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An Abrikosov vortex has a core where the superconducting order parameter is suppressed, surrounding circulating electric currents, and a winding of its quantum phase. A singly wound vortex carries one superconducting flux quantum in the appropriate bulk flux-quantization limit. The exact contour statement is fluxoid and flux quantization in a superconductor; the enclosed magnetic flux alone need not equal a flux quantum on a contour with appreciable electric current.

An atomic clock uses an atomic transition as a frequency reference for an oscillator; counting its calibrated cycles realizes a time interval. In a passive beam implementation, the chemical atoms are repeatedly prepared, interrogated and detected, while feedback control corrects the continuously running oscillator. The Ramsey separated oscillatory fields experiment explains how internal quantum phase becomes a measurable population signal.

The SI second fixes the unperturbed ground state hyperfine structure transition frequency of caesium-133 to exactly $9192631770\mathrm{Hz}$. This is a defining value for the ideal transition, rather than a guarantee that an operating apparatus has no shifts.^[ref]

A narrow fringe makes the center easier to resolve statistically; it does not certify an unbiased frequency. For example, with ideal $\pi /2$ pulses and a second-pulse oscillation phase offset ${\phi }_c$, the finite-pulse Ramsey transition probability approachesThis sign uses exactly the Rabi detuning convention and pulse Hamiltonian operator above, with the second pulse replacing ${\sigma }_x$ by $\cos {\phi }_c{\sigma }_x+\sin {\phi }_c{\sigma }_y$. The factor $2\pi$ converts angular frequency to ordinary frequency. For the original example, ${\phi }_c=0.010$ rad and $T=5\mathrm{ms}$ give a shift of about $-0.318\mathrm{Hz}$. For finite pulses or distributed flight times, use the full signal and its atomic clock frequency lock rather than inserting an unweighted mean $T$.

NIST-7 used optical pumping and fluorescence. Controls included field-sensitive transitions, independent beam-speed measurements, microwave power stabilization, and beam reversal for cavity quantum phase errors.^[ref]

The connection to special relativity is quantitative. A freely moving emitter's proper time advances more slowly than laboratory time by $\sqrt{1-v^2/c^2}$. With first-order propagation effects removed in the ideal comparison, its internal laboratory frequency is thereforeCorrecting an ensemble signal requires the effective velocity weights of preparation, interrogation and detection, not simply the oven's mean speed. Additional shifts from Zeeman splitting, unwanted light, collisions and cavity fields likewise require separate evaluation; feedback control locks to the observed line, including any uncorrected bias. Comparing clocks at different gravitational potentials additionally requires gravitational time dilation. The moving-clock experiments in twin paradox clock experiments compare calibrated clock readings along different world lines; the beam atoms' internal motion is part of the clock mechanism's own correction.

An atomic orbital is a one-electron spatial wavefunction used to describe an electron's state in a chemical atom. For a one-electron hydrogen atom, orbitals can be exact energy eigenstates; descriptions of many-electron atoms instead use an orbital approximation. A normalized atomic orbital has $\int |\varphi {|}^2{d}^3\mathbf{r}=1$, and the Born rule gives the position probability density $|\varphi {|}^2$. It is a function extending through space, not a prescribed classical orbit. ^[ref]

The linear combination of atomic orbitals combines these single-centre functions to approximate a molecular orbital. The orbital overlap measures their inner product, and their relative quantum phase controls the interference shown in molecular orbital theory.

The Bernstein-Vazirani algorithm identifies the coefficient string of a linear Boolean function with one Boolean quantum oracle call. It contrasts with the $n$ calls required by the classical query complexity of linear Boolean function identification. Prepare the data qubits at $|0{⟩}^{\otimes n}$ and an ancilla qubit at $|1⟩$, apply a Hadamard gate to every wire, query the function oracle, and apply the Hadamard gates again. The full output is $|a⟩|1⟩$.

