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An Euler strut is a slender elastic column under axial compression. Let its bending stiffness about the weaker section axis be $E{I}_A$ and its length be $L$. With small lateral deflection $y(x)$ and a dead compressive load $P$, the quadratic total potential energy isThe first term is bending energy; the negative term is work released by the load as bending shortens the end-to-end distance. Stationarity gives $E{I}_A{y}^{\prime \prime \prime \prime }+P{y}^{\prime \prime }=0$. For pinned ends, $y=y^{\prime \prime }=0$ at $0,L$, and $y\propto \sin (n\pi x/L)$ requires $P_n=n^2{\pi }^{2}E{I}_A/L^2$. The first instability is Euler's critical load,Below this load, the straight state has positive quadratic energy against these perturbations. At the threshold, the lowest bending mode has zero quadratic restoring energy; above it the straight state is unstable. For a rectangular section, $I_A=b{h}^3/12$ about the appropriate bending axis, so the smaller second moment of area controls the first buckling direction.

Endpoint constraints matter. Write $P_{\mathrm{cr}}={\pi }^{2}E{I}_A/(KL{)}^2$: $K=1$ for pinned-pinned, $2$ for fixed-free and $1/2$ for fixed-fixed conditions. This elastic instability differs from compressive material failure. Imperfections cause bending before the ideal threshold, and a short column may yield before Euler buckling occurs.

Let the particle have mass $m$, and assume its force is derived from a time-independent potential energy $V(x)$ during the stated interval. Differentiation givesFor $n\ne 0$, choose a branch on which $t=(x/A{)}^{1/n}$ is real. Conservation of energy is the quickest integration of Newton's second law:The additive constant $E$ is arbitrary. For instance, the displayed expression applies directly for $t>0$, $A\ne 0$ and $x/A>0$, without raising a possibly negative $A$ to a fractional power. Its derivative gives $-V^{\prime }(x)=mn(n-1)A{t}^{n-2}$ along the trajectory, as required. The second term has units of kinetic energy because $A$ has units $\mathrm{m}{\mathrm{s}}^{-\mathrm{n}}$.

For $n=1$, the velocity is constant, so the potential energy is constant on the visited interval; the expression above reduces to such a constant. For $n=0$, or $A=0$, the particle is stationary: the trajectory only fixes $V^{\prime }$ to vanish at its position and does not determine the potential energy elsewhere. These exceptional cases cannot determine a unique nonconstant function.

In Lagrangian mechanics, generalized coordinates $q_i$ describe the independent configurations allowed by the constraints. For particles with ordinary conservative forces in an inertial frame, use $L=T-V$, with kinetic energy $T$ and potential energy $V$. Holonomic constraints can often be built into the coordinates, avoiding explicit constraint forces.

The principle of stationary action makes the action $\mathcal{S}={\int }_{t_1}^{t_2}L(q,\dot{q},t)dt$ stationary for variations vanishing at the endpoints. Integrating the velocity variation by parts givesSince each independent variation is arbitrary, the Euler-Lagrange equations areIf nonconservative generalized forces are present, their components appear on the right. The formalism is invariant under suitable coordinate changes and adding a total time derivative to $L$ leaves the fixed-endpoint equations unchanged.

The generalized momentum is $p_i=\partial L/\partial {\dot{q}}_i$. If $q_i$ is cyclic, $\partial L/\partial q_i=0$ and $p_i$ is conserved. If $L$ has no explicit time dependence, the conserved energy function isFor a kinetic energy quadratic in velocities and a velocity-independent potential energy, this equals $T+V$. This connects symmetry to conservation laws.

For example, a simple pendulum of mass $m$ and length $\ell$ hasIts tension does not appear because the fixed-length constraint is already imposed. Expanding for small $\theta$ gives simple harmonic motion with $\omega =\sqrt{g/\ell }$. More generally, expansion of $T$ and $V$ to quadratic order about a stable equilibrium leads directly to the normal-mode eigenvalue problem.

Definition and equations. A normal mode is a motion in which every component of a linear system has the same time dependence with fixed amplitude ratios and phases. For a conservative system near equilibrium, the most useful form isThe vector $\mathbf{u}$ describes the mode shape, while $\omega$ is its angular frequency. Linear combinations of modes describe arbitrary sufficiently small motions when the modes form a complete basis.

