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The Stefan–Boltzmann law gives the total hemispherical radiant exitance of an ideal blackbody at absolute temperature $T$:Here $\sigma$ is the Stefan-Boltzmann constant. Total means integrated over all wavelengths; hemispherical means integrated over all outward directions with the projected area weighting. Thus $M_b$ is emitted power per actual emitting area, rather than directional radiance or spectral radiance. Absolute temperature must be in kelvin; raising a Celsius reading to the fourth power gives the wrong result. A uniform surface of area $A$ emits radiant flux $P_{\mathrm{emit}}=A{M}_b$. A real surface instead has $M=ϵ(T)\sigma T^4$, where $ϵ(T)$ is its total hemispherical emissivity. The older symbol $F$ in the formula above denotes this emitted radiant exitance.^[ref]

For an ideal blackbody, doubling absolute temperature multiplies radiant exitance by $16$. With the approximate Stefan-Boltzmann constant $5.670374419\times 10^{-8}\mathrm{W}{\mathrm{m}}^{-2}{\mathrm{K}}^{-4}$, the radiant exitances at $300\mathrm{K}$ and $600\mathrm{K}$ are approximately $459.300$ and $7348.805\mathrm{W}{\mathrm{m}}^{-2}$. This steep response explains why thermal radiation becomes so consequential at high temperature. It also enables heat transfer through a vacuum, where thermal conduction through a gas and convection are absent.

A short derivation integrates Planck's law in its frequency form. For a blackbody, direction-independent spectral radiance is $B_{\nu }(T)=2h{\nu }^3/[c^2(e^{h\nu /(k_{B}T)}-1)]$, where $h$ is the Planck constant, $k_B$ the Boltzmann constant and $c$ the speed of light. The outward hemisphere contributes $\int \cos \theta d\Omega =\pi$, soExpanding $(e^x-1{)}^{-1}={\sum }_{n=1}^{\infty }{e}^{-nx}$, nonnegative terms allow termwise integration. Repeated integration by parts gives ${\int }_0^{\infty }{x}^3{e}^{-nx}dx=6/n^4$; the Riemann zeta function value $\zeta (4)={\pi }^4/90$ gives the remaining integral as ${\pi }^4/15$. Hence $M_b=\sigma T^4$ with the coefficient in Stefan-Boltzmann constant. The angular integral is essential: omitting it confuses radiance with radiant exitance.

Stellar intensity interferometry measures a star's angular diameter by comparing fluctuations of detected light intensity at separated collectors. Each collector has its own photodetector; an analog multiplier or a digital correlator compares the electrical outputs. Changing the interferometric baseline changes the sampled spatial optical coherence. An unresolved star produces correlated fluctuations; a resolved extended source supplies different mixtures of emission directions, reducing their correlation.

This makes a useful telescope out of a surprising observable: the fluctuations discarded by an ordinary average-brightness measurement. Optical beams need not travel to a common combiner. A relative wave phase perturbation $E_2\mapsto e^{i\varphi }{E}_2$ leaves $|E_2{|}^2$ unchanged, so pure phase errors do not directly change the local light intensity. Electronic delay alignment remains necessary; intensity changes from atmospheric scintillation, collection losses, and instrumental noise still require controls.

Let $\mathbf{b}$ join the collectors and let ${\mathbf{s}}_0$ be the unit line of sight toward the star. The relevant interferometric baseline is its projection onto the plane of the sky:The reference arrival-time difference has magnitude $|\mathbf{b}\cdot {\mathbf{s}}_0|/c$, with speed of light $c$. Correct that delay, with a sign fixed by channel order, before averaging the residual correlation at $\tau =0$. The physical collector separation equals $B$ only when it is perpendicular to ${\mathbf{s}}_0$; tracking a star can change the projection even for fixed collectors.

The Stokes shift compares the lowest absorption-band maximum with the fluorescence emission spectrum maximum. Relaxation often makes $\Delta \lambda >0$. This comparison differs from using an arbitrary excitation wavelength. A spectral-density maximum can move when changing from per unit wavelength to per unit spectroscopic wavenumber; specify the spectral convention.^[ref]

An original illustrative energy budget makes the distinction concrete. Excitation at $450\mathrm{nm}$ and emission at $520\mathrm{nm}$ correspond to about $2.76$ and $2.38\mathrm{eV}$ per photon, using $E=hc/\lambda$ with Planck constant $h$ and speed of light $c$ in vacuum. The difference, about $0.37\mathrm{eV}$, must go elsewhere in the complete energy balance. These chosen wavelengths are not measured band maxima for a particular fluorophore.

