Thermoelectric effect Created 2026-10-13 Updated 2026-10-18
A thermoelectric effect couples heat transfer and the transport of electric charge: a temperature gradient can generate an electromotive force, while an electric current can carry heat and cause heating or cooling at a junction of different materials. This coupling makes electrical measurement of temperature possible through a thermocouple, and permits conversion of a sustained flow of heat into electrical work. A finite open-circuit voltage does not itself deliver power: electrical power requires an electric current through a load. Thermoelectric conversion therefore involves both electromagnetism and thermodynamics. [ref]
https://thermoelectrics.matsci.northwestern.edu/thermoelectrics/history.html. Northwestern thermoelectrics research group: thermoelectric effects and applications
. Thermoelectric generator 2026-10-20
Thermoelectric power factor 2026-10-20
The combination of Seebeck coefficient and electrical conductivity. Increasing it alone need not increase ZT if thermal conductivity rises as well.
Thermomechanical effect 2026-10-18
The thermomechanical effect couples a temperature difference to a pressure difference across a superleak. For the closed-chamber model in the apparatus figure, consider neighboring equilibrium states with small velocities, negligible height difference and pure helium-4. Let be chemical potential per unit mass, in . The Gibbs free energy differential per unit mass givesThe superleak allows the superfluid to redistribute until the two sides have equal . Setting therefore givesThe sign matters: heating one side at initially equal pressure lowers its ; inflow raises its pressure until chemical balance is restored. The hotter side has the higher pressure. The integral follows the constant- path; it need not be evaluated at fixed pressure when material properties vary appreciably.
For an original local example, stipulate constant , and . The predicted pressure difference is . These are teaching assumptions, not helium measurements. This static thermodynamics relation predicts neither the required heater power nor the filling time: those require heat leakage, channel conductance and chamber heat capacity. An outlet would introduce kinetic energy and a flowing balance, so the static is not a predicted fountain height.
Thermopile absorber 2026-10-18
A thermopile absorber converts incident electromagnetic radiation into heat near the thermocouple measuring junctions. Electrically separate junctions can share its temperature through thermal contact. The reference support provides a path for heat transfer and a comparison temperature; “cold” denotes this reference role, even if it is warmer than the absorber.
Distinguish incident power from absorbed power. A window, the illuminated area, and the absorption of the coating determine their relation. A detector's measured voltage sensitivity can depend on where a small illuminated spot lies.[ref]
Thermopile detectors by Hamamatsu Photonics K.K.. p. 3, §3-1 Sensitivity, Eq. (3-1) and following paragraph: uniform illumination versus a localized spot
The model in thermopile thermal response takes absorbed power as its input, so an optical calibration is a separate step. Thermopile radiative measurement 2026-10-18
PASCO's documented lamp experiment connects a TD-8553 thermopile sensor to a millivoltmeter and places it level with a lamp filament along a meter stick. Lamp and detector axes are aligned. With the lamp off, readings at several positions establish an average ambient thermal radiation background. With the lamp on at a fixed supply setting, detector readings at different distances are compared after background subtraction. Between readings, a reflective shield prevents the detector warming; its shutter also protects the reference junction when idle. Moving the shutter can move the sensor, so fixed geometry matters. The manual's lamp limits must be followed.[ref]
Thermal Radiation System: Instruction Manual and Experiment Guide, TD-8553, TD-8554A and TD-8555 by PASCO scientific. p. 1, Radiation Sensor; pp. 9–11, Experiment 2, Fig. 2.1, procedure and calculations: alignment, lamp-off ambient readings, heat shield and distance comparison
This protocol tests whether the background-corrected electric potential difference approximately follows the inverse-square law over a suitable distance range. It is a relative electromagnetic radiation measurement; those readings alone do not calibrate absorbed power in watts. The manual treats the filament as an approximate point source.[ref]
Thermal Radiation System: Instruction Manual and Experiment Guide, TD-8553, TD-8554A and TD-8555 by PASCO scientific. p. 3, Stefan-Boltzmann Lamp; p. 11, Experiment 2 calculations: point-source approximation and comparison against inverse squared distance
For an absolute calibration, independently known absorbed power and a monitored reference temperature would be needed. A useful additional control is to repeat a fixed detector position before and after a distance sweep: disagreement reveals possible drift. These additions test the measurement chain rather than assuming that background subtraction fixes every error. A finite source, changing illuminated area, reflections, changing reference temperature, and insufficient settling can alter the measured dependence. In particular, the time constant in thermopile thermal response explains why a quick reading and a settled reading may differ. The detector infers its own absorber temperature difference; inferring the source's temperature additionally requires its emissivity, optical geometry and an appropriate thermal radiation model.
