Interpret the sphere as an atom of iron, and assume neighbouring atoms touch without overlap. Its radius is , and its mass is , using atomic mass unit .
In the face-centered cubic lattice, atoms touch along a face diagonal: , so . Four atoms occupy a conventional cube. The hard-sphere atomic volume in cubic lattices therefore gives
In the body-centered cubic lattice, atoms touch along the body diagonal: , so . There are two atoms per conventional cube, giving
These are primitive unit cell volumes, not the volumes of the conventional cubes or of the atomic spheres. The denser FCC contact packing gives the higher mass density in this fixed-radius model. Actual hot phases have temperature-dependent dimensions and bonding, so these numbers should not be treated as exact experimental phase densities.
Twice the quadratic coefficient from the previous part is the band curvature . Thus the band effective masses are
Here and . In the weak-potential regime ,
Both have units of mass; their magnitudes are much smaller than in this asymptotic regime. The upper energy band has a local minimum and positive effective mass, while the lower energy band has a local maximum and negative effective mass. The exact lower-branch sign changes at in the two-wave formula; the intended weak-coupling limit lies below that threshold.
The physical meaning follows from the semiclassical equations for an electron wave packet in one energy band:
An upper-band electron near its minimum accelerates in the direction of the applied force, whereas a lower-band electron near its maximum accelerates opposite to it. At the extremum itself the group velocity is zero. A nearly filled lower energy band is conveniently described by electron holes with positive electric charge and positive effective mass . Negative curvature is a response of a crystal energy eigenstate, not a negative bare electron mass. These statements assume slow forcing that does not induce transitions across the band gap.
Let the infinite outer walls be at , the finite steps at , and the three potential energy values be . The original drawing specifies the ordering
The energy eigenstates can be chosen real. The Dirichlet boundary conditions are ; wavefunction matching at a finite potential step requires both and to be continuous at . In particular, neither finite step acts as an additional hard wall.
The time-independent Schrödinger equation gives
Thus a wavefunction is sinusoidal in a classically allowed region, with wavenumber , and a linear combination of exponential functions in a classically forbidden region, with inverse decay length . Its curvature changes sign relative to at a step crossing ; its slope does not jump.
By the Sturm oscillation theorem, the three energy eigenstates have exactly zero, one, and two interior nodes, respectively. Choose their global phases so that their slopes at the left wall are positive:
  • : a positive lobe in the left-hand potential well, followed by a nonoscillatory tail through the barrier and right-hand region. The tail reaches zero at the right wall. There are no interior nodes.
  • : two lobes of opposite sign in the left-hand potential well, with one interior node, followed by a nonoscillatory tail of the sign of the second lobe. Both the middle and right regions are classically forbidden regions.
  • : sinusoidal behavior in both outer regions, joined through the nonoscillatory barrier. There are two interior nodes in total. The right-hand wavelength is longer than the left-hand wavelength, because .
For , the right-hand piece is proportional to , rather than a pure decaying exponential: this enforces the finite-distance hard wall exactly. The barrier pieces likewise contain both exponential solutions. Their small tails are an instance of quantum tunnelling.
Figure 1.
Illustrative lowest three wavefunctions for the potential ordering in A1
. Details.
This is an original illustrative calculation, with vertical lines marking only the region boundaries. It uses , , , , , , and in arbitrary energy units. Its lowest energy eigenvalues are approximately , so it has exactly the required ordering. Here both nodes of the third wavefunction happen to lie towards the left; its dominant lobe is on the right. These precise positions and relative amplitudes are illustrative: the original drawing supplies no numerical lengths, barrier heights, or mass, so it does not determine a unique quantitative wavefunction. The required sketch features are the matching, curvature, hard-wall zeros, and ordered node counts.
A mass on a spring of stiffness , subject to linear viscous damping and a sinusoidal drive, obeys the forced harmonic oscillator equation
Here is displacement, has units , and is a force in newtons. A series RLC circuit is an electrical analogue, with , , and .
For free motion set and solve the characteristic equation . The roots distinguish three cases:
  • For underdamping, , the motion is , where . The amplitude decays on time and the frequency is reduced from its undamped value.
  • At critical damping, , the repeated root gives . This marks the boundary between oscillatory and nonoscillatory relaxation; it is the usual fastest settling without oscillation for a release from rest.
  • For overdamping, , with both roots real and negative. At large damping the slow root approaches , so increasing the resistance to motion can slow equilibration.
The constants are set by initial position and velocity. The mechanical energy and its rate of change in free motion are
For weak damping, the cycle-averaged energy decays approximately as . The quality factor is ; for it equals times stored energy divided by the loss per cycle. Logarithmic decrement of successive free-decay peaks determines experimentally.