Anti-Stokes emission has shorter wavelength than excitation. Additional energy, for example from a thermally populated level of molecular vibration or multiple excitation photons, makes it possible. The one-photon, initially relaxed drawing does not cover these cases.^[ref]

For a Planck function expressed as spectral radiance per frequency interval,$h$ is the Planck constant, $c$ the speed of light and $k_B$ the Boltzmann constant. Differentiating at fixed frequency givesThe proof uses ${\partial }_{T}x=-x/T$ and the chain rule. At low frequency, the multiplier tends to one, recovering the Rayleigh-Jeans law. At high frequency it grows approximately as $x$: the same fractional temperature change has a larger fractional brightness effect on the declining spectral tail.

For an original example choose $T=2.725\mathrm{K}$ and $\delta T=1\mathrm{mK}$. At $100\mathrm{GHz}$, $x=1.76119$, so the first-order fractional residual is $7.80415\times 10^{-4}$. At $300\mathrm{GHz}$, $x=5.28357$, it is $1.94881\times 10^{-3}$. Both spectra are exact blackbodies: this residual is a temperature mismatch, not evidence of a nonthermal spectrum. Fitting temperature before assessing remaining spectral residuals therefore removes a physically distinct degree of freedom. The figure divides by a fixed peak brightness rather than by the rapidly vanishing high-frequency tail.

The Thomson charge-to-mass experiment infers the magnitude of an electron's charge-to-mass ratio by combining electric and magnetic deflection of cathode rays. The central idea is to determine speed separately from magnetic curvature: a known speed turns the observed gyroradius into a measurement of $e/m$.

In 1897, J. J. Thomson used two grounded slits in an evacuated glass tube, then aluminium plates $5\mathrm{cm}$ long, $2\mathrm{cm}$ wide and $1.5\mathrm{cm}$ apart. A battery supplied their electric potential difference. Deflected cathode rays produced a phosphorescence patch on the glass; an external scale and movable luminous pointer recorded its position in darkness. Greater evacuation reduced gas electrical conductivity that screened the electric field; reversing plate polarity reversed deflection. External coils supplied the magnetic field, calibrated by induction against larger coils. He adjusted equal electric and magnetic deflections. ^[ref]

His comparison included air, hydrogen, carbon dioxide, and aluminium versus platinum cathodes, supporting a common carrier. He explicitly noted uncorrected magnetic bending outside the plates. His tables give $m/e$, the reciprocal of the magnitude used here. The inferred ratio alone could not separate electric charge from mass. ^[ref]

To connect this readout with the Lorentz force, derive a simple nonrelativistic model in modern SI notation. Let the uniform deflecting region have length $\ell$, followed by a field-free drift of length $L$. Assume a narrow speed distribution, small deflection angles, negligible collisions, and matching electric and magnetic field profiles. For an electron with speed $v$, the electric acceleration has magnitude $eE/m$, the transit time is approximately $\ell /v$, and the subsequent drift adds exit transverse velocity times $L/v$. Thus the displacement magnitudes measured separately with only electric field or only magnetic field areThe electric expression follows from constant transverse acceleration; the magnetic expression uses its small-deflection approximation. Equal displacement magnitudes then giveThis is an ideal derivation of the comparison principle, not a numerical reanalysis of the historical tube. Different exterior magnetic field profiles invalidate cancellation of the common geometrical factor. The comparison determines $e/m$ through deflection and the known apparatus dimensions; it does not require a downstream semicircle.

For a second, deliberately different teaching geometry, combine a velocity selector with a separate region containing only a uniform magnetic field $B_a$ perpendicular to the selected velocity. Here $B_s$ belongs to the velocity selector, while $B_a$ belongs to the analyzer: they need not be equal. The magnetic Lorentz force supplies the centripetal acceleration, soIf the analyzer turns the beam through a semicircle before it hits a screen in the entry plane, the separation $D$ between entrance and impact is the diameter: $r=D/2$. For a shorter observed arc, the screen displacement is not generally a radius; fit the appropriate circle geometry. This two-stage velocity selector and curvature apparatus is an original ideal teaching model, not a claim that Thomson's Fig. 2 used a separate selector and semicircular analyzer.