The mechanism is Bernstein-Vazirani phase kickback. The Pauli X gate has eigenvector $|-⟩=(|0⟩-|1⟩)/\sqrt{2}$ with eigenvalue $-1$. Thus the target flips become relative quantum phases on the data, givingThe final Hadamard transform maps this product to $|a⟩$, so computational-basis measurement recovers every coefficient with certainty. The ancilla preparation for the Bernstein-Vazirani algorithm ensures the required minus sign, and the Hadamard-conjugated linear oracle gives an exact quantum circuit interpretation. One query is optimal for $n\ge 1$, since without a query the output cannot depend on the unknown string.

A Berry phase is the geometric phase acquired when a nondegenerate energy eigenstate follows a closed cycle of parameters of a Hamiltonian operator in the ideal limit of the adiabatic theorem. The energy eigenstate must stay separated from other energy eigenstates by a nonzero spectral gap, and the parameters must change sufficiently slowly. Returning the Hamiltonian operator to its starting value returns the state to the same ray, but its quantum phase can remember the journey. The total quantum phase contains both the dynamical phase and the Berry phase.

The beauty of the Berry phase is that, within the adiabatic theorem's limit, it depends on the oriented path of the parameters rather than how long the journey takes. For a spin one-half qubit, the Berry phase of a Bloch-sphere latitude turns that memory into half a solid angle. Berry-phase interference with a reference path converts this geometry into a detection probability.

Michael Berry's 1984 paper formulated the geometric phase for cycles governed by the adiabatic theorem and derived the solid angle result for spin. Its bibliographic details are Proceedings of the Royal Society of London A, volume 392, pages 45–57, DOI 10.1098/rspa.1984.0023. ^[ref]; ^[ref]. The wider concept of geometric phase does not require every cycle to obey the adiabatic theorem: Aharonov and Anandan formulated a geometric phase for general cyclic quantum evolution in 1987. ^[ref].

An isolated qubit that acquires only a global phase has unchanged measurement probabilities. To reveal the Berry phase, use two coherent paths of a Mach-Zehnder interferometer, represented by a path qubit. In one arm the internal spin one-half qubit follows the loop; in the reference arm it stays in its starting energy eigenstate. Assume equal arm amplitudes, identical final internal states, cancelled relative dynamical phases, and calibrated fixed apparatus phases. In the model above, hold the reference Hamiltonian operator at its initial value for the same duration. Both arms then have energy eigenvalue $-\Delta /2$ and acquire the same dynamical phase $\Delta T/(2\hslash )$, so their relative dynamical phase vanishes in the ideal limit of the adiabatic theorem.

The joint quantum state before recombination then factors asThe Berry phase is now a relative quantum phase between the two paths. The calibrated plus output projects onto $|+⟩=(|\mathrm{ref}⟩+|\mathrm{loop}⟩)/\sqrt{2}$. The Born rule givesFor the Berry phase of a Bloch-sphere latitude, the plus-port probabilities at $\theta =0,60^{\circ },90^{\circ },180^{\circ }$ are respectively $1,1/2,0,1$. This ideal Mach-Zehnder interferometer measurement cannot distinguish $\gamma$ from $-\gamma$ or $\gamma +2\pi$ by itself; scanning a known reference phase can resolve the sign. An uncancelled relative dynamical phase would shift the fringe as well.

The Born rule connects a quantum state to measurement probabilities. Let $\{|j⟩\}$ be a complete orthonormal basis, finite or countably infinite, for a Hilbert space, and letAn ideal measurement distinguishing these basis vectors returns label $j$ with probabilityThis assignment is a physical measurement rule. Its compatibility with total probability one follows from orthonormality and normalization:The probabilities are the squared moduli, not the amplitudes themselves or the squares $a_j^2$. ^[ref].

If the basis is an eigenbasis of an observable, the reported numerical value is its eigenvalue. Several vectors can share one eigenvalue; the probability of that value is then the sum over the corresponding basis labels. More generally, a projective measurement with orthogonal projections $P_r$ assignsfor a pure state and a general density matrix $\rho$, respectively. This also covers mixed states and degenerate eigenspaces. The Born rule determines outcome statistics; the ideal conditional state change is specified separately by the Lüders rule. See projective measurement for that formulation and its assumptions. ^[ref].

