For a spherical star in Newtonian hydrostatic equilibrium, the total supporting pressure satisfieswhere zero external pressure is the idealized vacuum boundary condition. Substitute the enclosed mass from a, set , and integrate inwards:The supplied integral follows directly by differentiating . It yieldsThus , about for the Sun's parameters. This is precisely the equation of state of a polytrope of index one.
For nonrelativistic fully ionized hydrogen with electrons and protons at a common temperature, the gas pressure is . If gas pressure dominates, the resulting temperature profile isNumerically for the Sun's parameters, and tends to zero at the idealized outer edge.
If the photons are additionally assumed to be in local thermodynamic equilibrium with this gas, their radiation pressure is , with . The consistent temperature is instead the unique nonnegative root ofThe left side is strictly increasing in for , so the root is unique. Evaluating the radiation pressure at gives at most for the Sun's parameters, at the centre; the ratio decreases approximately as outwards. The gas-only profile is consequently an excellent approximation within this imposed stellar model.
Hydrostatic equilibrium by itself fixes total pressure, not how it is divided between gas and radiation. Thomson scattering alone does not enforce a common gas–radiation temperature or a Planck photon distribution. Without either neglecting radiation pressure or specifying the radiation field and its thermodynamic closure, a unique gas temperature cannot be inferred from the given mass density alone.
Here is the cosmological scale factor, is cosmic time and is the Hubble parameter. With a length, labels positively curved, flat and negatively curved spatial sections. This is unrelated to Question 1's specific orbital energy. The density is mass-equivalent energy density: has energy-per-volume units. In the displayed Friedmann equation has units ; the geometric cosmological constant is . For a separately conserved fluid of constant equation of state , the cosmological perfect-fluid continuity equation gives , so : zero for pressureless matter and one for radiation. With several fluids, sum their densities in the expansion equation and evolve each separately.
Setting cosmological spatial curvature and the cosmological constant to zero gives the mass-equivalent cosmological critical density,Its energy-density version is ; keeping this distinction is necessary when dividing a radiation energy density by below.
In an Einstein-de Sitter universe, integrates to and . With ,Here are the two epoch redshifts relative to today. This is elapsed cosmic time, not comoving distance divided by .
For collisionless preservation of a Planck spectrum, use frequency redshift as well as photon-number conservation. Let , so a frequency bin now corresponds to and initially. Collisionless propagation conserves photon number in the corresponding comoving bin:For an initial blackbody spectrum, insert its Planck distribution to obtainThe factors from the numerator cancel the spectral dilution factor, while the exponent changes only the temperature. Integrating gives photon number density proportional to and radiation energy density proportional to . Conservation of total photon number alone would not guarantee a blackbody spectrum shape; the frequency-bin mapping and absence of injection or spectral redistribution are essential.
For the numerical density comparisons, the supplied Hubble constant is . Taking and givesThe radiation specified here is cosmic microwave background photons only. Adding a relic neutrino density would change the photon-only matter-radiation equality result. The rounded present matter and vacuum fractions sum to one without this small photon contribution; the requested pairwise density comparisons do not require silently renormalizing them.
For the final unlabelled flight-time request, insert the case-(c) value into the stipulated Einstein-de Sitter formula:The two model ages are approximately and years. This uses exactly the instructed matter-only model with the same . It is not an exact age difference in the matter-plus-vacuum cosmology; a high-redshift matter-era normalization using would be a different approximation.
For spherical hydrostatic equilibrium, the stellar structure equations includeEliminate to obtain . Since through the interior, integration givesWith negligible surface pressure, this provesThis is a conservative lower bound; concentrating mass near the centre increases the required pressure.
For the temperature inference assume predominantly ideal gas support, a nearly fully ionized hydrogen–helium mixture with mean molecular weight , and the hottest region at the centre. A rigorous scale estimate follows from the stellar virial theorem, rather than substituting the mean mass density for the unknown central mass density. With negligible surface pressure,The ideal gas law gives . The mass-weighted mean temperature consequently obeysThis establishes several million kelvin under the stated physical assumptions. The central pressure inequality alone does not give a central temperature bound without an equation of state and information about mass density or an integrated argument.