For a worked example, stipulate $E=2.00\times 10^3\mathrm{V}{\mathrm{m}}^{-1}$, $B_s=1.00\times 10^{-3}\mathrm{T}$, $B_a=2.00\times 10^{-4}\mathrm{T}$, and $D=0.1136\mathrm{m}$. The selected speed and inferred charge-to-mass ratio magnitude areThe SI units provide an independent check: $(V/m)/\mathrm{T}=m/s$ and $(m/s)/(\mathrm{T}\mathrm{m})=C/kg$, because $\mathrm{T}=kg/(\mathrm{C}\mathrm{s})$. The charge-to-mass ratio of the electron is negative; this calculation gives its magnitude. The bending direction gives the sign of the electric charge once the magnetic field direction is known. Scaling both $e$ and $m$ by the same positive factor preserves every displayed trajectory, so an independent electric charge measurement is required to determine mass separately.

The curvature formula assumes nonrelativistic momentum $p=mv$. At higher speeds, the relativistic cyclotron orbit gives $p=\gamma mv=e{B}_{a}r$, hence $e/m=\gamma v/(B_{a}r)$, where $\gamma$ is the Lorentz factor; the ideal straight-through selection $v=E/B_s$ still follows from vanishing Lorentz force. The stipulated speed is about $0.0067$ times the speed of light, making $\gamma -1$ about $2.2\times 10^{-5}$. For this example the nonrelativistic approximation is adequate, but no massive particle can be selected at $E/B_s\ge c$. Finite slit widths, collisions with residual gas, uncertain magnetic field calibration, and fields outside the ideal boundaries limit a real inference; repeat at several selected speeds and analyzer strengths to test consistency of $e/m$ rather than trusting one spot position.

A free nonrelativistic charge driven by a weak plane electromagnetic wave has peak acceleration $|q|E_0/m$. Its time-averaged Larmor formula power is $q^4{E}_0^2/(12\pi {ϵ}_0{m}^2{c}^3)$. Divide by incident light intensity ${ϵ}_{0}c{E}_0^2/2$ to obtain the displayed cross section, independent of frequency. For an electron, it is $8\pi r_e^2/3$. The approximation assumes negligible Compton recoil kinematics and small driven velocity compared with the speed of light.

If one clock measures a proper time interval $\Delta \tau$ while moving at constant speed $v$ in an inertial frame, that frame measures $\Delta t=\gamma \Delta \tau$, where $\gamma$ is the Lorentz factor. The two spacetime events must lie on that clock's world line.

Suppose a clock moving at $0.6c$ advances by $4\mu \mathrm{s}$ between two ticks. Set $t=x=t^{\prime }=x^{\prime }=0$ at the first tick. The laboratory's synchronized clocks assign $\Delta t=1.25\times 4=5\mu \mathrm{s}$. During that interval the clock travels $\Delta x=0.6c\times 5\mu \mathrm{s}=3c\mu \mathrm{s}$, approximately $899.38\mathrm{m}$. The Minkowski interval checks the result:Both frames therefore recover the same $4\mu \mathrm{s}$ of proper time. This calculation is useful whenever a process is timed on a moving apparatus but described using laboratory clocks.

A light clock makes the mechanism visible. Two mirrors separated by $h$ perpendicular to the motion exchange a pulse; define one tick as its complete return to the lower mirror. In the clock's rest frame the tick takes $\Delta \tau =2h/c$. In the laboratory each half-tick lasts $T$ and the light traverses a diagonal, so the Pythagorean theorem givesFor $h=1\mathrm{m}$ and $v=0.6c$, each leg covers $1.25\mathrm{m}$ while the mirrors move $0.75\mathrm{m}$. The return tick lasts $2.5\mathrm{m}/c$ instead of $2\mathrm{m}/c$: the light has the same speed of light in both accounts. ^[ref].

Reciprocal time dilation is consistent: each inertial frame times the other frame's single moving clock using its own synchronized clock network. These comparisons use different simultaneous spacetime events. Comparing reunited clocks instead requires their complete world lines, as in the twin paradox.

Work in Minkowski spacetime, neglect gravity, and choose the stay-at-home clock's inertial frame. Let departure be $O=(t,x)=(0,0)$ and reunion be $R=(T,0)$. The home clock follows $x_H(t)=0$. A traveller moves outward with velocity $+v$ and returns with velocity $-v$, where $0<v<c$ and $c$ is the speed of light. The ideal world line has a sharp turnaround at $P=(T/2,vT/2)$:Each straight leg lies in an inertial frame, but no single traveller inertial frame covers both legs.