For a worked example, take the normalized qubit quantum stateThe squared moduli add to $3/4+1/4=1$. A computational-basis measurement, equivalently a measurement of the $Z$ Pauli matrix, hasThese probabilities do not depend on the relative quantum phase $\varphi$. Now choose the Hadamard basiswhose vectors are eigenstates of the $X$ Pauli matrix, also used by the Pauli X gate. The new probability amplitudes and probabilities areBoth probabilities are nonnegative and their sum is one. The relative quantum phase becomes visible because the two probability amplitudes add before their squared modulus is taken:

A Hadamard gate followed by a computational-basis measurement realizes these $X$ statistics, since $H|\pm ⟩=|0⟩,|1⟩$, respectively. Compare the two bases using fresh, identically prepared copies: a preceding measurement may change the state. The quantum superposition section shows why replacing the preparation by the mixed state $\mathrm{diag}(3/4,1/4)$ keeps the $Z$ statistics but gives $p_{+}=p_{-}=1/2$ for every $\varphi$.

The usefulness of the Born rule is this conversion from linear algebra to experimental predictions: calculate overlaps in the basis actually measured, then take squared moduli. Its appealing geometry is that changing basis redistributes probability while preserving total squared norm. The same rule relates an energy eigenstate expansion to an energy measurement and a position wavefunction to a probability density.

Born's 1926 paper on quantum scattering interpreted the outgoing-wave coefficients in terms of the probabilities of collision outcomes; a corrective footnote specified proportionality to the square of the amplitude. This is a historical scattering formulation, rather than the general density matrix formula above. ^[ref]; ^[ref].

A chirped Gaussian wave packet adds a quadratic quantum phase to the zero-mean Gaussian wave packet already evaluated above. Here $\sigma >0$ and $\kappa$ is a real dimensionless parameter. Its probability density function $|{\psi }_{\sigma ,\kappa }(x){|}^2$ is unchanged for every $\kappa$, so $⟨x⟩=0$ and $(\Delta x{)}^2={\sigma }^2$. Nevertheless, applying the momentum operator givesThe sign of the quantum covariance follows directly, without assigning a classical trajectory to the wavefunction:Here $r$ is a normalized symmetrized quantum covariance, analogous to a correlation coefficient. Positive $\kappa$ gives positive $C_{xp}$, and reversing $\kappa$ reverses $C_{xp}$ while leaving both variances unchanged. In the negative-exponent Fourier transform convention used above, the momentum density isConsequently the quantum uncertainty product and the covariance matrix determinant tell different stories:Every member of this pure state family saturates the Robertson-Schrödinger uncertainty relation. Only $\kappa =0$ saturates the Heisenberg uncertainty relation for this fixed pair of position and momentum axes. Thus being a Gaussian wave packet alone does not imply a minimum $\Delta x\Delta p$.

For a concrete comparison, choose a reference length $L$, put $X=x/L$, $P=pL/\hslash$, and set $\sigma =L$. The choices $\kappa =0,+2,-2$ all have $(\Delta X{)}^2=1$, but give $(\Delta P{)}^2=1/4,5/4,5/4$ and $C_{XP}=0,+1,-1$, respectively. The two nonzero cases have $r=\pm 2/\sqrt{5}$ and product $\sqrt{5}/2$; all three covariance matrices have determinant $1/4$.

The phase space curves in the figure satisfy $z^T{\Sigma }^{-1}z=1$ in the dimensionless coordinates, where $z=(X,P{)}^T$. They display second moments, not observed simultaneous position and momentum pairs. Their common area is $\pi \sqrt{\det \Sigma }=\pi /2$, although their coordinate projections differ.

This distinction is useful for predicting focusing. Under free particle evolution with mass $m$, $x(t)=x(0)+tp(0)/m$, soA negative chirp initially narrows the position distribution; positive chirp initially broadens it. For $\kappa <0$, the minimum occurs at $t_{\ast }=-2m{\sigma }^2\kappa /[\hslash (1+{\kappa }^2)]>0$ and has variance ${\sigma }^2/(1+{\kappa }^2)$. At that time the quantum covariance vanishes, and the unchanged momentum spread gives $\Delta x(t_{\ast })\Delta p=\hslash /2$. The extra initial product was a usable position-momentum correlation, not extra measurement backaction.