Differentiate the equation of state at fixed temperature:Above the transition, zero-field equilibrium has . Below it the stable pure phases have . ThusThis is the mean-field magnetic-susceptibility amplitude ratio. Below the transition, take a one-sided response in a selected ordered phase: the globally minimizing magnetization switches discontinuously between opposite phases when crosses zero. Its two-sided derivative at precisely zero field is therefore not the finite pure-phase magnetic susceptibility used in the ratio.
An equation of state relates equilibrium pressure, temperature and density. The ideal-gas form neglects intermolecular forces and excluded volume. A low-density real-gas expansion iswhere the virial coefficients encode interaction effects and generally depend on temperature.
A simple phenomenological example is the molar Van der Waals equationHere v is molar volume, b represents excluded volume and the attractive interaction lowers pressure through a. Its dilute expansion gives . It recovers the ideal-gas limit but is not a quantitatively universal equation for all real gases.
Below its critical temperature, the raw isotherm contains a region with , corresponding to negative isothermal compressibility and mechanical instability. Equilibrium phase separation replaces that segment by a coexistence pressure satisfying equal chemical potentials, equivalently the Maxwell equal-area construction. The critical point follows from :The distinction between an unstable homogeneous branch and a stable two-phase state is essential when interpreting a real-gas equation of state.
At zero applied field, time-reversal symmetry interchanges and without changing the free energy, so the analytic expansion contains only even powers. The term breaks this symmetry at fixed nonzero H. Stationarity and local stability requireFor at small field, the cubic term is higher order and . Thus the susceptibility as defined in the question isThe three requested free-energy sketches and their minima are given separately above.
For the plotted isotherms, divide the equation of state by nonzero M and rearrange:This is an Arrott plot: its slope determines b, and the isotherm through the origin identifies the mean-field Curie temperature.[ref]
Criterion for Ferromagnetism from Observations of Magnetic Isotherms by Anthony Arrott. 1957, abstract: molecular-field criterion from cubic magnetisation versus internal field at the Curie temperature
Under the paper's stated uniform-field Landau model, use H as supplied on its axis.The ordinate unit is . Reading the original graph gives slopes about – ordinate units per unit H/M, so the physical slope is approximately . ConsequentlyApproximate horizontal intercepts and the corresponding are:
The sign change brackets the transition between 19 and 25 K. A linear fit of across the four read-offs gives approximately andInterpolating only the two nearest isotherms also gives about 22 K. These are graph estimates, not exact recovered measurements.
Below at zero field, the stable branches have . Substitution gives the free-energy density relative to the omitted smooth background:The equilibrium excess heat-capacity density is below and zero above it. ThereforeThe all-isotherm linear fit gives about . Estimating the slope only between the 19 K and 25 K curves instead gives and a jump near . The lines are not exactly parallel and the intercepts are not perfectly linear in T, so a jump of order a few is supported; finer precision is not. This is per volume because F is a density; no sample volume is given to convert it to a total heat capacity.
If , the quartic truncation is unbounded below. Add a positive sixth-order term with . At zero field the coexistence conditions giveThus the zero-field transition is generically first order, with a discontinuous spontaneous magnetisation and possible metastability. It occurs before the quadratic coefficient reaches zero. The case is the tricritical boundary of this mean-field model; no value of c is invented.
Using and the stated Maxwell relation, interchange derivatives within a smooth single phase:Therefore depends only on temperature for the given temperature-linear equation of state. It need not be constant in temperature.
For a canonical ensemble, and . The kinetic and factorial factors do not depend on , so differentiating only the volume-dependent terms givesThus the equation of state isThe excluded-volume correction raises pressure relative to the same gas without that correction; the attractive mean-field term lowers it. No Stirling formula is required for this derivative.
First solve the equation of state for the volume:The Gibbs free energy has differential . At fixed temperature and particle number, integrate between the two pressures:ConsequentlyUse , keeping both endpoint pressures fixed while differentiating the difference:Equivalently, the Maxwell relation gives , whose pressure integral is the same result. These are the Gibbs free-energy change for a pressure-linear gas correction identities. The physical path requires and positive volume throughout. The correction has units of volume per particle, so each term in is an energy and each term in has units of energy per kelvin.