Thermopile thermal response 2026-10-18
A useful original model treats the thermopile absorber as one approximately uniform temperature with heat capacity , connected to a fixed reference temperature by thermal conductance . Both parameters are positive constants here. Let be an added absorbed power above the initial background. Linearize the outgoing heat transfer about that background. With measured from an initial state having , conservation of energy gives the first-order linear differential equationThe left side is the rate of stored energy; the two terms on the right are added power and outgoing heat transfer. The effective thermal conductance can include several paths, rather than just heat conduction along the wires. The model assumes a stable reference, negligible electrical loading, a common absorber temperature, and changes small enough for constant parameters.
For a step from zero to constant at , subtract the steady solution . The difference obeys exponential decay, so the initial condition fixesThe time constant has units . With the same constructed and , choose , and . ThenAt one time constant, the response is of its final value: . Reaching requires . A voltmeter read too soon therefore underestimates the steady signal even when its electrical calibration is perfect.
The steady ratio is in this constructed model. Halving thermal conductance doubles this ratio but also doubles the time constant if heat capacity stays fixed. Reducing heat capacity alone speeds the response without changing its steady value. Increasing gives a larger signal only at fixed individual temperature differences: adding legs can also change thermal conductance, heat capacity and electrical resistance. The algebra identifies coupled design choices, rather than predicting a particular manufactured detector.
A finite electrical resistance produces Thermal electrical noise. For nearly uniform absolute temperature and effective measurement signal bandwidth , its root mean square open-circuit voltage isHere is the Boltzmann constant. Thermal electrical noise in the sensing element is an important contribution, and the signal bandwidth enters its voltage variance.[ref]
Thermopile detectors by Hamamatsu Photonics K.K.. p. 3, §3-2 Noise, Eq. (3-2): element resistance, absolute temperature and measurement bandwidth
If identical pairs have fixed electrical resistance and fixed , then : the signal grows as while this noise grows as . The resulting signal-to-noise ratio grows only as under those assumptions. Reference temperature drift, environmental electromagnetic radiation, and meter noise remain separate limits; reducing signal bandwidth trades fast information for less integrated electrical noise. Thévenin's theorem Created 2026-10-13 Updated 2026-10-14
Thévenin's theorem replaces the terminal behavior of a linear resistive circuit by an ideal voltage source in series with a Thévenin resistance, whenever its terminal electric potential difference is a well-defined affine function of the delivered electric current. Fix terminals , write , and take positive out of the network at into the electrical load, returning through . ThenThe open-circuit voltage is the intercept at ; is the slope. Thus two parameters predict what happens when many different electrical loads are connected. The Wheatstone bridge detector loading calculation uses precisely this replacement to find the detector reading even when the bridge's two voltage dividers interact through its detector.
For example, a ideal voltage source with above and below a voltage divider junction supplies and at that junction relative to the lower terminal. Attaching a electrical load reduces its voltage to and draws . The equivalent explains why an unloaded divider ratio alone cannot predict a loaded output.
The equivalence concerns the chosen terminals, including the power delivered there. It does not identify internal branch electric currents or internal Joule heating. At open circuit the original divider still draws from its supply, while the equivalent's series branch carries no electric current. [ref]
Thevenin and Norton Equivalents, University of Houston teaching notes. Thevenin and Norton Equivalents, pp. 1–2, “The Idea” and “Important Notes”: equivalence at the specified terminals
Thévenin terminal response 2026-10-14
With the passive sign convention applied to the network, its entering electric current is , and the same relation becomes . The electrical load uses the passive sign convention with entering electric current , so it absorbs power . A positive delivered electric current therefore produces a voltage drop for positive ; changing the reference direction without changing the equation would give the wrong sign.