Choose the qubit computational basis $|0⟩,|1⟩$, also called the $Z$ basis, and the Hadamard basis $|\pm ⟩=(|0⟩\pm |1⟩)/\sqrt{2}$, also called the $X$ basis. Compare a coherent preparation of $|+⟩$ with choosing $|0⟩$ or $|1⟩$ at random with equal probabilities and discarding that label:These are original ideal preparation models. Their $Z$-basis probabilities are both $(1/2,1/2)$, because their quantum state populations agree. Their $X$-basis probabilities are respectively $(1,0)$ and $(1/2,1/2)$. Indeed $⟨+|{\rho }_{+}|+⟩=1$, whereas $⟨+|I/2|+⟩=1/2$. The missing off-diagonal quantum coherence therefore changes a prediction that the common populations cannot determine.

For a relative quantum phase $\varphi$, the coherent family instead hasThe last formula follows by adding or subtracting the two probability amplitudes before taking the squared modulus. At $\varphi =\pi$, the state is $|-⟩$ and the $X$ outcomes switch to $(0,1)$, while the $Z$ outcomes remain $(1/2,1/2)$. In contrast, $-|+⟩$ changes both components by the same global phase and retains the $X$ outcomes $(1,0)$. In photon polarization, the identification $|0⟩=|H⟩$, $|1⟩=|V⟩$ makes $|+⟩$ and $|-⟩$ the two orthogonal diagonal linear polarizations; these labels describe measurement bases, not spatial axes for photon spin.

Even perfect statistics in one basis cannot certify a preparation. The above $Z$ data fit both density matrices. Conversely, distinct preparation histories can yield the same quantum state:The off-diagonal terms cancel in the right-hand ensemble. Every measurement on the qubit alone then has identical probabilities for those two histories. A retained classical label would allow conditioning on different members of the quantum state ensemble; it is extra information beyond the unlabelled density operator.

For a coherent state, write $a|\alpha ⟩=\alpha |\alpha ⟩$ and $|\alpha ⟩={\sum }_n{c}_n|n⟩$ in number states. The annihilation operator gives $c_{n+1}\sqrt{n+1}=\alpha c_n$, so $c_n=c_0{\alpha }^n/\sqrt{n!}$. Normalization yields $|c_0{|}^2=e^{-|\alpha {|}^2}$. Thus photon statistics follows a Poisson distribution with $\mu =|\alpha {|}^2$, and the normal ordering of every moment gives $⟨(a^{†}{)}^k{a}^k⟩={\mu }^k$. This factorization is the defining virtue of coherent states for optical calculations.^[ref]

As an original comparison, choose $\mu =2$. Then $p_0=e^{-2}$, $p_1=p_2=2e^{-2}$, $\mathrm{Var}N=2$, and $⟨N(N-1)⟩=4$. A two-photon Fock state also has mean two but has $\mathrm{Var}N=0$ and pair moment two. ConsequentlyIn particular, $|1⟩$ cannot supply a pair. Nevertheless, photon statistics alone does not determine a quantum state: averaging $|\alpha ⟩⟨\alpha |$ over a uniform quantum phase removes its off-diagonal entries while retaining exactly the same $p_n$ and these equal-time moments.

A concrete quantum quench experiment loaded a Bose-Einstein condensate of ${}^{87}\mathrm{Rb}$ chemical atoms from a magnetic field trap into an optical lattice: three orthogonal $838\mathrm{nm}$ laser standing waves, with approximately $125\mu \mathrm{m}$ beam waists. An $80\mathrm{ms}$ loading ramp preceded a $50\mu \mathrm{s}$ increase in lattice depth. This suppressed quantum tunnelling while retaining each well's vibrational ground state. The switch preserved atom-number populations rather than freezing every motional degree of freedom.^[ref]