Classical translational statistics. Write the number density as and the thermal de Broglie wavelength as . Quantum exchange is negligible when wave packets rarely overlap:The equivalent state-counting statement is that the mean occupation of each thermally relevant one-particle state is much smaller than one. The equations in this question count one internal species; with equally populated spin states the relevant density per species is .
Let be the dimensionless quantum gas fugacity, with the lowest one-particle energy chosen as zero. Both quantum distributions can be writtenIf , then for all , recovering Maxwell–Boltzmann statistics. Conversely, low occupation even at the spectrum's bottom requires for bosons or for fermions; either condition impliesA single high-energy state can be sparsely occupied even in a degenerate gas, so the condition must hold across the relevant spectrum, not just for one arbitrarily chosen energy. Also, classical translational statistics does not imply that all internal excitation energies or other quantum effects can be ignored.
Grand partition function, density and pressure. Noninteracting particles have independent occupations of each one-particle state. Put . Summing the allowed occupations givesThereforeThe grand potential is for this homogeneous gas. Replacing the sum by and using givesThe mean number is , givingFor bosons, the grand sum requires when the ground energy is zero. A macroscopic condensate at the limiting must be separated from the continuum integral in the condensed phase. The following small- calculation is in the normal, nondegenerate regime, so that complication does not enter.
Density expansion and inversion. Expand the occupation as a geometric series:The Gaussian wavevector integral for its th term isIt follows thatFor the inverse series, put and try . Substitution gives , henceThe leading equality directly connects the density and occupancy criteria for classical behavior.
Pressure and its first quantum correction. Expanding the logarithm in the pressure expression gives one extra factor compared with the density series:Insert the inverse series. To second order in ,ThusThe first quantum correction at fixed density and temperature isIt is negative for bosons and positive for fermions, and vanishes in the classical density limit.
Virial coefficient. Define the number-density virial expansion byThe coefficient has units in this convention. Comparing terms givesThis is the exchange contribution to the second virial coefficient. It arises without a pair-interaction potential; the underlying gas is noninteracting. A molar-density convention would multiply this by the Avogadro constant. For equally populated internal species, exchange occurs within each species and the coefficient in terms of total density is smaller by a factor .
Why the two signs differ. Bosonic exchange symmetry enhances the probability of nearby identical bosons, whereas fermionic exchange symmetry suppresses nearby identical fermions in the same internal state. In the dilute regime, the normalized equal-time pair detection correlation isThe exchange part follows by squaring the Gaussian one-particle coherence factor . At zero separation this gives for bosons and for one-component fermions. Integrating the exchange pair weight provides a direct coefficient check:Bunching therefore acts like an effective statistical attraction in the dilute equation of state, lowering the pressure needed at fixed density. Exclusion acts like an effective statistical repulsion, raising it. Neither description asserts an actual interparticle force. Different internal fermion species do not exclude each other from a common spatial location in the same way, explaining the importance of the species convention.
Use the Gibbs-Duhem equation for a homogeneous, extensive, single-component thermodynamic phase:At fixed temperature, this becomes , with number density . Separately, at fixed particle number,The chain rule along the same isothermal process in the equation of state now givesConsequentlyThis is isothermal compressibility from chemical-potential response. Since chemical potential has units of energy per particle, the right-hand side has units of volume per energy, or , as required. The derivation assumes a smooth bulk equation of state; changing the fractions of coexisting thermodynamic phases at fixed pressure needs separate treatment.
Availability and total entropy. The reservoir changes by and . Its particle number and the system's particle number are fixed. The reservoir's first law of thermodynamics therefore givesAdd the system's entropy change. Because are constant,Thus define the availabilityAn additive constant in is immaterial; its value above the equilibrium reference is the exergy. The Second law of thermodynamics gives , hence . A stable equilibrium maximizes total entropy over the allowed variations and therefore minimizes . The environmental enter this definition even when the system has not yet reached their values. Because both thermal and mechanical exchanges are allowed, equilibrium here includes mechanical balance; equality of temperatures alone does not ensure the minimum.