The reason is linearity of Ohm's law, Kirchhoff's current law, Kirchhoff's voltage law, and the constitutive relations of any linear dependent electrical sources. Solve once at with the independent electrical sources present. Subtract this solution from a solution with prescribed delivered electric current : the fixed independent electrical sources cancel, leaving a homogeneous linear network whose terminal voltage change is proportional to . This is a short superposition principle argument for an affine function; the fixed offset need not vanish.
The qualification about a well-defined response matters. An ideal voltage source alone has . An ideal nonzero current source alone constrains and does not have a finite open-circuit voltage or a representation with finite coefficients. Linear dependent electrical sources can give negative resistance, and singular ideal networks may fail to have a unique finite response. Neither a finite nor a strictly positive passive follows merely from calling an electrical circuit linear. [ref]
Thevenin and Norton Equivalents, University of Houston teaching notes. Thevenin and Norton Equivalents, p. 11, “On a Negative Thevenin Equivalent Resistance”: dependent-source models can have negative equivalent resistance
Thomson cross-section Created 2026-10-18 Updated 2026-10-25
A free nonrelativistic charge driven by a weak plane electromagnetic wave has peak acceleration . Its time-averaged Larmor formula power is . Divide by incident light intensity to obtain the displayed cross section, independent of frequency. For an electron, it is . The approximation assumes negligible Compton recoil kinematics and small driven velocity compared with the speed of light.
Thrust Created 2026-10-18 Updated 2026-10-20
A propulsive force exerted on a body by an engine or another momentum-transfer mechanism. In a vehicle moving through a fluid, its direction need not coincide with the vehicle's actual velocity, and a transverse component can steer the motion. The component along the velocity contributes mechanical power ; a purely transverse component changes direction without doing instantaneous work. Rocket thrust is one particular mechanism and includes momentum carried by expelled material.
Total internal reflection Created 2026-09-29 Updated 2026-10-18
Total internal reflection occurs when a wave travels from higher to lower refractive index above the critical angle for total internal reflection, leaving no propagating transmitted plane electromagnetic wave normal to the interface.
At an infinite planar interface, total internal reflection returns all incident normal power in the reflected plane electromagnetic wave. Assume homogeneous dielectrics with isotropy, linearity, no dielectric loss, magnetic permeability , and positive real refractive indices . Above the critical angle for total internal reflection, both TE polarization and TM polarization have unit optical reflectance despite the external evanescent wave.[ref]
Interactive Optics by Sander Konijnenberg, Aurèle J.L. Adam and H. Paul Urbach. Basic Electromagnetic and Wave Optics, Total Internal Reflection and Evanescent Waves, equations (153)–(158)
This makes total internal reflection useful for guiding light in an optical fiber: suitable internal incidence angles keep energy inside successive boundaries. Its more surprising feature is that perfect optical reflectance coexists with an external electric field. The evanescent field in total internal reflection can interact with a nearby object, as the frustrated total internal reflection experiment demonstrates.
For an original idealized example, choose , at vacuum wavelength . At angle of incidence , Snell law for electromagnetic waves gives an angle of refraction , so a transmitted light ray still emerges. At , its direction becomes tangent to the boundary. At , the proposed sine of a real angle of refraction would be : the transmitted wavevector must instead have an imaginary normal component. These are predictions for the stipulated media, not measured properties of a particular block.
