doppler effect comparison should not be described as a field-off control of the later discovery. A spectrograph's finite spectral resolving power can merge several components into one. In particular, a count of visible spectral lines does not by itself count all energy eigenstates.

For a modern idealization of the gap, an electric potential difference $\Delta V$ over separation $d$ gives $|\mathcal{E}|\simeq |\Delta V|/d$ only if edge effects and the charge density in the gas are negligible. This is a calibration model, not a historical value assigned to Stark's apparatus. Similarly, a canal ray beam need not be a pure beam of neutral excited hydrogen atoms; the quantum mechanics model below isolates one neutral hydrogen atom from the source's preparation and collision processes.