Probability and curvature. For a fixed value of a macroscopic coordinate , let count the compatible system microstates. The product of the system and reservoir multiplicities isAll factors independent of enter a normalization constant, givingHere is the constrained or effective availability for this coordinate, including the multiplicity of any eliminated variables. A nonuniform coordinate measure must likewise be retained or incorporated in that effective availability.
At a stable interior minimum, and . Its Taylor expansion givesKeeping the quadratic term yields a normal distribution,This is availability curvature and equilibrium fluctuations. The quoted fluctuation formula holds at quadratic order in the Gaussian fluctuation approximation; it is not an exact identity for an arbitrary nonlinear . Higher terms can shift the mean away from its most probable value .
Bubble equilibrium. Keep the number of air molecules fixed and include the surface energy in the system's total internal energy. For constant surface tension , this contribution is , with no surface entropy under the stated approximation. Its differential isHenceIndependent thermal and volume variations give andThe air pressure is evaluated at ; since the bubble is closed it generally depends on volume, so this equation is implicit until an air equation of state is supplied. For a sphere, , , and the pressure jump becomes , the Young–Laplace equation for a single gas–liquid interface. There is no second surface as in a thin soap film.
Isothermal volume fluctuations. With the air maintained at , eliminate its entropy in favor of its Helmholtz free energy:The identity givesUsing the curvature result,These are the volume fluctuations of a closed gas bubble. Stability requires the denominator to be positive. The negative surface contribution reflects the concavity of ; gas compression supplies the positive restoring curvature. For ideal air, , and mechanical equilibrium reduces the denominator toThe units are consistent: is pressure, so has units , the units of a volume variance. Holding externally fixed while varying would remove the gas-compression term and change this stability problem; that is not the fixed-particle-number situation here.
Numerical size of the fluctuations. The volume conversion is important:Use the specified , and . ThenWith the Boltzmann constant ,Thus the fractional root mean square fluctuation and fractional variance are respectivelyThe absolute root mean square fluctuation is . The very small fractional value supports the local Gaussian fluctuation approximation. This estimate neglects exchange of dissolved air, variations of surface tension, shape fluctuations and temperature fluctuations, consistently with the prescribed fixed-number, isothermal bubble model.
Past exam of the topics in fluid mechanics course of the University of Oxford 2008 1 Solution 2026-10-31
The four dimensional equations express mass conservation, momentum balance with pressure, gravity and viscous stress, heat advection and conduction, and a linear thermal-expansion equation of state. For heating from below, suitable plate conditions are and at , and , at . No slip and thermal insulation on the sidewall provide one suitable lateral completion; prescribed lateral temperatures would be another specified thermal setup.
Let be thermal diffusivity and kinematic viscosity. Use , , and as length, time, velocity and temperature scales. Subtract the static reference pressure with and scale its remainder by . ThenDensity becomes . Substitution and division by the corresponding diffusion/viscous scales giveIn the Boussinesq small-density-contrast limit retain buoyancy while neglecting the other factors. At infinite Prandtl number, after any fast initial adjustment, the equations areThe velocity is instantaneously constrained by a viscous elliptic balance; the temperature still evolves.
Take the divergence of the vector Poisson equation. Derivatives commute, and divergence of a curl is zero, so . Its boundary value is zero, hence the maximum principle gives throughout . The vector identity now gives , orThe layer domain is simply connected because its horizontal section is simply connected. For a curl-free field on such a domain, define as its line integral from a fixed base point to . Contractibility of loops and Stokes theorem make the integral path independent, and differentiation gives its gradient equal to the field. Thus .
Incompressibility then gives , while the prescribed normal curl gives . Green's identity yieldsHence is constant on the connected domain and . The extra condition belongs to the stated potential boundary problem; the reconstruction argument above uses the divergence and normal-curl conditions. On a multiply connected domain a curl-free field need not be a globally single-valued gradient.
Finally . Taking the curl of the infinite-Prandtl momentum balance and using givesThe derivation is an instance of velocity reconstruction from a mixed-boundary vector Poisson problem.