Constructed ray geometry just below, at, and above the critical angle for refractive indices 1.5 and 1; arrows indicate directions rather than relative powers
. Details. A real semicircular-block experiment isolates this threshold. The University of Maryland laboratory instructions place a laser, motor-driven rotation stage and photodetector together; an aperture limits the detector voltage. The semicircular block is centered on the rotation axis, with the photodetector aligned along its flat face. The instructions identify a strong grazing-beam signal and a weaker signal just before the critical angle for total internal reflection. The readout is detector voltage versus stage angle. Retracing the incident laser beam identifies normal incidence for alignment.[ref]
Snell’s law and total internal reflection laboratory instructions, University of Maryland Department of Physics. pp. 1–2, alignment procedure and Total Internal Reflection apparatus and detector instructions
The semicircular shape supplies a geometric control: a light ray passing radially through the curved face enters at normal incidence, avoiding additional entrance refraction. The weaker signal near the flat face locates a limiting angle of refraction; a vanishing remote-detector signal alone would not establish that the external electric field vanishes. Beam width and alignment limit angular resolution; no measured threshold or decay depth is supplied.[ref]
Snell’s law and total internal reflection laboratory instructions, University of Maryland Department of Physics. p. 1, beam-position uncertainty prompt; p. 2, semicircular-block geometry and near-critical signal
Transformer (electrical engineering) 2026-10-18
An electrical transformer transfers energy between windings through electromagnetic induction. Its operation depends on changing magnetic flux, rather than a static magnetic field alone.
Transistor 2026-10-18
A transistor is a semiconductor device in which an input controls an output electric current. Used with biasing and an electrical load, it can form an electronic amplifier or a switch. Its power gain comes from an external supply: the input signal controls the conversion of supplied energy into output signal power.
The point-contact transistor makes the idea tangible: two nearby contacts interact through one piece of semiconductor. A bipolar junction transistor instead uses two p-n junctions and a thin intervening region. The distinction matters both for the history and for choosing a physical model.
Transistor small-signal amplifier 2026-10-18
An original teaching model exposes the roles of input loading, output loading and the supply. Choose a small-signal model with positive input electrical resistance , transconductance , and output electrical resistance . Its controlled output current source draws from the output node toward the reference node. This chosen sign gives an inverting voltage gain; it is not the historical contact circuit's sign convention.
Assume a fixed operating point, negligible reverse coupling, a frequency range where coupling capacitors pass the signal, and negligible other capacitances and transit delays. A collector resistor connects the output to a steady ideal supply ; an external electrical load is coupled through a capacitor, so it draws no direct current. The input source has series electrical resistance . All voltages below are small departures from the operating point. An ideal fixed supply has zero incremental voltage and therefore becomes the reference node in the small-signal model.
Define and , where . Input voltage division and output Kirchhoff's current law giveConsequently the port voltage gain, overall source-to-output voltage gain, and load current gain magnitudes areThis current gain uses load electric current, not all the controlled-source electric current. It is also a different port definition from the historical emitter-to-collector current gain. Larger attenuates the input; smaller attenuates the output.
For a sinusoid input signal, use root mean square voltages. The power gain from accepted input signal power to useful load power isUnlike , this tends to zero as either or . Differentiation givesThus matching the output electrical load maximizes delivered power in this unilateral resistive model. For fixed source voltage, input loading multiplies by ; the accepted-input power gain above excludes the loss in .
Choose , , , and . Then . With and root mean square, the input is and the inverted output has magnitude root mean square. Hence and : . These are calculated values of the chosen model, not historical measurements.
With the same parameters but , while . At , while . Neither current gain nor voltage gain alone establishes power gain.
For the direct current load line in the figure, choose , and , consistent with . Locally extend the model as . With the external electrical load isolated at direct current, its intersection with is . Keeping small compared with the available voltage headroom is essential; extrapolation to arbitrarily large signals would be unphysical.
At the chosen operating point the collector supply delivers : is dissipated in and in the output device. Under a small signal, that energy flow is redistributed to provide load power. The incremental controlled current source hides the supply's steady energy flow; it does not create energy. A real complete amplifier also needs its input biasing network and has further losses. This calculation establishes neither its total efficiency nor a universal law for point-contact transistors.
Transmission line 2026-10-18
A transmission line guides travelling voltage and current waves. Its distributed electrical properties determine its characteristic impedance. A mismatch at a terminal produces reflected waves; available power, delivered power and returned power are distinct quantities.