After variable hold times, releasing the traps and taking photon absorption images after $16\mathrm{ms}$ of flight revealed disappearance and return of interference peaks. Background-subtracted peak counts supplied a coherent fraction. Varying final depth tested the predicted revival period $h/U$; varying initial depth tested the collapse's sensitivity to atom-number statistics. Peak broadening outside counting windows and spatial variation of $U$ limited later signals.^[ref]

Here $U$ is the on-site interaction energy. The approximate isolated-well Hamiltonian operator $H=U\hat{n}(\hat{n}-1)/2$, with number operator $\hat{n}$, gives different quantum phases to its number states, which later rephase. This is a many-level realization of the distinction between fixed populations and changing quantum phases.^[ref]

Bose-Einstein condensation concerns occupation of a one-particle state. Matter-wave coherence concerns field correlations between positions or times. Superfluidity concerns a flow response, including suppression of dissipation under appropriate conditions. A density peak diagnoses neither a relative quantum phase between two separately prepared clouds nor a critical flow speed. These observables require different experiments.

For example, in a single-mode fixed-number Fock state, $⟨\hat{a}⟩=0$ but $⟨{\hat{a}}^{†}\hat{a}⟩=N$. Writing $\hat{\psi }(\mathbf{r})=\varphi (\mathbf{r})\hat{a}$ for that occupied mode givesThus vanishing mean field does not imply vanishing first-order matter-wave coherence. For two independent fixed-number modes, $⟨{\hat{a}}^{†}\hat{b}⟩=0$: there is no ensemble mean interference term establishing a fixed relative quantum phase. Interpreting fringes in an individual detection record requires considering correlations and the measurement; assigning a pre-existing definite relative quantum phase is unnecessary.

Wolfgang Ketterle's lecture describes a separate coherence test: two condensates expanded into one another and produced fringes. Selectively removing one condensate made the fringes disappear on alternating preparation cycles, testing against diffraction from the confinement. This compared two-cloud and one-cloud signals; it did not measure dissipationless flow.^[ref]

A Josephson junction can make a collective quantum phase behave as a measurable dynamical coordinate. In current-biased Josephson phase dynamics, the Gauge-invariant Josephson phase $\varphi$ moves in a tilted Josephson washboard potential; the junction's capacitance supplies its effective inertia. A trapped phase gives zero mean electric potential difference, while sustained phase advance produces a nonzero mean electric potential difference. Quantized phase levels in a Josephson junction and quantum escape of a current-biased Josephson junction test quantum mechanics for this collective coordinate.

Begin with a stipulated parallel electrical circuit: an ideal sinusoidal Josephson junction, capacitance $C>0$, and effective electrical resistance $R>0$. The Kirchhoff node law and Josephson effect giveHere $I_b$ is the constant bias electric current, $I_{\mu }$ is a deliberately applied microwave electric current, and $I_N$ represents unwanted fluctuating electric current. Multiplication by $\hslash /(2e)$ puts the undriven equation into the mechanical formThe effective inertia is a coefficient for a dimensionless quantum phase, not a literal material mass moving through the insulating layer. The capacitor's energy, $C{V}^2/2=M_{\varphi }{\dot{\varphi }}^2/2$, provides a direct check of that identification. The effective $R$ includes loading by the external electrical circuit; a constant parallel $R$ is an approximation over the relevant frequency range.

The useful design freedom is that $I_b$ changes the confinement while $C$ changes its inertia. The same manufactured device can therefore connect a classical oscillation, discrete energy levels, and escape to an electrical readout. The Martinis-Devoret-Clarke circuit experiments separate these questions experimentally. John Clarke, Michel H. Devoret and John M. Martinis shared the 2025 Nobel Prize in Physics for circuit experiments establishing macroscopic quantum tunnelling and discrete energy levels.^[ref]

An eigenstate of the rotating-frame Rabi Hamiltonian returns to the same laboratory ray after a full drive period. Its quantum phase includes both the rotating-frame energy and the sign of a full spin rotation. For spin $s$ and magnetic label $\mu$, the factor is $(-1{)}^{2s}{e}^{-i\mu \Omega T}$. Expanding the rotating-frame splitting to first order in the drive frequency and subtracting the adiabatic dynamical phase leaves $-\mu$ times the oriented solid angle of the field loop. Dropping the full-rotation sign gives a spurious half-integer-spin offset.