For driven motion the complete answer is the decaying free transient plus a steady response at the driving angular frequency:
At low frequency, and the displacement is nearly in phase with the drive. At , the lag is and . At high frequency, and the lag tends to . The displacement resonance maximum lies at
only when . Thus an underdamped oscillator need not have a nonzero-frequency displacement resonance peak.
In the steady state the mean input power equals the mean dissipated power:
This absorption peaks exactly at , rather than at . Its half-power points have bandwidth , so for this linear model. For weak damping, a high quality factor therefore means a narrow strong resonance and a long free-decay time. Exactly zero damping at resonant driving has no finite steady response: a secular amplitude grows with time.
An Euler strut is a slender initially straight elastic column under axial compression. For a uniform bending stiffness and a small transverse displacement , the second-order potential energy under a conservative compressive load is
The bending term is positive; shortening releases load potential. Stationarity yields . Pinned ends impose and zero end bending moments, . Substitution of gives
The straight configuration loses stability first in the longest admissible bending mode. The second moment of area is geometric, not a mass moment of inertia. Boundary conditions matter: a fixed-free column has effective length , while fixed-fixed ends have effective length , changing the threshold by factors and . Slenderness, elastic material response, alignment and the weak bending direction must be checked. Imperfections produce bending before the ideal threshold, and a short column can yield or crush first. Linear buckling theory does not predict an unlimited deflection or a complete postbuckling curve.
A galilean transformation relates inertial frames in uniform relative translation. For the velocity of the primed origin,
Absolute time and invariant acceleration make Newton's second law retain its form for the usual nonrelativistic interactions. For a particle of mass , and . Momentum and kinetic energy are frame dependent, although an isolated system's conservation laws hold in either inertial frame. Relative velocities and collision predictions are consistent between frames. A rotating or accelerating frame instead requires inertial-force terms. Maxwell equations with a fixed light speed are not Galilean invariant; Lorentz transformations replace these relations when relativistic effects matter.
Kepler's laws of planetary motion state that, in the relative two-body description, bound trajectories are ellipses with the attracting body at a focus, the radius vector sweeps equal areas in equal times, and the square of the period is proportional to the cube of the semimajor axis for a fixed total mass. Their Newtonian derivation is especially informative. With relative coordinate and , the inverse-square acceleration is . Its zero torque conserves , fixing a plane and the areal velocity .
For , the orbit equation is as a function of polar angle. Therefore
Bound negative-energy motion has and semilatus rectum . Dividing ellipse area by areal velocity gives
For a planet much lighter than its star, replace by . Zero-energy and positive-energy encounters are parabolic and hyperbolic rather than periodic ellipses. Perturbations from other bodies and departures from point-mass Newtonian gravity can precess or otherwise modify the orbit; Kepler's laws are a two-body approximation, not an exact rule for every observed planetary path.
A tidal force measures the difference of gravitational acceleration across an extended object. A freely falling reference frame removes a spatially uniform acceleration, but not its gradient. For a distant point mass at distance and direction from the reference centre, a small internal displacement gives
The tidal tensor has eigenvalues radially and in each transverse direction: radial stretching and transverse squeezing. Its trace vanishes in the source-free region, consistent with the gravitational Gauss law. An associated relative potential is .
The scale is across size , not the centre's absolute gravity . This distinction explains how a more distant massive object can exert a large force but a modest tide. Opposite-side stretching supports the elementary two-bulge picture; real ocean tides also involve rotation, basin geometry and fluid dynamics, so the static gradient alone does not predict coastal heights or timing. The same gradient stresses satellites and can disrupt a self-gravitating body when it competes with the body's own gravitational restoring acceleration.
A fluid is described on a continuum scale by density, pressure and velocity fields. An Eulerian field is measured at fixed position; a material element changes at rate . mass conservation requires
For incompressible flow this becomes . A streamline is instantaneously tangent to velocity, whereas a pathline follows a particle through time; they coincide in a steady flow but need not in an unsteady one.
For an ideal inviscid fluid, pressure and body forces give the Euler equation. In the constant-density gravitational case,
A stationary impermeable boundary requires zero normal velocity, but inviscid theory does not impose no slip. Taking its steady projection along a streamline gives . If the flow is also irrotational in the connected region, that constant is shared between streamlines. Inviscid does not mean irrotational: rotating ideal-fluid flows are possible. A velocity potential exists locally for an irrotational field, and in incompressible flow it obeys Laplace's equation. The Bernoulli assumptions must be checked before converting a pressure difference into a speed.[ref]
Real fluids transmit shear stress. An incompressible Newtonian fluid with constant dynamic viscosity obeys
The constitutive shear stress is proportional to strain rate, and stationary solid boundaries usually impose no slip. viscosity diffuses vorticity and converts organized mechanical energy into heat; its local dissipation is nonnegative. It cannot generally be included merely by changing the constant in a lossless Bernoulli equation.