For any differentiable timelike curve in this home inertial frame, its clock accumulates proper time through the integralApply it separately to the traveller's two legs. With the Lorentz factor $\gamma =(1-v^2/c^2{)}^{-1/2}$,For $v=0.6c$ and $T=10\mathrm{yr}$, the Lorentz factor is $\gamma =1.25$. The turnaround is $3$ light-years away at home time $5\mathrm{yr}$. The traveller records $4\mathrm{yr}$ outward and $4\mathrm{yr}$ returning: the reunited clocks read $10\mathrm{yr}$ and $8\mathrm{yr}$. These are illustrative model values, not experimental measurements.

The same integral gives a short geometric explanation: $\sqrt{1-v(t{)}^2/c^2}\le 1$, so every such competing timelike curve between these fixed spacetime events has $\Delta \tau \le T$. Equality requires zero velocity throughout, apart from sets of zero duration. Thus the straight home world line maximizes proper time in this Minkowski spacetime problem. This statement concerns fixed endpoints and an inertial home clock; in a gravitational field, compare paths using the appropriate metric tensor.

U. Berzinsh coauthored research on electron affinity.^[ref]

For chlorine, a published photodetachment threshold is $A_{\mathrm{ea}}/(hc)=29138.59(22)\mathrm{c}{\mathrm{m}}^{-1}$, approximately $3.612725\mathrm{eV}$ per chemical atom. Here $h$ is the Planck constant, $c$ the speed of light, and the inverse-length unit expresses an energy through a spectroscopic wavenumber. The parentheses give the reported uncertainty in the last digits, not a range of possible sign conventions.

U. Ljungblad coauthored research on electron affinity.^[ref]

For chlorine, a published photodetachment threshold is $A_{\mathrm{ea}}/(hc)=29138.59(22)\mathrm{c}{\mathrm{m}}^{-1}$, approximately $3.612725\mathrm{eV}$ per chemical atom. Here $h$ is the Planck constant, $c$ the speed of light, and the inverse-length unit expresses an energy through a spectroscopic wavenumber. The parentheses give the reported uncertainty in the last digits, not a range of possible sign conventions.

Ultraviolet is electromagnetic radiation with wavelengths shorter than the violet end of ordinarily visible light. The CIE convention uses $100$–$400\mathrm{nm}$, subdivided into UV-A at $315$–$400\mathrm{nm}$, UV-B at $280$–$315\mathrm{nm}$ and UV-C at $100$–$280\mathrm{nm}$. These divisions name intervals; they do not mark universal changes in every material's response. The boundary with visible light is not sharp, and other fields use near-, far-, vacuum- and extreme-ultraviolet divisions. ^[ref]. For example, NASA's Solar Dynamics Observatory observes extreme-ultraviolet bands below $100\mathrm{nm}$; the CIE interval is therefore not the full extent of astronomical ultraviolet usage. ^[ref].

The CIE ultraviolet interval corresponds to frequencies about $7.49\times 10^{14}$–$3.00\times 10^{15}\mathrm{Hz}$ and photon energies $4.97\times 10^{-19}$–$1.99\times 10^{-18}\mathrm{J}$, using vacuum wavelength and $E=hc/\lambda$ with Planck constant $h$ and speed of light $c$. Shorter wavelength means larger energy per photon; larger irradiance means more incident power per area. These are different comparisons. At the same incident power, a $254\mathrm{nm}$ ultraviolet beam has fewer photons per second than a $940\mathrm{nm}$ infrared beam, even though each ultraviolet photon has more energy.

A common ultraviolet mechanism is photon absorption promoting an electron from a ground state to an excited state of a chemical atom or molecule. By contrast, many infrared absorption bands involve stretching or bending chemical bonds. For either mechanism, both the energy difference and the coupling to the incident electromagnetic field matter. One concrete example is the $217\mathrm{nm}$ absorption discussed for butadiene: an electron moves between molecular orbitals, and the position of the absorption reveals their energy separation. Ultraviolet absorption can therefore probe molecular orbitals, while infrared spectroscopy probes many molecular motions. ^[ref].