Transmitted power 2026-10-25
The energy flux carried into a transmitted wave, integrated over the relevant cross section. The power transmission coefficient compares this with incident power. A displacement or field-amplitude transmission coefficient must be converted with the appropriate wave impedances; its squared modulus alone need not be the power fraction. This distinction applies both to electromagnetic waves and transverse string waves.
Triple-point cell 2026-10-14
A triple-point cell turns phase coexistence into a reproducible reference for thermometer calibration. The NIST water-cell demonstration uses a sealed glass vessel containing water of specified isotopic composition and an open central thermometer well. Cooling this well with solid carbon dioxide and alcohol freezes an ice mantle while leaving liquid water and its vapor. The coolant is outside the sealed sample; the sample's vapor space does not communicate with room air.[ref]
Triple-Point Cell (NIST demonstration). Triple-Point Cell, preparation description, uploaded 21 December 2016
In the actual NIST cell-comparison experiment, newly frozen mantles were compared with an aged reference mantle in a controlled maintenance bath. A warm aluminium rod melted a thin inner layer around the well, allowing the mantle to rotate freely and establishing an ice–water interface close to the sensor. A standard platinum resistance thermometer and a resistance bridge measured the electrical resistance ratio to a calibrated, temperature-controlled reference resistor. Readings at two currents permitted extrapolation to zero electrical power, correcting self-heating; measured immersion depths supplied hydrostatic pressure corrections. Comparing preparations over time tested stabilization rather than assuming freshly frozen ice was ready.[ref]
Effects of different methods of preparation of ice mantles of triple point of water cells on the temporal behaviour of the triple-point temperatures by G. T. Furukawa and others. Furukawa, Mangum and Strouse, Effects of different methods of preparation of ice mantles of triple point of water cells on the temporal behaviour of the triple-point temperatures (1997), Abstract, §1 and §§3.2–3.5: aged reference, inner melt, bridge readout, zero-power and hydrostatic corrections
The inference is a reproducible fixed-point response for the thermometer, not a direct reading of three chemical potentials. The reference cell anchors the comparison; a water point alone does not determine a thermometer's response at every other temperature. The ideal argument excludes impurity and isotope variation, finite interface effects and unintended heat transfer; real cells also require adequate immersion and stable electrical references. Repeatability is evidence that these effects are controlled, not a reason to omit their uncertainty.
Since 20 May 2019 the kelvin has been defined through a fixed numerical value of the Boltzmann constant. The thermodynamic temperature of the water triple point is consequently a measured quantity with uncertainty, rather than an exact value imposed by the kelvin definition. Its continued use as an assigned reference on the International Temperature Scale of 1990 is a separate convention.[ref]
On the revision of the International System of Units (SI), 26th CGPM Resolution 1 (2018). Resolution 1 of the 26th CGPM (2018), effective date; Appendix 2, third bullet; Appendix 3, kelvin definition
[ref]The International System of Units (SI), ninth edition, SI Brochure. §2.3.1: practical temperature scales and ITS-90
Tunnel diode Created 2026-10-18 Updated 2026-10-20
A tunnel diode is a p-n junction with sufficiently heavy semiconductor doping on both sides to make a thin depletion region and permit substantial interband tunnelling. The neutral regions are degenerate semiconductors. Its distinctive forward current-voltage characteristic contains a peak followed by a valley: over part of the curve, increasing the applied electric potential difference decreases the electric current. The Esaki tunnel-diode experiment made this behavior experimentally concrete.
The useful quantity is the local slope, not the ratio of total voltage to total electric current. With conventional electric current entering the positive-voltage terminal, defineNegative differential resistance means , hence where defined. A forward operating point can still have , and absorbed power . A small voltage increase then gives a negative current increment; this does not make the total electric current negative or turn the device into an unlimited source of energy. The external supply sets the operating point and supplies the energy available for an electronic amplifier.