In a long straight circular tube, steady fully developed laminar flow has
This Hagen-Poiseuille equation follows by balancing the axial pressure gradient with viscous shear and setting . The parabolic profile, the fourth-power radius sensitivity and the pumping power are experimentally distinct consequences. Entrance regions, rough walls, non-Newtonian response or a changing temperature require additional modelling.
The Reynolds number compares inertia with viscosity. Small values favor creeping-flow balances; high values permit thin boundary layers, separation and turbulence, although transition depends on geometry and perturbations, not one universal critical number. At high Reynolds number an outer flow can be approximately inviscid while near-wall viscosity still determines drag. This resolves why a zero-drag ideal potential-flow model cannot predict the resistance of an ordinary moving body. In turbulent flow, fluctuating Reynolds stresses redistribute momentum and increase the required pressure drop; averaging the equations introduces closure requirements.
A controlled tube experiment measures pressure difference and collected volume per time while changing forcing. Use tracers or a velocity probe to test profile shape, allow sufficient entrance length, and monitor radius and temperature independently. Repeat with reversed flow and at several rates to test offsets and linearity. Dye mixing alone does not measure viscosity or establish a fully developed velocity profile. The original figure below separates a specified laminar velocity profile from an independent pressure/discharge measurement.
A normal mode is a motion in which all displacement coordinates oscillate at one angular frequency with fixed amplitude ratios. For small conservative oscillations, the symmetric stiffness and mass matrices give the generalized eigenvalue problem for small oscillations, . For positive mass and a stable equilibrium, its mass-orthogonal eigenvectors span the motion. A superposition of these modes, with phases and amplitudes fixed by initial displacements and velocities, gives the general solution; different modes need not share a phase.
Use upward end displacements. The spring compressions are and , while the beam's centre rises by . The potential energy is
Static force balance gives , cancelling the linear terms and leaving
For a uniform beam, its central moment of inertia in the vertical plane is . To first order in the tilt, . Its translational and rotational kinetic energies are
Thus and . The normal modes of a rigid beam on two end springs have eigenvectors
The first translates without tilt; the second rocks about a stationary centre. Ordinary frequencies are and .
Assume the system had settled before the end load leaves, and put that load at end 1. Its extra static spring load is at that end and zero at the other. Therefore , , and both initial velocities vanish because no impulse is imparted. Decomposing into the two normal modes gives
Only the symmetric mode contributes to the centre position:
The datum is the unloaded beam's equilibrium height; no absolute height is supplied. The rocking mode is present even though it cancels out of this coordinate. These results use small tilt, , ideal light vertical springs and negligible damping.
Use the Euler-Bernoulli beam equation for a uniform slender elastic beam, small deflection and small slope, neglecting axial tension, shear deformation, rotational inertia of a cross-section and damping. Let be Young's modulus, the second moment of area about the neutral axis, and the mass per unit length. If density instead denotes mass per volume, replace this by . The bending stiffness is ; the small-slope curvature is . The bending and kinetic energies are
Twice integrating the variation of by parts gives the restoring load per unit length. Newton's second law therefore gives
At a pivot, displacement is fixed but slope is free; zero end bending moment gives . This also follows from the natural boundary term in the variation.
With separation of variables, gives
Choose the time normalization . Initial rest removes the sine time term, so . The spatial characteristic roots are , giving
The two conditions at give and , hence . At , addition and subtraction of give and . Nontrivial positive-frequency modes therefore have and . Thus the simply supported beam normal modes are
The zero-frequency cubic solution also vanishes under these four endpoint conditions, so is not an additional mode.
For the specified release, small slope requires . Expand the initial deflection in the Fourier sine series. Its coefficients are
Writing , the resulting motion is
Only odd normal modes occur because the initial profile is symmetric about the midpoint, and their amplitudes decrease as . The frequencies grow as , so the motion is dispersive and is not a single shape multiplied by one cosine. Nevertheless the ideal undamped solution is exactly periodic with period . At all odd-mode cosines vanish, so the bar is instantaneously straight; at it has the opposite initial deflection. The first mode dominates displacement, with third-mode amplitude only of the first.