Phase diagram Created 2026-09-24 Updated 2026-10-14
A phase diagram partitions a space of thermodynamic variables into regions occupied by different equilibrium thermodynamic phases and records the phase coexistence curves between them. For a pure, one-component substance, a pressure–temperature phase diagram gives one point for each pair . In a single-thermodynamic phase region both controls can vary independently. On a two-thermodynamic phase phase coexistence curve, they obey one relation; at a triple point, both are fixed. These statements assume bulk thermodynamic equilibrium, fixed composition and no additional applied fields.[ref]
Gibbs Phase Rule (MIT 10.213 course material). Gibbs Phase Rule, single-, two- and three-phase counts and final pressure–temperature diagram paragraphs
At fixed temperature and pressure, the stable bulk thermodynamic phase minimizes Gibbs free energy for a fixed amount of substance. For a pure substance this is a comparison of chemical potentials on a common normalization. Two candidate thermodynamic phases coexist where and neither is exceeded in stability by a third thermodynamic phase. Differentiating their equality gives the Clapeyron equation. Thus a phase coexistence curve is a locus of equal stability, rather than a trajectory that every heated sample must follow.[ref]
The following original cartoon uses dimensionless positive coordinates and , with arbitrary reference scales . It represents no particular substance and contains no measured data. Stipulate a triple point at , a liquid-gas critical point at , and these drawing rules:They specify sublimation, liquid–gas phase coexistence and melting boundaries for the picture. They are not an equation of state, do not predict latent heat or mass density, and do not supply a quantitative critical theory. In particular, the melting slope is merely an illustrative choice.
Generic dimensionless pressure–temperature phase diagram: curves, triple point and liquid-gas critical point
. Original cartoon with stipulated drawing rules. Three distinct bulk thermodynamic phases coexist at ; the liquid–gas boundary ends at . The fluid region beyond that endpoint is connected: no extra boundary is implied by the fading background. These coordinates are not water data. Details.For example, at fixed the melting boundary is at and the liquid–gas boundary is at . Heating from to therefore starts in liquid, crosses phase coexistence at , and ends in gas. In an equilibrium conversion at that crossing, added heat can change the phase fraction at fixed temperature through latent heat. The pressure–temperature point alone does not specify how much of each thermodynamic phase is present: for that one needs an additional amount or volume constraint.
Now connect exactly the same endpoints by raising from to at , moving to at , then lowering to . The first leg stays on the liquid side because ranges only from to and . The second leg lies above the entire liquid–gas boundary, whose largest drawn pressure coordinate is ; the third lies beyond its largest temperature coordinate, . No leg crosses a first-order phase transition boundary. The middle leg passes through a supercritical fluid region, with and , and the final leg returns to a gaslike state continuously.
The same liquid and gas endpoints: crossing phase coexistence or going around the liquid-gas critical point
. Original dimensionless cartoon. The orange constant-pressure path crosses the liquid–gas boundary at . The blue path follows to to to and avoids every drawn phase coexistence curve. Dashed coordinate guides locate the critical endpoint without representing additional boundaries. Details.Avoiding a first-order phase transition does not mean that no heat or work is exchanged. Along the detour, mass density, enthalpy and heat capacity may change substantially but continuously. The liquid-gas critical point itself has singular behavior, so the detour goes around it rather than through it. This connected fluid region is the striking lesson of a phase diagram: a familiar change from liquid to gas need not involve boiling across a sharp boundary.
An equilibrium phase diagram also does not predict how rapidly a conversion occurs. Metastability and a barrier described by classical nucleation theory can delay the observed phase transition. Nor should a binary-composition phase diagram be read as the same picture: its coexistence regions and lever rule encode composition and phase fractions, and can occupy an area even though pure-substance two-thermodynamic phase coexistence occupies a curve in the pressure–temperature plane.