Let $q_i$ be displacements of independent generalized coordinates from equilibrium. Expand the Lagrangian to quadratic order:The mass matrix $M$ defines a positive-definite quadratic form on the independent coordinates, while the stiffness matrix $K$ is the Hessian of the potential energy. Substituting a mode gives the generalized eigenvalue problem for small oscillationsA practical calculation identifies the equilibrium, chooses independent coordinates, computes the quadratic kinetic and potential energies, solves for the eigenvalues and then obtains their eigenvectors. One can equivalently diagonalize the real symmetric matrix $M^{-1/2}K{M}^{-1/2}$. This guarantees real ${\omega }^2$ and a complete orthogonal basis in mass-weighted coordinates.

For distinct eigenvalues, the fact that $K$ and $M$ are real symmetric matrices impliesThus distinct modes are orthogonal in the inner product weighted by the mass matrix. Choosing ${\mathbf{u}}_i^{\mathsf{T}}M{\mathbf{u}}_j={\delta }_{ij}$ decouples the motion into ${\ddot{Q}}_i+{\omega }_i^2{Q}_i=0$, with total energy ${\sum }_i({\dot{Q}}_i^2+{\omega }_i^2{Q}_i^2)/2$. A positive-definite matrix $K$ gives positive eigenvalues and oscillatory stability. Zero modes can describe rigid translations or rotations without restoring force; a negative eigenvalue gives exponential instability rather than an oscillatory mode.

Symmetry. A symmetry preserving both quadratic energies maps modes into modes of the same frequency. Coordinates adapted to symmetry divide the eigenvalue problem into smaller independent blocks. For two identical subsystems, exchanging them gives symmetric and antisymmetric modes. The degeneracy of normal modes means that independent modes share one frequency. Higher-dimensional group representations of a symmetry can enforce such degeneracies; symmetry does not require every pair of modes to be degenerate, and accidental degeneracies can also occur. Within a degenerate eigenspace, orthogonal linear combinations are equally valid mode shapes.

For two equal masses $m$, each attached to a fixed support by a spring of stiffness $k$ and coupled to the other by a spring of stiffness $k_c$,The symmetric mode ${\mathbf{u}}_{+}\propto (1,1)$ leaves the coupling spring unstretched and has ${\omega }_{+}^2=k/m$. The antisymmetric mode ${\mathbf{u}}_{-}\propto (1,-1)$ stretches it and has ${\omega }_{-}^2=(k+2k_c)/m$. Superposing the two gives beats when their frequencies are close.

Continuous systems. The same idea replaces matrices by differential operators and mode vectors by functions satisfying boundary conditions. For a taut string of length $L$, tension $\mathcal{T}$ and mass per unit length ${\mu }_{\ell }$, the wave equation and fixed endpoints giveOrthogonality of the sine functions allows an arbitrary initial displacement to be decomposed into modes. Changing the endpoints changes the spectrum: boundary conditions are part of the physical mode problem.

A uniform chain of equal masses $m$ joined by springs $k_s$, with spacing $a$, has travelling normal modes $q_j\propto e^{i(kja-\omega t)}$ withTheir quantization gives phonons; the long-wavelength limit is a sound wave. Rectangular electromagnetic cavity modes satisfy Maxwell's equations and conductor boundary conditions, with $\omega =c|\mathbf{k}|$ in vacuum. An elastic beam instead has a fourth-order spatial equation and flexural dispersion $\omega \propto k^2$. These examples show how restoring forces and geometry determine the frequency spectrum.

Real systems. Small-amplitude motion is often approximately linear even when the full equations are nonlinear. Large amplitudes produce frequency shifts, mode coupling and transfer of energy between modes. Friction broadens resonances and makes free oscillations decay. A damping matrix proportional to $M$ or $K$ can retain the undamped mode shapes; general damping need not, and the appropriate eigenfrequencies and modes can be complex. External periodic forcing predominantly excites modes near resonance, with amplitude set by coupling to the forcing and dissipation. Imperfections split ideal degeneracies, while radiation or coupling to a surrounding fluid can remove energy from the chosen subsystem. Normal modes remain useful when linearization, the boundary conditions and the treatment of damping accurately describe the motion being measured.