There is initial curvature incompatibility at a moment-free beam end: the prescribed parabola has , whereas a moment-free pivot requires zero curvature at an endpoint. Therefore the data do not define a classical solution with curvature continuous through the two end-time corners. They do define a finite-energy weak solution after release of the forces or end moments that prepared the initial shape. The sine expansion represents that solution: its displacement reproduces the initial parabola, each mode satisfies the released endpoint conditions, and gives finite bending energy. One must not differentiate the initial series twice at its endpoints and assign the interior parabola's curvature there. This qualification leaves the modal displacement prediction intact.
Figure 1.
Original modal evolution after releasing a parabolic elastic beam deflection
. Details.
Kepler's third law for negligible planet mass gives . Therefore . The furthest point is apoapsis, so
The supplied orbital period and eccentricity are sufficient; no present-day ephemeris is needed.
Let be circumferential tension. A small arc subtending has inward resultant and mass . Its centripetal acceleration gives . Circumferential stress is and the strain is . Thus the centrifugal strain of a thin elastic hoop is
Use the unstrained radius and cross-section at this order. The approximation requires , a slender hoop and linear elastic response; the area cancels.
A small displacement in a homogeneous isotropic elastic solid obeys linear elasticity. With Lamé constants and mass density , momentum balance gives
A longitudinal plane wave has displacement parallel to its propagation direction and changes local volume. A transverse wave has perpendicular displacement and produces shear. Substitution gives
An ideal fluid has no static shear modulus and cannot support this bulk transverse elastic wave. A thin rod with free lateral surfaces instead supports an extensional long-wavelength mode with speed ; its transverse contraction changes the effective stiffness, so it should not be identified with the unbounded-solid longitudinal mode.
Stress and displacement boundary conditions produce reflection, transmission, mode conversion and guided waves. Viscoelasticity and scattering can attenuate waves; finite geometry can make guided modes dispersive even when the bulk elastic constants are frequency independent. Wave speed depends on both material stiffness and the allowed deformation.
Choose body-fixed principal axes through a fixed point or the centre of mass, with principal moments . Angular momentum has components . The inertial derivative is the body derivative plus , so Euler's equations read
They avoid differentiating the rotating inertia tensor in laboratory coordinates. Torques must refer to the chosen point, and the displayed fixed moments require a rigid body.
For zero torque, laboratory angular momentum is constant, while its components can change in the body frame. Both and rotational kinetic energy are conserved. The intersections of their constant-value surfaces constrain the motion. For distinct , steady rotation about either extreme principal axis is stable against small perturbations, whereas rotation about the intermediate axis is unstable. For example perturbing rotation about axis 2 gives
whose coefficient is positive. A symmetric body has additional simplifications and can precess. Conservation of laboratory angular momentum does not imply constant body-frame angular velocity.
A velocity field assigns a velocity to each point. Following a fluid parcel rather than holding position fixed gives the material or convective derivative
The convective term can accelerate fluid even in a steady flow, for example as a stream narrows. Conservation of mass is ; constant-density incompressible flow has .
For an incompressible Newtonian fluid of constant density and viscosity, with conservative body-force potential per mass , momentum balance is
Neglect viscosity and assume steady flow. Dotting with an element along a streamline, or using , gives
This is Bernoulli's equation: pressure work, kinetic energy and gravitational potential energy interconvert. In a connected irrotational region under the same assumptions, is the same for all streamlines. In a rotational flow it can vary between them. Viscous dissipation, pumps or unsteady motion require the corresponding modified balance; the steady inviscid expression cannot be applied indiscriminately.
Vorticity measures local fluid rotation. For constant-density incompressible flow it evolves by
showing vortex stretching and viscous diffusion. A potential flow has locally, so irrotational incompressible motion satisfies . Boundary conditions then determine flows around simple shapes. A multiply connected region can have circulation even when its local vorticity vanishes; ideal potential flow also misses no-slip boundary layers and viscous drag.
For a Newtonian fluid, shear stress is proportional to strain rate. No-slip at solid walls produces velocity gradients and dissipation. Fully developed laminar pipe flow, for example, has
The Reynolds number compares inertial and viscous terms. Small values favour creeping-flow approximations; large values can permit thin boundary layers and turbulence, without guaranteeing turbulence in every geometry. The appropriate flow model follows from conservation laws, constitutive properties, boundaries and scale comparisons.
At coexistence, the two phases have equal chemical potential. For a single component, , with entropy and volume measured on the same molar or mass basis. Equating the phase derivatives along coexistence gives . Reversible latent heat satisfies , hence
Here and are coexistence pressure and absolute temperature, is latent heat for transforming phase 1 to phase 2, and uses the same amount of material as .