The Davisson–Germer experiment turned elastic scattering from nickel into evidence for a matter wave. The search became a deliberate wave test in 1926, with diffraction beams found early in 1927. The earlier crystal investigation had begun in 1925; the de Broglie wavelength proposal was already present in the 1924 thesis.^[ref]

A heated tungsten ribbon supplied electrons; gun apertures selected a narrow beam. Two $1\mathrm{mm}$ apertures were $8\mathrm{mm}$ apart; the gun ended $7\mathrm{mm}$ from a nickel crystal cut parallel to its $\{111\}$ planes. An adjustable electric potential difference set the speed. The beam struck normally inside an evacuated, field-free enclosure with target and outer electrodes at one potential. A double-box collector, $11\mathrm{mm}$ from the target with a $1\mathrm{mm}$ entrance, selected directions. A retarding electric potential difference rejected slower electrons; the inner collector fed a sensitive galvanometer. Moving the collector scanned colatitude; rotating the crystal scanned azimuth.^[ref]

The readout was collected electric current, not a photograph of electron paths. Voltage scans held the gun-plate current constant because incident-beam current could not be held constant; the overall current trend therefore needed caution. A strong feature developed at $54\mathrm{V}$ near $50^{\circ }$ colatitude. Surface heating distinguished crystal beams from adsorbed-gas beams; finite apertures and background shifted or broadened apparent peaks.^[ref]

At the bright beam's colatitude, an azimuth scan revealed three companion directions, matching crystal symmetry. The test compared wavelengths inferred from diffraction angles and known crystal spacings with wavelengths inferred from accelerating voltage and momentum; the 1937 lecture displayed this comparison against $U^{-1/2}$. Agreement across beam directions supplied more evidence than one angular peak.^[ref]

The inference is about coherent quantum phases in scattering probabilities. It does not establish a wavy particle trajectory, and a collector-current experiment does not resolve individual detection events. Predicting the full intensity additionally requires the material's scattering amplitude, its surface condition, and instrumental angular acceptance; the de Broglie wavelength alone predicts none of those strengths. The following finite-row electron diffraction model isolates phase addition without attempting to reproduce the nickel measurements.

At zero electric potential difference, $\dot{\varphi }=0$ permits a nonzero constant quantum phase and hence a steady pair electric current. Under an imposed electric current $I_b$ with $|I_b|<I_c$, a static solution satisfies $\sin \varphi =I_b/I_c$. The low-energy branch has $\cos \varphi >0$. For example, a stipulated $I_b=I_c/2$ gives $\varphi =\pi /6$ modulo $2\pi$; it does not require a voltage drop. In the ideal current-biased energy $-E_J\cos \varphi -(\hslash I_b/2e)\varphi$, the positive second derivative on that branch explains its local stability.

The superconducting critical current $I_c$ is a maximum available static pair electric current, not the inevitable electric current under a voltage bias. At $V=0$ the initial state and circuit select a phase and a current. Above $I_c$ this sinusoidal model has no static phase solution, but its two relations alone do not predict the complete resistive current-voltage characteristic, switching dynamics or hysteresis. Those require the circuit and dissipative channels.

In the 1923 note Waves and Quanta, Louis de Broglie proposed a periodic process associated with rest energy, remaining in phase with a wave along the moving particle's path. He distinguished the internal frequency slowed by time dilation from the wave frequency based on total energy.^[ref] The proposal developed into his 1924 thesis.^[ref] In the 1929 lecture The wave nature of the electron, he reconstructed the argument using a Lorentz transformation.^[ref]

Here is that quantum phase argument in modern notation. Set ${\omega }_0=m{c}^2/\hslash$ in the rest frame. A Lorentz transformation to a frame where the particle has velocity $v$ givesAlong $x=vt$, proper time is $\tau =t/\gamma$, soThis is the harmony: evaluating the spatial wave at the moving particle gives the slower clock phase. At fixed $x$, its angular frequency is instead $E/\hslash =\gamma {\omega }_0$. Since $k=p/\hslash$, the de Broglie wavelength follows as $\lambda =2\pi /k=h/p$. The proposed clock was a theoretical construction, not an observed mechanical vibration.