The radial force is $F_r=-dU/dr=-3A{r}^2$. A nontrivial circular orbit therefore requires $A>0$, so that the force is inward. Balancing its magnitude against the required centripetal acceleration givesThusThis is the circular-orbit energy ratio in a power-law potential, $2K=r{U}^{\prime }(r)=sU$ for $U=A{r}^s$, with $s=3$. It uses the zero of potential energy specified by $U=A{r}^3$; adding a constant would change the ratio without changing the motion. For $A<0$, the force is outward and no such free circular orbit exists.

Classification of attractive inverse-square orbits. Write the potential energy as $U=-\kappa /r$, with $\kappa =GMm>0$ and zero at infinity. For nonzero angular momentum $J$, the Kepler orbit is a conic,Negative total orbital energy gives an elliptic orbit, $0\le e<1$. Its special case $e=0$ is the circular Kepler orbit, at the minimum energy permitted for that $J$, $E=-m{\kappa }^2/(2J^2)$. Zero energy gives a parabolic Kepler orbit, $e=1$, and positive energy a hyperbolic Kepler orbit, $e>1$. For $J=0$, the motion is radial: these are degenerate limiting trajectories and may strike the centre or the finite planetary surface.

The scattering geometry. The impact parameter $b$ is the perpendicular offset of the undeflected incoming asymptote from the centre, not the actual periapsis radius $r_{\min }$. Gravity bends the incoming path toward the planet.

The grazing threshold. At infinity, conservation of energy and angular momentum give $E=m{v}_{\infty }^2/2$ and $J=mb{v}_{\infty }$. At closest approach the radial speed is zero, so the velocity is tangential andEliminating $v_p$ givesThis increases monotonically with $r_{\min }>0$. Setting $r_{\min }=R$ gives the grazing impact parameter in gravitational focusing,Here $v_{\mathrm{esc}}=\sqrt{2GM/R}$ is the surface escape speed. The expression has units of length. Equality is the tangency limit; a strictly noncolliding trajectory requires $b>b_{\min }$. At high speed, $b_{\min }\to R$, while at low speed $b_{\min }\sim \sqrt{2GMR}/v_{\infty }$. Thus gravitational focusing enlarges the collision cross-section to $\pi b_{\min }^2$.

Deflection angle. For this hyperbola,The asymptotes occur at $\cos {\varphi }_{\infty }=-1/e$. The change of velocity direction is $\chi =2{\varphi }_{\infty }-\pi$, giving $\sin (\chi /2)=1/e$. Hence the gravitational scattering angle satisfiesFor the grazing trajectory this isIt is the attractive counterpart of the Rutherford impact-parameter relation; the sign of the transverse bending changes, but the positive deflection magnitude has this same form.

Range of angles. Along the grazing family, varying $v_{\infty }>0$ givesThe limits are $\chi \to 0$ as $v_{\infty }\to \infty$ and $\chi \to \pi$ as $v_{\infty }\to 0^{+}$. Neither endpoint is reached at finite positive speed. The low-speed limiting orbit still has a finite periapsis, but an increasingly distant incoming asymptote.

Initially and finally the block and lake are at the same temperature. After the falling block has come to rest, its lost gravitational potential energy has dissipated into internal energy of the lake and surroundings. In the idealization that all $mgh$ is ultimately thermalized in the lake at $T_0=283.15\mathrm{K}$,The block returns to its original thermal state, so its net entropy change is zero. Mechanical potential energy carries no thermal entropy that must be subtracted. ThusUse of $g=9.80\mathrm{m}{\mathrm{s}}^{-2}$ gives the same three-significant-figure answer. Splashing and any temporary heating do not change this final-state balance if their mechanical energy is eventually dissipated in the same reservoir.

For a slender elastic beam undergoing small bending, cross-sections remain approximately plane and perpendicular to the centreline. At distance $z$ from the neutral axis, longitudinal strain is ${ϵ}_{xx}=-z\kappa$, where $\kappa$ is curvature. Linear elasticity gives ${\sigma }_{xx}=E{ϵ}_{xx}$, so the bending moment has magnitudeHere $I$ is the second moment of cross-sectional area, not a mass moment of inertia. For width $b$ and depth $h$ in the bending direction, $I=b{h}^3/12$. The cubic depth dependence explains why a deep beam resists bending more effectively than the same material spread sideways.

For a uniform beam with transverse displacement $y(x)$, $\kappa \simeq y^{\prime \prime }$ and bending energy is $\frac{1}{2}\int EI(y^{\prime \prime }{)}^{2}dx$. Balancing transverse load $q(x)$ yields the Euler-Bernoulli beam equation $EI{y}^{\prime \prime \prime \prime }=q$ under a consistent sign convention. Supports specify values of deflection, slope, moment or shear; the equation alone does not fix the response.