For vaporization, neglect liquid molar volume compared with ideal-vapour volume . The ideal-vapour Clausius-Clapeyron approximation becomes
Using the normal boiling reference , and the supplied constant gives
This deliberately constant-latent-heat extrapolation does not reproduce the supplied triple-point pressure exactly. It predicts the liquid-vapour branch, metastable against ice below the triple-point temperature; it is not a precision sublimation-pressure prediction.
The phase diagram has solid, liquid and vapour regions meeting at the triple point. The sublimation and vaporization boundaries have positive slopes, whereas the ordinary ice–water boundary slopes negatively because ice has larger specific volume. The liquid–vapour line terminates at a critical point; the original schematic below emphasizes topology and marks the supplied triple point.
Figure 1.
Schematic pressure–temperature phase topology of ordinary water, with negative melting slope and the supplied triple point
. Details.
For the melting-pressure estimate, Archimedes' principle gives , so
Convert the molar evaporation heat using water molar mass , rounded from the tabulated value .[ref] An enthalpy cycle through vapour then gives
This uses the question's temperature-independent evaporation heat all the way to the triple point; no replacement experimental fusion heat is inserted. The melting pressure inferred from flotation and latent heats, on holding and constant, is
using and . Linearizing the logarithm about the triple point gives instead of . Both are estimates within the stated constant-property approximation; the negative melting slope makes a positive pressure necessary to lower the melting temperature.
Capacity convention. The printed equation requires to be volumetric heat capacity, in . If “specific heat capacity” means per unit mass instead, the storage term is and both denominators in the printed equation must contain . This distinction is fixed by dimensions.
For a fixed material region , conservation of thermal energy gives the heat balance with volumetric heat generation,
Use the divergence theorem, and constant coefficients. Since the region is arbitrary,
The heat source is power per volume, while is thermal conductivity rather than thermal diffusivity.
For uniform electrical conductivity and imposed current, current density is and Joule heating is . A long, steady, cylindrically symmetric wire therefore satisfies
Integration gives . Regularity at makes , and the surface condition fixes the remaining constant. Thus the Joule-heated cylindrical wire has
Here denotes the printed radial coordinate and avoids confusing it with mass density. The centre is hotter by .
For the air boundary, the internal flux at is . Equate this to . The Newton cooling of a Joule-heated wire gives
Multiplication by circumference verifies that surface loss per length equals , the electrical power per length. The full air-cooled profile uses this surface temperature plus the same parabolic interior excess, assuming constant material properties and negligible end losses.
With the standard liquid-water approximation , each portion has mass . The equal heat capacities give final temperature by energy conservation. For an insulated mixing process with no other changes,
The reversible integrals evaluate entropy differences between equilibrium states; the actual heat transfer is irreversible. These are two portions of the same substance, so there is no additional ideal-mixture compositional entropy.
A fictitious force is a term required when writing Newton's second law in an accelerating frame; it comes from the coordinate choice rather than a new interaction. For axes rotating at constant about a fixed inertial origin,
Apply this identity twice to position to get . Moving the last two terms to the right of gives the stated Coriolis and centrifugal forces. An accelerating origin or changing rotation rate would add further terms.
A slowly rotating fluid planet follows an equipotential of gravitational plus centrifugal potential. The centrifugal potential is , most negative at the equator. An outward equatorial shift raises gravitational potential and restores the balance, producing an oblate figure. Self-gravity also changes with the shape; no flattening coefficient follows from rotation alone without a density model.
Using local north and radial-up unit vectors, the centrifugal acceleration on a stationary mass is
It points away from the rotation axis: upward and equatorward, at angle to radial up in the northern hemisphere. Its vertical fraction of gravitational force is
using a day for this approximate number. The resultant effective weight tilts equatorward relative to radial down. A plumb-defined local vertical already follows effective gravity; the component calculation uses the spherical radial vertical. A supported stationary mass of course has zero net acceleration.
For the Coriolis deflection of vertical launch and drop, retain only first order in , use effective constant , and neglect horizontal velocities in the Coriolis term as instructed. With east positive, vertical velocity gives and no northward acceleration. For launch, and the flight time is . Integrating with zero initial horizontal velocity gives
The landing is westward. The westward velocity accumulated on ascent is only recovered on descent, so the two displacement contributions do not cancel.
For release from rest at , , , and . Thus
The drop lands eastward with one quarter the launch-return displacement magnitude. North–south corrections from horizontal Coriolis coupling are beyond the retained approximation.
Figure 1.
Original centrifugal geometry and opposite east–west deflections for launch-return and drop trajectories
. Details.