Photon gas 2026-10-13
A photon gas is a collection of photons described statistically as radiation. Here the equilibrium model is homogeneous, isotropic electromagnetic radiation in vacuum at temperature : each photon has energy , with momentum and frequency , and there are two independent transverse states of electromagnetic polarization. An absorbing cavity with walls at a common temperature provides a way to establish this thermal equilibrium. The bulk formulas assume cavity dimensions much larger than the typical wavelength , so the electromagnetic mode density in a box can replace individual cavity modes by a continuum. [ref]
https://davidtong.org/teaching/statistical-physics/statmechhtml/S3#S3.SS2. David Tong, Statistical Physics, §3.2: photon energies, polarizations and cavity equilibrium
The crucial constraint is whether photon emission and photon absorption, or other number-changing processes, can equilibrate the photon population. When they can, photon number is not an independently conserved quantity and the equilibrium photon chemical potential is . For each polarization and frequency, the mean occupation number then follows the Bose-Einstein distribution:If number-changing processes are ineffective but number-conserving interactions redistribute energy, a constrained Bose-Einstein distribution can instead have with chemical potential fixed by the number constraint. Thus thermal equilibrium with respect to energy exchange alone does not establish . The zero value can also persist in an already prepared Planck photon distribution during suitable subsequent evolution; continual photon emission is not required to preserve it. [ref]
https://academic.oup.com/ptep/article/2014/6/06B107/1560917. Hiroyuki Tashiro, CMB spectral distortions and energy release in the early universe (2014), §3.1: kinetic equilibration without full photon-number equilibration
Combining with the two-polarization density of states, , gives the Planck photon distribution and the spectral photon energy density:Here is the spectral radiance in Planck's law; is stored energy density per unit frequency, not outgoing power per area. Their different units are connected by the full-sphere solid angle and the speed of light . The Boltzmann constant is , and is the Planck constant. [ref]
The equilibrium equation of state is particularly simple:The radiation constant is the same constant called in black-body radiation; is the Stefan-Boltzmann constant. An outline of the energy density calculation substitutes and uses . The radiation pressure follows because the angular average of the squared directional component of photon momentum is for isotropy; the thermodynamic derivation of blackbody radiation pressure supplies an independent route. These formulas describe the radiation contribution, not the cavity walls. The isotropic massless relation survives a different isotropic spectrum, whereas the coefficient in requires the zero-chemical potential Planck photon distribution.
For a computed example with stipulated , the photon energy density is and the radiation pressure is . The photon number density in the International System of Units isHere is the Riemann zeta function. The mean photon energy differs from the energy at the peak of a spectral curve: counting photons and weighting them by energy emphasize different frequencies. The calculations use the exact International System of Units values of the Planck constant, Boltzmann constant and speed of light. [ref]
https://www.nist.gov/si-redefinition/meet-constants. NIST, Meet the Constants: exact SI defining constants
A motivating observation is the cosmic microwave background spectrum measured by the Far Infrared Absolute Spectrophotometer (FIRAS) aboard COBE. Its apparatus used a polarizing Michelson interferometer, with one input viewing a roughly seven-degree sky patch and the other an internal blackbody. Scanning mirrors changed the optical path length difference; heat-sensitive detectors recorded the varying power, and Fourier transform spectroscopy recovered the spectral difference. Operation outside the terrestrial atmosphere removed atmospheric emission and absorption, while shielding and cooling the optics in a helium cryostat suppressed the instrument's own radiation. [ref]
https://lambda.gsfc.nasa.gov/data/cobe/firas/doc/FES4_APP_B.pdf. Mather, Fixsen and Shafer, Design for the COBE Far Infrared Absolute Spectrophotometer, apparatus and systematic-error controls
Absolute calibration came from moving an external blackbody into the sky aperture, filling the same beam used for the sky. This was an iron-loaded epoxy absorber shaped as a re-entrant cone. Repeated reflections made it a close approximation to a blackbody, while thermometers supplied its temperature. Mather and colleagues explicitly evaluated reflections, temperature gradients, radiation leaking through the material and leakage around its edge. These are limits on how faithfully the calibrator realizes thermal equilibrium radiation, rather than details that can be eliminated merely by calling it black. [ref]
https://arxiv.org/abs/astro-ph/9810373. Mather et al., Calibrator Design for COBE FIRAS (1999): absorber geometry and calibration error budget
During sky observations the internal blackbody temperature was adjusted to nearly null the spectral difference, reducing gain and drift errors. Fixsen and colleagues' 1996 analysis used calibrated spectra over wavenumbers to , about to . They separated the sky's spatially uniform component, its dipole and Galactic emission, and varied sky cuts and foreground templates as controls. The resulting cosmic microwave background spectrum agreed with a single Planck function, with reported RMS deviations below 50 parts per million of its peak brightness. This is a residual statistic over the analyzed spectrum, not a pointwise relative error bound at every frequency. [ref]
https://arxiv.org/abs/astro-ph/9605054. Fixsen et al., The Cosmic Microwave Background Spectrum from the Full COBE/FIRAS Data Set (1996), §§2, 5 and 5.3
The observation motivates using a photon gas as a physical model rather than merely a formal counting exercise. Its interpretation has a clear boundary: agreement with Planck's law constrains departures from an equilibrium spectral shape within the calibrated band and foreground assumptions; it does not directly measure radiation pressure or entropy density of a photon gas. Nor does it establish that today's cosmic microwave background is continually re-equilibrating with matter. A previously thermal spectrum can retain its Planck function shape as expansion of the universe lowers every photon frequency in the same proportion. The usefulness of the model is that one measured spectral temperature, together with its equilibrium assumptions, predicts energy density, radiation pressure, photon number density and entropy density of a photon gas consistently.