Now apply a compressive end load $P>0$. A small deflection shortens the axial projection by $\frac{1}{2}\int (y^{\prime }{)}^{2}dx$, so the total potential energy relative to the straight configuration isIts stationary equation isFor pinned ends, $y(0)=y(\ell )=0$ and the end moments vanish, so $y^{\prime \prime }(0)=y^{\prime \prime }(\ell )=0$. The candidate shapes $y=A\sin (n\pi x/\ell )$ require $P=EI(n\pi /\ell {)}^2$. The first loss of stability is consequentlyAt smaller $P$, the quadratic energy is positive; beyond this threshold the straight configuration no longer minimizes it. End restraint changes the threshold: clamped–clamped gives $4{\pi }^{2}EI/{\ell }^2$ and clamped–free gives ${\pi }^{2}EI/(4{\ell }^2)$, equivalently an effective-length correction. A column buckles in the direction of smaller flexural rigidity. Euler buckling is a geometric instability within elastic response; yielding or crushing can occur first for a short thick strut. Large deflections, shear deformation and imperfections require refinements of the ideal slender-beam model.

Choose zero gravitational potential energy at infinite separation. The spacecraft's conserved total orbital energy isAt periapsis and apoapsis, the radial velocity vanishes, so the velocity is perpendicular to the radius. The conserved angular momentum magnitude is thereforeThe angular momentum vector is normal to the fixed orbital plane. The respective units are joules and $\mathrm{kg}{\mathrm{m}}^2{\mathrm{s}}^{-1}$. These expressions use Newtonian gravity and the approximation $M\gg m$.

Use a Hohmann transfer orbit. At the initial radius $r_0$, make a short prograde burn parallel to the existing velocity. The increased speed changes the circular Kepler orbit into an elliptic orbit whose periapsis is the burn point and whose apoapsis lies on the desired larger circle. Coast for half the transfer orbital period to apoapsis.

At that point the transfer velocity is again tangent to the target circle, but its magnitude is smaller than the circular speed there. A second short prograde burn raises it to the required circular speed. Thus both burns increase the instantaneous speed and preserve its direction at the burn, even though the final circular speed is lower than the original one. During the coast the spacecraft loses kinetic energy while gaining gravitational potential energy.

The figure illustrates $3r_0$ for the subsequent parts, but the same construction works for any larger target radius. The impulsive approximation neglects the distance travelled during each burn and keeps both circles and the transfer ellipse coplanar.

In the small-body approximation, write ${\chi }_{\mathrm{eff}}=\chi /(1+N_d\chi )$, with $\chi =\mu -1$. The induced magnetic dipole moment is $\mathbf{m}=VM\hat{\mathbf{z}}=V{\chi }_{\mathrm{eff}}{H}_0\hat{\mathbf{z}}$. Its effective interaction potential energy at fixed source current isThe factor $1/2$ accounts for inducing the moment: differentiating $-m(z)B_0(z)$ as if the moment were permanent would double the force. Equivalently, the instantaneous dipole force is $F_z=md{B}_0/dz$. Thus the force on a small linearly magnetizable body isFrom part (b), $d{H}_0/dz=-3a^{2}Iz/[2(a^2+z^2{)}^{5/2}]$. HenceFor the ideal slender rod, ${\chi }_{\mathrm{eff}}\simeq \mu -1$. If the source's printed magnetisation is imposed instead, its corresponding conditional answer isFor $\mu >1$ and $z>0$, both expressions point toward the loop, where the applied magnetic field is stronger; for $z<0$ the direction reverses toward the loop plane. A material with diamagnetism, ${\chi }_{\mathrm{eff}}<0$, reverses this attraction. The force is in newtons, since a magnetic dipole moment times a field gradient has units $\mathrm{A}{\mathrm{m}}^2\mathrm{T}{\mathrm{m}}^{-1}$. Both formulas assume linear response, negligible saturation and approximately uniform applied field across the sample.

Newton's second law takes its familiar form $m\mathbf{a}=\mathbf{F}$ in an inertial frame. Axes fixed to a turning apparatus or to the Earth form a rotating reference frame. Extra inertial forces account for the acceleration of these coordinates. Their values depend on the chosen reference frame; physical interactions such as gravity, tension and contact forces must still be included separately.