Subsequent chemical reactions depend on the absorbing chemical substance and its environment; the label ultraviolet alone does not predict a reaction rate. At sufficiently short wavelength, a photon can cause photoionization if its energy exceeds the relevant ionization energy. There is no single wavelength that separates all ionizing from all nonionizing behavior for every chemical substance. Likewise, eventual heating after photon absorption is possible in both ultraviolet and infrared. The distinction is useful because different optical spectra expose different processes, not because the two ranges obey different laws of electromagnetism.

Ritter's 1801 observation used a chemical readout rather than a thermometer. In Caltech/IPAC's account, sunlight passed through a glass optical prism and silver chloride was placed in different parts of the optical spectrum. Darkening was weak toward red, stronger toward violet, and pronounced beyond the visible violet edge. The measured evidence was a change in the chemical substance's appearance at a spatial location with no visible color, establishing radiation beyond the eye's ordinary range. It was not a calibrated measurement of a universal ultraviolet optical spectrum. ^[ref].

A controlled modern interpretation of such a chemical test would compare equal exposure durations and matched fresh samples, keep an unexposed sample in darkness, monitor temperature, and distinguish scattered visible light from the intended short-wavelength beam with characterized filtering. These are proposed controls, not an assertion that Ritter performed them. Unequal sample preparation or heating can change a reaction rate. The optical prism, terrestrial atmosphere and sample response restrict which wavelengths the test detects. Darkening is a detector-weighted response, so its spatial maximum is not automatically the maximum of incoming radiant flux or of photon energy.

Thomas Larason and Jeanne Houston's NIST report documents a quantitative ultraviolet detector comparison. An argon source feeds a double-diffraction grating spectrometer; a shutter and mirrors deliver the selected band to a working-standard or test photodiode, successively at the same position. A beam splitter supplies a monitor photodiode. Amplifiers and voltmeters record detector and monitor simultaneously; shutter-closed readings provide dark baselines. The $200$–$500\mathrm{nm}$ scan, typically with $4\mathrm{nm}$ bandpass, measures spectral responsivity. Monitor normalization suppresses source drift; known spectral lines calibrate wavelength. The report assesses temperature effects and unwanted light outside the band, weighted by detector response. The latter need not cancel between different spectral responsivities. ^[ref].

This determines electrical response without visual perception. Bandpass and spatial nonuniformity limit the calibration; aging and changed temperature can affect later use. The scan includes visible light and ultraviolet; no response below $200\mathrm{nm}$ follows from it.

For a narrow beam, the idealized substitution calculation isHere $R$ is spectral responsivity; $I$ and $M$ are dark-subtracted detector and monitor electric currents. This follows by writing $I=RP$ for each detector and using the monitor to track changes in radiant flux. It assumes linear response, unchanged beam splitting and collection geometry, and a sufficiently narrow band. For an illustrative standard with $R_{\mathrm{std}}=0.15\mathrm{A}{\mathrm{W}}^{-1}$, ratios $I_{\mathrm{std}}/M_{\mathrm{std}}=2.0$ and $I_{\mathrm{test}}/M_{\mathrm{test}}=1.6$ give $R_{\mathrm{test}}=0.12\mathrm{A}{\mathrm{W}}^{-1}$. These invented arithmetic inputs illustrate the method; they are not NIST measurements.

An independent photon-counting model connects spectral responsivity to quantum efficiency. If $\eta (\lambda )$ is the number of collected electrons per incident photon, there is no internal multiplication, and $q$ is the elementary charge, thenAt illustrative constant $\eta =0.60$ and $P=1\mu \mathrm{W}$, this gives about $0.123\mu \mathrm{A}$ at $254\mathrm{nm}$ and $0.455\mu \mathrm{A}$ at $940\mathrm{nm}$. The ultraviolet readout is smaller in this model because there are fewer incident photons, not because their individual energies are smaller. Real quantum efficiency depends on wavelength, windows, absorption and carrier collection; a detector's band gap and construction determine its usable range. Constant $\eta$ across these two wavelengths is an analytical comparison, not a claimed specification of a real photodiode.

The curve is the calculated relation $E=hc/\lambda$, and the shaded ranges use the stated CIE conventions. The lower diagram abstracts the detector comparison rather than reproducing an instrument drawing. Together with the infrared heat-balance illustration, it shows why a calibrated detector response, rather than what looks bright to an observer, is the bridge between invisible radiation and a quantitative measurement.