An original idealized construction explains the shape. Put the n-type semiconductor on the left and the p-type semiconductor on the right. Take as the elementary charge and . Increasing forward bias lowers the right-hand electron energy levels relative to the left. Denote the two reservoir electrochemical potentials by , so that . At zero temperature, occupied left-hand conduction band states extend up to ; empty right-hand valence band states start at . For transfer conserving electron energy, the available interval isIt is nonempty only when its upper endpoint exceeds its lower endpoint. Both an occupied initial quantum state and an empty final quantum state must exist at the same energy. The Pauli exclusion principle prevents transfer into an already occupied final quantum state.
For the original diagram, choose arbitrary energy units with , , and , where is in those units. The available interval has widthThus , , , and . Initially forward bias opens a transfer window; further forward bias closes it by moving the right-hand valence band edge below the left-hand conduction band edge. This is a state-counting illustration, not a formula for a measured electric current.
Tunnel diode: energy band alignment and occupied-to-empty state overlap
. Original chosen energy band construction, with n-type semiconductor on the left and p-type semiconductor on the right. Blue shading denotes occupied reservoir states; orange hatching denotes empty reservoir states. Green arrows mark equal-energy transfer. The central barrier and band bending are schematic; all energies are arbitrary, and the drawing is not an experimental image or measured band profile. Source. Details.For reverse bias, the transfer direction changes: occupied right-hand valence band states can feed empty left-hand conduction band states. In the same construction, opens the interval for this reverse transfer. A narrow depletion region allows a large reverse quantum tunnelling electric current at small electric potential difference, whereas the ordinary Shockley diode equation predicts only a small reverse saturation electric current before diode reverse breakdown. At zero biasing, equal reservoir occupations give zero net electric current; quantum tunnelling does not require a net equilibrium flow.
A finite-temperature refinement replaces sharp occupation cutoffs with the Fermi-Dirac distribution. An illustrative weak-transfer expression isHere describes allowed initial/final quantum states and their coupling, and are Fermi-Dirac distributions with the respective electrochemical potentials. The occupation difference follows by subtracting the reverse transfer factor from the forward one: . An overlap interval alone does not determine : transmission probability, density of states, crystal momentum selection and phonons can matter. A complete germanium calculation is more demanding than multiplying two constant density of states factors. At larger forward bias, ordinary carrier injection and diffusion supply a rising current branch even after direct band overlap is lost.
Tunnel-diode load-line stability 2026-10-18
A current-voltage characteristic determines possible steady operating points; it does not alone determine their linear stability. Consider an ideal voltage source feeding a tunnel diode through a resistor , with a positive constant capacitance across the junction. Assume a quasistatic device relation and neglect inductance, transit delays, noise and heating. Kirchhoff's current law gives the original one-state modelA steady operating point satisfies : the device curve intersects the descending supply line. This is the source-side counterpart of a resistive load line. A small perturbation obeysThus the equilibrium point is locally attracting if and unstable if the inequality reverses. Equality requires higher-order analysis. Even on a negative differential resistance segment, a sufficiently small supply electrical resistance can stabilize this model. The assumption about the electrical circuit matters: an inductive or delayed circuit has additional state variables and may behave differently.
Choose an original toy forward characteristic, with no fitted device parameters:where , and . For every , , so this entire forward curve absorbs positive total power. NeverthelessThe model therefore separates negative differential resistance from negative total . The corresponding peak and valley are at approximately and ; these voltages deliberately differ from the historical peak.
With and , the supply line is . The intersection equation factors exactly:The three operating points are , and . Their values of are respectively , and . The outer two attract nearby trajectories; the middle one repels them. This is bistability in the specified one-state electrical circuit.
For the second panel, choose and . Now andThere is exactly one real operating point, again . Here , despite the device's own slope . With , the perturbation decays with time constant ; the unstable middle point of the first panel has growth time .
The one-state autonomous model supports switching between attracting operating points after a perturbation or parameter change; it cannot produce a nonconstant periodic orbit. A proposed oscillator needs additional dynamics. This limitation is useful: a load-line intersection establishes a possible steady reading, the slope test establishes local attraction in a specified model, and neither calculation alone predicts an oscillation frequency for a real tunnel diode.