Let the rotating origin have inertial acceleration $\mathbf{A}$, and let its axes have angular velocity $\mathbf{\Omega }(t)$. For any vector $\mathbf{q}$, the rotating-frame derivative formula isEach rotating basis vector changes by $\mathbf{\Omega }\times {\mathbf{e}}_i$, which proves this rule by expanding $\mathbf{q}$ in that basis. Apply it twice to the position relative to the moving origin. With ${\mathbf{v}}^{\prime }$ and ${\mathbf{a}}^{\prime }$ measured in the rotating axes,Consequently the equation in the rotating reference frame isThe additional terms are the translational inertial force, Coriolis force, Euler force and centrifugal force, respectively. The last two simplify when the angular velocity is constant: the Euler force vanishes, while the other rotation terms remain.

The centrifugal force points away from the rotation axis. If ${\mathbf{r}}_{\perp }$ is the perpendicular displacement from that axis, thenFor uniform rotation it has potential energyA mass at rest relative to a turntable can therefore be described as having an inward tension or friction balancing its outward centrifugal force. In an inertial frame, the inward physical force instead produces the required centripetal acceleration. These are two descriptions of the same motion; one must not insert the rotating-frame outward term into the inertial equation as an additional physical interaction.

A rotating liquid gives a useful quantitative example. For a liquid in hydrostatic equilibrium relative to a vessel rotating uniformly about the vertical axis,Along the free surface the pressure is constant, so ${\Omega }^{2}sds-gdz=0$ andThe surface is a elliptic paraboloid. This is the balance of gravity and the centrifugal force in the rotating description. On the Earth, the same outward acceleration reduces effective gravity, most strongly at the equator, and contributes to the planet's equatorial bulge.

The Coriolis force depends on relative motion:It is perpendicular to both $\mathbf{\Omega }$ and ${\mathbf{v}}^{\prime }$, vanishes for motion along the rotation axis, and reverses when the relative velocity reverses. The dot product givesThus the Coriolis force does no work in the rotating reference frame: it changes the direction of motion rather than directly changing the rotating-frame kinetic energy. For example, on a horizontal turntable rotating anticlockwise as viewed from above, an outward-moving slider has a clockwise Coriolis acceleration, whereas an inward-moving slider has an anticlockwise one. The deflection can be observed by comparing a laboratory camera with a camera rotating with the table.

For slow horizontal motion on the Earth at latitude $\lambda$, keep the vertical component ${\Omega }_E\sin \lambda$ of its angular velocity. In east-north coordinates $(u,v)$ the horizontal Coriolis acceleration isIt deflects motion to the right in the northern hemisphere and to the left in the southern hemisphere. In large-scale atmospheric and oceanic motion it can balance a horizontal pressure gradient, giving geostrophic balance. With $\hat{\mathbf{z}}$ upward, the steady horizontal equation without friction isThe resulting velocity runs along lines of equal pressure. This approximation requires rotation to dominate local inertial changes; it is inappropriate close to the equator where $f$ tends to zero.

The Foucault pendulum gives another terrestrial example. In the small-angle approximation, its horizontal coordinates satisfyTo first order in the small ratio ${\Omega }_E/{\omega }_0$, the oscillation plane precesses relative to the ground at angular rate $-{\Omega }_E\sin \lambda$: clockwise in the northern hemisphere, zero at the equator, and one revolution per sidereal day at a pole. The Coriolis force explains this changing orientation without requiring energy input. Together these examples show why inertial forces are useful whenever the apparatus or environment supplies naturally rotating coordinates.

Direct differentiation gives ${\psi }^{\prime \prime }/\psi =x^2/a^4-1/a^2$. Inserting this into the Schrödinger equation and separately matching the $x^2$ and constant terms yieldsFor $V_0=m{\omega }_0^2/2$, $a^2=\hslash /(m{\omega }_0)$ and $E=\hslash {\omega }_0/2$. The normalizable Gaussian has no nodes, as expected for the nondegenerate one-dimensional ground state of this confining potential.