The de Broglie wavelength is the distance over which a matter wave accumulates one full spatial quantum phase cycle in its propagation direction:Here $h$ is the Planck constant, $\mathbf{p}$ is the momentum, and $\mathbf{k}$ is the angular wavevector. The scalar $p$ in $\lambda =h/p$ means the positive momentum magnitude, not a signed component. Reversing a momentum reverses the wavevector without making the wavelength negative. At zero momentum there is no finite spatial phase period: the limiting wavelength diverges.

This relation makes microscopic diffraction accessible with particles: increasing the momentum shortens the wavelength until it is comparable with the spacings in a crystal scattering problem. The electron accelerating-voltage wavelength gives a practical way to tune this scale, while the Davisson–Germer experiment tests it by comparing electron diffraction directions with independently known crystal geometry. The same relation applies to neutral particles in a neutron interferometer; electric charge is not a requirement for a matter wave.

The wavelength belongs to the wavefunction, not to a sinusoidal path of a particle. A free-particle momentum convention makes the distinction especially clear: a plane wave has a rotating complex quantum phase but a constant probability density. A localized wave packet contains a range of momenta and therefore generally has a range of wavelengths, rather than one exact spatial period.

Choose an isolated pair of energy levels, with ground state $|g⟩=(0,1{)}^T$ and excited state $|e⟩=(1,0{)}^T$. Use the Pauli matrices in the ordered basis $(|e⟩,|g⟩)$, so ${\sigma }_z=\mathrm{diag}(1,-1)$. After subtracting the mean energy, prescribe the laboratory Hamiltonian operatorThe unperturbed energy gap is $\hslash {\omega }_0$, the drive has angular frequency $\omega$, and $\varphi$ fixes its oscillation phase at the chosen time origin. All of ${\omega }_0$, $\omega$, the Rabi angular frequency $\Omega$ and the Rabi detuning $\delta$ are in radians per second; ordinary frequency is angular frequency divided by $2\pi$. In particular, $\Omega$ here is the coefficient multiplying the cosine in $H_{\mathrm{lab}}/\hslash$, not twice that coefficient.

Write $|{\psi }_{\mathrm{lab}}⟩=R(t)|{\psi }_{\mathrm{rot}}⟩$ with $R(t)=\exp (-i\omega t{\sigma }_z/2)$. Transforming the Schrödinger equation gives $H_{\mathrm{rot}}=R^{†}{H}_{\mathrm{lab}}R-i\hslash R^{†}\dot{R}$. The rotating-wave approximation drops terms at angular frequency $2\omega$, leavingThis approximation requires $\Omega ,|\delta |\ll {\omega }_0,\omega$, and an interaction duration over which omitted corrections remain small. It also assumes that other energy levels can be neglected. Resonance alone does not justify either assumption. An exactly co-rotating drive has no discarded counter-rotating component; the linearly oscillating laboratory drive above does.

The Pauli matrix multiplication law gives $K^2={\Omega }_{\mathrm{eff}}^{2}I$. Separating even and odd terms of the matrix exponential therefore proveswith the continuous limit $U=I$ when $\Omega =\delta =0$. Starting from $|g⟩$, the upper probability amplitude is $-i{e}^{-i\varphi }(\Omega /{\Omega }_{\mathrm{eff}})\sin ({\Omega }_{\mathrm{eff}}t/2)$. The Born rule givesThe rotating transformation only changes the quantum phases of these basis states, so their laboratory populations are the same. Rabi detuning tilts the rotation axis of the Bloch vector: it increases the oscillation rate to ${\Omega }_{\mathrm{eff}}$ but caps the transferred population at ${\Omega }^2/({\Omega }^2+{\delta }^2)$. A fixed drive oscillation phase cancels from this single-pulse population when the initial state is $|g⟩$. It still fixes the relative quantum phase of a resulting quantum superposition and matters when another pulse supplies a phase reference.