A unit of length is a specified reference magnitude used to express a length. In $\ell =3\mathrm{m}=300\mathrm{cm}$, the physical length is unchanged; only its numerical value and chosen unit change. This separates a physical dimension from a unit convention.

The SI base unit is the metre, symbol $\mathrm{m}$. It is defined by fixing the vacuum speed of light at exactly $299792458m/s$, with the second defined independently through the caesium frequency. Thus realizing a metre can connect length measurement to a measured time interval or a calibrated optical frequency.^[ref]

Unit conversion should preserve dimensions: converting $2\mathrm{km}$ to $2000\mathrm{m}$ changes a length by a factor of $1000$ in its numerical representation, while the corresponding area changes by $1000^2$. Astronomical units, light-years and parsecs are useful for different astronomical distance scales; the choice does not alter the distance being measured.

Suppose standard collinear boosts have the Lorentz transformation form, but initially assign speed scales $a$ and $b$ to two successive transformations with relative velocities $v$ and $u$. Their composition has spatial and temporal diagonal factors proportional to $1+uv/a^2$ and $1+uv/b^2$, respectively. Closure within the same calibrated transformation family requires these factors to agree, forcing $a^2=b^2$ for generic nonzero boosts.

This argument fixes a universal reciprocal squared speed; it does not establish that it is nonzero. The common limit $1/a^2=0$ gives the consistent Galilean transformation family. A finite invariant speed of light is an additional empirical property of spacetime and electromagnetism, expressed by the second of the postulates of special relativity. It cannot be deduced by excluding the Galilean limit through boost composition alone.

A monochromatic wave in vacuum has frequency $\nu$ and wavelength $\lambda$ related by $\nu \lambda =c$, where $c$ is the speed of light. During one oscillation period $T=1/\nu$, a constant-wave phase surface travels one wavelength, so $\lambda =cT$. Equivalently, the plane electromagnetic wave relation $\omega =ck$ with angular frequency $\omega =2\pi \nu$ and wavenumber $k=2\pi /\lambda$ gives the same result.

As a calculated example, a vacuum radio wave with $\nu =300\mathrm{MHz}=3.00\times 10^8\mathrm{Hz}$ has $\lambda =0.999308\mathrm{m}$ using $c=299792458m/s$. Doubling frequency halves wavelength, independently of wave amplitude and wave intensity. The frequency spectrum of a pulse contains multiple frequencies; the relation applies to each vacuum component, rather than assigning one exact wavelength to the whole pulse. In a homogeneous medium replace $c$ by the appropriate phase velocity; the vacuum equation does not assert that all media have the same wavelength at a given frequency.

Vacuum permeability is the magnetic permeability appearing in the vacuum Maxwell equations. In SI, it relates vacuum magnetic field strength to magnetic flux density through $\mathbf{B}={\mu }_0\mathbf{H}$ and obeys ${\mu }_0{\epsilon }_0{c}^2=1$, where $c$ is the speed of light and ${\epsilon }_0$ the vacuum permittivity.

Vacuum permittivity is the electromagnetic constant ${ϵ}_0$ in Coulomb's law and the Vacuum Maxwell equations. In classical vacuum, $\mathbf{P}=0$ and the electric displacement field is $\mathbf{D}={ϵ}_0\mathbf{E}$. A material's permittivity includes its electric polarization response; vacuum permittivity supplies the common reference, not a separate adjustable material property. Its SI unit is farad per metre.

For elementary calculations, vacuum permittivity is approximately $8.854\times 10^{-12}F/m$. This is a deliberately rounded value, not an exact decimal or a statement of current measurement precision.^[ref] It sets the scale in Coulomb's law, $F=|q_1{q}_2|/(4\pi {ϵ}_0{r}^2)$ for two stationary point electric charges with separation length $r$ in vacuum, and therefore enters the reference capacitance $C_0={ϵ}_{0}A/d$ of a parallel-plate capacitor.