The normalization integral is $|C{|}^{2}a\sqrt{\pi }=1$. Choose its irrelevant global phase so thatFor the oscillator ground-state density in a comparison wavelength, choose a free comparison particle with the same total energy. It has $p=\sqrt{2mE}=\hslash /a$, hence comparison wavelength $\lambda =h/p=2\pi a$. ConsequentlyThe bound density is localized on scale $a=\lambda /(2\pi )$, with standard deviation $\lambda /(2\pi \sqrt{2})$, rather than being spatially uniform like the density of a single free plane wave. The comparison does not assign constant free-particle momentum to the bound state; its total energy also includes potential energy.

A conservative force has work depending only on the endpoints, so it can be writtenThe arbitrary additive constant in potential energy has no effect on force. A smooth curl-free force is conservative on a simply connected domain; a hole or excluded singularity requires checking global circulation as well.

Uniform gravity has $U=mgz$, central gravity has $U=-GMm/r$ with zero at infinity, and a linear spring has $U=k{x}^2/2$ relative to equilibrium. If the potential is time independent and no other force does work, $K+U$ is conserved by the work-energy theorem. A time-dependent potential or nonconservative work can change mechanical energy; having an instantaneous gradient force alone is not sufficient for energy conservation. ^[ref]

Here $V(x)$ is potential energy, $E$ is the stationary-state total energy eigenvalue, and $\psi (x)$ is its spatial wavefunction. Wavefunction normalization gives $\int |\psi {|}^{2}dx=1$, and $|\psi {|}^{2}dx$ is the probability of finding the particle in $dx$.

A bound state requires $-V_0<E<0$. Inside the well the equation is ${\psi }^{\prime \prime }=-k^2\psi$, whereas outside it is ${\psi }^{\prime \prime }=q^2\psi$, withThe ground state is even and has no node, selecting $\cos (kx)$ inside. Normalizability selects decaying, not growing, exterior exponentials. Continuity of $\psi$ and ${\psi }^{\prime }$ givesThe first excited state, if present, is odd: a sine inside and opposite-sign decaying tails outside. Matching gives $-k_1\cot (k_{1}a/2)=q_1>0$. On its first odd branch, $\pi /2<k_{1}a/2<\pi$, hence $k_{1}a>\pi$. Since $k_1^2<2m{V}_0/{\hslash }^2$, existence requiresThis is the first odd bound-state threshold of a square well. There is no excited bound state below that threshold; equality gives a non-normalizable zero-energy limiting state, not an extra bound state.

For the numerical well,The exterior probability of a symmetric finite-well state includes both tails:The threshold is $9.40\mathrm{eV}$, exceeding the well depth, so there is no excited bound state. The rounded supplied coefficients integrate to $0.9973$ rather than exactly one; this rounding does not change the quoted probability precision materially.

A gravitational field is force per unit test mass, $\mathbf{g}=\mathbf{F}/m$. Newton's law of universal gravitation gives the field of a point mass M:The potential is potential energy per unit mass, with zero at infinity for an isolated mass. Fields and potentials superpose. The potential difference fixes the work per unit mass, and a conservative gravitational field has zero circulation around a closed path.

For a continuous mass distribution, the gravitational Gauss law is $\oint \mathbf{g}\cdot d\mathbf{S}=-4\pi G{M}_{\mathrm{enc}}$. A spherical body therefore has the same exterior field as a point mass at its centre. Inside a uniform sphere of density $\rho$,The field is continuous at its surface and vanishes at its centre. An empty spherical shell has zero interior field but a nonzero constant interior potential. Near a small region of Earth's surface one may approximate $\mathbf{g}$ as uniform and the potential change as $g\Delta h$. Farther away its spatial gradient produces tidal relative accelerations. Escape to infinity from radius R requires speed $\sqrt{2GM/R}$ when rotation and other bodies are neglected.

A field assigns a physical quantity to each point. Gravitational field is force per unit test mass; electric field is force per unit test charge. In a conservative, time-independent field,Write $U=m\Phi$ for gravitational potential $\Phi$, or $U=q\varphi$ for electric potential $\varphi$, giving $\mathbf{g}=-\nabla \Phi$ and $\mathbf{E}=-\nabla \varphi$. A point mass has $U=-GMm/r$ with zero at infinity, while two point charges have $U=Qq/(4\pi {ϵ}_{0}r)$. Only potential-energy differences matter; a constant can be added freely. The mechanical energy $K+U$ is conserved if no nonconservative forces do work. A magnetic Lorentz force $q\mathbf{v}\times \mathbf{B}$ does no work on a point charge and generally cannot be represented by a position-only scalar potential energy.