Platinum resistance thermometer Created 2026-10-14 Updated 2026-10-20
A resistance thermometer using platinum as its sensing material. It provides the temperature readout in the saturation-pressure equilibrium measurement.
Transduction turns electrical resistance into a temperature indication. A uniform wire has , with electrical resistivity , length , and cross-sectional area . Stronger atomic vibrations at higher temperature scatter electrons more, increasing platinum's electrical resistivity; impurities and crystallographic defects also contribute.[ref]
Guide on Secondary Thermometry: Industrial Platinum Resistance Thermometers by Jonathan Pearce and others. Guide on Secondary Thermometry: Industrial Platinum Resistance Thermometers, §2.1, printed pp. 6–7: resistivity, electron scattering, and impurities
A small known electric current and measured electric potential difference give through Ohm's law; a resistance bridge can instead compare the element with a reference resistor. Inverting the calibrated response then gives the sensing element's temperature. This makes electrical readout convenient, but the platinum resistance thermometer lead resistance error, resistance thermometer self-heating, and resistance thermometer immersion test explain why a stable display alone is insufficient. The gas thermometer supplies a contrasting route through an equation of state; the saturation-pressure equilibrium measurement shows why a trustworthy independent temperature readout matters.
Quasistatic process 2026-10-14
A quasistatic process is an ideal limit in which a changing thermodynamic system passes through a sequence of states arbitrarily close to thermodynamic equilibrium. Its intermediate pressure, temperature and volume are therefore well defined and obey its equation of state. Driving must be slow compared with the system's own equilibration, rather than merely taking a long time on a clock. A reversible thermodynamic process additionally allows both system and surroundings to be restored without net change; friction can produce entropy even in a quasistatic process.[ref]
For a computed example, take a fixed amount of substance of ideal gas in a sealed cylinder with a frictionless piston, in contact with a heat bath at absolute temperature . Reduce the external load in infinitesimal steps so that the piston expands from to . In the reversible limit, the gas pressure exceeds the external pressure by an infinitesimal amount during expansion, and the heat transfer occurs across an infinitesimal temperature difference. Exact mechanical equilibrium would give no driving force; the limiting imbalance supplies motion while preserving equilibrium intermediate states.[ref]
Along this reversible isothermal expansion, the ideal gas law givesHere is the molar gas constant; specifying fixes an energy scale, without choosing and separately. The initial and final equilibrium states are and . Count work delivered to the surroundings as positive. The reversible work is the shaded area beneath the pressure-volume curve:The integral of supplies the natural logarithm. Since internal energy of an ideal gas depends only on temperature, ; the first law of thermodynamics, , gives to the displayed precision. The heat bath replaces the energy delivered as work.[ref]
Now start from the same initial state, but abruptly lower the external pressure to the constant value . There is a finite initial pressure imbalance, so this is an irreversible expansion rather than a quasistatic process. Assume the piston begins and ends at rest, has no net change in stored energy, and has no external friction; relaxation occurs within the gas and its heat bath. After motion has settled and the heat bath has restored temperature , mechanical equilibrium and the ideal gas law give . The work delivered to the constant load isThis work follows directly from load force times piston displacement, using for piston area . Intermediate gas states need not have a single equilibrium pressure or temperature. In particular, neither at the bath temperature nor describes the actual gas during this irreversible motion. The rectangle below plots the known external load; its upper edge is not an equilibrium gas path.