Since the revised SI took effect on 20 May 2019, the numerical value of vacuum permittivity in SI units is determined experimentally, rather than fixed exactly by the unit definitions. The numerical values of the elementary charge $e$, Planck constant $h$ and speed of light $c$ are fixed exactly. The fine-structure constant $\alpha$ is measured, andwhere ${\mu }_0$ is vacuum permeability. Consequently vacuum permittivity and vacuum permeability have experimental uncertainty, while their product is exact in SI units because $c$ is exact. This is a change in metrological status, not a new material dependence of vacuum permittivity.^[ref]

The velocity-addition formula translates a particle's velocity between two specified inertial frames. Let $S^{\prime }$ move at signed velocity $V$ along the $x$-axis of $S$, with parallel axes and $|V|<c$, where $c$ is the speed of light. Define $u_x=dx/dt$ and $u_x^{\prime }=d{x}^{\prime }/d{t}^{\prime }$ for the same particle's world line, using position and time measured within the corresponding inertial frame. With Lorentz factor ${\gamma }_V=(1-V^2/c^2{)}^{-1/2}$, the forward Lorentz boost gives

For collinear motion, write $u=u_x$ and $u^{\prime }=u_x^{\prime }$. The inverse velocity-addition formula isThis is the composition of the particle's velocity in $S^{\prime }$ and that frame's velocity relative to $S$. The velocities must belong to this same chain of reference frames, with directions specified. Two arbitrary quoted speeds cannot be inserted blindly. Each velocity measurement uses distances and clocks in a single inertial frame, with Einstein synchronisation for separated clocks.

For example, let $V=0.6c$ and let the particle travel at $u^{\prime }=0.6c$ in $S^{\prime }$. Its velocity in $S$ isThe Galilean transformation would instead give $u=u^{\prime }+V=1.2c$, which fails here. For light moving along the positive axis, $u^{\prime }=c$ gives $u=c$; $u^{\prime }=-c$ similarly gives $u=-c$. Negative directions also work for massive particles: at $V=0.6c$, $u^{\prime }=-0.6c$ gives $u=0$, while $u^{\prime }=-0.8c$ gives $u=-5c/13$. Thus “addition” means composition of signed velocities, rather than addition of their magnitudes.

A short derivation differentiates the Lorentz transformation: $d{x}^{\prime }={\gamma }_V(dx-Vdt)$ and $d{t}^{\prime }={\gamma }_V(dt-Vdx/c^2)$. Dividing these differentials gives the longitudinal velocity-addition formula. The transverse formulas use $d{y}^{\prime }=dy$ and $d{z}^{\prime }=dz$, but the same transformed time denominator; omitting it would ignore the relativity of simultaneity. Replacing $V$ by $-V$ gives the inverse. When both relative and particle velocities are small compared with the speed of light, the denominator is close to one and the nonrelativistic limit recovers the Galilean transformation.

The formula lets us compare particle motion in a moving apparatus and a laboratory without losing the invariant speed of light. Einstein's 1905 paper derives the coordinate change in §3 and the composition of velocities in §5, including the collinear formula, its light-speed case, and composition of parallel transformations. ^[ref]. The rapidity parametrization makes the collinear composition particularly simple.

A wavefront connects points with the same wave phase at one specified time. It is a surface, rather than the trajectory of a particular piece of light. For a scalar monochromatic wave written as $u(\mathbf{r},t)=A(\mathbf{r})\cos \Phi (\mathbf{r},t)$, a wavefront is a connected level set of the phase function $\Phi$; different surfaces can share the same wave phase modulo $2\pi$. A plane wave has planar wavefronts. An outward wave from an ideal point source in a uniform medium has spheres as wavefronts, while an optical lens can turn nearly planar wavefronts into converging ones. The wavefront describes wave phase, not wave amplitude: drawing it does not say how bright the beam is. ^[ref]

The relation to light rays becomes precise in a stationary medium with isotropy, negligible loss and a real positive scalar refractive index $n(\mathbf{r},\omega )$. In the geometrical optics limit, spatial changes in the refractive index and wave amplitude are slow on the local wavelength scale. For a single smooth propagation branch, writeHere $\omega >0$ is the angular frequency, $c$ is the vacuum speed of light, $S$ has units of length, and the last relation is the optical eikonal equation. The local wavevector is $\mathbf{k}=\nabla \Phi =k_0\nabla S$. Its direction is normal to a smooth wavefront, since a gradient is normal to its level sets. A forward light ray has unit tangent vector $d\mathbf{r}/ds=\nabla S/n$, so it follows this normal under the stated assumptions. Along that light ray, $dS/ds=\nabla S\cdot (d\mathbf{r}/ds)=n$: the change in $S$ is the optical path length. This is the short geometric argument linking wavefronts, light rays and optical path length. ^[ref]