Here $V(x)$ is potential energy, $E$ is the stationary state's total energy, and $\psi (x)$ is its spatial probability amplitude. The wave function has time factor $e^{-iEt/\hslash }$; $|\psi {|}^2$ is a position probability density for a normalized state. Stationary plane-wave scattering solutions are idealizations described by probability-current ratios, or components of a normalizable wave packet.

Above an upward step, a classical particle is fully transmitted with reduced speed. Quantum mechanically the abrupt wavelength change generally produces both reflected and transmitted amplitudes even though both regions are classically allowed. With unit incident amplitude and no wave arriving from the right,The reflected component has signed wavevector $-k_1$ and the same wavenumber magnitude as the incident component. A finite potential jump with constant mass and no delta interaction requires continuity of $\psi$ and ${\psi }^{\prime }$:The probability current $j=(\hslash /m)\mathrm{Im}({\psi }^{\ast }{\psi }^{\prime })$ gives probability reflection and transmission $\mathcal{R}=|r{|}^2$ and $\mathcal{T}=(k_2/k_1)|t{|}^2$, with $\mathcal{R}+\mathcal{T}=1$. The amplitude $t$ may exceed one without violating conservation of total probability, because the transmitted group speed is smaller.

For $0<E<V_0$, let $\kappa =\sqrt{2m(V_0-E)}/\hslash$. The bounded right-hand solution is $t{e}^{-\kappa x}$, an evanescent wave tail with amplitude penetration scale $1/\kappa$. It carries no outgoing probability current in an infinitely long forbidden half-space, so reflection is total. This differs from transmission through a finite potential barrier, where a second boundary can support quantum tunnelling.

For a downward step, replace $k_2$ by $\sqrt{2m(E+V_0)}/\hslash >k_1$. The same boundary conditions give a nonzero negative $r$, corresponding to a reflected amplitude with phase reversal. If reflection were forbidden, $r=0$ would require both $t=1$ and $k_1=k_2$, impossible for a nonzero step. Reflection therefore does not require a classical potential barrier; the discontinuity of wavenumber mismatch is enough.

For the specified electron energies, $k_2/k_1=\sqrt{40/100}=\sqrt{0.4}$, so the requested amplitude coefficients areThe corresponding probability coefficients are approximately $\mathcal{R}=0.05069$ and $\mathcal{T}=0.94931$. electron mass cancels from these ratios; there is no need to invent an additional material effective mass.

A time-independent conservative force defines a conservative vector field on a domain when the work between two points is independent of path, equivalently when every closed-path work integral vanishes. Define a potential energy $U$ by $\boxed{\mathbf{F}=-\nabla U}$ and $U(B)-U(A)=-{\int }_A^B\mathbf{F}\cdot d\mathbf{r}$. The additive constant is arbitrary; only differences affect work. A vanishing curl is necessary, and is sufficient on a simply connected domain under the usual smoothness assumptions. Local zero curl by itself need not guarantee a single-valued global potential on a domain with holes.

For a test mass outside a point or spherical mass, $U=-GMm/r$ with zero at infinity reproduces the inward gravitational force. Near a surface with approximately uniform downward gravity, $U=mgz$ when $z$ increases upward. A linear spring has $U=k{x}^2/2$. In electrostatics the electric potential is energy per unit charge, so $U=qV$ and $\mathbf{E}=-\nabla V$; potential and potential energy have different units and roles.

For motion under a time-independent conservative force, $d(K+U)/dt=0$. nonconservative forces change the mechanical energy by their work, and an explicitly time-dependent potential can exchange energy with the external agency changing it. A time-varying magnetic field can give a circulating electric field, so not every electric field is electrostatic or conservative. Conversely, zero magnetic work on a charge does not turn a velocity-dependent magnetic force into an ordinary position-potential force.

The ground-state energies are $1.50\mathrm{eV}$ and $0.376\mathrm{eV}$, respectively. For a particle in a box of width $L$, the wave function must vanish at both infinite walls. The lowest nonzero standing wave therefore has wavelength $2L$, giving the kinetic energy eigenvalueUsing the electron mass and converting joules to electronvolts givesDoubling the confinement length divides this kinetic energy by four. A zero potential energy inside the box does not imply zero total energy: a constant, zero-momentum wave function cannot satisfy both wall conditions unless it vanishes everywhere. This is a concrete manifestation of quantum confinement and the Heisenberg uncertainty principle.