The same equilibrium endpoints give different work for reversible and constant-load expansion
. The blue curve is the reversible ideal gas path. The dashed orange line is constant external pressure, whose rectangle gives of load work. The additional blue shading is available in the reversible case. Black points mark the common gas endpoints; the open orange point marks the initial external load, and the dotted gap indicates the initial imbalance. No irreversible internal gas path is drawn. Details.The entropy accounting makes the difference precise. Because entropy is a state function, both expansions have the same gas entropy change, computed along the reversible isothermal expansion:The thermal reservoir stays at and loses heat , so . Assume the ideal load stores work without an entropy change. The combined entropy production is thereforeNo numerical entropy unit is implied by alone: or must also be specified. The lost work opportunity is for this comparison. This calculation uses equilibrium endpoints and the reservoir's temperature, without assigning equilibrium intermediate states to the irreversible gas. [ref]
https://openstax.org/books/university-physics-volume-2/pages/4-6-entropy. OpenStax, §4.6: entropy as a state function and reversible reference paths
For another boundary choice, let the same ideal gas expand into an initially evacuated compartment of volume inside a rigid, insulated vessel of total volume . Removing the partition causes free expansion: no load is moved and no heat crosses the outer boundary, so and . After equilibration the temperature is again , the pressure is , and the gas entropy has increased by . The outer vessel has fixed volume; the gas's accessible volume doubles. Restoring the initial gas state requires compression and removal of heat, changing the surroundings. Equal endpoints do not make free expansion reversible. [ref]
https://openstax.org/books/university-physics-volume-2/pages/4-1-reversible-and-irreversible-processes. OpenStax, §4.1: insulated free expansion and restoration
A slowly moving piston with dry friction supplies a different caution: its gas can remain arbitrarily close to thermodynamic equilibrium, yet rubbing still converts work into heat and produces entropy. If the frictional force has a nonzero slow-motion limit, its dissipated energy over a fixed travel does not vanish with speed. Reversing the motion reverses friction, so infinitesimally changing the external load cannot retrace the same operation and restore the surroundings. The heat capacity calculations additionally exclude friction and other dissipative work.[ref]
The usefulness of a quasistatic process is that it replaces detailed motion by a readable sequence of equilibrium states. An equation of state and an integral then turn a pressure-volume drawing into an energy budget. The beautiful distinction is that internal energy and entropy depend on the endpoints, while heat and work record how the change was performed. Reversible benchmarks expose how much work an irreversible device sacrifices, while entropy production explains why simply making it slower need not recover that opportunity.
Radiation fluid has no regular free surface 2026-10-14
A connected nonvacuum perfect fluid with equation of state obeys the stationary radiation density law with . On a compact region of a regular spacetime, a smooth Killing vector field has bounded norm. Consequently cannot tend to zero at a finite regular free surface. A vanishing timelike norm instead makes the density diverge. A radiation-filled cavity can have a material wall with nonzero boundary pressure; this is a different boundary condition.
Radiation pressure Created 2026-09-28 Updated 2026-10-14
Radiation pressure is the normal momentum flux transferred by electromagnetic radiation to a surface. A photon travelling in vacuum carries momentum , where is its energy, its frequency, the Planck constant and the speed of light. Photon absorption transfers that momentum; specular reflection reverses its normal component. This lets light exert a force even when almost no energy becomes heat in the receiver.
Two useful formulas describe different preparations. A directed beam normally incident on a stationary perfect absorber gives pressure , and on a stationary perfect mirror gives . Here is light intensity, the incident power per beam cross-sectional area perpendicular to propagation, in . An isotropic photon gas has pressure , where is its radiation internal energy per volume, in . Stored energy density and travelling energy flux must be distinguished: an isotropic field can have zero net energy flux and positive radiation pressure.
The physical appeal is that the same momentum conservation connects a single photon collision, a mirror's measurable force, and a radiation-filled cavity's equation of state. The directional calculation below complements radiation pressure on a perfectly absorbing surface; the equilibrium spectrum and its temperature dependence belong to blackbody radiation and the photon gas.