The diagram shows incident and transmitted branches separately, with the reflected branch omitted. Its stipulated refractive indices are $n_1=1$ and $n_2=3/2$, and its incident angle is $30^{\circ }$ to the interface normal. At a stationary interface, the frequency and tangential wavevector agree on the two sides: Snell's law gives $\sin {\theta }_2=1/3$, hence ${\theta }_2\approx 19.4712^{\circ }$. The wavefronts turn while their normal spacing decreases from ${\lambda }_0$ to $2{\lambda }_0/3$, where ${\lambda }_0$ is the vacuum wavelength. More explicitly, with $x$ normal to the interface and $y$ tangential, take $S_1=\sqrt{3}x/2+y/2$ for $x<0$ and $S_2=\sqrt{2}x+y/2$ for $x>0$. These functions agree at $x=0$; the drawn wavefronts are $S_j=m{\lambda }_0$ at $t=0$ with ${\varphi }_0=0$. This is an exact piecewise plane wave phase construction for the stipulated transparent media, not measured material data. ^[ref]

The normal-to-wavefront rule requires its assumptions. In a medium with anisotropy, the wavevector remains normal to a smooth wavefront, but the group velocity and energy flux need not follow it. ^[ref] Near a wave caustic, where multiple light rays meet, one smooth phase function may no longer describe the field; diffraction and the full wave amplitude matter. A wavefront is also not generally a surface of equal pulse arrival time. In a medium with optical dispersion, a monochromatic wave phase moves with the phase velocity, while a sufficiently narrow wave packet follows the group velocity. Even identical optical path lengths at one frequency can give different group delays. The usual equal-travel-time picture needs a common launch reference and a nondispersive ray model; an arbitrary broadband disturbance has no single monochromatic wavefront.^[ref]

The wavelength $\lambda$ is the spatial period of a monochromatic wave, measured at a fixed time along the wavevector. For a plane wave with a sinusoid as its profile, it is the distance between consecutive wave crests, or between any consecutive points with the same wave phase modulo $2\pi$:Here $\mathbf{k}$ uses angular wavenumber, $f$ is ordinary frequency, and $v_p$ is phase speed. A distance between arbitrary zero crossings need not be a wavelength: consecutive zeros of a sinusoid are only $\lambda /2$ apart, with opposite slopes. In a standing wave, consecutive nodes of a standing wave are also $\lambda /2$ apart; $\lambda$ refers to the constituent travelling waves, even though the nodes of a standing wave do not travel.

Across a stationary interface between stationary linear media, the incident, reflected and transmitted monochromatic waves have the same frequency. The boundary conditions must hold at every time: terms oscillating with different angular frequencies cannot cancel throughout the entire time record. Each medium's dispersion relation then determines its own angular wavenumber and wavelength, soFor electromagnetic radiation in a transparent medium with refractive index $n$, $v_p=c_0/n$ and $\lambda ={\lambda }_0/n$, where $c_0$ is the vacuum speed of light. A synthetic example with ${\lambda }_0=600\mathrm{nm}$ and $n=1.5$ gives $\lambda =400\mathrm{nm}$ at the same frequency. This conservation argument assumes time-independent linear material response and a stationary interface in the chosen frame. A moving interface can produce a Doppler effect; time-dependent or nonlinear response can change or generate frequencies.^[ref]

A broad frequency spectrum generally supplies many component wavelengths, rather than one wavelength for an entire pulse. Even two tones have both their individual wavelengths and a different overall repetition distance: the $2$- and $8$-cycle-per-metre sum in spatial sampling of a wave repeats after $0.50\mathrm{m}$, but contains the finer $0.125\mathrm{m}$ structure. A narrow wave packet can have an approximate carrier wavelength; the wave envelope propagates approximately at group velocity, determined by the slope of the dispersion relation. Substituting that group velocity into $\lambda =v_p/f$ generally gives the wrong carrier wavelength. Where the medium varies slowly, local wavelength gives a more useful description.

The Wien displacement constant is the constant of proportionality $b$ in ${\lambda }_{\max }T=b$. From the exact International System of Units values of the Planck constant, speed of light and Boltzmann constant,The units follow from $hc/k_B$: $(\mathrm{J}\mathrm{s})(\mathrm{m}{\mathrm{s}}^{-1})/(\mathrm{J}{\mathrm{K}}^{-1})=\mathrm{m}\mathrm{K}$. The defining constants are exact; the displayed decimal is rounded. ^[ref]